Engineering Commons^™

Effect Of Lanthanum Doping On Phase Transition, Piezoelectric And Energy Storage Properties Of Lead-Free 0.93(Bi0.5na0.5)Tio3‒0.07batio3 Ceramics, Pathit Premwichit, Songphop Jaila, Sasiporn Prasertpalichat

Journal of Metals, Materials and Minerals

In this study, lead-free (Bi0.465Na0.465Ba0.07)(1–x)LaxTiO3 (x=0.0‒0.04) ceramics were synthesized using a conventional solid-state reaction method. All samples showed a single-phase perovskite structure with pseudocubic symmetry. The dense microstructure revealed a decrease in average grain size as x increased. La3+ addition stabilized polar nanoregions (PNRs), shifting the ferroelectric to relaxor phase transition temperature (TF₋R=104℃ for x=0.0) to below room temperatures as La3+ content increased. This resulted in a transition from a rectangular to a relaxor-like thin P–E loop (x≥0.01), indicating a shift from ferro-electric (FE) to relaxor ferroelectric (RFE), which …

Structural Tuning Of Bioi Toward Bi O /Agi Heterostructures Via Room-Temperature Ion Exchange For Improved Photocatalytic Activity, Varunya Atimayulerd, Sorawit Thueanbangyang, Kittiyaporn Singsumphan, Ganyaporn Wongwaen, Cheewita Suwanchawalit, Montri Aiempanakit

Journal of Metals, Materials and Minerals

In this work, a bismuth oxide/silver iodide (Bi2O3/AgI) heterojunction photocatalyst was successfully fabricated via a room-temperature ion exchange process using bismuth oxyiodide (BiOI) as a morphology-directing precursor. Building upon our previous work on solvent-modulated BiOI nanostructures, this study employs a chemical transformation route to develop interfacially connected heterostructures while preserving key morphological features. Structural, morphological, and optical characterizations, including X-ray diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier-transform infrared spectroscopy, and ultraviolet–visible diffuse reflectance spectroscopy, provided supporting evidence for the successful formation of Bi2O3/AgI heterojunctions with likely close interfacial contact. The optimized Bi2O3/AgI composite with a 50:50 mass ratio …

Aluminium Oxide Particles-Containing Organogels For Cleaning Of Optical Glass Surfaces, Galina Vladimirovna Lyamina, Oksana Valerievna Dubinina, Alfa Edison I Lela

Journal of Metals, Materials and Minerals

Hypothesis:  Some types of cleaning methods are not very effective and can actually increase damage to the optical parts being cleaned. As an alternative to these methods, we propose the use of gel-like substances to remove contaminants from optical surfaces. We have developed a method for cleaning optical glass surfaces that uses organogels, which are based on copolymers of methyl methacrylate and methacrylic acid. These organogels are loaded with polyethylene glycol, and aluminum oxide particles (Al2O3), which help to effectively remove contaminants without causing damage to the surface.   Experiments:  Al2O3 nanoparticles prepared by a Nano Spray Dryer were added to …

Applications Of Reservoir Simulation And Machine Learning In Subsurface Energy Systems For Decarbonization, Seyedmohammadmehdi Nassabeh

Theses: Doctorates and Masters

The transition to a low-carbon future necessitates innovative approaches to carbon management and hydrogen storage, particularly in the context of enhanced oil recovery (EOR) from hydrocarbon reservoirs. This study employs advanced analytics and machine learning techniques to optimize carbon management strategies. One key focus of this research is to evaluate the effectiveness of flue gas and CO2 in Water Alternating Gas (WAG) injection within a homogeneous fractured carbonate reservoir characterized by low porosity and permeability. A computational model was developed to depict the flow regime in the reservoir and simulate reservoir fluid behavior using Eclipse (E300) software, various hybrid EOR …

Characterization Of Properties And Defects Of Alternative Matrix Materials For 3d Printed Continuous Carbon Fiber Reinforced Composites, Noah Darren Osborne

Graduate Theses, Dissertations, and Problem Reports (ETD)

Additive manufacturing, commonly known as 3D printing, has the potential to transform the production of end-use parts by facilitating the creation of complex shaped, low-volume components that are expensive to manufacture using traditional methods. However, thermoplastic polymer matrices currently utilized in 3D printing of carbon fiber composites, often lack the mechanical properties needed for aerospace applications. To address this issue, researchers have developed fiber-reinforced 3D-printed composites using an innovative two-step process which involves printing 3D preforms using fused deposition modeling, followed by compression molding. However, most previous work involves the use of nylon-based polymer matrices while there are a number …

Green Bank Chime/Frb Outriggers Commissioning And Analog System Development, Kholoud Sharif Tag Alkhatem Khairy

Graduate Theses, Dissertations, and Problem Reports (ETD)

The main objective of this thesis is to document the development and commissioning of the Canadian Hydrogen Intensity Mapping Experiment. (CHIME) outrigger at the Green Bank Observatory. (GBO) in Green Bank, WV. This novel cylindrical wide-field radio transient telescope is currently operating in conjunction with CHIME. The CHIME outrigger at GBO aims to contribute significantly to the field of radio astronomy, with implications for both Fast Radio Burst. (FRB) science and broader astronomical research. The construction and commissioning of the CHIME outrigger at the GBO mark a pivotal step forward in pursuing high-precision wide-field detection and localization of radio transients, …

Development Of A Spray Pipe Evaporator For Application On Unproductive Salt Farm Land In Indonesia, Srie Muljani, Ketut Sumada, Alfian Rizki Pradana, Caecilia Pujiastuti

ASEAN Journal of Community Engagement

This article discusses the development of a prototype spray pipe evaporator and its efficiency in producing salt in Indonesia. Due to the length of the salt harvesting season in Indonesia, many salt farmers have closed their business doors, leaving many salt ponds abandoned. The spray pipe evaporator prototype was designed to produce a brine solution with a salinity of 23–24 Be from seawater, which has a salinity of 2.5–3.5 Be, in less than 3 days. This is faster than the conventional process of a brine solution salinity of 24 Be. The prototype spray pipe evaporator was assessed in a 20 …

Inspection Program Effectiveness Key Performance Indicator For Pressurized Static Equipment Integrity At Offshore Platform, Teuku Ahmad Haekal, Johny Wahyuadi Soedarsono, Badrul Munir, Muhammad Yudi Masduky Sholihin

Journal of Materials Exploration and Findings

One of the key challenges in asset integrity management system at offshore platform is the lack of visibility regarding performance issues and program effectiveness. Without proper performance measurement systems, it becomes difficult to address positive or negative trends promptly and for management to stay informed about the status and the impact of the inspection program. Therefore, Key Performance Indicator (KPI) is needed to measure inspection program effectiveness to prevent undesirable equipment failures that could lead to Loss of Primary Containment (LOPC) or Process Safety Event (PSE). The developed KPI is the ratio of the number of non-leak inspection findings with …

Metakaolin-Based Geopolymer Concrete; Synthesis, Development And Characterization, Heba Fouad

Theses and Dissertations

Geopolymers are rendered as an essential sustainable replacement to the widely used Ordinary Portland Cement (OPC) which causes immense carbon dioxide emissions, hence a detrimental impact on society’s health and the environment. Geopolymers are three-dimensional networks of polymerized tetrahedral silicate and aluminate in the form of Q4(4Al), Q4(3Al) and Q4(2Al) which act as the principal binding phase in concrete. Past research has reported the synthesis of geopolymers from different aluminosilicates precursors, their characterization, and their wide range properties. However, previous studies still have not properly investigated effective range of synthesis ratios for a particular source material, optimum curing regimes, short- …

Dendrite-Free Strategies For Aqueous Zinc-Ion Batteries: Structure, Electrolyte, And Separator, Gang Wu, Wu-Hai Yang, Yang Yang, Hui-Jun Yang

Journal of Electrochemistry

Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently. The development and utilization of renewable, sustainable, and clean energy sources, such as wind and solar, are crucial. However, the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent. Aqueous zinc-ion batteries (AZIBs) have received widespread attention due to their unique advantages, such as high energy density, cost-effectiveness, environmental friendliness, and safety. However, AZIBs face significant challenges, mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries, leading to battery …

Electrochemical-Method-Induced Strong Metal-Support Interaction In Pt-Cnt@Sno2 For Co-Tolerant Hydrogen Oxidation Reaction, Shen-Zhou Li, Zi-Jie Lin, Qi-An Chen, Zhao Cai, Qing Li

Journal of Electrochemistry

Inducing the classic strong metal-support interaction (SMSI) is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles (NPs) with supports. Conventional thermal reduction method for inducing SMSI processes is often accompanied by undesirable structural evolution of metal NPs. In this study, a mild electrochemical method has been developed as a new approach to induce SMSI, using the cable structured core@shell CNT@SnO₂ loaded Pt NPs as a proof of concept. The induced SnO_x encapsulation layer on the surface of Pt NPs can protect Pt NPs from the poisoned of CO impurity in …

Contributions To Journal Of Electrochemistry, The Flagship Journal Of Chinese Chemical Society Electrochemical Committee, Will Be Listed As A New Recommendation Policy For China Youth Awards Of Electrochemist, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

All-Solid-State Sodium-Ion Batteries: A Leading Contender In The Next-Generation Battery Race, Rui-Jie Zhu, Ze-Chen Li, Wei Zhang, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui

Journal of Electrochemistry

All-solid-state lithium-ion batteries (LIBs) using ceramic electrolytes are considered the ideal form of rechargeable batteries due to their high energy density and safety. However, in the pursuit of all-solid-state LIBs, the issue of lithium resource availability is selectively overlooked. Considering that the amount of lithium required for all-solid-state LIBs is not sustainable with current lithium resources, another system that also offers the dual advantages of high energy density and safety— all-solid-state sodium-ion batteries (SIBs) —holds significant sustainable advantages and is likely to be the strong contender in the competition for developing next-generation high-energy-density batteries. This article briefly introduces the research …

Safety And Optimality Monitors For Learning-Enabled Systems Using Conformal Prediction, Jackson Cox

McKelvey School of Engineering Graduate Student Theses & Dissertations

The use of machine learning to create data-driven plant models and controllers has led to an increased need for safety and optimality monitors for model-based systems. System plant models are subject to uncertainty due to learning constraints such as unseen data and overfitting or physical constraints such as unknown dynamics and noise. This uncertainty is detrimental to safety-critical systems and must be properly regulated. To curb this uncertainty, we create prediction sets using the guarantees provided by Conformal Prediction. With a user-specified high probability, these prediction sets contain the true plant system states for an entire prediction horizon, which we …

Optimization Of Tps Films Using An Adaptive Design Of Experiments Approach In A Bayesian Optimization Framework, Theresa Marks, Gracie White, Scott Lohman, Mayank Malhotra

The Journal of Purdue Undergraduate Research

Plastic pollution, amounting to 12 million tons annually, necessitates sustainable alternatives to single-use plastics. Compostable thermoplastic starch (TPS) films show promise but lack strength and durability compared to traditional plastics. This study employs an adaptive design of experiments (DoE) approach to enhance TPS films by optimizing testing points. The research focuses on varying concentrations of plasticizers (acetic acid and glycerol) in a water and potato starch mixture, aiming to identify the optimal ratio maximizing tensile strength and % elongation at break. Gaussian process regression (GPR) with uncertainty estimation and Bayesian optimization (BO) utilizing an acquisition function (AF) are employed. The …

Mae Enewsbrief July-Sept 2024, Department Of Mechanical And Aerospce Engineering, Michigan Technological University

Department of Mechanical and Aerospace Engineering eNewsBrief

No abstract provided.

Striking A Balance: Market Shock & Responses In Automotive Components Manufacturing, Emma Lane Mcgahey

All Theses

This thesis examines the effects of extreme market shocks on supply chain dynamics within the automotive industry. Through an analysis of demand data from an automotive manufacturer to its component suppliers (January 2018 to May 2024), the study investigates the relationship between market shocks and supply chain responses, providing insights into how auto components inventory management handles downstream responses to market shocks. With supporting public data—from FRED, BLS, and the U.S. Census Bureau resources—we explore two primary relationships: the impact of market shocks on the Average Standard Deviation of Demand (SDO) and the effect of demand variability on expedited pricing …

Influence Of Hygrothermal Conditions Of The Bistability Of Asymmetric Carbon Fiber Laminate Composites, Celia Hill

All Theses

Carbon fiber-reinforced polymer (CFRP) laminates have widespread use in many industries because of their exceptional strength-to-weight ratio. Carbon fiber laminates following an asymmetric layup orientation can exhibit bistability meaning the laminate can exist at two stable geometric configurations. The morphing characteristics of bistable CRFP has a growing level of interest because of its potential in various applications including space aircraft structures for easy repair, automotive structures for energy dissipation and ergonomics, robotics for flexible motion and energy harvesting. Existing research shows that both moisture and temperature affect the material properties and behavior of CFRP laminates, however, the influence of moisture …

Thermal Conductivity Characterization Of High Oleic Vegetable Oils Based Hybrid Nanofluids Formulated Using Gnp, Tio2, Mos2, Al2o3 Nanoparticles For Mql Machining, Anthony Chukwujekwu Okafor, Tobechukwu Kingsley Abor, Saidanvar Esanjonovich Valiev, Ignatius Echezona Ekengwu, Abiodun Saka, Monday Uchenna Okoronkwo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper presents the results of thermal conductivity characterization of six high oleic soybean oil (HOSO) and four high oleic canola oil (HOCO)-based hybrid nanofluids formulated with four types of nanoparticles (Graphene nanoplatelet (xGnP), TiO2, MoS2, and Al2O3) at nanoparticles wt.% concentration from 1 % to 7 % in 1 % increment using the two-step method for use in MQL machining of difficult-to-cut metals. Thermal conductivity of the formulated hybrid nanofluids were measured using Thermtest Transient Hot Wire Liquid Thermal Conductivity Meter at temperatures from 25 °C to 75 °C in increment of 10 °C. Obtained results showed that thermal …

Enhanced Redox Storage And Diverse Intercalation In Layered Metal Organic Frameworks With A Staggered Stacking Mode, Satya Prakash Suman

Open Access Theses & Dissertations

Two-dimensional metal organic frameworks (2D MOFs) with honeycomb-like porous sheets are of growing interest for applications in electrochemical energy storage and electrocatalysis. Notably, 2D MOFs that host their porous sheets in eclipsed or slipped-parallel stacking modes possess continuous one-dimensional pores (1D) and have been widely studied. In contrast, related 2D MOFs with a staggered stacking mode have reduced porosity, are relatively rare, and are largely unexplored for applications. Here we report 2-fold enhanced redox storage and intercalation of diverse ions in a staggered-stacked, nonporous 2D MOF over its eclipsed-stacked, porous counterpart. Interestingly, both MOFs, despite undergoing similar ligand-centered redox processes, …

Elucidating The Effect Of Milled Glass And Graphite Fiber On The Quasi-Static Properties Of Vinyl Ester Resin Composites, Sarahi Mendivil

Open Access Theses & Dissertations

Composite materials can be tailored to various applications, making them one of the most conventional materials. Their ability to enhance desired characteristics enables higher strength while maintaining light weight. However, understanding defects and manufacturing limitations is crucial for optimizing their fabrication processes. This paper focuses on the manufacturing processes of open molding with controlled variations to establish an optimal technique aimed at minimizing defects, such as bubble formation where the focus is on mitigating defects and ensuring uniform dispersion of fiber in fiber-reinforced composites. After refining the manufacturing process, composites with varying resin-to-fiber concentration ratios were manufactured using glass and …

Ultra-High Temperature Ceramics: Materials, Manufacturing, And Machine Development, Joseph Matthew Munoz

Open Access Theses & Dissertations

This research aimed to advance the 3D printing of ultra-high-temperature ceramic matrix composites (UHTCMCs) and develop a custom Direct Ink Writing (DIW) system with multimaterial and in-line mixing capabilities. The study first focused on creating ZrB₂–SiC composites reinforced with aligned silicon carbide fibers (SiCf) using paste extrusion. By formulating suspensions with a preceramic polymer (SMP-10), ZrB₂, and SiCf, the study assessed how fiber alignment influenced key properties such as thermal and electrical conductivity and mechanical strength. Green curing and pyrolysis transformed the printed parts into UHTCMCs, with results showing substantial improvements in thermal conductivity—nearly double that of non-aligned parts—and a …

Intrinsic, Doped And Alloyed Gallium Oxide Films For Optoelectronics, Francelia Sanchez Escobar

Open Access Theses & Dissertations

Due to the impressive advancement of present technology and increasing energy consumption, there is increasing demand for energy-efficient multifunctional devices based on low-cost, eco-friendly material systems. Gallium oxide (Ga2O3) is an emerging semiconductor with potential for the next generation of power electronics and optoelectronic devices due to its ultra-wide bandgap of 4.8 eV and high theoretical breakdown voltage of 8 MV/cm among other intrinsic properties. Some of the possible applications of β-Ga2O3 include ultra-violet (UV) solar blind photodetectors, field effect transistors, solar cells, and chemical sensors. However, to utilize its full potential, understanding the mechanistic aspects of thin film growth …

Assessing Khumbu Region Glaciers Mass Balance Change Using Geospatial Techniques From 2012 To 2024, Yashvi Jagatbhai Shah

Electronic Theses, Projects, and Dissertations

The glaciers in the Hindu Kush Himalaya are critical for sustaining the water supply of South Asia's major rivers, upon which over 230 million people, both in the mountainous regions and lowland areas, depend. Climate change is driving rapid glaciers melt near the summit of Mount Everest, located at an elevation of approximately 7,906 meters (25,938 feet). This has resulted in glacier thinning occurring up to 80 times faster than the original ice formation. However, due to their disposition in a complex topographic setting and inaccessible terrain, continuous glacier observations pose significant challenges.

This study evaluated the mass balance of …

Greek Key-Inspired Fractal Metamaterials With Enhanced Flexibility And Energy Absorption., Zhennan Zhang

Electronic Theses and Dissertations

Architected materials with intricate three-dimensional (3D) geometries offer unique properties and functionalities but face challenges in manufacturing costs and complexity. This research explores the integration of simple 2D Greek Key-inspired lattices into fractal designs to achieve exceptional mechanical performance. Using 3D printing and kerfing, these fractal structures demonstrate enhanced flexibility and energy absorption capabilities. Through three-point bending and in-plane tensile tests, the 2D fractal lattices exhibited a 600-fold reduction in bending force and a tensile stretch capacity of up to 520%, significantly outperforming brittle parent materials. Out-of-plane compression tests revealed a five-fold increase in energy absorption compared to honeycomb structures, …

Development Of Uranium Fluoride Microstructures, Harry Jang

UNLV Theses, Dissertations, Professional Papers, and Capstones

Uranium microstructured materials with controlled size and shape have found applications in several branches of the nuclear industry including as targets for medical isotopes production, fuels for nuclear reactors, standards for analytical measurements, and energy sources for space exploration. Morphological studies of actinide materials are also highly relevant to nuclear forensics-related work. Other potential applications include information storage, catalysis, sensors, and luminescent devices. Most studies on uranium microstructured materials have focused on binary oxides, nitrides, carbides, and fluorides, with the spherical shape being the dominant morphology. Prior to the work reported in this dissertation, aside from UF4 microspheres (ms) and …

Removal Capabilities Of Zeolite And Zero Valent Iron With High-Level Waste Tank Radionuclides And Metals: Cesium, Strontium And Chromium, Colette R. Towles

UNLV Theses, Dissertations, Professional Papers, and Capstones

High level nuclear waste (HLW) has been disposed for temporary storage in underground steel tanks at the Department of Energy Nuclear sites. For example, at the Hanford Site, WA, and Savannah River Site (SRS), SC, HLW account for eighty-eight million gallons (Mgal) and 450 million Curies (MCi) of radioactivity. In the early nuclear activity at Hanford, the waste was discharged to single-shell steel tanks, and the lack of secondary containment allowed leaks, contaminating soil and groundwater. Despite tremendous efforts to stabilize the liquid waste at nuclear sites, treatment is complex, costly, and time-consuming; therefore, HLW may have to be stored …

Density-Driven Investigations Of Ruthenium Binary Compounds Rux2 (X = O, S, N), Melanie White

UNLV Theses, Dissertations, Professional Papers, and Capstones

Exploration and fine-tuning of the energy landscape of materials can be accessed by means of changes in material density, a key principle of high pressure research. Density-driven changes impact variations in oxidation states and coordination numbers for the element constituents of a compound. Pressure-induced modification of intrinsic density can promote the formation of new materials, variations in physical properties, and transformations in crystallographic symmetry. With this as our foundation, we focus on ruthenium binary compounds - altering the anion species to change electronegativity while probing pressure and temperature effects. This led us to the present study of ruthenium oxide RuO2, …

Synthesis And In Vitro Testing Of Mg-6zn-Xhap Biocomposites From Beef Bone As Biodegradable Bone Implant Material, Jojor Lamsihar Manalu, Francisca Tjhay, Theodora Kristoforus, Sovian Aritonang

Journal of Mechanical Engineering Science and Technology (JMEST)

This study aimed to develop biodegradable Mg-6Zn hydroxyapatite (Mg-6Zn HAp) biocomposites for potential use in bone replacement applications. The hydroxyapatite (HAp) powders, sourced from cow bone, were synthesized through an eco-friendly and cost-effective process, leveraging bioresources for material sustainability. The Mg-6Zn and HAp powders were mechanically mixed through ball milling for six hours to ensure homogeneity. The resultant powder mixture was then subjected to isostatic pressing at a high pressure of 570 MPa, forming a dense coin-shaped composite with a 1.5 cm diameter. This coin was consolidated in a capsule furnace at elevated temperatures for one hour to enhance material …

Analysis Of Tidal Energy Potential In The Merauke Papua River Waters Indonesia, Peter Sahupala, Daniel Parenden

Journal of Mechanical Engineering Science and Technology (JMEST)

The purpose of this study is as a source of information to study the potential of tidal energy at the estuary of the Maro River in the waters of Merauke Regency. This study uses a quantitative method, while the method for determining the location of the study used is the purposive sampling method where the data collection point is right at the end of the estuary of the Maro River because it faces directly onto the Arafura Sea. Tide data for 5 months, namely September 1, 2023 to January 31, 2024 with a pool area of 1,260,000 m2, with the …