Engineering Commons^™

Activity Coefficient For Infinite Dilute Solution By Gas-Liquid Chromotography, Suresh Jivabhai Patel

Theses

Gas-liquid partition chromatography has been used to determine the activity coefficient for very dilute solutions of solute in non-volatile solvents.

Other, more classical methods of determining the activity coefficient are laborious and are neither as accurtate nor as precise as desired.

The systems studied were:

(1) Benzene-Dinonyl Phthalate

(2) Cyclohexane-Dinonyl Phthalate

(3) Benzene-Squalane

(4) Cyclohexane-Squalane

All systems were studied over the column temperature range of 50° to 110°C with constant pressure and sample size. A study was also made on the effect of column pressure at constant temperature and sample size. One system was studied with variable sample size but …

Heat Transfer To Non-Newtonian Fluids In Turbulent Flow, Donald S. Smalley, George Vassil

Theses

An investigation of the heat transfer characteristics of non-Newtonian solutions in turbulent flow is presented. The range of flow behavior indices (n) was examined from 0.69 to 0.88. The consistency index (K) was investigated over the range of 0.00008 to 0.002 lbsf x sec^n'/ft². The Reynolds number varied between 2200 to 25,000.

Two methods of correlating film coefficients which have been previously developed were examined. Improvement in the reliability of correlation is demonstrated by modifications proposed in this work.

Brittle Fracture Of Carbon Steel, Ronald Robert Stang

Theses

This thesis is a report on the research and engineering efforts made, since 1957, to further define the causes and means for the prevention of catastrophic brittle fracture of carbon steels at ambient temperatures. All of the data based on the literature published from 1958 to 1965 has been critically examined and correlated.

Included are discussions of the factors affecting brittle fracture and the tests used to predict resistance Of steels to brittle fracture. Correlations of tests with actual service performance and relationships between tests are discussed. A review and critical evaluation of present day steel specifications as they affect …

The Thermal Conductivity With Vapor Pressure For N-Paraffin Hydrocarbons, Jacob Tolsma

Theses

A literature search of the thermal conductivity of pure liquids has been made and experimental values have been compiled. Study of the theory of the thermal conductivity of liquids indicated that a relationship exists between thermal conductivity and viscosity. Previous investigations have found an almost linear relationship between the logarithms of viscosity and vapor pressure for n-paraffin hydrocarbons. In this investigation the logarithm of thermal conductivity plotted versus the logarithm of vapor pressure for the same series was also found to be almost linear. The equation of the line when combined with a linearized Antoine equation in terms of the …

A Study Of Emulsion Viscosities, Frederick R. Cummings

Theses

The apparent viscosity of stable emulsions has been measured and evaluated. The systems studied consisted of various oil in water emulsions, utilizing a series of six n-paraffins from heptane to octadecane. The system was stabilized with a conventional emulsifying agent. The apparent viscosity of these emulsions was studied in relation to (a) the concentration of the disperse phase and, (b) the viscosity of the hydrocarbon used as the continuous phase.

It was established that the volume concentration of the disperse phase had considerable effect on the apparent viscosity of the emulsion. An increase in the concentration of the disperse phase …

The Effect Of Column Diameter On The Efficiency Of Packed Fractioning Towers, William Lintner

Theses

The object of this work was to study the effect of packed column diameter on the fractionation efficiency so that a more reliable engineering approach could be employed in the scaling up of fractionating columns.

The height equivalent to a theoretical plate (HETP) was employed to compare column efficiencies in this study. The HETP was calculated for several gas mass velocities through columns of one-inch, two-inch and three-inch diameter, packed with one-quarter inch Berl saddles. All data were collected at total reflux conditions employing the standard n-heptane-methylcyclohexane binary.

The results indicated that the efficiencies of the one-inch and two-inch diameter …

An Investigation Of The Mechanism Controlling The Co-Deposition Of Aluminas With Copper During Electrodeposition Of Copper, James Edward Hoffmann

Theses

Experimental work was undertaken to determine the mechanism controlling the co-deposition of aluminas with copper during electrode-position of copper. The aluminas were present in the copper plating electrolytes as an insoluble disperse phase.

Three possible mechanisms for co-deposition of aluminas were studied, They were mechanical inclusion, electrophoretic deposition, and adsorption.

The results of experimental studies established that mechanical inclusion was not a significant factor in the mechanism controlling co-deposition of aluminas with copper.

Theoretical considerations of the compositions of the copper plating electrolytes indicated that co-deposition of aluminas by an electrophoretic mechanism was highly unlikely. The conclusions arrived at by …

Electrolytic Polishing Of Copper And Nickel Silver, Halle Abrams

Theses

To facilitate the study of surface conditions on ultrasonic weldability, electrolytic polishing was used to obtain four types of surfaces on copper and nickel silver (alloy D). A500 orthophosphoric acid bath was used, and the necessary operating conditions to obtain these surfaces were established. In accordance with current electrolytic polishing theory, the existence of the anode viscous layer and anode surface film was observed, and their role in the polishing process is discussed. By means of metallurgical techniques and surface profile measurements, it is shown that the four types of surfaces are significantly different, and good reproducibility of these surfaces …

The Effect Of An Electrical Corona Discharge Upon The Reaction Of So2 To So3 In Low Concentration So2 - Air Mixtures, Edward James Malarkey

Theses

An investigation of a pilot plant electrical dust precipitator was conducted to determine its ozone generating characteristics in air as well as the ability of the ozone formed to convert gaseous SO₂ to particulate SO₃. It was anticipated that in addition to the known primary particulate dust and mist removal function of a precipitator, a secondary gaseous removal facility was inherent in its operation.

Ozone formation quantities were determined at varied air flow and electrical power input levels to the precipitator. Maximum ozone generation was 0.02 pounds per hour at an energy input level of 113 KW-HR …

Fugacity Coefficients Of Gases In Binary Mixtures, David Albin Olson

Theses

A proposed, method of Joffe for determining fugacity coefficients of gases In binary mixtures is presented. The method is evaluated by calculating 320 pairs of fugacity coefficients and comparing the results with experimental data and with values calculated by the method of Pitzer.

Joffe derived the expression for fugacity coefficients by employing the technique of Gamson and Watson. The expression is based on the three-parameter corresponding states principle as previously presented by Pitzer and a proposed definition of the pseudocritical properties.

The method of Pitzer and the proposed method of Joffe both require the same data.

This study is based …

The Separation Of Radioactive Technetium And Zirconium By Electrodialysis And A Study Of The Behavior Of Technetium In Aqueous Solutions, William Victor Andoe

Masters Theses

"The rapid increase in radioisotope applications necessitates improved technology for separation and purification of the fission product elements. Electrodialysis techniques employing Permutit anion exchange membrane(3148) were used to separate technetium from zirconium. The method was based upon the stability of the pertechnetate ion in alkaline solutions and the precipitation of zirconium from alkaline solutions. The separation of radiotechnetium and radiozirconium was effected with a two cell electrodialysis unit employing an anion exchange membrane. The solution medium consisted of fluoride and nitrate ions which were made basic with sodium hydroxide. The minimum basicity for a good separation was 0.1N NaOH"--Abstract, page …

Thermal Degradation Of Poly (Methyl Methacrylate) In Solution In Various Solvents, Ya-Chih Chen

Masters Theses

"A study has been made of the thermal degradation of poly (methyl methacrylate) of different molecular weights in toluene, ethyl acetate and chloroform. Four poly (methyl methacrylate) samples having molecular weights of 2,210,000, 733,000, 320,000, and 43,00, respectively were studied in this investigation. The results indicated that the polymer having a molecular weight of 2,210,000 undergoes degradation while the low molecular weight polymers having molecular weights of 733,000, 320,000, 43,000 undergo reverse polymerization"--Abstract, page [ii].

Thermal Degradation Of Poly (Methyl Methacrylate) In Solutions In A Closed System, Vikram Pranjivandas Parikh

Masters Theses

"A study has been made of the thermal degradation of poly (methyl methacrylate) of two different molecular weights, 2,303,000 and 43,000, in 1,2-dichloroethane in a closed system. The results indicated that the polymer having a molecular weight of 2,303,000 undergoes degradation while the low molecular weight polymer 43,000 undergoes reverse polymerization, and the molecular weight remains constant. The molecular weight of high molecular weight samples after 48 hours decreased from 2,303,000 to 2,232,000 and 1,690,400 at 50⁰C and at 98.5⁰C, respectively"--Abstract, page [i].

The Electrochemical Oxidation Of Crotonic Acid, John L. Cannaday

Masters Theses

"The purpose of this investigation was to explain the mechanism of the electrochemical oxidation of crotonic acid on platinized-platinum anodes at 80⁰C.

A current-potential study was conducted using the parameters of pH and crotonic acid concentration. Faradaic efficiency was determined by measurement of CO₂ production.

Oxidation occurred both in acidic and basic solutions.The Faradaic efficiency was approximately 100 per cent.

The results were interpreted in terms of a mechanism having the following characteristics.

(a) The first charge transfer is the rate determining step.

(b) The rate is the sum of the rates for two parallel reactions. In strongly acidic solutions, …

Mass Transfer In The Electrodialytic Desalination Of Brackish Water And A Correlation Of Experimental Data With Theory, James Shih-Jiann Yang

Masters Theses

"The object of this work is an experimental investigation into the possibility of obtaining an increase in mass transfer in the electrodialysis of brackish water by altering the physical character of the selective membrane, and a correlation of experimental mass transfer data with theory"--Introduction, page 1.

The Kinetics And Mechanisms Of The Reaction Of Benzyl Chloride With Potassium T̲-Butoxide In T̲-Butyl Alcohol, Der-Rong Chen

Masters Theses

"Benzyl chloride is a moderately reactive halide. Substitution of the Cl⁻ by other nucleophiles, e.g., HO⁻, AcO⁻, S₂O₃⁻, Br⁻ etc. proceeds almost quantitatively in solutions at convenient temperatures ... The object of this study was to investigate if the less basic t̲-butoxide in t̲-butyl alcohol would afford the same product, viz., stilbene; and, if so, by what mechanism. A study of the products and kinetics of the interaction between benzyl chloride and potassium t̲-butoxide in t̲-butyl alcohol therefore has been initiated"--Introduction, page 1.

Oxidation Of Ortho-Xylene To Phthalic Anhydride Using A Fluidized Bed Catalysis, Jyue-Sheng Wang

Masters Theses

"This investigation was conducted to study the vapor-phase oxidation of o-xylene to phthalic anhydride in a fluidized bed reactor. Parameters investigated during the study were temperature, molar ratio of air to o-xylene vapor, and space velocity. The catalyst used was vanadium pentoxide supported on a silica base and diluted with potassium sulfate. The studies were conducted on a laboratory scale"--Abstract, page ii.

Study Of Deformation Of Non-Oscillating Droplets In Liquid Media, Arun Kumar Agrawal

Masters Theses

"The object of this investigation was to find a method for predicting the deformation of non-oscillating liquid droplets which are moving in liquid media, from a knowledge of droplet size and the physical properties of the continuous and dispersed phase systems. The deformation of thirteen liquid-liquid systems was experimentally studied in this investigation"--Abstract, page i.

An Analysis Of Pressure Build-Up Theory, Hansraj J. Patel

Masters Theses

"Various theories regarding the pressure build-up characteristics for producing wells are analyzed. The merits and limitations of each theory are discussed. The error involved in plotting the pressure build-up data for the case of well-bore pressure versus shut-in time is pointed out. Equations have been presented for the various quantitative determinations of reservoir properties which can be obtained from typical pressure build-up data. Utilizing all the previous methods presented in the literature, a recommended procedure for field application is proposed. One oil well and three gas wells have been analyzed using the recommended procedure with the attendant calculations given in …

A Study Of Degradation In The Pumping Of Dilute Polymer Solutions, I-Chung Chang

Masters Theses

"In the course of an investigation of the turbulent flow properties of dilute high polymer solutions in organic solvents, a number of supplementary investigations were required. These were: 1. Determination of the molecular weights of a number of polymers by intrinsic viscosity measurements. 2. Determination of the effect of pumping on the degradation of high polymers in dilute solutions. This included development of a method for estimating the concentration of dilute polymer solutions. 3. Determination of the effects of density, viscosity and non-Newtonian behavior on the calibration of turbine flow meters"--Introduction, page 1.

Performance Of A Reciprocating Packed Extraction Column, Thomas Vardaman Konkle

Masters Theses

"The performance of a mechanically-aided liquid extraction column was investigated utilizing the methyl isobutyl ketone-acetic acid-water ternary extraction system. Mechanical power was added to the extraction system by reciprocating a wire-mesh packing of high void volume at various frequencies and displacements. The effects of total throughput on performance were studied in increments of 5,000 pounds per hour per square foot up to the onset of flooding, and the column performance was evaluated as a function of power addition to the extraction system. In comparing the various types of mechanically-aided extraction columns, it was determined that the throughputs achieved with the …

The Production Of Glutamic Acid By Fermentation, Tsun-Hsiung Li

Masters Theses

"The method of producing glutamic acid by fermentation was studied in shake flasks and in a five liter fermentor. Strains of the micro-organism, Micrococcus glutamicus, were used to produce glutamic acid under different conditions ... A literature review of the general properties of glutamic acid and industrial methods of glutamic acid production was made. A detailed discussion of the fermentation method of glutamic acid production was also included"--Abstract, page ii.

Radiation Induced Polymerization Of Methyl Methacrylate, Ko-Hung Liu

Masters Theses

"A study has been made of the gamma radiation effect on the rate of polymerization of methyl methacrylate monomer, and also to determine the effects of the presence of clay of known composition and of other solids on the rate of polymerization. The results indicate that the monomer undergoes polymerization and then degradation as a function of radiation time at a given gamma flux"--Abstract, page ii.

Radial Water Encroachment - An Approximation, Tommie C. Wilson

Masters Theses

"This presentation consists of the application of empirical equations for the calculation of the water influx into a radial oil reservoir in which the history of the rate and cumulative water influx are equated to the pressure decrements and time. This new analysis, based on William Hurst's solution for the steady-state water influx, yields an accurate method for determining water influx through the application of simple linear empirical equations. These linear approximations reproduce the rigorous influx solutions to a maximum deviation of 1.6 per cent"--Abstract, page ii.

The Design Of A Sensitive Probe For Mass Flux Measurements Of Water Vapor In Air, Devendra Vaikunthlal Mehta

Masters Theses

"This investigation pertains to the construction and investigation of a sensitive probe to determine the possibility of measuring the mass flux of water vapor in air under non-flow steady state conditions. The probe was a small electrolysis cell is which the electrolyte (partially hydrated phosphorus pentoxide) was used as the sensing element. The rate of mass transfer was determined by measuring the amount of direct current flowing through the acid film"--Abstract, page i.

The Anodic Dissolution Of Cadmium In Nitrate Solution, Eh Deng

Masters Theses

"It is only relatively recently that the immensity of the problem of corrosion prevention has begun to be realized. In times when materials were plentiful, the problem did not seem so pressing. Now that a finite limit can be seen for the world*s resources of metals, and the cost of finding, mining and extracting them has become ever more expensive, the problem of controlling the destructive processes of corrosion has become an urgent one.

The basic mechanism of the anodic dissolution of metals such as cadmium, zinc, silver and magnesium in salt solutions is not completely known. Although several mechanisms …

The Dissolution Of Magnesium In Strong Acids And Neutral Solutions, Cheng-Ken Chi

Masters Theses

"The increasing demand for magnesium and magnesium- base alloys in the manufacture of aircraft has stimulated a great amount of research into the corrosion characteristics of these materials. The result of such research has been the development of suitable magnesium alloys and protective coatings to retard corrosion.

The basic mechanism of the anodic dissolution of metals such as magnesium, zinc, and cadmium in salt solutions is not completely known. Several schools of investigators have proposed different and opposing theories to explain the discrepancies which often arise between coulometer data and the weight loss of metal electrodes in certain salt solutions. …

Anodic Dissolution Of Silver In Aqueous Solutions, Jagdish Shantilal Sanghvi

Masters Theses

"Silver and platinum, although not used extensively in industry, find considerable use in specialized work. Silver, because of its much lower cost, is used to a greater extent than platinum. Since silver has a high position in the electromotive series, it is very resistant to chemical attack. It is unaffected by alkaline conditions even at high temperatures and hence silver is used in ladles and molds for producing pure sodium and potassium hydroxides. This and its excellent electrical conductivity makes it a very useful material in circuitry.

It has been reported in the literature that when active metals such as …

Kinetics Of Base-Catalysed Reactions, Kunjvihari Ramanlal Mehta

Masters Theses

"The work of Wulfman on the mechanism of the Michael reactions suggests that the normal Michael reaction is second order kinetically, with the rate being proportional to the concentration of the acceptor and the active form of the addendum. A detailed reaction mechanism of normal Michael reaction was not proposed due to insufficient data which resulted from analytical difficulties. This investigation involves the study of the kinetics of normal Michael reaction from the stand point of base strength, solvent concentration and acidity of the reactants, solvent and products"--Experimental. A. Purpose of Investigation, page 17.

Permeability And Additive Absorption And Extraction In Lubricating Greases, Eugene Hsiung-Jen Tu

Masters Theses

"A permeability apparatus was used to measure the permeability coefficients of eight Lithium-Calcium greases and ten Baragel greases in which the viscosity and type of the oil component were varied. The oil present in each grease was used for its permeability measurement.

An improved sample packing technique was developed to improve the repeatability of permeability measurements. Repeatability of ± 3% was achieved. In general the permeability coefficients of the non-soap Baragel greases were higher than those of the lithium-calcium greases with comparable oil components, and those of greases containing paraffinic oils were higher than these containing naphthenic oils. The effect …