Engineering Commons^™

A Brief Review Of Research Progress In The Development Of Engineering Models For Lithium Ion Batteries, Da-Wei Wang, Dong-Jiang Li, Jun Li, Yong Yang

Journal of Electrochemistry

Lithium ion battery has become an important and popular electrochemical device for energy storage.Suitable evaluation and understanding of electrochemical performance and state of charge play a key role in the applications of lithium ion batteries.Construction and utilization of engineering modeling for lithium ion batteries is an effective way to fulfill this target.In this paper,engineering models of lithium ion batteries based on electrochemical reaction,ionic diffusion and migration are introduced.The emphasis is placed on the development of engineering models by the introduction of side reaction,phase transition,stress and energy.The applications of engineering models in such simulations as charge-discharge,concentration distribution,current distribution,state of charge,stress and …

Preparation And Application Of Nano-Nio As Anode In Lithium-Ion Batteries, Cheng-Dong Bai, Jia-Jia Chen, Qi Zhang, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

In this work, the nano-NiO material was prepared by hydrothermal method. The surface morphologies and electrochemical properties of nano-NiO material were investigated. The special nano-NiO material with porous surface assembling honeycombs(100-200nm) was obtained by using surface active agents. The discharge capacity of nano-NiO electrode up to 2385.7 mAh/g was achieved at current density of 0.1A/g in the first circle,while 1100mAh/g could be maintained after 100 circles. At current density of 2.0A/g, the discharge capacity of 600 mAh/g was obtained. And when the current density was reduced to 0.1A/g, the discharge capacity was restored to 1050 mAh/g. The nano-NiO electrode exhibited …

Microemulsion Preparation And Electrochemical Characterization Of Pt/C，Ptir/C Electrocatalysts, Ya-Ping Zeng, Sheng Sui

Journal of Electrochemistry

The Pt/C electrocatalysts were prepared by three different systems and the PtIr/C electrocatalysts were prepared with four different Ir contents. The samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), cyclic voltammetry (CV), potentiostatic and potentiodynamic polarizations measurements. The experimental results confirmed that the electrocatalyst particles prepared by the microemulsion method were well distributed on XC-72R supports with the active particle sizes of 5～10nm and good electrocatalysts activity. The Pt85Ir15/C electrocatalysts showed the highest overall electrochemical activity in unitized regenerative fuel cell.

The Electrochemical Properties Of Cathode Materials Limxv3-Xo8, Hui Yang, Gang-Gang Zhao, Juan Li

Journal of Electrochemistry

The cathode material of LiMxV3-xO8 was fabricated by sol-gel method using citric acid as a chelating agent and doping transition metal ions M (Mn, Ti, Co and Ni). The structure, morphology and electrochemical proprieties of the LiMxV3-xO8 samples were investigated by XRD, TGA/DTA, SEM, charge-discharge and CV measurements. The results showed that different calcining temperatures result in different structures and morphologies, which lead to different discharge capacities. The specific discharge capacity of the sample calcined at 500℃ for 6 h was up to 300.4 mAh/g in the first cycle, and the capacity decreased with the increasing of calcining temperature. The …

Electrochemical Properties Of Tungstogermanate And Electrocatalysis Of H2o2 On Gew11co/P-Opd/Gc Electrode, Li-Li Zhu, Jian-Ying Qu, Jue Wang, Hao-Yue Feng

Journal of Electrochemistry

The electrochemical properties of Co-substituted trimeric tungstogermanate containing Keggin fragments were studied. Cyclic voltammograms revealed two couples of reversible redox peaks on glassy carbon (GC) electrode in acid solutions. They corresponded to two-electron reductions accompanying by the additions of four protons and three protons, respectively, both were controlled by adsorption. The differences in the peak potentials of 2-electron-4-proton and 2-electron-3-proton reactions were 31 mV and 35 mV, respectively..Furthermore, the tungstogermanate (GeW11Co) modified GC electrode with functionalization by poly(o-phenylenediamine) (P-oPD) was prepared readily by electropolymerization. The GeW11Co/P-oPD/GC electrode could electrocatalyze the reduction of hydrogen peroxide, which showed good stability and quick …

Preparation And Characterization Of Casno3 Anode Material For Lithium Ion Batteries, Ran Sun, Zi-Geng Liu, Ya-Qi Jiang

Journal of Electrochemistry

In this study the precursor CaSn(OH)6 was prepared via a hydrothermal process, and its composition, surface feature and phase-transition were characterized by XRD, SEM and DSC-TGA. The shapes of CaSn(OH)6 crystals were effectively controlled by adjusting the volumn ratio of H2O and CH3CH2OH solvents. Perovskite CaSnO3 could be obtained by calcination of CaSn(OH)6 at 800 ℃. The reversible capacity of 334.4 mAh/g with good cycling stability could be achieved with the CaSnO3 electrode.

Preparation And Characterization Of The Lani0.6fe0.4o3-Δ Cathode For Intermediate Temperature Solid Oxide Fuel Cell, Hang Liu, Bo Huang, Xin-Jian Zhu

Journal of Electrochemistry

The LaNi0.6Fe0.4O3-δ as cathode material for intermediate temperature solid oxide fuel cell was prepared using a combustion synthesis technique. The X-ray diffraction (XRD) pattern showed that the single-phase LaNi0.6Fe0.4O3-δ perovskite could be obtained after heat treatment at 600°C. The TEM and SEM images of the synthesized powders revealed that the grains were 50-100nm. According to the electrochemical impedance spectra (EIS), the polarization resistance of the symmetric cell LaNi0.6Fe0.4O3-δ/ScSZ/LaNi0.6Fe0.4O3-δ sintered at 1050°C was the smallest (0.70Ω?cm2, 0.27Ω?cm2 and 0.12Ω?cm2 at 750°C, 800°C and 850°C, respectively). In the presence of the Fe-Cr alloy interconnection at 750°C, the cathode performance showed that, with …

Dynamic Modeling And Characteristic Analysis Of Proton Exchange Membrane Fuel Cell, Qiu-Hong Jia, Ming Han, Bin Deng, Cai-Zhi Zhang

Journal of Electrochemistry

In this paper, a dynamic model of PEMFC is developed to estimate the dynamic performance of PEMFC by analyzing in detail the influence factors of voltage of PEMFC including various losses. The partial pressure of hydrogen and oxygen is obtained using the differential form of the ideal-gas equation in this model. The steady-state model is obtained by setting reasonable parameter values. The simulation results and experimental results have good consistency, which shows that the simulation model is correct, reasonable and effective. It analyzed the dynamic response characteristics of the output voltage and the partial pressure of hydrogen in condition of …

Indirect Electrochemical Reduction And Cotton Dyeing Process In Fe(Ⅲ)-Oxalate-Calcium Gluconate System, Qing-Zhi Wang, Wei Wang

Journal of Electrochemistry

The electrochemical behavior and possible reaction mechanism in Fe(Ⅲ)-oxalate-calcium gluconate system were studied by cyclic voltammetry. The results showed that Fe(Ⅱ)-gluconate was the final reductant. The reduction time, the working voltage and the cathode area influenced the current efficiency. The high current efficiency of 89% for the indirect electrochemical reduction of Vat Scarlet R could be achieved with reduction time of 10 min, working voltage of 4 V and cathode area of 40 cm2 in Fe(Ⅲ)-oxalate-calcium gluconate system.

Preparation And Capacitance Characteristics Of Nickel Oxide Electrode With Mesh-Like Structure, Hui Xu, Zhen-Jun Peng, Dong-Hong Guo, Jun-Ling Li

Journal of Electrochemistry

The mesh-like structure of NiO electrode was obtained by first preparing the precursors via hydrothermal process using nickel sulfate and carbamide as reactants, sodium hexametaphosphate as a surfactant, and followed by calcination of the precursors at 400 ℃. The structure, morphology and capacitance characteristics of NiO electrode were characterized by XRD, SEM and constant current charge-discharge testing techniques. The effects of hydrothermal temperatures on the electrochemical properties of NiO electrode were investigated. The results showed that the better property of nickel oxide was obtained when the mole ratio of nickel to urea was 1:4 and the hydrothermal temperature was 140℃. …

Causes Of The Blackout: The Grid Operation And Environment, Almoataz Youssef Abdelaziz

Almoataz Youssef Abdelaziz

Despite huge advancements in different power system components, operations, and protection technologies, todayÕs power systems are more vulnerable to blackouts than ever before. Deregulation, market competition, and increasing demands, in addition to less investment in transmission assets, all contribute to the critical state power systems operate at. Two main characteristics of the power system are always being put under the scope of study, reliability and security. This paper takes a subjective thorough look at the previous numerous blackout events, surveyed by the authors, that have been encountered by different power systems around the globe and classifies them into different types …

Interconnection Of Oman And Uae Electric Power Systems, Omar H. Abdalla, Rashid Al-Badwawi, Hilal S. Al-Hadi, Hisham A. Al-Riyami, Ahmed Al-Nadabi, Karim Karoui, Ariadne Szekut

Omar H. Abdalla

Power Control And Security Games For Wireless Communication Networks, Bo Liang

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

In this thesis, game theoretic analysis of wireless communication networks has been performed. Game theory provides valuable tools can be used to solve problem of conflict and cooperation in wireless communication networks. Game theoretic tools can be applied to multiple layers of wireless networks. First, we consider power control issues at the physical layer of wireless networks. A game theoretic analysis for resource allocation policies in fading interference channels in the presence of quality of service (QoS) constraints is performed. We model a two player non-cooperative power control game and assume that both transmitters and receivers know the channel side …

Bonding Of Polydimethylsiloxane Microfluidics To Silicon-Based Sensors, Long-Fang Tsai, William C. Dahlquist, Seunghyun Kim, Gregory P. Nordin

Faculty Publications

We investigate bonding polydimethylsiloxane (PDMS) to silicon using a thin (~2μm) intermediate adhesive layer stamped onto a PDMS piece prior to bonding. In particular, we compare as adhesive layers Sylgard 184 and 182 curing agents and a UV curable adhesive (NOA 75). We examine the effect of both curing temperature and duration on curing agent bond strength. Bond strengths for the different adhesives are determined by measuring the average burst pressure at a PDMS-silicon interface using a PDMS test design. We find that Sylgard 184 curing agent gives the highest bond strength with burst pressure of 700 kPa or more …

Circular And Near-Circular Polarization States Of Evanescent Monochromatic Light Fields In Total Internal Reflection, R. M. A Azzam

Electrical Engineering Faculty Publications

Conditions for the production of near-circular polarization states of the evanescent field present in the rarer medium in total internal reflection of incident monochromatic p-polarized light at a dielectric-dielectric planar interface are determined. Such conditions are satisfied if high-index (>3.2) transparent prism materials (e.g., GaP and Ge) are used at angles of incidence well above the critical angle but sufficiently below grazing incidence. Furthermore, elliptical polarization of incident light with nonzero p and s components can be tailored to cause circular polarization of the resultant tangential electric field in the plane of the interface or circular polarization of the …

Efficient Database Generation For Decision Tree Based Power System Security Assessment, Venkat Krishnan

Venkat Kumar Krishnan

No abstract provided.

High Speed And Low-Complexity Hardware Architectures For Elliptic Curve-Based Crypto-Processors, Reza Azarderakhsh

Electronic Thesis and Dissertation Repository

The elliptic curve cryptography (ECC) has been identified as an efficient scheme for public-key cryptography. This thesis studies efficient implementation of ECC crypto-processors on hardware platforms in a bottom-up approach. We first study efficient and low-complexity architectures for finite field multiplications over Gaussian normal basis (GNB). We propose three new low-complexity digit-level architectures for finite field multiplication. Architectures are modified in order to make them more suitable for hardware implementations specially focusing on reducing the area usage. Then, for the first time, we propose a hybrid digit-level multiplier architecture which performs two multiplications together (double-multiplication) with the same number of …

Thermodynamic Limit To Photonic-Plasmonic Light-Trapping In Thin Films On Metals, Eric A. Schiff

Physics - All Scholarship

We calculate the maximum optical absorptance enhancements in thin semiconductor films on metals due to structures that diffuse light and couple it to surface plasmon polaritons. The calculations can be used to estimate plasmonic effects on light-trapping in solar cells. The calculations are based on the statistical distribution of energy in the electromagnetic modes of the structure, which include surface plasmon polariton modes at the metal interface as well as the trapped waveguide modes in the film. The enhancement has the form 4n²+nλ/h (n – film refractive index, λ – optical wavelength, h …

Bearing-Only Cooperative-Localization And Path-Planning Of Ground And Aerial Robots, Rajnikant Sharma

Theses and Dissertations

In this dissertation, we focus on two fundamental problems related to the navigation of ground robots and small Unmanned Aerial Vehicle (UAVs): cooperative localization and path planning. The theme running through in all of the work is the use of bearing only sensors, with a focus on monocular video cameras mounted on ground robots and UAVs. To begin with, we derive the conditions for the complete observability of the bearing-only cooperative localization problem. The key element of this analysis is the Relative Position Measurement Graph (RPMG). The nodes of an RPMG represent vehicle states and the edges represent bearing measurements …

Field-Effect Amperometric Immuno-Detection Of Protein Biomarker, Jiapeng Wang, Siu-Tung Yau

Electrical and Computer Engineering Faculty Publications

The field-effect enzymatic detection technique has been applied to the amperometric immunoassay of the cancer biomarker, carcinoma antigen 125 (CA 125). The detection adopted a reagentless approach, in which the analyte, CA 125, was immobilized on the detecting electrode, which was modified using carbon nanotubes, and the detection signal was obtained by measuring the reduction peak current of the enzyme that was used to label the antibody. A gating voltage was applied to the detecting electrode, inducing increase in the signal current and therefore providing amplification of the detection signal. The voltage-controlled signal amplification of the detection …

Towards Trustworthy Coordination For Web Services Business Activities, Hua Chai, Hongle Zhang, Wenbing Zhao, P. M. Melliar-Smith, L. E. Moser

Electrical and Computer Engineering Faculty Publications

We present a lightweight Byzantine fault tolerance (BFT) algorithm, which can be used to render the coordination of web services business activities (WS-BA) more trustworthy. The lightweight design of the BFT algorithm is the result of a comprehensive study of the threats to the WS-BA coordination services and a careful analysis of the state model of WS-BA. The lightweight BFT algorithm uses source ordering, rather than total ordering, of incoming requests to achieve Byzantine fault tolerant, state-machine replication of the WS-BA coordination services. We have implemented the lightweight BFT algorithm, and incorporated it into the open-source Kandula framework, which implements …

Turbine, Vijaya Krushna Varma Mr

VIJAYA KRUSHNA VARMA Mr

Varma designed ultra modern and high efficiency turbines which can use gas, steam or fuels as feed to produce electricity or mechanical work for wide range of usages and applications in industries or at work sites. Varma turbine engines can be used in all types of vehicles. These turbines can also be used in aircraft, ships, battle tanks, dredgers, mining equipment, earth moving machines etc, Salient features of Varma Turbines. 1. Varma turbines are simple in design, easy to manufacture, easy to operate and maintain. 2. Varma turbines are less expensive. 3. Varma turbines have a great power to weight …

Anatomy Of A Nanoscale Conduction Channel Reveals The Mechanism Of A High-Performance Memristor, Feng Miao, John Strachan, Jianhua Yang, M Zhang, Ilan Goldfarb, Antonio Torrezan, Peter Eschbach, Ronald Kelley, Gilberto Medeiros-Ribeiro, R Stanley Williams

Electrical and Computer Engineering Faculty Publication Series

By employing a precise method for locating and directlyimaging the active switching region in a resistive random access memory (RRAM) device, a nanoscale conducting channel consisting of an amorphous Ta(O) solid solution surrounded by nearly stoichiometric Ta2O5 is observed. Structural and chemical analysis of the channel combined with temperature-dependent transport measurements indicate a unique resistance switching mechanism.

Anatomy Of A Nanoscale Conduction Channel Reveals The Mechanism Of A High-Performance Memristor, Feng Miao, John Strachan, Jianhua Yang, M Zhang, Ilan Goldfarb, Antonio Torrezan, Peter Eschbach, Ronald Kelley, Gilberto Medeiros-Ribeiro, R Stanley Williams

Jianhua Yang

Flutter Analysis Of Rx-420 Balistic Rocket Fin Involving Rigid Body Modes Of Rocket Structures, Novi Andria

Makara Journal of Technology

Flutter Analysis of RX-420 Balistic Rocket Fin Involving Rigid Body Modes of Rocket Structures. Flutter is a phenomenon that has brought a catastrophic failure to the flight vehicle structure. In this experiment, flutter was analyzed for its symmetric and antisymmetric configuration to understand the effect of rocket rigid modes to the fin flutter characteristic. This research was also expected to find out the safety level of RX-420 structure design. The analysis was performed using half rocket model. Fin structure used in this research was a fin which has semispan 600 mm, thickness 12 mm, chord root 700 mm, chord tip …

Flexible Connection Elastomeric Rubber As A Pounding Resisting Element Between Two Adjacent Buildings, Yuskar Lase, James Jatmiko Oetomo

Makara Journal of Technology

Flexible Connection Elastomeric Rubber as a Pounding Resisting Element between Two Adjacent Buildings To solve pounding problem of two adjacent buildings, structural designer usually employs a dilatation between the structures or make the two structures as a monolith structure. Other alternative is by using an elastomeric rubber as a pounding resisting element between the two structures. Effectiveness in applying elastomeric rubber component as flexible connection of two adjacent structures is the main focus of this paper. Various simulations such as structure models, earthquake excitations and openings in gap element are studied. Observation of maximum structural responses will be performed for …

Effect Of Copper Addition On Mechanical Properties And Electrical Conductivity Of Pp/C-Cu Bipolar Plate Composites, Anne Zulfia, Taufik Abimanyu, Verina Warga Dalam

Makara Journal of Technology

Effect of Copper Addition on Mechanical Properties and Electrical Conductivity of PP/C-Cu Bipolar Plate Composites. Bipolar plate is a major component in PEM fuel cell which possess main function of collecting and removing electrons from anode to cathode. Therefore, materials for bipolar plates produced must have high electrical conductivity. To obtain bipolar plate materials which is cheap, lightweight and high conductivity, so it is developed bipolar plates material based on PP/C-Cu composite. PP/C-Cu composites has been made by mixing all materials then compounding, rheomix, hot blending and hot press. Cu (Copper) has been used various from 0.1 wt%, 1 wt% …

Analytical And Computational Simulation Approaches To Design Low Energy Glass Block, Floriberta Binarti, Agustinus Djoko Istiadji, Prasasto Satwiko, Priyo Tri Iswanto

Makara Journal of Technology

Analytical and Computational Simulation Approaches to Design Low Energy Glass Block. An environmentally friendly process was developed to produce a low embodied energy glass block from waste glasses. The energy efficiency of the glass block is represented by its thermal conductance (U) <3.177 W/m2.K and solar transmittance (SHGC) ≤0.25 as well as visible light transmission (VT) ≥0.27. A cavity was applied to reduce U value while insignificantly reducing VT. Analytical method was used to calculate the U value of glass blocks, ignoring the effect of convection. Ecotect program was used to analyze light level (VT) and heat load (SHGC) of each model. Effect of convection was simulated using a CFD program, which showed air velocity inside the cavity and temperature gradient in glass blocks. Comparing to an application with 3 mm float glass, energy efficiency obtained through applying the glass blocks could reach 96%. This simulation study ignored the presence of adhesive among glass layers that potentially reduces the VT and the SHGC of the glass blocks.

Improvement Of High Temperature Oxidation Of Low Carbon Steel Exposed To Ethanol Combustion Product At 700 °C By Hot-Dip Aluminizing Coating, Mohammad Badaruddin

Makara Journal of Technology

Low carbon steel (AISI 1005) was coated by hot-dipping into a molten Al-10% Si bath at 700 °C for 18s. After hotdipping treatment, the coating layers consisted of Al, Si, FeAl3, τ5-Fe2Al8Si, and Fe2Al5. The bare steel and the aluminized steel were isothermally oxidized at 700 °C in ethanol combustion product at atmospheric pressure for 49 h. The aluminized steel shows good performance in high temperature oxidation because the formation of Al2O3 layer on the coating surface. The growth of iron oxide nodules on the surface coating was accelerated by rapid outward diffusion of Fe-ions due to the presence of …

Optimation Of Nitrogen And Phosphorus In Azolla Growth As Biofertilizer, Hany Handajani

Makara Journal of Technology

Nitrogen is one of the most important minerals for living organisms. Azolla is known as a small water fern which can fix nitrogen through the symbiotic association with the blue green algae Anabaena. Experimental studies were carried out in the glass house, investigating the growth of Azolla using different levels of nitrogen and phosphorus in the media. The experiment used 12 treatments with 3 levels of nitrogen (0, 5, and 10 mg atom/L) and 4 levels of phosphorus (0, 10, 20, and 30 mg atom/l) in a factorial design with 3 replicates. The results show that the highest biomass for …