Digital Commons Network^™

Development And Photophysical Characterization Of Bioinspired Materials, Qaisar Maqbool

USF Tampa Graduate Theses and Dissertations

Porphyrins are versatile aromatic macrocycles with unique photophysical properties that make them attractive for applications in light harvesting, photocatalysis, and sustainable energy conversion. Incorporating porphyrins into metal-organic frameworks (MOFs) offers a unique opportunity to modulate their photophysical behavior through spatial confinement and host–guest interactions. This thesis explores how structural modifications influence porphyrin excited-state behavior through a multi-stage investigation. The work begins by comparing the photophysical properties of two cationic porphyrins: tetra(N-methylpyridyl) porphyrin(TMPyP) and tetra(4-N,N,N-trimethylanilinium) porphyrin(4TANP). While TMPyP exhibits significant singlet–charge transfer (S₁–CT) state mixing due to charge delocalization onto peripheral pyridinium groups, 4TANP lacks comparable behavior. The localized nature of …

Evaluating The Protective Role Of Epo-R76e In Oxidative Stress-Induced Cell Death In Retinal Pigment Epithelium, Jemima Alam

USF Tampa Graduate Theses and Dissertations

Age-Related Macular Degeneration (AMD) causes dysfunction and loss of Retinal pigment epithelium (RPE). The degeneration and death of RPE cells causes irreversible visual impairment. Oxidative stress is a widely accepted triggering factor for RPE dysfunction. A hormone called Erythropoietin (EPO) is responsible to facilitate the erythropoiesis process, prevents progenitor cells from apoptosis and protects photoreceptors downregulating retinal degeneration. In this study, we aim to elucidate the role of EPO in downregulating oxidative stress in RPE. It is hypothesized that EPO will have a positive impact on suppressing oxidative stress and ferroptosis-mediated RPE degeneration due to its vital role in apoptosis …

Topics In Knot, Quandle, And Quiver Theory, Brooke Jones

USF Tampa Graduate Theses and Dissertations

This dissertation explores the algebraic and combinatorial structures arising from the study of knot theory through the lens of quandles, their colorings, and associated quiver and ring constructions. It is organized around three central themes: the analysis of quandle coloring quivers for torus links, the development of polynomial invariants and quiver invariants for stuck knots and links, and the algebraic and graphical study of quandle rings. The first chapter begins with an introduction to relevant concepts throughout the dissertation.

In the second chapter, we classify quandle coloring quivers of torus links using dihedral quandles. We describe these quivers as weighted …

Integrative Multi-Omics And Clinical Data Analysis For Predicting Recurrence And Survival In Uterine Cancer, Varun Sai Raigir

USF Tampa Graduate Theses and Dissertations

The prediction of uterine cancer recurrence is very important for assisting women in reducing the cancer risks and also for the growing field of personalized medicine. The primary aim of this thesis is to investigate the integration of various omics data alongside clinical and therapeutic information to predict survival in uterine cancer. The combination is very important for understanding the risk factors, including clinical aspects, genetics, and the treatment schedule, in order to prescribe the appropriate way to reduce the risk of recurrence, make clinical interactions easier, and enhance personalized patient care. This study utilizes the publicly accessible TCGA dataset, …

Volatile Organic Compound (Voc) Sensing Trend Among Novel 2d/3d Materials, Mohammad Shakhawat Hossain

USF Tampa Graduate Theses and Dissertations

Volatile Organic Compounds (VOCs) present significant health risks to both humans and animals. Long term exposure to certain VOCs belonging to certain chemical classes can cause both short- and long-term effects including nausea, damage to the central nervous system, and cancer. VOCs can be found in various everyday products like varnishes, paints, cooking items, cleaning products, nail polishes etc. Because of their ubiquitous nature, health concerns and risks regarding VOC exposure have become even more pressing. In this study, the VOC sensing capabilities and trends of novel 2D, and 3D materials (perovskite, and phthalocyanines) have been explored through electrochemical and …

Automated Data Analysis For Concussion Patient Records: A Flutter-Based Desktop Application, Fhaheem Tadamarry

USF Tampa Graduate Theses and Dissertations

Concussions are a prevalent and complex medical condition requiring careful clinical assessment and data-driven insights for effective management. This thesis presents the development of an automated data analysis system for concussion patient records, integrating Flutter-based desktop application development with SQL-driven data processing. The system provides a streamlined, interactive interface for clincians and researchers to upload, visualize, and analyze patient data efficiently.

The proposed solution automates data cleaning, preprocessing, and statistical analysis, ensuring robust and reliable insights into demographic, clinical, and recovery-related factors. Key analyses include sex-based differences injury mechanisms, prior head injury impact, mood disorder correlations, and time-to-treatment variations. The …

Understanding The Interplay Between Nutritional Status And Depression Among Community-Dwelling Older Adults, Mary R. Goldsworthy

USF Tampa Graduate Theses and Dissertations

By the year 2050, it is projected that the population of individuals aged 60 years and older will increase by 47 percent, reaching a total of 82 million in the United States. Many older adults experience depressive symptoms, and some never recover from it. Depression is one of the most common psychiatric disorders among older adults. Approximately 3.2% of community-dwelling older adults experience major depressive disorder in a 12-month period, although many more experience clinically significant depressive symptoms, with a recent estimate of 35% based on a global meta-analysis. In addition to physical functioning and depressive symptoms, another domain in …

Dnajb6: A Potent Dnajb Chaperone In Regulating Tau Proteostasis, Abigail R. Esquivel

USF Tampa Graduate Theses and Dissertations

Neurodegenerative diseases often feature the pathological buildup of misfolded proteins, and tau is a principal culprit in multiple tauopathies. One chaperone of emerging interest is DnaJB6b, a member of the Hsp40/DnaJ family, which exhibits potent anti-aggregation activity against several disease-related proteins. Recent investigations highlight its unique capacity to recognize and neutralize aggregation-prone forms of tau. DnaJB6b appears potent against multiple variants of tau and may be acting against tau, in part, by directing misfolded tau toward proteasomal clearance. The first lines of evidence come from systematic chaperone screens, where DnaJB6b repeatedly emerged as a strong suppressor of tau seeding. Further …

Exploring Corona Discharge In Electrostatic Printing For Electronics And In Other Application, Zijian Weng

USF Tampa Graduate Theses and Dissertations

The field of printed electronics (PEs) is expanding rapidly, driven by increasing market demand. According to reports, the global market for PEs is expected to reach $23 billion by 2026, with a compound annual growth rate of 18.3% from 2023 to 2028. This growth necessitates the development of innovative printing technologies that can meet these demands efficiently, delivering high-quality, high-resolution PEs suitable for applications in health, environmental monitoring, sports, aerospace, and more.

Currently, PEs manufacturing relies on two main groups of printing technologies. Contact printing methods offer high-speed production but struggle with precision, while non-contact methods provide high resolution but …

The Prideful Ass: Using Augustine's Neoplatonic Theory Of Sin To Investigate Curiosity In Apuleius' Golden Ass, Danielle E. Booth

USF Tampa Graduate Theses and Dissertations

Ancient discourse about the beneficial yet predominantly dangerous role of curiosity inattaining knowledge was prevalent in the Roman Empire around the 2nd century C.E. when the North African author, Apuleius, composed his Latin novel, the Golden Ass. Although there is no shortage of modern scholarship that focuses on how Apuleius dramatizes obsessive intrigue by means of his protagonist, Lucius, contemporary publications seldom reorient the discussion to consider how unclear he is about the unstated source of curiosity, as I do in the following thesis. Approaching this topic through the context of ancient Neoplatonism, I argue Augustine of Hippo – a …

Awful, Yet Awe-Full: The Sublime Dystopia Of Blade Runner 2049, Charles E. Butt

USF Tampa Graduate Theses and Dissertations

Blockbuster dystopian sci-fi features stories of environmental collapse, authoritarian governments, out of control corporations, unbounded consumerism, and other awful possibilities. Scholars of science fiction broadly agree that this genre explores collective fears, anxieties, and speculations about the present and future. At the same time, film scholars have established that dystopian sci-fi cinema is compelling, and audiences respond to their effects-driven visuals, photorealistic mise-en-scene, and dramatic narratives. This creates an apparent paradox: Blockbuster cinematic aesthetics portray undesirable worlds desirably. I resolve this paradox by arguing that the worldbuilding of spectacle-driven, dystopian sci-fi cinema is Romanticized. That is, the provocative style of …

Murine Studies On Ketogenic Modulation Of Metabolism And Epigenetics In Olfaction- Based Learning, Lps Inflammatory Response, And Sex Dimorphisms In Dietary Response, Sara E. H. Moss

USF Tampa Graduate Theses and Dissertations

Ketogenic diets are well-established therapeutic interventions for epilepsy, with documented neuroprotective effects arising from their metabolic, antioxidant and anti-inflammatory properties. Beyond epilepsy, ketogenic therapies are under investigation for various conditions including Alzheimer disease, cancer, diabetes, and cardiovascular disease. These diets suppress insulin levels and shift metabolic physiology toward fat and ketone body metabolism. This elevates circulating levels of ketone bodies, namely beta-hydroxybutyrate, acetoacetate, and acetone, which serve as both energy substrates and signaling molecules. The state of elevated ketone bodies (ketosis) can be achieved with various formulations of a ketogenic diet as well as exogenous ketone supplementation, though the signaling …

Navigating The College-To-Career Transition: Social Capital And Career Readiness Of First-Generation College Students Participating In The Professional Skills Mentoring Program, Olivia T. Davis

USF Tampa Graduate Theses and Dissertations

This study investigates how first-generation college (FGC) students utilize social capital to navigate the challenging transition from college to career, addressing a critical gap in the literature given the increasing emphasis on post-graduation employment and the unique obstacles these students face. FGC students often lack the same access to professional networks and career resources as their peers, highlighting the need for targeted support programs. This research explores the impact of the Professional Skills Mentoring Program (PSMP) on FGC student career readiness.

Drawing on Yosso's (2005) Community Cultural Wealth framework, this qualitative case study examines how FGC students leverage their diverse …

Mindfulness In Action: A Critical Reflective Self-Study Exploring Mindfulness, Goal Attainment, And The Adult Learning And Development Experience, Michelle Yvette Catlin

USF Tampa Graduate Theses and Dissertations

Through a Critical Reflective Self-Study, this dissertation explores adult learning and development with a focus on the psychological construct of mindfulness and its role in goal attainment. The self-study places me as the subject and centers on my reflections, insights, and lessons learned through my doctoral professional development journey at a large public research university. My experience began with a research focus on mindfulness and mindfulness training for cognitive performance and adult learning and development, and later in my doctoral program, I gained further insight into the facilitation of goal attainment when I studied, practiced, and worked in university student …

Barriers To Engagement Of Care For Patients Presenting With Comorbid Human Immunodeficiency Virus (Hiv) And Major Depression Or Anxiety Disorder Diagnoses, Rachel C. V. Kingsley

USF Tampa Graduate Theses and Dissertations

Despite significant global advancements in HIV care, engagement in continuous HIV care remains a challenge, particularly for individuals living with comorbid HIV and mental health disorders. This dissertation examines the barriers to continuous HIV care for those individuals living with comorbid HIV and depression and/or anxiety in the Tampa Bay area. This dissertation argues that dual health challenges are dually challenging. This study highlights how structural vulnerabilities, how feelings of inclusion and exclusion impact engagement in care, and socioeconomic challenges intersect to shape patient experiences and impact adherence to treatment. Drawing on critical medical anthropology, structural violence, embodied belonging, and …

Fractional Calculus Approach For Learning Unknown Dynamic System, Haowei(Alice) Chen

USF Tampa Graduate Theses and Dissertations

The rapidly growing interest in data-driven modeling and fractional-order systems highlights a keychallenge in modern science and engineering: capturing long-memory effects and nonlinear behaviors in real-world dynamical processes. Conventional integer-order methods, while powerful, often overlook the history-dependent nature of many phenomena—ranging from viscoelastic materials to anomalous diffusion and hereditary feedback systems. This dissertation addresses that gap by blending fractional calculus with cutting-edge machine learning to create robust, memory-aware modeling and control frameworks.

Beginning with an extension of Dynamic Mode Decomposition (DMD) to fractional-order systems, we introduce Fractional Dynamic Mode Decomposition (F-DMD) as a data-driven tool that leverages Mittag- Leffler functions …

Modeling The Pollution From Latrines In A Low- And Middle-Income Country Setting, Christopher Nenninger

USF Tampa Graduate Theses and Dissertations

Latrines are an important sanitation infrastructure that are critical to the United Nations’ effort to end open defecation and achieve the target regarding safely managed sanitation outlined in Sustainable Development Goal #6. This global effort has led to 40,000,000 new users being introduced to improved latrines each year, and this number is expected to increase as the world’s population grows. One of the drawbacks related to these new latrine additions is the potential increase in pollution from hydraulically connected latrine pits to shallow groundwater. This is especially problematic in low- and middle-income countries (LMICs), where communities are more likely to …

Springscape: The Nature Coast And The Making Of Modern Florida, 1820s-Present, Douglas E. Ponticos

USF Tampa Graduate Theses and Dissertations

According to an oft-repeated tale, the Florida we know today emerged as a dreamscape of tourism, retirement, and suburbanization during the second half of the twentieth century. Growth victimized nature. This dissertation deeply unsettles that story. The history of the Nature Coast exposes not just nature’s agency but its primacy in the development of modern Florida.

Using surveys, maps, census data, personal correspondence, government documents, business records, timber reports, advertising materials, and hydrological research, this dissertation follows time and water across landscapes, into the Upper Floridan Aquifer, and back out again. Each chapter explores a single landscape within the Nature …

“I Learned A Lot Of Things That I Felt Already In My Heart”: Fatherhood Meanings And Dilemmas In Residential Treatment, Jared V. Worwood

USF Tampa Graduate Theses and Dissertations

Wanting to maintain or create a connection with their child, fathers in residential treatment face challenges as they navigate physical separation, restricted interaction, and substance use stigma. However, parenting services that help fathers navigate these parenting challenges in residential programs are few and rarely studied. Working alongside a local parenting non-profit, Champions for Children, this dissertation evaluated a visitation playgroup for fathers in residential treatment and their children while also seeking theoretical insight into how fathers make meaning of fatherhood during residential treatment. A study design informed by engaged communication scholarship and the phronetic, iterative approach is used to collect …

The Kinematics And Aerodynamics Of Freely Flying Tiny Insects, Evan J. Williams

USF Tampa Graduate Theses and Dissertations

Tiny insects are an extremely diverse set of organisms that have important engineering and economic applications. These organisms often fly and readily disperse distances that far exceed their body lengths. The mechanisms behind tiny insect flight are not well understood and present complex kinematics and unintuitive aerodynamics that depart from both fixed-winged mechanisms and larger insects. In addition, their tiny spatial and fast temporal scales make them exceedingly difficult to study, and to date, the field has relied on numerical studies and dynamic scaling. Herein, we describe three projects that significantly advanced our understanding of tiny insect flight and experimental …

An Exploration Of The Experiences Of Perinatal Depression And Anxiety Among Pregnant And Parenting Adolescents In The Tampa Bay Area Of Florida, Olajumoke Adetoun Ojeleye

USF Tampa Graduate Theses and Dissertations

Perinatal depression (PND) and perinatal anxiety (PNA) are increasing among pregnant and parenting adolescents (PPAs), with PNA often underrecognized. This leads to significant socioeconomic costs and adverse maternal consequences if untreated. Hence, this dissertation explores the experiences of PND and PNA among PPAs, focusing on their knowledge gaps, perception, mental health needs, care preferences, and access to PMH care. The research employs a qualitative design (free-listing and in-depth interviews) to gather participant insights. Key findings reveal that many PPAs possess limited knowledge about PNA when compared to PND. Lack of support from partners, family, and peers emerged as the topmost …

Development Of S(Vi) And S(Iv) Chemistry: From Asymmetric Synthesis To Covalent Reactive Groups, Chuan Shan

USF Tampa Graduate Theses and Dissertations

This dissertation mainly covers the development of synthetic methodologies related to several heteroatom functional groups, including phosphonates P(V), sulfoximines S(VI), sulfonimidamides S(VI), sulfonimidoyl fluorides S(VI), and sulfinamides S(IV). The interests in these functionalities are not only out of chemistry curiosity but also due to their pharmaceutical importance indicated by the existing drug molecules that contain these functional groups. The first chapter introduced the importance of phosphonates in biochemistry and organic synthesis, also provided some essential background of our synthetic efforts. The second chapter described the phosphonate synthesis from commercially available starting materials, with the purpose to obtain heterocyclic phosphonates in …

Respiratory Muscle Strength Training For Persistent Dyspnea In Individuals With Post-Covid-19, Sandra P. Morgan

USF Tampa Graduate Theses and Dissertations

Severe acute respiratory syndrome 2 coronavirus has resulted in more than 775 million known cases and greater than seven million deaths globally. Up to 25% of patients experience ongoing symptoms three months after the acute illness, and up to 30% of these individuals report persistent dyspnea. The overall aims of this dissertation are to 1) examine the risk factors and predictors for developing persistent dyspnea, 2) measure the effects of respiratory muscle strength training on dyspnea, pulmonary symptoms, quality of life, pulmonary function, and functional capacity, and 3) compare the outcomes of two different respiratory muscle strength training interventions.

In …

“Smart Trap”: A Portable Device For Real-Time Mosquito Capturing And Classification Using Image-Based Analysis, Fahim Rahman

USF Tampa Graduate Theses and Dissertations

Capturing mosquitoes in real-time and taking high-quality images for classification with state-of-the-art methods is not only time-consuming but also expensive. Sometimes even carefully controlled environments and experimental setups fail to capture living mosquitoes. Catching live mosquitoes is necessary to be able to study aspects of their physiology and behavior that cannot be investigated by collections of resting mosquitoes and dead specimens, and to help estimate the local population numbers. My thesis introduces a “Smart Trap”, a small portable device that can attract mosquitoes in real-time, capture them, take high-quality images with dual cameras, and store those images in the cloud. …

Vietnam Syndrome And The Genetic Consequences Of Agent Orange Poisoning: A Materialist Approach, Moriah M. Haley

USF Tampa Graduate Theses and Dissertations

The aim of this thesis was to propose and apply a materialist approach to “Vietnam Syndrome” found at the intersection of masculinity, disability, and state power as it manifests in modern military strategy. Through an analysis of the physical veteran body rendered infertile from Agent Orange poisoning during the Vietnam War, the material conditions of infertility are found to have threatened the hegemonic masculinity on which the military relied for its justification and continuation amongst young American men. The turn to technological warfare was intended to remedy the insufficiency of the military body, but the solution was costly and ineffective …

Protracting The Immediate: Time As Form In Contemporary Horror, Kennedy Kelley

USF Tampa Graduate Theses and Dissertations

This thesis examines the expression and experience of temporality in horror films of the last decade. Whereas early twenty-first century horror was characterized by high-octane jump scares, current horror is marked by contemplative slowness. I argue that the elongated duration of recent horror extends an experience of indeterminate anxiety that attunes us to an expansive relationality, offering a corrective not only to contemporary logics of immediacy, but also to the frequently constricting nature of embodiment as a theoretical concept. Recent horror scholarship tends to center sensuous propinquity in response to a long history of gaze theory’s disembodied passivity. While these …

The Manosphere’S Reception Of The Women Auteurs Behind The ‘Man-Eating’ Jennifer’S Body (2009) And ‘Man-Hating’ Barbie (2023), Hilda Sheridan-Hewlett

USF Tampa Graduate Theses and Dissertations

Scholarship on women filmmakers has not significantly emphasized the burden women auteurs carry when bracing themselves for the reception from misogynistic community discourse online, the manosphere. Director Greta Gerwig and screenwriter Diablo Cody are not simply perceived as filmmakers but as birth mothers of their work: Barbie (2023) and Jennifer’s Body (2009) which convey inherently popular feminist narratives. I argue Cody and Gerwig faced the wrath of the men online because they are inextricably linked to their productions, the feminization of their work in the eyes of the manosphere equals personalization. Despite Cody having the freedom to write any film …

Predicting Freshwater Spring Distribution Using Maxent Modeling: A Case Study In Groundwater Management Area 9 (Gma-9), Texas, Zayed Mallick

USF Tampa Graduate Theses and Dissertations

Freshwater springs are one of the most vital groundwater sources and they have been a reliable water source for mining, irrigation, drinking, and farming, particularly in hot and arid regions like Groundwater Management Area-9 (GMA-9), Texas. However, excessive groundwater extraction, climate change, and environmental degradation have created tremendous stress on the sustainability of freshwater springs and as a result, they might not be able to meet the future water demand. This study uses the Maximum Entropy (MaxEnt) model to predict the distribution of springs in GMA-9 and to identify the key topographic and climatic factors influencing their occurrence. This study …

Synthesis, Characterization And Delamination Studies Of Metallic Thin Films Prepared Using Sputtering And Ebeam Evaporation Methods, Anoop Joseph

USF Tampa Graduate Theses and Dissertations

In many mechanical applications, including the manufacturing, automotive, and cutting tool sectors, metallic thin film coatings are crucial due to their tribological and protective properties. This research focuses on the development of metallic thin films of Aluminum (Al), Chromium (Cr) and Titanium (Ti) using deposition techniques like Sputtering and Electron Beam Evaporation. Metallic thin films were fabricated, with variations in thickness for each material, allowing for an in-depth study of the effects of Sputtering and Ebeam Evaporation deposition method on film characteristics. The thickness of these metallic thin films were evaluated using High-Resolution Scanning Electron Microscopy (HRSEM) and Profilometer while …

Functional Characterization Of Cryopreserved Plasmodium Yoelii Sporozoites In Vitro, Victoria I. Mills

USF Tampa Graduate Theses and Dissertations

Malaria is a major global health burden, contributing to morbidity and mortality across various continents. Due to challenges in malaria research and its advancements, developing novel interventions and further understanding host-parasite interactions is required for future studies. Plasmodium vivax is a human malaria species that is difficult to maintain in laboratory settings, posing obstacles in research. Cryopreservation offers a reliable method to provide a consistent supply of sporozoites for reproducible studies. Plasmodium yoelii is a rodent malaria model commonly used in studies due to its genetic similarity to human malaria species. Utilizing cryopreserved P. yoelii sporozoites potentially extends their usability …