Engineering Commons^™

The Catalytic Behavior For Ni-W Electrode Modified By Carbon Ion Beam Implantion, Jishuang Zhang, Yaojiao Lv, Qinglian Li, Baoen Shen

Journal of Electrochemistry

The hydrogen evolution activity in acidic and basic mediums for Ni-W electrodemodified by carbon ion bean implantation was investigated. The experimental results show thiselectrode has superior catalytic activity for the hydrogen evolution reaction than that of the unmodified Ni-electrode. Long period testing of electrolysis under high current density show that this electrode hasalonger useful life hence it is a practical electrode material. The temperature effect of electrocatalytic property was also inverstigated. The experimental regularities are explained on the basis of the formation of surface multialloys of Ni-W-WC.

The Effect Of Some Ions On Cr2O72- Anodic Formation Process At Pt And Pbo2 Electrodes, Shixiong Jin, Zhigang Zhou, Lan Wang

Journal of Electrochemistry

The influence of Ag₂SO₄, Li₂SO₄, Na₂SO₄, K₂SO₄, (NH₄)₂SO₄,MgSO₄ and KF on the evolution of O₂ and the formation of Cr₂O at Pt and PbO₂ anodes was investigated in mixed H₂SO₄-Cr₂(SO₂)₃ solutions. The kinetic data related respectively to Cr₂O formation and O₂ evolution at Pt and PbO₂ anodes were measured by method of resolving the steady-state polarization curve. The Tafel slope …

A Investigation Of Hydrogen-Storage Alloy As Catalytic Electrode For Hydrogenation Of Nitrobenzene, Shigang Lu, Hanxi Yang, Changfa Wan

Journal of Electrochemistry

Since hydrogen-storage alloy ean not only absorb hydrogen atoms to form highlyreactive metal hydride as hydrogen source by electrolysis but also possesses a certain catalytic activityfor hydrogenation,it is thus feasible to utilize the allov as a novel electrode for electrolvtichydrogenation in organic electroreduction. This work employed misch metal AB₅ type alloy as acatalytic electrode and studied the electrochemical hydrogenation of nitrobenzene.

The hydrogen-storage electrode (MH) was a plastic bonded electrode sheet made from a paste of Mm(NiCoMnAl)₅ alloy powder and teflon emulsion. The electrolysis was performed at constantcurrent and controlled potential in a three electrode cell of H-type …

Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/SbAd Electrode, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic activity for the oxidation of formaldehyde and formic acid ona Sb-modified platinum (Pt/Sb_ad) was investigated. Results showed that the Pt/Sb_ad electrode was electrocatalytically more active than a Pt electrode in the anodic oxidation of formaldehyde and formicacid. In the case of formaldehyde, an oxidation peak appeared at a potential of ca. 0.7V. During the oxidation of formic acid, a 4-fold increase in the 1st peak current was observed. The Sb-modified platinum electrode was found to be most electrocatalytically active at a coverage of 0.75±0.05. The electrocatalytic activity of the Pt/Sb_ad electrode can be best …

Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye

Journal of Electrochemistry

The Variations of crystal lattice parameters of Li_xCoO₂ during charge anddischarge have been st ud ied by XRD and AAR spectroscopy. It was found that the Li_xCoO₂ crystalvolume expanded during charge and contracted during discharge. The crystal lattice structure was broken because of the formation of Co₃O₄ when deeply charge.The variation of lattice parameter C₀ value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case. In case of preheating for 20 hours at 700℃ before operating high temperature, the …

The Electrode Process Of Y(Ⅲ) On Copper Electrode And Its Surface Metallizing, Chungen Zhou, Shuzhen Duan

Journal of Electrochemistry

The reduction of yttrium ion on copper electrode in NaCl-KCl-YCl₃ molten saltshas been investigated. The results indicate that the formation of intermetallic compounds is occuredbefore the metallic yttrium to be formed. The formation of intermetallic compounds is controlled bythe process of which yttrium atoms are diffusing into copper electrode. The kinetic characters todiffusion of yttrium atoms were also discussed.

Development Of Nial-Based Intermetallic Alloys: Effect Of Chromium Addition, R. Tiwari, Surendra N. Tewari, R. Asthana, A. Garg

Chemical & Biomedical Engineering Faculty Publications

The mechanical behavior of dual-phase NiAl(Cr) microstructures, consisting of elongated primary NiAl grains aligned with an intergranular NiAl-Cr eutectic phase, produced by extrusion of a cast NiAl(Cr) alloy, has been examined. Chromium addition to create a dual phase NiAl-based aligned microstructure leads to large increases in the yield strength but no significant toughness improvement. This is achieved primarily by solid solution hardening and precipitation hardening. The constitutional hardening rate resulting from deviations from stoichiometry in the nickel-rich NiAl was estimated to be about 66 MPa per atomic per cent of nickel.

Aeration And Operation Of An Immobilized Cell Oxidative Bioreactor, James Joseph Woods

Theses

The primary purpose of this work is to help define the optimum window of operations for an immobilized cell oxidative bioreactor. The analytical technique employed requires no outside verification (such as G.C. analysis) and is independent of liquid flow rate. Method of aeration has been determined to be an important parameter for optimizing bioreactor efficiency, and optimization of the quantity of hydrogen peroxide added to provide oxygen during bio-oxidation has been investigated. Ammonium hydroxide as a fixed nitrogen source can be used to restore the vitality of the bioreactor under certain conditions.

The effects of several different methods of providing …

Low Pressure Chemical Vapor Deposition Of Copper Films From Cu(I)(Hfac)(Tmvs), Wei-Shang King

Theses

Recently, copper has been found as a possible substitute for Al alloys because of its low resistivity (1.67 μΩ • cm) and potentially improved resistance to electromigration. Conventional physical vapor deposition (PVD) method do not provide the conformal deposition profile for the high density integrated circuit, therefore, chemical vapor deposition (CVD) has become the most promising method for the resulting conformal profile.

In this work, a cold wall, single wafer, CVD tungsten reactor was used for the deposition of copper with Cu(I)(hfac)(tmvs). Film growth rates were between 100 to 800 A/min depending on processing conditions, and an Arrhenius type activation …

The Photolithographic Patterning Of Porous Silicon Using Silicon Nitride And Silicon Carbide Films As Masks, Hong Wang

Theses

In this study, a simple photolithographic pattern process for porous silicon is described. The process utilizes silicon nitride or silicon carbide coated on the top of silicon wafer as a masks. Then a test pattern was projected on the sample by illumination during anodic etching in HF:ethanol solution which produced microcracks in regions illuminated during anodization. Creation of these microcracks resulted in formation of porous silicon in the underlying regions. The cracking is related to the stress in the thin film. The films with tensile stress exhibit cracking while compressive stress samples do not. Compared to silicon carbide films, silicon …

Synthesis Of Silicon Oxide/Vycor Composite Membrane Structures By An Optimized Lpcvd Process, Abhijit Datta

Theses

This study is focused on development of highly selective ceramic membrane structures consisting of silicon dioxide films synthesized by low pressure chemical vapor deposition (LPCVD) on mesoporous Vycor substrates. The ability of easily altering the composition of such films by varying the LPCVD processing parameters affords the opportunity of microengineering the pore structure by reducing the diameters of pre-existing pores in the support. The process parameters investigated include, deposition temperature, total pressure, and flow rate of oxygen. Both the kinetics and select properties of the deposits were examined. The growth rate as a function of temperature was seen to follow …

Using Matlab To Illustrate The 'Phenomenon Of Aliasing', Sol Neeman, Ph.D.

Engineering Studies Faculty Publications and Creative Works

The phenomenon of aliasing is important when sampling analog signals. In cases where the signal is bandlimited, one can avoid aliasing by ensuring that the sampling rate is higher than the Nyquist rate . But in cases where the signal is not bandlimited , aliasing is unavoidable if the signal is not filtered before it is sampled. It is then crucial to understand the phenomenon in order to estimate the distortion generated when the signal is reconstructed from its samples. Using the software package MATLAB by MathWorks, Inc ., two examples are presented. The first is a pure sinusoid which …

Eigenproperties Of Nonclassically Damped Dynamic Systems, Daniel Patrick Malone

Masters Theses

"This thesis develops perturbation series solutions for the eigenvalues and eigenvectors of nonclassically damped dynamic systems for the case where the unperturbed system has repeated eigenvalues. The case of repeated eigenvalues is much more complicated than the case of perturbing a system with distinct eigenvalues. Because of this difficulty, only a specific category of dynamic systems with repeated eigenvalues is addressed. Namely, only those systems that when perturbed have series solutions of the form of a power series. This category of systems can be easily identified by an a priori check developed in the application section of this thesis. The …

Nonlinear Finite Element Micromechanic Analysis Of Thermoplastic Composite Of Recycled High Density Polyethylene Reinforced With Short Glass Fibers, Qiming Lou

Masters Theses

This thesis studied the nonlinear micromechanic behavior of thermoplastic composite of recycled high density polyethylene (HDPE) reinforced with short glass fibers using finite element method. The composite material was modeled using a micromechanic unit cell to simulate the stress distribution between the plastic matrix and the fiber in the composite. Nonlinear behavior of recycled HDPE and imperfect bonding between the fiber and matrix were investigated. Load-bearing capability of the fiber was evaluated using stress partition ratio (SPR) in the composite models. The effect of fiber aspect ratio on the stress distribution of the composite was studied to optimize the material …

Solar Heater For Curing Tobacco Part I: Overview And Theory, J John

Tanzania Journal of Engineering and Technology (TJET)

This is two parl paper. In part one of the papet; an overview on the use Of packed beds on heat collectors To be used in natural convection systems is presented. A brief theoretical background and literature review has also been presented. Theoretical analysis and performance equations are pre- sented in detail. Two zypes of absorbers are proposed for investigation. The firs,' one will be with flow below the absorber and the other with flow "'through " {he absorber. These shall be compared with the conventional flat plate collector. For comparing the performance, packings of different materials, shapes, and sizes …

A Fracture Kinetics Analysis Of Hydrogen Embrwi'lement, J Mshana

Tanzania Journal of Engineering and Technology (TJET)

In studies on stress corrosion cracking caused by hydrogen embrittlement of metals, it has been observed that within the high remperature range rhe Armenius activation energy is negative. This is quite unusual Since ther- mall)' activated crack g.'vwth processes are controlled by positive appar- ent activation energy. The unders/auding of this effect is of inleavst to design and maintenance engineers. The study demonstrates, with a syn- thesis method, a physically rigorous and rational kinetics Of thermally activated processes of some aspects ofenvironment assisted crack growth. It is show that the observed crack growth behavior may be described by single barrier …

Model For Complete Drawdown Of Floating Solids In Stirred Tank Reactors, J Mmbaga

Tanzania Journal of Engineering and Technology (TJET)

A Semi-empirical model has been developed on the basis of Kolmogoroff's theory of isotropic turbulence to determine the minimum drawdown speed for floating solids in a mechanically agitated vessel. An adjustable pa- rameter in the model is found to be afunction of impeller type and position in a vessel. A simplified representation of macroscopicflow pattern, rep- resenting the circulation flow in a vessel depending on impeller pumping characteristic is developed to account for recirculation pattern.

Measurement Of Dust Resistivity And The Effect Of Filter Operating Parameters On Its Value, S Issangya

Tanzania Journal of Engineering and Technology (TJET)

Methods of measuring electrical sensitivity of a dust layer have been outlined and the porous electrodes cell was used to measure the electrical resistivity of a dust layer and to determine the influence of various parameters. Dust layer thickness and applied voltage had no influence. Resistivity depended on particle size, packing density, temperature, and air relative humidity. Glass beads and limestone powders of different mean particle sizes were used. Temperature was varied from 20–100 °C and air moisture ranged from dry to near saturation. The results may help in understanding the performance of electrically enhanced fabric filters, which are influenced …

Design Approach For Small Scale Continuous, Steady State Plants, O Kaunde

Tanzania Journal of Engineering and Technology (TJET)

One of the major steps in the design of a process plant is development of an appiopriate flowsheet. At this step, the technical solutions may be con- sidered in relation to the social and economic factors. In this paper, guide- lines for developing a flowsheet for continuous, steady State process in a developing country environment have been proposed. To illustrate the pro- posed guidelines, a case study involving design of an ethanol distillation plant has been used.

Improved Heat Transfer By Means Of Steam Injection In A Shell & Tube Heat Exchanger, O Kaunde

Tanzania Journal of Engineering and Technology (TJET)

When designing a heat exchanger; one aims at attaining high heat transfer rates SO as to minimise heat transfer area and therefore the overall cost. This paper presents a method of improving the overall heat travsfer coef- ficient of a conventional shell and tube heal exchanger. The method in- volves injecting steam into the process fluid as it enters the heat exchanger thus effecting mixing of fluid as it travels along the exchanger Tests car- • ried out using this technique showed a significant increase in the overall heat transfer coefficient values.

Application Of Improved Pressure Transducers For Pressure Measurements, P Mtui

Tanzania Journal of Engineering and Technology (TJET)

Substantial improvement of low sensitivity pressure transducers aiming at obtaining a more realistic output signal is discussed. The output signal direct from these transducers has deficiencies of amplitude attenuation and phase lag, thus the measured values are not necessarily the true in- stantaneous values. In order to correct for such shortcomings the unit step response of these transducers is also studied experimentally. A math- ematical model is established based on the experimental results to build up a compensation circuit which is then included in the instrumentation setup to eliminate these deficiencies. The effectiveness of the compensated transducer is demonstrated by …

Influence Of Arc Discharge Duration On Turbulent Mass Burning Rate, E Mushi

Tanzania Journal of Engineering and Technology (TJET)

The influence of arc discharge duration on turbulent mass burning rate was investigated for turbulent r.m.s vglocities of u '=1.73 m/s and u'=4.5 nfs. Methane air mixtures were used at equivalence ratios ranging from 0.83 to / .25. Flame size was obtained through schiieren photography while the intensity Of CH chemiluminescence emissions was used to measure mass burning rate. A variable spark duration unit was used for ignition sparks and all the experiments were done in a fan stirred bomb. Discharge duration has no effect when the equivalence ratio is I. For higher values longer duration inoeases the burning rate …

Investigation Into The Behavior Of Geometrically Nonlinear Composite Arches, John C. Bailey

Theses and Dissertations

This research modifies the existing finite element formulation of a potential energy based large deformation and moderate rotation theory. Hermitian shape functions replace the existing linear bending angle interpolations. Negligible differences between the two formulations indicate the underlying kinematics limit the accuracy, not the finite element interpolations. Using the new program, numerous nonlinear arch geometries are modeled to investigate the effects of arc length and thickness variations. Local and global snapping phenomena are captured as well as through the thickness shear driven nonlinearities.

Fatigue Behavior Of A Cross-Ply Metal Matrix Composite At Elevated Temperature Under Strain Controlled Mode, Leon B. Dennis

Theses and Dissertations

This research extends the existing knowledge of cross-ply metal matrix composites (MMC) to include fatigue behavior under strain-controlled fully reversed loading. This study investigated fatigue life, failure modes and damage mechanisms of the SCS-6-Ti-15-3, [O-9O]_2s, MMC. The laminate was subjected to fully reversed fatigue at elevated temperature (427° C) at various strain levels. Stress, strain and modulus data were analyzed to characterize the macro-mechanical behavior of the composite. Microscopy and fractography were accomplished to identify and characterize the damage mechanisms at the microscopic level. Failure modes varied according to the maximum applied strain level showing either mixed mode …

Viscoplastic Characterization And Fatigue Modeling Of Titanium Based Metal Matrix Composites, Mark A. Foringer

Theses and Dissertations

Viscoplastic characterization and fatigue modeling of titanium-based metal matrix composites was accomplished by combining a unified viscoplastic theory, a nonlinear micromechanics model, and a linear damage accumulation model. First. Ti 15-3 was characterized using the Bodner-Partom viscoplastic theory. A micromechanics model was then employed in a linear damage accumulation fatigue model to predict the fatigue behavior of titanium based composites. The viscoplastic behavior predictions of the micromechanics model were used to eliminate separately defined time dependent terms in the fatigue model. Also, a new linear damage accumulation model was developed from the fatigue behavior of the composite constituents. Finally, it …

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite Subjected To Tension-Tension Cycling With Hold Time, Scott A. Grant

Theses and Dissertations

This study was carried out to investigate the elevated temperature behavior of the SiC-MAS5 cross- ply [0-90]_4S ceramic matrix composite manufactured by Corning Inc. to fatigue with loading waveforms that combine the characteristics of stress rupture and high cycle fatigue. The test results were compiled in the form of S-N (cycles to failure), S-T (exposure time versus cycles to failure), S-S (energy exposure versus cycles to failure), normalized modulus degradation, strain progression, and hysteresis loop progression. From the mechanical behavior demonstrated by these curves, relationships between the effect of the environment and loading waveform were developed. In addition, a …

Characterization Of Fatigue Behavior Of 2-D Woven Fabric Reinforced Ceramic Matrix Composite At Elevated Temperature, Daniel J. Groner

Theses and Dissertations

This study investigated the fatigue behavior and associated damage mechanisms in notched and unnotched enhanced Sic-SiC ceramic matrix composite specimens at 1100°C. Stiffness degradation, strain variation, and hysteresis were evaluated to characterize material behavior. Microscopic examination was performed to characterize damage mechanisms. During high cycle-low stress fatigue tests, far less fiber-matrix interface debond was evident than in low cycle-high stress fatigue tests. Notched specimens exhibited minimal stress concentration during monotonic tensile testing and minimal notch sensitivity during fatigue testing. Damage mechanisms were also similar to unnotched.

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite At Elevated Temperature Under Tension-Tension Loading, Craig D. Steiner

Theses and Dissertations

This study investigated the fatigue behavior and damage mechanisms of a [0-90]_4s SiC-MAS ceramic matrix composite under tension-tension loading at two elevated temperatures and two frequencies. Stress and strain hystereses, maximum and minimum strain, and modulus of elasticity were evaluated to characterize the material behavior. Microscopy and fractography were used to evaluate damage progression and mechanisms. Fatigue life was independent of frequency at both temperatures.

Investigation Of Tension-Compression Fatigue Behavior Of A Notched Cross-Ply Metal Matrix Composite At Elevated Temperature, Matthew W. Yocum

Theses and Dissertations

This research extends the existing knowledge of MMC fatigue damage mechanisms by studying the tension-compression fatigue behavior of a notched cross-ply laminate MMC at elevated temperature. A [0-90]_2S SCS-6-Ti-15-3 laminate with a center hole was subjected to tension-compression fatigue at 427 °C (800 °F). Stress and strain data was taken to evaluate macro-mechanic behavior of the material. Microscopy and fractography were performed to characterize the damage on a micro-mechanical level. Crack initiation and progression was monitored using acetate face replicas. Four cracks were found to develop around the periphery of the hole, two of which became dominant and proceeded …

Investigation Of Tension-Compression Fatigue Behavior Of A Unidirectional Metal Matrix Composite At Elevated Temperature, Darren L. Kraabel

Theses and Dissertations

This study investigated the fatigue behavior in a unidirectional metal matrix composite under tension-compression loading conditions. Stress-strain responses, modulus and strain trends were monitored to characterize damage. Fractography and microscopy were used to characterize failure modes. Fatigue life curves were plotted base on different parameters such as stress and strain. Tension-compression fatigue life was shorter than the obtained under tension-tension fatigue cycling. Creep, observed in tension-tension. fatigue cycling, and the effects of the compressive load on the plastic zone around the crack tip explain shorter life under tension-compression fatigue loading.