Engineering Commons^™

Clearance Of Solid Household Waste With The Reception Of Alternative Types Of Energy Carriers, Rakhmatullayev F, Turabdhanov S

Technical science and innovation

The research is devoted to improving the technology of obtaining alternative types of energy carriers by applying methods of pyrolysis of unclaimed types of solid domestic wastes of biological origin, which also allow solving the tasks of improving the ecological situation in the places of formation. The practical value and relevance of this research lies in the development of advanced technology for obtaining alternative fuels. The proposed pyrolysis unit allows producing gaseous and liquid hydrocarbons in a continuous cycle. In the atmosphere of the gasifying agent (air, oxygen, water vapor, carbon dioxide or their mixture), the gasification process is primarily …

Fluid-Driven Fracture Initiation From Oil And Gas Wells Considering Lifetime Stresses, Andreas Michael

LSU Doctoral Dissertations

Fluid-driven fracture initiation from oil and gas wells is examined in detail. The dissertation covers three subtopics: drilling, completion (stimulations), and post-blowout capping-induced fracture initiation.

Drilling-induced tensile fractures (DITFs) are located in an azimuth orthogonal to wellbore breakouts and are observed from image logs obtained during drilling operations. Fully analytical criteria for the orientation of DITFs initiating from wells in porous, permeable media are derived considering fluid infiltration from a pressurized wellbore. DITF orientation (longitudinal or transverse-to-the-wellbore) is used to constrain the magnitude of the local maximum horizontal principal stress. The range of the possible stress states is indicated on …

Atom Trapping And Its Role On The Nucleation & Growth Of Platinum Nanoparticles, Deepak Kunwar

Chemistry and Chemical Biology ETDs

Diesel oxidation catalysts deactivate due to Pt sintering, a major problem in automotive industries. To make sure they operate effectively throughout the lifetime of the vehicle, automotive industries are putting an excessive amount of Pt. There is a need to develop a catalyst that serves long term performance with minimal use of Pt. Jones et al^.1 demonstrated that ceria traps Pt atoms. His work generated some logical and valid questions such as what is the mechanism for the formation of anomalously large Pt particles? What is the upper limit of Pt metal loading in the form of single atoms …

Numerical Study Of The Effect Of Gas Distributors And Baffles On The Bubble Distribution, Gas And Solid Mixing In A Fluidized Bed, Xuelian Xing

Electronic Thesis and Dissertation Repository

In this study, the multi-phase Eulerian-Eulerian two-fluid method (TFM) coupled with the kinetic theory of granular flow (KTFG) was used to investigate hydrodynamics of particle flows (Geldart Group B) in a lab-scale fluidized bed Geldart Group B particles, operating in bubbling and turbulent regimes. The effect of gas distributors and baffles on the distribution of the gas bubbles, and the mixing of gas and solids were investigated under various superficial gas velocities.

The numerical model is validated by experimental results from two different measurement methods with various gas distributor configurations and a superficial gas velocity ranging from 0.4 m/s to …

Incorporation Of Lignin In Natural And Synthetic Biomaterials To Alter Mechanical And Biochemical Properties For Enhanced Wound Healing, Jorge Alfonso Belgodere

LSU Doctoral Dissertations

It is estimated that chronic, non-healing wounds affect more than 6.5 million Americans annually, with an estimated healthcare cost beyond $14 billion. Here, we attempted to create composites of natural (collagen type I or gelatin-methacrylate) or synthetic (poly(ethylene glycol) polymers incorporating a natural plant component, lignin, to combat the costs and limitations current wound healing methods face. Three-dimensional matrices of collagen type I (Col I) are widely used in tissue engineering applications for its abundance in many tissues, bioactivity with many cell types, and excellent biocompatibility. Inspired by the structural role of lignin in plant tissue, we found that sodium …

Adsorption And Reconfiguration Of Amphiphiles At Silica-Water Interfaces: Role Of Electrostatic Interactions, Van Der Waals Forces And Hydrogen Bonds, Yao Wu

LSU Doctoral Dissertations

The ability to explore and predict metastable structures of hybrid self-assemblies is of central importance for the next generation of advanced materials with novel properties. As compared to their thermodynamically stable forms, the kinetically stabilized materials show improved functionality potentially over their stable counterparts. The self-assembly processes usually originate from weak intermolecular interactions, involving a dynamic competition between attractive and repulsive interactions. These weak forces, including van der Waals (vdW), electrostatic interaction and the hydrogen bonding (H-bonding), can be tuned by external stimuli, e.g., confinement, temperature and ionization, and consequently driving hybrid materials into different configurations. It is challenging to …

Effect Of Catholyte Concentration On Current Production During Chocolate Industry Wastewater Treatment By A Microbial Fuel Cell, Diana Rahayuning Wulan, Suprihanto Notodarmojo

Makara Journal of Technology

Microbial fuel cells (MFCs) use bacteria as a catalyst to oxidize organic and/or inorganic substrates and produce electric currents. Wastewater could function as an electron donor in the anode chamber and, thus, represents a very promising energy source. Catholytes, as electron acceptors, influence power production in MFCs by increasing the availability of electrons. The present research aims to determine the influence of catholyte concentration on current production in an aerobic two-chamber MFC. Aerobic treatment was carried out in the two-chamber MFC operated in an incubator at 37  1 °C with and without aeration in the cathode chamber. Wastewater from …

Evaluation Of Il-17a And Il-17f Gene Expression In Peripheral Blood Mononuclear Cells In Different Clinical Stages Of Chronic Hepatitis B Infection In An Iranian Population, Tannaz Akbari Kolagar, Seyed Reza Mohebbi, Fatemeh Ashrafi, Shahrzad Shoraka, Hamid Asadzadeh Aghdaei, Mohammad Reza Zali

Makara Journal of Technology

Hepatitis B virus (HBV) infection is one of the main causes of liver damage, which can also lead to chronic hepatitis B (CHB) infection. More than 240 million individuals worldwide are chronic carriers of HBV. Among individuals with CHB who are untreated, approximately 15% – 40% will progress to liver cirrhosis or cancer. The interactions between HBV and host immune response play significant roles in the progression of CHB. CHB can be generally divided into four different clinical phases: immune tolerance (IT), immune clearance, inactive carrier, and Hepatitis B surface antigen (HBsAg)-negative reactivation phase (ENEG). Many studies showed that interleukins …

Redesign Of Product Packaging With Kansei Engineering: Empirical Study On Small-Medium Enterprises In Indonesia, Amalia Suzianti, A. Aldianto

Makara Journal of Technology

Small-medium enterprises (SMEs) in Indonesia have been proven to be one of the important pillars of the national economy. Unfortunately, some problems hinder their development, and one of the critical problems is the quality of product packaging. The packages of SME products are considered poor, dirty, and unattractive. Packaging problem is one of the factors why consumers are less interested in buying and why SME products always lose in the competition with other products. This study discusses how to employ Kansei engineering to design better SME product packaging with a focus on psychological (affective) aspects. This research concludes that there …

Effect Of Landfill Leachates On Some Water Quality Indicators Of Selected Surface Water And Groundwater At Ilokun, Ado-Ekiti, Nigeria, Olorunwa Omofunmi, Adesola Satimehin, Abraham Oloye, Okwunna Umego

Makara Journal of Technology

This study was conducted to examine the impact of dumpsites on the quality of groundwater and surface water. The water samples and leachates were collected from dumpsites in respective zones. The physicochemical properties of the samples were examined and determined in accordance with the standards of the American Public Health Association. Results indicated that the groundwater and surface water that are close to the dumpsites have an electrical conductivity of 385 and 245 Sd/cm, total dissolved solids of 168 and 128 mg/L, a turbidity of 4.6 and 22 NTU, a total alkalinity of 103 and 50 mg/L, a total hardness …

Microstrip Filters: A Review Of Different Filter Designs Used In Ultrawide Band Technology, Hussain Bohra, Giriraj Prajapati

Makara Journal of Technology

In this study, optimization techniques applied in designing microstrip bandpass ultra-wideband (UWB) filters are presented. Optimization based on various defected ground structure techniques, resonator designs, and type of dielectric materials is discussed. Microstrip bandpass filters implemented at UWB frequency bands used in wireless communication systems have key features to control frequency response in passband and stopband. Optimization techniques are studied to attain optimum performance of bandpass microstrip filters to ensure minimum insertion loss, high selectivity, compactness, sharp transitions at cut-off frequencies, high return loss, and excellent linearity. Extensive study shows that proper selection of fabrication techniques and type of material …

Effect Of Pvdf-Ca Ratio On Electrospun Membrane For Water–Oil Filtration Application, Mohamad Haziq Alias, Izan Izwan Misnon, Rajan Jose

Makara Journal of Technology

Oil spillage and generation of industrial water–oil wastewater mixture ignite a focus on filtration technology. Electrospinning technique provides a versatile route in producing tunable diameter and pores in nanofiber filtration membrane development. In this work, polyvinylidene difluoride (PVDF) and cellulose acetate (CA) electrospun membrane at different concentration ratios were synthesized for water–oil filtration application. The polymeric solutions were characterized using viscometer and conductivity testing, whereas the membranes were analyzed using contact angle, tensile test, scanning electron microscopy (SEM), and filtration testing of oil (dichloromethane). Conductivity test showed a decreased conductivity along with decrement of CA ratio in the polymeric solution. …

Performance-Shaping Factors Of Personnel Performing Evacuation And Escape On Offshore Installations In Tropical, Norafneeza Norazahar, Nur Azizah Arryanie Morshidi, Arshad Ahmad, Wijayanuddin Mohd Ali

Makara Journal of Technology

Performance-shaping factors (PSFs) are used to address the strengths and weaknesses of workers performing escape and evacuation activities. These PSFs are time, environmental factors as stressors, complexity of activities, experiences and training, interaction between workers and emergency equipment, workers’ physical conditions, and procedures. This paper presents a survey work on fitness for the duty of workers performing basic offshore survival and emergency response training. The training provides credible scenarios of escape and evacuation in case of an emergency of offshore installations in tropical waters. The survey is conducted among participants of the tropical basic offshore safety induction & emergency training …

Calcium Sulfate-Containing Glass Polyalkenoate Cement For Revision Total Knee Arthroplasty Fixation, Leyla Hasandoost, Adel Alhalawani, Omar Rodriguez, Alireza Rahimnejad Yazdi, Paul Zalzal, Emil H. Schemitsch, Stephen D. Waldman, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Poly (methyl methacrylate) (PMMA) bone cement is used as a minor void filler in revision total knee arthroplasty (rTKA). The application of PMMA is indicated only for peripheral bone defects with less than 5 mm depth and that cover less than 50% of the bone surface. Treating bone defects with PMMA results in complications as a result of volumetric shrinkage, bone necrosis, and aseptic loosening. These concerns have driven the development of alternative bone cements. We report here on novel modified glass polyalkenoate cements (mGPCs) containing 1, 5 and 15 wt% calcium sulfate (CaSO₄) and how the modified …

Wetting-Driven Formation Of Present-Day Loess Structure, Yanrong Li, Weiwei Zhang, Shengdi He, Adnan Aydin

Faculty and Student Publications

© 2020 The Authors Present-day loess, especially Malan loess formed in Later Quaternary, has a characteristic structure composed of vertically aligned strong units and weak segments. Hypotheses describing how this structure forms inside original loess deposits commonly relate it to wetting-drying process. We tested this causal relationship by conducting unique experiments on synthetic samples of initial loess deposits fabricated by free-fall of loess particles. These samples were subjected to a wetting-drying cycle, and their structural evolutions were documented by close-up photography and CT scanning. Analysis of these records revealed three key stages of structural evolution: initiation (evenly distributed cracks appear …

The Effect Of Carbonate Rock Wettability On The Performance Of Low Salinity Water Flooding: An Experimental Approach, Hildah Nantongo

Chemical and Petroleum Engineering Theses

The performance of low salinity waterflooding (LSWF) in different wettability environment is still unclear for the oil industry. The concessions among researchers are that low salinity does not work in water-wet carbonate oil reservoirs. In this project carbonate core flooding experiments on cores with different wettability’s conditions, including water-wet, oil-wet, and intermediate wettability were performed at reservoir conditions of pressure and temperature. Seawater was selected as a base water and its concentration & composition were modified through dilution and/or spiking with sulfate. The base water was diluted with water 10 and 50 times and spiked with sulfate to 2 and …

Calcium Phosphate/Ionic Liquid Ptfe Composite Membrane For Proton Exchange Membrane Fuel Cell Applications, Ahmad Ibrahim Hasan Ka’Ki

Theses

The dependence on fossil fuels can be possibly reduced by the utilization of renewable energy sources. Fuel cells offer a promising alternative for renewable power generation. Among the various types of fuel cells, Proton Exchange Membrane Fuel Cell (PEMFC) is recently attracting attention due to its several advantages of high-power density, all solid structure, and silent operation. The diverse types of materials used in this type of fuel cell raised drawbacks related to fuel cell cost and durability. By far, Nafion of DuPont is still the current state-of-the-art membrane for PEMFCs. It is known for its high ionic conductivity and …

Growth Of Microalgae For Simultaneous Treatment Of Industrial Wastewater And Biodiesel Production, Mohammed Ahmad Abujayya

Chemical and Petroleum Engineering Theses

The treatment of industrial wastewater contaminated with phenols is among the main challenges in the chemical, and particularly the petrochemical industry. Phenols, which present in considerable amounts in industrial wastewater, are toxic even at low concentrations. Therefore, it is essential to reduce their concentrations in water to harmless levels before being discharged. On the other hand, the dependence on the conventional fossil sources of energy, which is non-renewable, is not sustainable and can cause harmful environmental impacts. Therefore, in this work, the dual utilization of microalgae as a cheap and efficient means to remove phenolic compounds commonly found in refinery …

Modulating Mechanical Properties Of Polymer Composites Via Colloidal Particle Reinforcement, Yusheng Guo

LSU Master's Theses

Additive manufacturing allows the rapid process of complex objects with excellent design flexibility. However, the products often exhibit poor mechanical properties when pure polymer is applied as printable material. In this work, we demonstrate that printability of polymer can be dramatically improved when particle filler is added to form reinforced polymer composites. Furthermore, the interaction between filler and polymer matrix leads to the enhancement in mechanical properties of the printed product. The material reinforcement induced by addition of fillers enables the wide application of polymer composites to print structures with unique features. In the printing of silica-reinforced pNIPAM composite, we …

Using Reactive Dissipative Particle Dynamics To Understand Local Shape Manipulation Of Polymer Vesicles, Qinyu Zhu, Timothy R. Scott, Douglas R. Tree

Faculty Publications

Biological cells have long been of interest to researchers due to their capacity to actively control their shape. Accordingly, there is significant interest in generating simplified synthetic protocells that can alter their shape based on an externally or internally generated stimulus. To date, most progress has been made towards controlling the global shape of a protocell, whereas less is known about generating a local shape change. Here, we seek to better understand the possible mechanisms for producing local morphological changes in a popular protocell system, the block copolymer vesicle. Accordingly, we have combined Dissipative Particle Dynamics (DPD) and the Split …

A Model For The Anodic Carbonization Of Alkaline Polymer Electrolyte Fuel Cells, Qi-Hao Li, Ying-Ming Wang, Hua-Long Ma, Li Xiao, Gong-Wei Wang, Jun-Tao Lu, Lin Zhuang

Journal of Electrochemistry

The alkaline polymer electrolyte fuel cell (APEFC) has made appreciable progress in recent years but is still suffering performance loss during discharge with air as the oxidant. Several theories have been suggested to interpret the loss. However, efforts are still needed to reach a clear quantitative understanding. Based on the major experimental findings in combination with thermodynamics and kinetics of the reactions involved in the anode, this paper presents a model featuring layered carbonization in the anode and relevant grouped equations. The simulation results generated from the latter are compared with experiments, and possible principles to suppress the performance loss …

Facile Synthesis Of Nitrogen-Doped Graphene-Like Active Carbon Materials For High Performance Lithium-Sulfur Battery, Quan-Hua Meng, Wen-Wen Deng, Chang-Ming Li

Journal of Electrochemistry

Lithium-sulphur (Li-S) battery is regarded as a promising energy storage device because of its high theoretical capacity. However, the low S utilization and short cycling life limit the commercial applications. In this work, nitrogen-doped graphene-like carbon (NGC) materials were synthesized by simply pyrolyzing and carbonizing the mixture of melamine (C₃H₆N₆) and L-cysteine (C₃H₇NO₂S). The graphene-like structure in NGC effectively buffered the volume change of S during the discharge/charge process and improved the cycling stability. Meanwhile, nitrogen-containing functional groups in NGC facilitated the transportation of ions and suppressed the …

Mechanisms Of Asymmetric Membrane Formation In Nonsolvent-Induced Phase Separation, Jan Ulric Garcia, Tatsuhiro Iwama, Eva Y. Chan, Douglas R. Tree, Kris T. Delaney, Glenn H. Fredrickson

Faculty Publications

We report the first simulations of nonsolvent-induced phase separation (NIPS) that predict membrane microstructures with graded asymmetric pore size distribution. In NIPS, a polymer solution film is immersed in a nonsolvent bath, enriching the film in nonsolvent, and leading to phase separation that forms a solid polymer-rich membrane matrix and polymer-poor membrane pores. We demonstrate how mass-transfer-induced spinodal decomposition, thermal fluctuations, and glass-transition dynamics—implemented with mobility contrast between the polymer-rich and polymer-poor phases—are essential to the formation of asymmetric membrane microstructures. Specifically, we show that the competition between the propagation of the phase-separation and glass-transition fronts determines the degree of …

Cfd Simulations Of Bubble Column Equipped With Bundles Of Concentric Tubes, Glen C. Dsouza

Electronic Thesis and Dissertation Repository

Bubble column reactors are multiphase contactors that have found several industrial applications owing to various attractive features including excellent thermal management, low maintenance cost due to simple construction and absence of moving parts. In order to attain desired performance for a given application, these reactors are usually equipped with internals such as vertical tube bundles to facilitate heat transfer. The column hydrodynamics and turbulence parameters are altered when the column is occluded with internals which adds to the complexity of the problem. The use of Computational Fluid Dynamics (CFD) tools for the study of multiphase flows has gained a lot …

Experimental And Numerical Study Of Polymorphism In Crystallization Processes, Mengxing Lin

Electronic Thesis and Dissertation Repository

Polymorphism, which is exhibited in more than half of the active pharmaceutical ingredients, has a direct impact on the stability, bioavailability and processability of the product. Despite extensive studies on polymorphism in the field of crystal engineering, the control of polymorphism is still one of the most challenging tasks in pharmaceutical manufacturing.

The aim of this work is to crystallize the desired polymorph with the help of process modeling and process analytical technologies. First, we investigated the crystallization properties of imatinib mesylate, including polymorphism characterization, solubility measurement, polymorphic transformation and kinetic parameter estimation, as they are the fundamental information for …

Mucilage-Capped Silver Nanoparticles For Glucose Electrochemical Sensing And Fuel Cell Applications, Ziad Khalifa, Moustafa Zahran Dr, Magdy Zahran Prof, Magdi Abdel Azzem Prof

Chemical Engineering

A simple, cost-effective and green mucilage-capped silver nanoparticles (Mucilage-AgNPs) modified glassy carbon electrode (GC) composite was constructed for efficient and facile electrochemical oxidation of glucose for the first time. Mucilage-AgNPs were synthesized through the direct chemical reduction of Ag+ by mucilage extracted from Opuntia ficus-indica. Mucilage-AgNPs were identified and characterized using ultraviolet-visible spectroscopy, transmission electron microscopy and square wave voltammetry. Modification of the GC with AgNPs was carried out via a transfer-sticking technique with an immobilization time of 1 h. The Mucilage-AgNPs/GC composite was studied as a possible anode for glucose oxidation in a biofuel cell. The composite resulted in …

Comparison Of Flow Solutions For Naturally Fractured Reservoirs Using Complex Analysis Methods (Cam) And Embedded Discrete Fracture Models (Edfm): Fundamental Design Differences And Improved Scaling Method, Aaditya Khanal, Ruud Weijermars

Jasper Department of Chemical Engineering Faculty Publications and Presentations

The present study compares flow paths in reservoirs with natural fractures, solved with Complex Analysis Methods (CAM), to those solved with Embedded Discrete Fracture Models (EDFM). One aim is to define scaling rules for the strength (flux) of the discrete natural fractures used in CAM models, which was previously theoretically defined based on the expected flow distortion. A major hurdle for quantitative benchmarks of CAM with EDFM results is that each of the two methods accounts for natural fractures with different assumptions and input parameters. For example, EDFM scales the permeability of the natural fractures based on a cubic equation, …

Thermostabilization Of Viruses Via Complex Coacervation, Xue Mi, Whitney C. Blocher Mctigue, Pratik Umesh Joshi, Mallory K. Bunker, Caryn L. Heldt, Sarah L. Perry

Michigan Tech Publications

Widespread vaccine coverage for viral diseases could save the lives of millions of people each year. For viral vaccines to be effective, they must be transported and stored in a narrow temperature range of 2–8 °C. If temperatures are not maintained, the vaccine may lose its potency and would no longer be effective in fighting disease; this is called the cold storage problem. Finding a way to thermally stabilize a virus and end the need to transport and store vaccines at refrigeration temperatures will increase access to life-saving vaccines. We explore the use of polymer-rich complex coacervates to stabilize viruses. …

Modification Of Inuline By Iodic Acid, Rakhmanberdiyev Gappar, Ibragimova Кomila, Аxmedov Оliy

CHEMISTRY AND CHEMICAL ENGINEERING

In order to further modify inulin with drugs, the process of introducing reactive aldehyde groups into the inulin macromolecule was carried out. Aldehyde groups were introduced by oxidizing inulin with iodic acid. The process of oxidation of inulin and cellulose with iodic acid was compared. The quantities of aldehyde groups in the oxidized samples were estimated, their molecular weights were determined, IR spectra were measured, the iodine number of the inulin dialdehyde and their oxidation state were determined.

Synthesis Of 1,2,3-Triazoles Based On Propargyl Ethers Of Carbamate, Djuraev Abdukahhor, Yakubxodjaeva Malika, Ataxodjaeva Matluba, Gaibullaev Oibek

CHEMISTRY AND CHEMICAL ENGINEERING

By the interaction of propargyl esters of carbamate derivatives with phenylazide, 1,2,3- triazole derivatives were synthesized. Their anti-inflammatory activity was subsequently studied.During the study of biological activity, a relationship was established between the anti- inflammatory activity and the chemical structure in the studied series of 1,2,3-triazole derivatives.