Arts and Humanities Commons^™

Experimental And Numerical Investigation Of An Electrospray Rf Ion Funnel, Eric Miguel Tridas

USF Tampa Graduate Theses and Dissertations

Using experimental techniques along with computational fluid dynamics and electrodynamic simulations the performance of the first of three focusing elements in an electrospray macromolecular patterning system was assessed. The performance of this element, the ion funnel, was analyzed by varying the parameters and electric field applied to the system including electrospray emitter to atmosphere-vacuum interface capillary distance, temperature of the desolvating heater, injection rate of solution and the voltage applied to the jet disruption element. Results indicated that processes involved in injecting larger droplets into the chamber resulted in a less effective transmission of the ions through the funnel. Droplet …

Comparative Developmental Transcriptomics Of Echinoderms, Roy Vaughn

USF Tampa Graduate Theses and Dissertations

The gastrula stage represents the point in development at which the three primary germ layers diverge. At this point the gene regulatory networks that specify the germ layers are established and the genes that define the differentiated states of the tissues have begun to be activated. These networks have been well characterized in sea urchins, but not in other echinoderms. Embryos of the brittle star Ophiocoma wendtii share a number of developmental features with sea urchin embryos, including the ingression of mesenchyme cells that give rise to an embryonic skeleton. Notable differences are that no micromeres are formed during cleavage …

An Interactive Guide To Self-Discovery For Women, Elaine J. Taylor

USF Tampa Graduate Theses and Dissertations

This project is a translation of ideas I have encountered in my journey through Women's Studies. With this interactive book, I offer a concise, understandable, and empowering method for self-discovery from one feminist's perspective. Traditional self-help materials often set the reader up as the one with the issue or problem and they rarely call out the functioning systems of oppression as a stumbling block or offer ways to circumvent them. With this project, I hope to shine light on the functioning systems of gender discrimination, racism, classism, and heterosexism, and to provide a framework for understanding. There are three main …

Structure And Agency: An Analysis Of The Impact Of Structure On Group Agents, Elizabeth Kaye Victor

USF Tampa Graduate Theses and Dissertations

Different kinds of collectives help to coordinate between individuals and social groups to solve distribution problems, supply goods and services, and enable individuals to live fulfilling lives. Collectives, as part of the process of socialization, contribute to the normalization of behaviors, and consequently, structure our ability to be self-reflective autonomous agents. Contemporary philosophy of action models characterize collective action as the product of individuals who have the proper motivations to perform cooperative activities (bottom-up); or they begin with the social-level phenomena and explain this in terms of individual actions and the mental states that motivate them (top-down). One general goal …

On The Development Of The Extradosed Bridge Concept, Steven Lynn Stroh

USF Tampa Graduate Theses and Dissertations

The Extradosed Prestressed Bridge represents a relatively new bridge type. The first of this type bridge was constructed in Japan in 1994, and Japan has since built at least 29 examples of this bridge type. Throughout the rest of the world, another 34 of this bridge type have been built, with most countries having only one, or at most a few, examples. A broader application of this bridge type has been hampered by lack of design information and in particular lack design criteria for the stay cables. The purpose of this dissertation is to progress the understanding and application of …

A Head Start To Learning: Exploration Of A Parent-Directed Intervention To Promote Early Literacy Skill Development, Ashley Nicole Sundman-Wheat

USF Tampa Graduate Theses and Dissertations

This study examined the effects of a parent-led intervention focused on developing children's early literacy skills within the home setting. The lesson plans contain scripted steps for completing activities to teach letter names and phonological awareness skills. Archival data were analyzed from a study conducted with 26 families from three Head Start centers. Thirteen families completed the intervention and thirteen families were enrolled in a control condition which provided information on shared reading strategies. Children in the intervention group performed at statistically significant higher levels on measures of letter naming, phonological awareness, vocabulary/oral language, and comprehension. Parents rated both the …

Mapping And Assessing Urban Impervious Areas Using Multiple Endmember Spectral Mixture Analysis: A Case Study In The City Of Tampa, Florida, Fenqing Weng

USF Tampa Graduate Theses and Dissertations

The advance in remote sensing technology helps people more easily assess urban growth. In this study, the utility of multiple endmember spectral mixture analysis (MESMA) is examined in a sub-pixel analysis of Landsat Thematic Mapper (TM) imagery to map urban physical components in Tampa, FL. The three physical components of urban land cover (LC): impervious surface, vegetation and soil, were compared using the proposed MESMA with a traditional spectral mixture analysis (SMA). MESMA decomposes each pixel to address the heterogeneity of urban LC characteristic by allowing the number and types of endmembers to vary on a per pixel basis. This …

Shelf-Scale Mapping Of Fish Distribution Using Active And Passive Acoustics, Carrie Christy Wall

USF Tampa Graduate Theses and Dissertations

Fish sound production has been associated with courtship and spawning behavior. Acoustic recordings of fish sounds can be used to identify distribution and behavior. Passive acoustic monitoring (PAM) can record large amounts of acoustic data in a specific area for days to years. These data can be collected in remote locations under potentially unsafe seas throughout a 24-hour period providing datasets unattainable using observer-based methods. However, the instruments must withstand the caustic ocean environment and be retrieved to obtain the recorded data. This can prove difficult due to the risk of PAMs being lost, stolen or damaged, especially in highly …

Something Is Askew In Florida's Water: Arguing For A Better Descriptive Statistic For Positively Skewed Water-Quality Data, Amie October West

USF Tampa Graduate Theses and Dissertations

ABSTRACT

It may be of no surprise that water quality data is right-skewed, but what appears to be overlooked by some is that the arithmetic mean and standard deviation most often fail as measures of central tendency in skewed data. When using the arithmetic mean and arithmetic standard deviation with nutrient data, one standard deviation about the arithmetic mean can capture nearly all of the data and extend into negative values. Representing nutrient data this way can be misleading to viewers who are using the statistics, and making assumptions, to understand the characteristics of those waters. Through an in-depth statistical …

Competing Narratives: Hero And Ptsd Stories Told By Male Veterans Returning Home, Adam Gregory Woolf

USF Tampa Graduate Theses and Dissertations

This qualitative study seeks to extend the existing body of scholarly literature on returned veteran civilian reintegration by exploring "hero" and "Post-Traumatic Stress Disorder" narratives. The character of the hero, as a social construct located within hegemonic notions of masculinity, is widely portrayed and believed to possess highly prized, extraordinary, almost superhuman personal qualities. However, this widely disseminated belief stands at odds with some of the stories returned veterans tell. This qualitative study explores and illuminates the enigmatic intersectionality of hero and PTSD narratives.

Extant hero and PTSD narratives contain paradoxical implicit meanings embedded within them. The hero is understood …

Sea Surface Height: A Versatile Climate Variable For Investigations Of Decadal Change, Philip Robert Thompson

USF Tampa Graduate Theses and Dissertations

Decadal variations in climate are important, because the magnitude of sustained decadal change is often much larger than the often discussed background trends. Climate variability at interannual and longer periods is most often discussed in the context of climate modes defined by sea level pressure (SLP) and sea surface temperature (SST) patterns. However, SLP and SST are not capable descriptors of ocean dynamics. The approximately two decades of global sea surface height (SSH) measurements from satellite altimetry reveal substantial low-frequency redistributions of heat and salt in the ocean, which may or may not be related to defined climate modes. In …

Molecular Dynamics Of The Rna Binding Cavity Of Influenza A Non-Structural Protein 1 (Ns1) Rna Binding Domain, Christi Leigh Whittington

USF Tampa Graduate Theses and Dissertations

Molecular dynamics simulations were performed on the influenza A non-structural protein 1 (NS1) RNA binding domain (RBD), a homodimer. Fourteen simulations were performed at 298K, nine ionized with 0.1M KCl and five with no ions. Several analysis techniques were employed to study RBD residue flexibility. The focus of the study was the RNA binding cavity formed by side chains of helix 2 (chain A) and helix 2’ (chain B) and cavity intermonomeric salt bridges. Opening of the salt bridges D29–R46’ and D29’–R46 was observed in several of the trajectories. The RNA binding cavity has large flexibility, where the dimension and …

Moral Friction, Moral Phenomenology, And The Improviser, Benjamin Scott Young

USF Tampa Graduate Theses and Dissertations

This dissertation offers a phenomenology of that mode of self-interpretation in which it becomes possible for an interpreter to intentionally participate in the production of moral norms to which the interpreter himself or herself feels bound. Part One draws on Richard Rorty's notion of the "ironist" in order to thematize the phenomenon I call "moral friction"; a condition in which an interpreter becomes explicitly aware of the historical and cultural contingencies of their own moral vocabularies, practices, and concerns and as a result find themselves incapable of feeling the normative weight implicit in these. Part Two draws on Heidegger's existential …

Integrable Couplings Of The Kaup-Newell Soliton Hierarchy, Mengshu Zhang

USF Tampa Graduate Theses and Dissertations

By enlarging the spatial and temporal spectral problems within a certain Lie algebra, a hierarchy of integrable couplings of the Kaup-Newell soliton equations is constructed. The recursion operator of the resulting hierarchy of integrable couplings is explicitly computed. The integrability of the new coupling hierarchy is exhibited by showing the existence of infinitely many commuting symmetries.

Selling The Third Wave: The Commodification And Consumption Of The Flat Track Roller Girl, Mary Catherine Whitlock

USF Tampa Graduate Theses and Dissertations

In an ethnographic examination of the "modern" roller derby movement that began in the early 2000s, I explore Women's Flat Track Derby in Florida. What does it mean to be a roller derby player? How is she conceptualized and commodified? Or more centrally, how is third wave feminism used as a catalyst of this commodification? In order to fully appreciate, understand, and even embrace roller derby, I look at roller derby leagues as social movement organizations (SMOs) in order to note how they frame themselves and maintain collective identity the commodification of third wave feminism. First, I will explore various …

Catalytic Tri-Reforming Of Biomass-Derived Syngas To Produce Desired H2:Co Ratios For Fuel Applications, Devin Mason Walker

USF Tampa Graduate Theses and Dissertations

This study focuses on upgrading biomass derived syngas for the synthesis of liquid fuels using Fischer-Tropsch synthesis (FTS). The process includes novel gasification of biomass via a tri-reforming process which involves a synergetic combination of CO2 reforming, steam reforming, and partial oxidation of methane. Typical biomass-derived syngas H2:CO is 1:1 and contains tars that deactivate FT catalyst. This innovation allows for cost-effective one-step production of syngas in the required H2:CO of 2:1 with reduction of tars for use in the FTS. To maximize the performance of the tri-reforming catalyst, an attempt to control oxygen mobility, thermal stability, dispersion of metal, …

Stochastic Modeling Of Network-Centric Epidemiological Processes, Divine Wanduku

USF Tampa Graduate Theses and Dissertations

The technological changes and educational expansion have created the heterogeneity in the human species. Clearly, this heterogeneity generates a structure in the population

dynamics, namely: citizen, permanent resident, visitor, and etc. Furthermore, as the heterogeneity in the population increases, the human mobility between meta-populations patches

also increases. Depending on spatial scales, a meta-population patch can be decomposed into sub-patches, for examples: homes, neighborhoods, towns, etc. The dynamics of human

mobility in a heterogeneous and scaled structured population is still its infancy level. We develop and investigate (1) an algorithmic two scale human mobility dynamic model for a meta-population. Moreover,the two …

Evaluation Of Repeated Biomarkers: Non-Parametric Comparison Of Areas Under The Receiver Operating Curve Between Correlated Groups Using An Optimal Weighting Scheme, Ping Xu

USF Tampa Graduate Theses and Dissertations

Receiver Operating Characteristic (ROC) curves are often used to evaluate the prognostic performance of a continuous biomarker. In a previous research, a non-parametric ROC approach was introduced to compare two biomarkers with repeated measurements. An asymptotically normal statistic, which contains the subject-specific weights, was developed to estimate the areas under the ROC curve of biomarkers. Although two weighting schemes were suggested to be optimal when the within subject correlation is 1 or 0 by the previous study, the universal optimal weight was not determined. We modify this asymptotical statistic to compare AUCs between two correlated groups and propose a solution …

Asymmetric Intra- And Intermolecular Cyclopropanation By Co(Ii)- Based Metalloradical Catalysis, Xue Xu

USF Tampa Graduate Theses and Dissertations

Metal-catalyzed cyclopropanation of olefins with diazo reagents has attracted research interest because of its fundamental and practical importance. The resulting cyclopropyl units are recurrent motifs in biologically important molecules and can serve as versatile precursors in organic synthesis. Since they were first introduced in 2004, Co(II) complexes of D₂-symmetric chiral amidoporphyrins [Co(D₂-Por*)] have emerged as a new class of catalysts for asymmetric cyclopropanation. These metalloradical catalysts have been shown to be highly effective for asymmetric intermolecular cyclopropanation of a broad scope of substrates with different classes of carbene sources, particularly including electron-deficient olefins and acceptor/acceptor-substituted …

Smart Packaging: A Novel Technique For Localized Drug Delivery For Ovarian Cancer, Eva Christabel Williams

USF Tampa Graduate Theses and Dissertations

Localized drug delivery is emerging as an effective technique due to its ability to administer therapeutic concentrations and controlled release of drugs to cancer sites in the body. It also prevents the contact of harsh chemotherapy drugs to healthy regions in the body that otherwise would become exposed to current treatments.

This study reports on a model chemotherapy drug delivery system comprising non-ionic surfactant vesicles (niosomes) packaged within a temperature-sensitive chitosan network. This smart packaging, or package-within-a package system, provides two distinct advantages. First, the gel prevents circulation of the niosomes and maintains delivery in the vicinity of a tumor. …

Effects Of Random Cross-Sectioned Distributions, Fiber Misalignment And Interphases In Three-Dimensional Composite Models On Transverse Shear Modulus, Jarrett Zitko

USF Tampa Graduate Theses and Dissertations

Finite element analysis was implemented to evaluate the transverse shear modulus of a unidirectional glass/epoxy fiber-matrix composite based on pure shear displacement boundary conditions. Unit cells consisting of three-dimensional glass cylinders surrounded in square-cuboid epoxy matrices were modeled to represent "Representative Volume Element" (RVE) configurations in periodic and random-periodic square cell arrangements of variable size. Three RVEs were constructed and analyzed: A single unit cell, a 9-cell (3 x 3) array, and a 25-cell (5 x 5) array. Additionally, the unit cell was modeled to include an interphase. Three sets of cell arrangements were constructed and evaluated: a periodic square …

Synthesis And Physical Properties Of Group 14 Intermetallic Clathrates, Stevce Stefanoski

USF Tampa Graduate Theses and Dissertations

The search of materials relevant for thermoelectric and magnetocaloric applications, as well as materials that interact with light, is an important aspect of the materials science. Such materials can be used for solid-state power generation and refrigeration, as light sources, detectors, or controllers. Intermetallic clathrates have long been of interest for the materials science research. The promise these materials hold for useful applications ranges from thermoelectrics to photovoltaics and optoelectronics to potentially ultra-hard materials and magnetic cooling applications. Their unique physical properties are intimately related to their intriguing structural properties. Thus a fundamental understanding of the chemistry and physics of …

Resisting Criminalization Through Moses House: An Engaged Ethnography, Lance Arney

USF Tampa Graduate Theses and Dissertations

Neoliberal restructuring of the state has had destructive effects on families and children living in urban poverty, compelling them to adapt to the loss of social welfare and demolition of the public sphere by submitting to new forms of surveillance and disciplining of their individual behavior. A carceral-welfare state apparatus now confines and controls the bodies of expendable laborers in urban spaces, containing their threat to the neoliberal socioeconomic order through criminalization and workfare assistance, resulting in a new symbiosis of prison and ghetto. The resulting structures of punishment, police surveillance, and criminalization primarily surround African Americans living in high …

Can You Believe She Did That?!:Breaking The Codes Of "Good" Mothering In 1970s Horror Films, Jessica Michelle Collard

USF Tampa Graduate Theses and Dissertations

The threats found in horror films change with time, each decade consisting of threats that were most frightening for the time period. Horror film scholars, such as Andrew Tudor, determined that in 1970s horror films the threat has migrated from external forces into the home and the family. Invading aliens and monsters were thrown replaced by psychosis and evil children. This notion of making the familiar unfamiliar and threatening is paralleled in concerns addressed during the second-wave of feminism; women were making the normative and familiar idea of mother unfamiliar as they migrated from the private and into the public …

Talking About Talk: The Problem Of Communication As An Object Of Study In Public Participation Research, Lauren Leigh Cutlip

USF Tampa Graduate Theses and Dissertations

When citizens participate in risk assessment and decision-making for environmental and other issues that affect members of the public, more robust decisions may be made. Public participation in policy decisions is not only more democratic, but it also enables members of the public to contribute valuable expertise to the decision-making process. However, the development of an effective forum for such participatory projects has been difficult. Participation mechanisms that foster dialogue and interactive exchange between participants have been regarded as the most beneficial, but the practical application of these mechanisms has been observed to be problematic. The goal of this study …

The Mediating Role Of Regulatory Focus In The Relationship Between Transformational/Transactional Leadership And Follower Work Outcomes, Erin J. Walker

USF Tampa Graduate Theses and Dissertations

The purpose of this research was to integrate the areas of leadership and motivation by examining how leaders' behaviors affect their followers' regulatory foci. Specifically, a separate laboratory experiment and field survey were conducted to determine whether leader transformational and transactional behaviors shape followers' work-based promotion and prevention regulatory foci, which in turn affect followers' outcomes at work. Overall, there was limited evidence that inspirational motivation and contingent reward leader behaviors were related to follower work-based regulatory focus, and work-based regulatory focus was related to several work-related outcomes. The moderating role of chronic regulatory focus on the relationship between leader …

Paleo-Indian To Spanish Occupation Around Choctawhatchee Bay, Northwest Florida, As Documented In A Private Artifact Collection, Deena Woodward

USF Tampa Graduate Theses and Dissertations

This project documents and analyzes a substantial private collection of artifacts from archaeological sites around Choctawhatchee Bay, northwest Florida. The goals are to determine what the materials can contribute to the archaeological record, how they enhance our knowledge of the people who lived there over the past 2000 years, and how this information can be used to expand or contradict models of prehistoric lifeways in this region. This is done by comparing artifact assemblages, looking at site distribution patterns, and using pXRF trace-element analysis to compare Late Archaic clay objects with those from elsewhere along the Gulf.

Examination of the …

Lower Sacraments: Theological Eating In The Fiction Of C. S. Lewis, Gregory Philip Hartley

USF Tampa Graduate Theses and Dissertations

For years, critics and fans of C. S. Lewis have noted his curious attentiveness to descriptions of food and scenes of eating. Some attempts have been made to interpret Lewis's use of food, but never in a manner comprehensively unifying Lewis's culinary expressions with his own thought and beliefs. My study seeks to fill this void. The introduction demonstrates how Lewis's culinary language aggregates through elements of his life, his literary background, and his Judeo-Christian worldview. Using the grammar of his own culinary language, I examine Lewis's fiction for patterns found within his meals and analyze these patterns for theological …

Painting Puertorriqueñidad: The Jíbaro As A Symbol Of Creole Nationalism In Puerto Rican Art Before And After 1898, Jeffrey L. Boe

USF Tampa Graduate Theses and Dissertations

In the three decades surrounding the Spanish-American war (1880-1910), three prominent Puerto Rican artists, Francisco Oller (1833-1917), Manuel E. Jordan (1853-1919), and Ramón Frade (1875-1954) created a group of paintings depicting "el jíbaro," the rural Puerto Rican farm worker, in a way that can be appropriately labeled "nationalistic." Using a set of motifs involving clothes, customs, domestic architecture and agricultural practices unique to rural Puerto Rico, they contributed to the imagination of a communal identity for creoles at the turn of the century. ("Creole" here refers to individuals of Spanish heritage, born on the island of Puerto Rico.) …

Stable Isotope Analysis Of Busycon Sinistrum To Determine Fort Walton-Period Seasonality At St. Joseph Bay, Northwest Florida, Ryan Michael Harke

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Recent archaeological investigations indicate that coastal Fort Walton cultures in the St. Joseph Bay region of northwest Florida emphasized marine and estuarine foraging. These late prehistoric (A.D. 1000-1500) peoples collected fish, shellfish, and other aquatic resources. At the Richardson's Hammock site (8Gu10), radiocarbon-dated to about A.D. 1300, as at dozens of other shell middens around this salty bay, large gastropods were a major subsistence component. This adaptation is in sharp contrast with that of contemporaneous inland Fort Walton societies, who relied on maize agriculture. It is unknown whether coastal groups represent separate hunter-gatherer-fisher populations or seasonal migrations by inland …