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Hot-Carrier Dynamics And Transport Mechanisms In Inas/Alassb Multiple Quantum Wells, Herath Pathiranage Janaka Chathuranga Piyathilaka

Graduate Theses, Dissertations, and Problem Reports (ETD)

Semiconductor photovoltaics convert light into electricity through the extraction of photo-excited charge carriers. Among the most important parameters for a photovoltaic cell are good optical absorption in the desired region of the electromagnetic spectrum, and sufficient excited-state lifetimes and mobilities of the photocarriers to allow for charge separation and extraction before recombination. For solar cell applications there are significant challenges to overcome to improve the efficiency of the light-to-electricity conversion. The cells are most commonly made of silicon, which has a nearly perfect bandgap for absorbing the most solar radiation, an indirect bandgap to give a long photocarrier lifetime and …

Generation Of High Performing Morph Datasets, Kelsey Lynn O'Haire

Graduate Theses, Dissertations, and Problem Reports (ETD)

Facial recognition systems play a vital role in our everyday lives. We rely on this technology from menial tasks to issues as vital as national security. While strides have been made over the past ten years to improve facial recognition systems, morphed face images are a viable threat to the reliability of these systems. Morphed images are generated by combining the face images of two subjects. The resulting morphed face shares the likeness of the contributing subjects, confusing both humans and face verification algorithms. This vulnerability has grave consequences for facial recognition systems used on international borders or for law …

Landmark Enforcement And Principal Component Analysis For Improving Gan-Based Morphing, Samuel W. Price

Graduate Theses, Dissertations, and Problem Reports (ETD)

Facial Recognition Systems (FRSs) are a key target for adversaries determined to circumvent security checkpoints. Morph images threaten FRS by presenting as multiple individuals, allowing an adversary to swap identities with another subject. Although morph generation using generative adversarial networks (GANs) results in high-quality morphs without possessing the spatial artifacts caused by landmarkbased methods, there is an apparent loss in identity with standard GAN-based morphing methods. In this thesis, we examine landmark-based and GAN-based morphing methods to fuse the advantages of both methodologies. We propose a novel StyleGAN2 morph generation technique by introducing a landmark enforcement method. Considering this method, …

Characterization And Coherent Spin Selective Manipulation Of Quantum Dot Energy Levels, Tristan Anthony Wilkinson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Semiconductor quantum dots (QDs) are promising candidates to fulfill a wide range of applications in real-world quantum computing, communication, and networks. Their excellent optical properties such as high brightness, single-photon purity, and narrow linewidths show potential utility in many areas. In order to realize long term goals of integration into complex and scalable quantum information systems, many current challenges must be overcome. One of these challenges is accomplishment of all necessary computing operations within a QD, which might be enabled by coherent manipulation of single QD energy level structures. In the realm of scalability for quantum devices, a way to …

Microvascular Consequences Of Engineered Nanomaterial Inhalation Exposure And Subsequent Reproductive Outcomes, Krista Lee Garner

Graduate Theses, Dissertations, and Problem Reports (ETD)

Nano-titanium dioxide (nano-TiO₂) is a commonly utilized engineered nanomaterial found ubiquitously in consumer products. While benefits of ENM utilization in are undeniable, nanoparticle inhalation has been linked to cardiovascular consequences and altered microvascular responses. Given these outcomes, it is important to explore vulnerable timepoints, such as gestation, as robust vascular adaptations are essential for maternofetal health.

The first aim of this dissertation was to assess myogenic responsiveness following maternal nano-TiO₂ inhalation. Fetal aortic responses were evaluated on gestational day (GD) 20 to assess how exposure may impact the F1 generation. Myogenic responsiveness within the uterine radial arteries …

Clitic Doubling: The Case Of Nariño Andean Spanish, Jessica Paola Jurado Eraso

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis examines the behavior of clitic doubling in Nariñense, a little-studied Andean Spanish variety spoken in the southwest of Colombia, and compares it to well-studied varieties such as standard Peninsular, Rioplatense, and other Andean Spanish varieties. Its aim is to present novel data about clitic doubling in order to shed more light into the extensive literature about this phenomenon in Spanish. Through spontaneous speech recordings obtained from thirty native speakers of Nariñense, 133 sentences involving clitic doubling were analyzed. Features such as agreement matching between the clitic and the doubled NP, use of the preposition a to introduce the …

Frayed Connections: How Long-Term Nitrogen Additions Disrupt Plant-Soil Interactions And The Carbon Cycle Of A Temperate Forest, Brooke A. Eastman

Graduate Theses, Dissertations, and Problem Reports (ETD)

Forests are expected to mitigate some of the negative effects of climate change by sequestering anthropogenic carbon (C) from the atmosphere, but the degree to which they drawn down C will depend on the availability of key nutrients, such as nitrogen (N). There is a fair amount of uncertainty in the future of the forest C sink, mostly owing to the fate of soil organic matter (SOM) and soil heterotrophic respiration to future conditions. In N limited systems, plants allocate a significant amount of their photosynthate belowground for the acquisition of nutrients, but under conditions of chronic N deposition, plants …

Appalachian Broadcast News Coverage Of The Coronavirus: A Content Analysis Of Media Framing In The Midst Of A Health Crisis, Jensen M. Mills

Graduate Theses, Dissertations, and Problem Reports (ETD)

Media framing of broadcast news is more than identifying an issue, but rather interpreting and explaining the issue for others to better understand. Previous framing scholarship in broadcast news, as well as COVID-19 specifically, has focused mostly on national or international news, so this research explores broadcast coverage from a local perspective in a rural location. During the health crisis of COVID-19, the specific use of media frames can impact how people made sense of the pandemic. Through a content analysis of 165 newscast scripts from five different local news stations in Appalachia, this study contributes to the understanding of …

The Vanishing Frontier: Economic And Social Change In Western North Carolina, 1945-1970, Elisabeth Avery Moore

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation works to integrate the growth of regional tourism into the existing historiography of economic development in Appalachia and the postwar American South. Regional leaders introduced an economic transition throughout western North Carolina that emphasized the growth of regional tourism. By centering this study on the growth of regional tourism, this research also analyzes regional boosters’ efforts to manufacture and commodify a racialized and classed folk culture within the region for tourist consumption. In the late nineteenth century, journalists and folklorists had emphasized the deviance of mountain life and simultaneously romanticized the area as a land of rugged, white …

The Bigger Picture: Wrongful Conviction Documentary Thematic Vs Episodic Framing, Alecsandra N. Vac

Graduate Theses, Dissertations, and Problem Reports (ETD)

True crime documentaries have gained popularity in the past decade, but those focusing on wrongful conviction cases have been on the rise (Doughty, 2018). Advocates against wrongful conviction, such as the Innocence Project, have been utilizing entertainment media to increase awareness on the issues present in the criminal justice system. However, the framing of wrongful conviction causes and cases (ex: focusing on extreme accusations of police misconduct and intentional forensic evidence tampering) could lead to a bias in how the viewers understand how miscarriages of justice occur. The primary research question being investigated here is, how are these advocacy-recommended documentaries …

Evaluating Effects Of Sediment On Microbial Loading In A Drinking Water Distribution System, Erika Osborne

Graduate Theses, Dissertations, and Problem Reports (ETD)

Drinking water distribution systems (DWDS) are critical for protecting public health by ensuring safe water is transported from centralized treatment facilities to consumers. Sediment accumulation in DWDS is a common challenge that water utilities face that may pose some health risks when waterborne pathogens colonize biofilms formed on the sediment surface. Water utilities often establish flushing routines to help mitigate sediment accumulation in their system but the role that sediment plays in contributing to the total microbial loading in the system is unclear. The main objective of this study was to determine if sediment in a DWDS presents a significant …

Tandem Addition/Fragmentation Reactions Of Vinylogous Acyl Sulfonates, Kristen S. Nerbecki

Graduate Theses, Dissertations, and Problem Reports (ETD)

Fragmentation methodology has been used in organic synthesis to produce complex organic compounds. This work is focused on fragmentation reactions leading to the subsequent construction of neopentylene-fused carbocycles, which are found in several important natural products and are difficult to prepare. These are produced by utilizing an optimized fragmentation methodology from the Dudley group. The methodologies build starting materials called nonaflates and triflates with a gem-dimethyl substituent that is seen in many natural products. Nonaflates and triflates are similar in structure, but nonaflates pose benefits that are an advantage over triflates, like cost effective synthesis and more stable compounds. A …

An Exploration Of The Effects Of Mindfulness On Pain: The Role Of Pain Catastrophizing, Ilana Haliwa

Graduate Theses, Dissertations, and Problem Reports (ETD)

Chronic pain is a complex global public health concern associated with a host of negative outcomes, including loss of productivity, decreased quality of life, and greater likelihood of developing a mental health disorder. Initial evidence indicates that mindfulness-based interventions (MBIs) improve pain symptomatology. However, most MBIs are time and resource intensive, and it is unclear how mindfulness may improve the pain experience. The purpose of the present set of studies was to test the effects of a brief, app-based MBI on pain experience, and to examine whether pain catastrophizing was a statistical mediator of any effect. Two studies were conducted …

Capillary Electrophoresis: Method Development And Application In Biomolecule Analysis, Lindsay Marie Veltri

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Capillary Electrophoresis: Method Development and Application in Biomolecule Analysis

Lindsay Veltri

Biomolecule analysis is essential in disease diagnostics and the development of therapeutic agents. There is a vast array of methods available for biomolecule analysis, however, capillary electrophoresis is well-suited due to minimal sample consumption (~nanoliters of solution) and fast analysis times. In this report, capillary electrophoresis was used to analyze glycosylation of therapeutic proteins. Additionally, a capillary electrophoresis-mass spectrometry method is reported for the analysis of proteins.

Post-translation protein modifications like glycosylation, play an important in protein structure and function. Modifications of protein glycosylation can lead to improved …

Essays In The Consequences Of Occupational Regulation, Noah J. Trudeau

Graduate Theses, Dissertations, and Problem Reports (ETD)

Occupational regulation affects many people across many aspects of life. This dissertation research investigates the consequences of occupational regulation across three different areas of study: economic history, urban and regional economics, and health policy.

The first chapter investigates the historic licensing of emigrant agents. In the period following the US Civil War, firms wished to capitalize on the availability of African American labor. To do so they hired emigrant agents, also known as labor agents, to hire and help with the migration of individuals from the South. Faced with out-migration at the hands of the labor force, some southern states …

Comparison Of Antimicrobials And Delivery Methods On The Inactivation Of Listeria Monocytogenes On Apples, Rebecca B. Stearns

Graduate Theses, Dissertations, and Problem Reports (ETD)

Introduction: Due to multi-state outbreaks of listeriosis on apples in 2015, 2017, and 2019, Listeria Monocytogenes (L. monocytogenes) has been deemed an emerging, under researched pathogen by the USDA-NIFA. Therefore, this study evaluated the efficacy of SaniDate 5.0®’s (SD) ability to inactivate L. Monocytogenes on apples when delivered through electrostatic sprayer (ES), garden sprayer (GS), and dip methods.

Methods: Organic apples were dip-inoculated with L. monocytogenes for 5 min and then dried for 10 min. Once dried, the inoculated apples were untreated (control), sprayed with water only, or treated with SD, 0.0064, 0.1, 0.25 and 0.50% for 20 …

Modeling Post-Crisis Monetary Policy, James Dean

Graduate Theses, Dissertations, and Problem Reports (ETD)

Chapter 1, co-authored with Scott Schuh, examines whether the Taylor Rule still adequately captures monetary policy despite unconventional monetary policies (UMP) and the policy rate near zero in 2009-2015. We find structural breaks at 2007:Q3 in macro models with a shadow funds rate. Taylor Rule coefficients shift back toward pre-1984 estimates and breaks occurred in non-policy parameters. Results are similar with the effective funds rate, so either breaks are not due to UMP or the shadow rate is an insufficient specification of UMP. Chapter 2 incorporates the term structure and the Fed’s average inflation targeting (AIT) framework into the model …

Gender Leadership Imbalance In Sport Organizations In Latin America, Monica Yamile Gonzalez-Cuevas

Graduate Theses, Dissertations, and Problem Reports (ETD)

The purpose of the study was to examine gender imbalance at the leadership level of sport administration at National Olympic Committees (NOC), National Paralympic Committees (NPC), and National Sport Organizations (NSF) of countries members of the Pan American Sports Organization (PASO). Specifically, this study examined how social and human capital, socio-cultural aspects of each country, and power-based discourses affect the advancement of women’s careers at the micro, meso, and macro levels of analysis.

A total of 12 participants were selected to participate in this study. Participants were all female sport administrators holding the position of president, vice-president, or secretary-general of …

The Heart Of Everything In The Middle Of Nowhere: The Role Of Rural Identity In The Formation And Deployment Of Political Attitudes In Pennsylvania, Mikaela G. Zimmerman

Graduate Theses, Dissertations, and Problem Reports (ETD)

The world of American politics continues to infiltrate households across the United States as technological advancement extends the reach of breaking news and government action. With this expanding reach, communities all over the country are digesting and contemplating their place in national politics more fervently than ever. At the crux of this discussion is the backbone of political engagement and action—identity and its resulting political attitudes. For decades, partisanship has been a point of contention amongst American citizens. Cities across the nation showcase protests, demonstrations, town hall meetings, and more illustrating citizens’ care for their democratized input in government affairs. …

Extension Of A Bayesian Method For Viral Genome Re-Sequencing To Multi-Dimensional Parameters, Sarah Fleischer

Graduate Theses, Dissertations, and Problem Reports (ETD)

Next Generation Sequencing (NGS) refers to all sequencing methods post Sanger Sequencing. Sequencing By Synthesis is the most well-known method, however it’s inaccessible price is difficult for some. Thus, a different method also exists, re-sequencing– which relies on a reference genome to check the validity of each base call. The standard for determining the validity of a base call is a one parameter quality score. But, previously a two-parameter Bayesian method was successfully used for re-sequencing the viral genome. However, a quality parameter was previously not used in the construction of the cumulative density function for the likelihood. This paper …

Medicaid In The Orthodontic Community: Provider Trends And Perceptions, Miranda L. Fabrega

Graduate Theses, Dissertations, and Problem Reports (ETD)

Background and Objectives: Medicaid is a federal and state insurance program aimed at helping economically disadvantaged individuals and families with gaining access to health care. Lack of provider participation in the Medicaid program leaves many Medicaid-eligible individuals with the inability to obtain certain medical services, such as orthodontic care. The objective of this study was to use an electronic survey to better understand the beliefs and behaviors of orthodontists in regard to participation in the Medicaid program, and to determine if differences exist between Medicaid providers and non-Medicaid providers. Experimental Design and Methods: Survey: Requests to participate in an electronic …

Cbct Use In Orthodontic Residency Programs In Usa, Su Min Han

Graduate Theses, Dissertations, and Problem Reports (ETD)

Background and Objectives: Cone beam computed tomography (CBCT) scans in dentistry have been up and coming forms of x-ray technology that allows cross-sectional images to form a comprehensive 3-dimensional representation of the mouth. While the typical use for CBCT imaging is reported to be for implant dentistry, there are many contexts in which it is indicated in orthodontics. There are various schools of thought regarding when CBCT is indicated for specific diagnosis of problems or general use in the collection of initial, progress and post-treatment orthodontic records. There are programs that follow the Radiology guidelines for taking CBCT scans10 and …

Critical Perspectives On Produce Prescription Programs & Us Federal Nutrition Policy, Alanna K. Higgins

Graduate Theses, Dissertations, and Problem Reports (ETD)

Produce prescription programs, interventions operating at the intersection of food access and public health, are steadily increasing in number across the United States since 2010. I leverage key informant interviews, participant observations, and event ethnographies to form a four-year institutional ethnography of the implementation of produce prescriptions within West Virginia alongside a legal-policy archaeology methodology to understand how produce prescriptions have been institutionalized and funded within the US Farm Bill. While much of produce prescription program growth is attributed to an expansion of federal funding starting in 2014, this dissertation demonstrates that these programs and the federal legislation which has …

A Multi-Method Evaluation Of Parent And Child Factors Associated With Child Abuse Potential, Lindsay R. Druskin

Graduate Theses, Dissertations, and Problem Reports (ETD)

Child abuse is a pervasive, global problem impacting millions of children (Stoltenborgh et al., 2015). Researchers have largely relied on the use of parent-report questionnaires to examine a variety of risk factors for child abuse (see Azar, 2002; Stith et al., 2009), leaving a gap in the research regarding the link between observed parent and child behaviors and child abuse potential. Utilizing a sample of families clinically referred for child behavioral problems, the proposed study pursued a multi-method approach to explore relations between parent factors (parent attachment, emotion regulation, harsh behaviors, and stress), child factors (child disruptive behaviors), and the …

A Shock To The System: Analyzing Ethnocentric Populist Support Before And After Crises, Kyu Chul Shin

Graduate Theses, Dissertations, and Problem Reports (ETD)

Using the question of what is driving the support for populists in the mid-late 2010s in Western Europe and the United States as the starting point, this dissertation attempts to answer a number of different questions related to populists: Were the reasons behind support for populists in countries that saw an increase in support for populisms similar to those that saw a decrease in support? Are the reasons for supporting right-wing populists different from more general ethnocentric populists? Are the reasons that Americans supported Donald Trump similar or different from the reasons behind support for Western European populists? Following migration-related …

Amelioration Of Mitochondrial Bioenergetic Dysfunction In Diabetes Mellitus: Delving Into Specialized And Non-Specific Therapeutics For The Ailing Heart, Andrya Jean Durr

Graduate Theses, Dissertations, and Problem Reports (ETD)

Morbidity and mortality of the diabetic population is influenced by many confounding factors, but cardiovascular disease (CVD), remains the leading cause of death. Mitochondrial dysfunction is central in the development of cardiac contractile dysfunction, with decreased mitochondrial bioenergetic function, increased dependence on free fatty acid utilization, and a decrease in glucose utilization having been shown to contribute to contractile dysfunction. Strategies targeting the amelioration of mitochondrial bioenergetic function are attractive for limiting diabetes-induced heart failure, and preserving health-span. The goals of this dissertation were to assess two mitochondrial-centric approaches for the amelioration of mitochondrial and cardiac contractile dysfunction in diabetes …

Design And Control Of Intensified Membrane Reactor Systems Through Module-Based Design Approach, Brent Bishop

Graduate Theses, Dissertations, and Problem Reports (ETD)

As interest in the modularization and intensification of chemical processes continues to grow, more research must be directed towards the modeling and analysis of intensified process units. Intensified process units such as membrane reactors pose unique challenges pertaining to design and operation that have not been fully addressed in the reported literature. This work aims to address the design and control challenges caused by the integration of phenomena and the loss of degrees of freedom (DOF) that occur in the intensification of modular membrane reactor units.

First, a novel first-principles approach for modeling membrane reactors is developed using the AVEVA …

Ethane Dehydrogenation For Light Olefins Production Over Stable Catalyst, Xiaoyan Wang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Accompanied by the development of modern industry, the demand for light olefins (e.g., ethylene, propylene, butene, butadiene) increases year by year. Light olefins are important intermediates in producing polymers (Polyethylene, Polypropylene, etc.) and rubber (Styrene Butadiene Rubber, Polybutadiene rubber, etc.). The primary process for the production of light olefins is steam cracking of petroleum liquids (naphtha and distillate fuel oil). It is an energy-intensive process, requiring high temperature (750-850℃) and pressure (1.0-4.5 MPa). Meanwhile, due to undesired side reactions, this process has lowered the efficiency of light olefins production and suffers from severe coking issues. Furthermore, as petroleum liquids become …

A Study On Supereulerian Digraphs And Spanning Trails In Digraphs, Omaema A. Lasfar

Graduate Theses, Dissertations, and Problem Reports (ETD)

A strong digraph D is eulerian if for any v ∈ V (D), d+D (v) = d−D (v). A digraph D is supereulerian if D contains a spanning eulerian subdigraph, or equivalently, a spanning closed directed trail. A digraph D is trailable if D has a spanning directed trail. This dissertation focuses on a study of trailable digraphs and supereulerian digraphs from the following aspects.

1. Strong Trail-Connected, Supereulerian and Trailable Digraphs. For a digraph D, D is trailable digraph if D has a spanning trail. A digraph D is strongly trail- connected if for any two vertices u and …

The Purpose And Process Of Commissioning New Music For Low Brass Instruments: A Guide, Michael Kennard Waddell

Graduate Theses, Dissertations, and Problem Reports (ETD)

The euphonium, trombone, and tuba do not have the breath of solo and chamber music repertoire that other instruments such as the piano or violin do. The majority of works being written for these instruments today is being written via direct commissions and commission consortiums. This research analyzes the importance of expanding the repertoire of these instruments, along with detailed guidance on starting a consortium project and seeing it through to completion. The author, and interviewees Frank Gulino, Adam Frey, and George Alberti, detail their experiences working on consortium projects, and their views on the ethical importance of advancing the …