Digital Commons Network^™

Developing A Simplified Method Of Measuring Ultrafine Particulate Matter Dose Concentrations For Diesel Emissions, Nafisat Ohunene Isa

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Developing a Simplified Method of Measuring Ultrafine Particulate Matter Dose

Concentrations for Diesel Emissions

Ultra-fine particulate matter (UFP), particularly from diesel emissions, poses significant health and environmental risks due to its small size and potential to penetrate deep into the respiratory system. Accurate measurement of UFP concentrations is essential for assessing exposure and mitigating health impacts. However, current methods for measuring UFP can be complex, time-consuming, and costly. This study aims to develop a simplified method for efficiently measuring UFP concentrations from diesel emissions, which will enable easier and more widespread monitoring of air quality and public health impacts. …

Authoritarian Control Over Election Administration, Nazar Boyko

Graduate Theses, Dissertations, and Problem Reports (ETD)

Street-level election bureaucracy (SLEB) remains one of the least studied aspects of authoritarian elections. Our current understanding of micro-level election administration in autocracies is fragmented and unsystematic. In this dissertation, I develop and test a theory of authoritarian SLEB that comprehensively addresses key elements of election administration: the incentivization and mobilization of election commissioners, the establishment of control over election commissions, the monitoring of their performance, and the post-election reshaping of their personnel composition. Drawing on rational choice theory, I propose a framework in which autocrats are seen as outcome-maximizers who strategically design SLEB to achieve their electoral goals. The …

Individual And Collective Properties Of Tunable Photochemical Belousov-Zhabotinsky Micro-Reactors, Kudakwashe Benedict Shumba

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cell-like model chemical systems are powerful tools that can be used to explore the role of intercellular coupling on population level behaviors in communities of biological cells. Firstly, we present a new method for fabricating such micro-reactors using the photosensitive Belousov–Zhabotinsky (BZ) reaction system employed in silica microparticles. These BZ micro-reactors have a tunable response to photochemical coupling, varying from a fully excitatory response to a fully inhibitory response. Their response can be tuned through variations in either the reactive mixture or, on an individual micro-reactor level, by changes in the synthesis temperature used during the fabrication of the silica …

Demonstrating The Potential Of Biophilic Design, Sustainable Site Initiatives, And Regenerative Landscape Design To Transform Neglected And Underutilized Spaces Into Vibrant, Eco-Friendly Hubs In Mckeesport Pennsylvania., Chinweuba Stephen Kikanme

Graduate Theses, Dissertations, and Problem Reports (ETD)

McKeesport is a city located along Monongahela and Youghiogheny rivers in Allegheny County, Pennsylvania, about 13 miles southeast of Pittsburgh. It is part of the River metropolitan area. McKeesport, once a thriving center of steel production, is now facing significant challenges associated with industrial decline, urban blight, flood hazard, population decline, brownfield sites and environmental degradation. However, the transformation of neglected spaces within the city into sustainable and vibrant urban hubs offers a powerful opportunity for revitalization. By incorporating natural elements such as green roofs, urban agriculture, and native plant restoration, this project seeks to create spaces that not only …

Global China In Pakistan: Mixed-Methods Analysis Of Symbolic Domination, Social Media Geopolitics, And Security Corridors, Davide Giacomo Zoppolato

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation explores the discursive and material dimensions of China’s global rise through a case study of the Belt and Road Initiative (BRI) in Pakistan. As China becomes a leading provider of development finance, its infrastructure-led approach is reshaping geographies across the Global South. Focusing on the China–Pakistan Economic Corridor (CPEC)—the BRI’s flagship project—I examine how Chinese and Pakistani actors co-produce development through discourses, infrastructures, and security regimes. Structured around three articles, the dissertation analyzes: (1) the official diplomatic discourses of Chinese state institutions and their reception by Pakistani media outlets; (2) the curated geopolitical discourses of Chinese social media …

Leveraging Physiological Signal Activity And Self-Report Data To Assess Students’ Trust In “My Friendly Mind” App And Its Impact On Their Mental Health Knowledge: A Mixed-Method Phase 1 Clinical Trial Focusing On Depression And Attention Deficit Hyperactivity Disorder From Human Factors Standpoint., Yeganeh Shahsavar

Graduate Theses, Dissertations, and Problem Reports (ETD)

Mental health issues have become a significant global public health concern, especially among younger generations. The growing number of mental health challenges, combined with limited access to quality care, makes the problem even worse. Studies reveal that over 70% of individuals worldwide in need of mental health services do not receive appropriate care. Digital health technologies have the potential to enhance mental health services by making them more accessible and affordable. Despite the increasing popularity of mental health mobile applications (mHealth), there remains a lack of robust evidence of their effectiveness and the level of user trust, particularly in areas …

From Bobcat To Bursts: Multi-Messenger Constraints On Supermassive Black Holes And Binaries, Jessica Sydnor

Graduate Theses, Dissertations, and Problem Reports (ETD)

Supermassive black hole binaries (SMBHBs) are a natural consequence of hierarchical galaxy formation and evolution. When galaxies merge, their central supermassive black holes (SMBHs) are expected to form bound pairs that evolve from kiloparsec to sub-parsec separations under the influence of dynamical friction, stellar scattering, and gas dynamics. Ultimately, these SMBHs reach the regime where gravitational wave emission dominates and drives the final inspiral and coalescence. Understanding the formation, evolution, and observational signatures of SMBHBs is critical to advancing multi-messenger astrophysics, particularly in the era of pulsar timing arrays (PTAs) and the upcoming Laser Interferometer Space Antenna (LISA), which opens …

Media Framing Of The Local And National News Coverage Of The East Palestine Train Derailment, Lauren Delo

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research examined digital news coverage of the East Palestine train derailment to determine the frames and dominant frames used in both local and national coverage of the disaster, and whether these frames differed over time. Specifically, this research used a content analysis of digital newspaper articles from five media outlets—three national level and two local level—and applied the frames identified from Colistra’s (2010) study of print news coverage of the 1972 Buffalo Creek mine disaster. Results revealed significant differences between the most frequently used frames between local and national coverage, shifts in frame usage over time within each media …

Investigating The Physiological, Metabolomic, And Transcriptomic Changes In Response To Telomerase Deletion In Saccharomyces Cerevisiae, Taizina Momtareen

Graduate Theses, Dissertations, and Problem Reports (ETD)

Telomerase is an enzyme found in rapidly dividing cells that maintains chromosome ends and prevents the loss of genetic information during cell division. When telomerase is inactive, cells gradually lose their telomeres and eventually stop dividing. In yeast, a rare subset of cells can bypass this growth arrest by switching to a recombination-based mechanism to maintain telomeres. Therefore, yeast provides a powerful system to study this adaptation, as telomerase-deficient strains can generate 'survivors' that mimic the Alternative Lengthening of Telomeres (ALT) pathway observed in some human tumors. In this work, my goal was to examine how a telomerase-null (TLC1 …

Rare Earth Element Recovery From Acid Mine Drainage Using Ion Exchange And Selective Precipitation Processes, Paubla Andrea Gallego Lopez

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rare earth elements (REEs) are used in high-tech applications due to their electromagnetic and optical properties. As global demand for REEs surges, the limitation of primary mineral deposits has increased interest in alternative sources. One such source is acid mine drainage (AMD), which, although typically low in REE concentration, offers a promising avenue for recovery. Among the emerging recovery methods, ion exchange has shown promise due to its effectiveness at low concentrations and lower operational cost than conventional techniques such as acid leaching and solvent extraction.

This research focused on developing a recovery process by combining ion exchange with selective …

Distress Tolerance And Sleep Quality: Potential Moderating And Mediating Factors, Alivia Kay Murdock-Frazier

Graduate Theses, Dissertations, and Problem Reports (ETD)

Research has shown that insomnia and poor sleep quality are related to a variety of negative physical and mental health outcomes. There is emerging evidence that the psychological construct of distress tolerance is related to the quality of one’s sleep, including the presence of insomnia. However, few studies have explored how additional factors may be related to this association. This study aimed to replicate previous research supporting the association between distress tolerance and sleep and exploring this relation by examining three different hypotheses (e.g., health behaviors, perceived stress, and emotion regulation) that could potentially explain how these two variables are …

Systematic Methodologies For Magnetic Materials Design, Andres Tellez Mora

Graduate Theses, Dissertations, and Problem Reports (ETD)

Understanding and predicting the magnetic behavior of materials from first principles is one of the central challenges in condensed matter physics. This dissertation presents a systematic framework that bridges ab initio calculations, many-body physics, and effective spin models to analyze magnetic materials in particular, but also more general quantum systems. Starting from the electron many-body Hamiltonian and the second quantization formalism, we derive Density Functional Theory (DFT) and explain how magnetic properties emerge from exchange interactions and can be interpreted as perturbations to the magnetization density. To capture these effects efficiently, we construct Heisenberg models from first principles using the …

Exploration Of Coping And Mental Health In West Virginia Farmers, Jodi Meadows Richmond

Graduate Theses, Dissertations, and Problem Reports (ETD)

Compared nationally, West Virginia currently ranks lowest for life expectancy, highest for drug related deaths and 35^th for access to adequate health (WV DHHR Organization Assessment & Strategic Plan, 2022). The state also ranks first in the nation for depression with one in four adults experiencing some form of depressive condition each year (CDC, 2020). The rurality of the state may limit social interaction and availability of medical treatment facilities (Brew et al., 2016).

The situation is even more dire for those in farming-related occupations. Farmers often struggle with management stress, utilizing appropriate coping strategies, and accessing mental health …

Not Far Enough: The West Virginia Human Rights Commission And The Civil Rights Movement, David Solomon

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis investigates the West Virginia Human Rights Commission and its action surrounding the Civil Rights Movement. The Commission represented the liberal ideals that led white moderates to be potent allies of the Civil Rights Movement. Throughout the years following its inception, the Commission investigated and documented many instances of Jim Crow that were crushing Black communities in West Virginia. However, the limits of its liberal approach prevented it from creating solutions that would address the power structures that supported discrimination in West Virginia. By the late 1960s, Black frustrations with the lack of meaningful change boiled over into riots …

From Sequencing To Conservation: Genomic Analysis Of Three Sportfish Species In West Virginia, Andrew Johnson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Situated in the Appalachian Mountains, one of the oldest mountain ranges on Earth, West Virginia waters boast rich ichthyofauna including native sportfish species walleye (Sander vitreus), largemouth bass (Micropterus nigricans), and muskellunge (Esox masquinongy). These three species are all native to the contemporary Ohio River watershed and play a major recreational and ecological role in local fisheries. Ecologically, all three species are apex predators and play a key role in ecosystems by directly influencing local fish assemblages. As dominant apex predators all three species are highly sought after in recreational fisheries with largemouth bass …

Optical Measurements Of Magnetic Fields In Low-Temperature Plasmas Via Quantum Spectroscopy, Tyler James Gilbert

Graduate Theses, Dissertations, and Problem Reports (ETD)

Accurate characterization of the magnetic field strength and direction within a plasma is increasingly important as experiments attempt to probe the physics of plasmas at kinetic scales. Non-perturbative laser-based diagnostics which are spatially and temporally localized—such as laser-induced fluorescence (LIF) and Thomson scattering for the measurement of ion and electron distribution functions, respectively—are increasingly relied on for measurements in laboratory plasmas. This work seeks to develop a spatially and temporally localized non-perturbative laser-based diagnostic for the measurement of magnetic fields in laboratory-relevant plasmas. Two such techniques are investigated here: Zeeman-split LIF and quantum beat spectroscopy (QBS).

Zeeman-split LIF measures the …

Police Abuse In America And The Search For Remedy, Howard Ryan

Graduate Theses, Dissertations, and Problem Reports (ETD)

The dissertation contends that, despite many diligent efforts—from mass protests to a presidential task force—America is not yet on path to remedying its outsized patterns of police abuse. The abuse problem is broadly characterized herein through a “triad” of over-enforcement, excessive force, and racial discrimination. The Washington Post’s “Fatal Force” database, covering the years 2015 through 2024, is offered as a bellwether of American progress in addressing its police abuse; and, it is observed, the nation’s yearly count of fatal police shootings of civilians has been increasing, rather than decreasing.

To help make sense of our lack of national progress, …

White Paper And Black Water: Environmental Control Of Labor In Appalachian Paper Mill Communities, Matthew C. Powell

Graduate Theses, Dissertations, and Problem Reports (ETD)

In several small Appalachian communities, the West Virginia Pulp & Paper Company dominated the local landscape. The company stripped the mountainsides of spruce trees for pulpwood and used rivers for industrial processes and waste disposal. The small towns along these rivers and between these mountains relied on paper mills for employment. Corporate control over the natural environment, and water more specifically, was a necessary requirement for paper production, but also acted as a source of power over employees and their communities. When paper workers sought to organize, the company responded by leveraging their control over the environment against them to …

Performance Is In The Eye Of The Beholder: Exploring The Moderating Role Of Psychological Perspective Distancing Within Thought Self-Leadership In An Organizational Context, Christopher Bryton Neck

Graduate Theses, Dissertations, and Problem Reports (ETD)

Self-leadership, or the process through which individuals perform various cognitive and behavioral strategies to attain the self-direction and self-motivation necessary to perform in desired ways, has consistently been evidenced to enhance individuals’ performance through promoting a variety of positive individual cognitions, such as self-efficacy, positive affect, and engagement and through diminishing key threatening mental states such as stress, negative affect, and dysfunctional thinking (Harari et al., 2021; Knotts et al., 2022). The cognitive component of self-leadership, thought self-leadership (TSL) has been found to be particularly impactful, aiding the individual to modify and adapt their dysfunctional thinking to be more constructive …

Comparative Analysis Of Electrode Encapsulation Reliability: Planar Vs. Thermoformed Interdigitated Neural Electrodes In Biomedical Engineering, Tatum Peyerl

Graduate Theses, Dissertations, and Problem Reports (ETD)

Durable dielectric encapsulation is crucial for the long-term function of implantable neural electrodes; however, the reliability of curved, thermoformed coatings remains underexplored. This study addresses that gap by comparing planar (non-thermoformed) and thermoformed interdigitated neural electrodes (IDEs) encapsulated in Polyimide-2611. Both device types underwent accelerated in vitro aging in phosphate‑buffered saline (PBS) at 67 °C for approximately 91 days, simulating two years of physiological exposure. Post-accelerated aging evaluation included electrochemical impedance spectroscopy (EIS) from 0.1 Hz to 100 kHz to monitor moisture‑induced leakage, and high‑voltage breakdown testing under saline immersion to assess dielectric strength. After aging, all electrodes maintained impedance …

Asset Mapping: A Tool Used To Identify Community Resources, Gentry Shrewsbury

Graduate Theses, Dissertations, and Problem Reports (ETD)

Background: Physical activity is vital for health and quality of life; however, for individuals with disabilities, there are numerous barriers to participation. In rural and low-socioeconomic regions, barriers such as lack of awareness, limited restrooms, and lack of public transportation create challenges when attempting to be physically active. Using the Asset-Based Community Development (ABCD) framework, this study examined physical activity resources within Mercer County, West Virginia, and evaluated their accessibility for individuals with disabilities.

Methods: A qualitative research design was implemented using three data collection strategies: (1) a google search to identify existing physical activity opportunities followed by a windshield …

Three Essays On The Socioeconomics Of Drinking Water Pfas Contamination, Nabin Babu Khanal

Graduate Theses, Dissertations, and Problem Reports (ETD)

Per- and polyfluoroalkyl substances (PFAS) are a group of over 15,000 synthetic compounds widely used for their resistance to heat, stains, grease, and water. While central to many modern conveniences, ingestion of PFAS is increasingly linked to adverse human health outcomes and are now detected globally in drinking water systems. This dissertation investigates three interrelated aspects of PFAS contamination in U.S. drinking water: (1) socioeconomic determinants and spatial patterns of contamination; (2) the economic impacts of contamination on residential property values; and (3) the effect of inconsistent PFAS regulations on public trust in environmental governance.

Using data from the U.S. …

Raman Spectroscopy For Rapid Quantification Of Macronutrients In Heirloom Beans, K. Chandler Williams

Graduate Theses, Dissertations, and Problem Reports (ETD)

Quantification of macronutrients in food requires a large investment in facilities and instrumentation as well as ongoing expenses of labor, reagents, and hazardous waste disposal. These costs pose a significant barrier to determining macronutrient quantities in the thousands of uncharacterized landrace and heirloom crops and discourage traditional crop breeding projects from ensuring that their selected crops maintain desirable macronutrient profiles in addition to target agronomic traits. Our objective was to test whether a hand-held Raman spectrometer—a technology which has found use in plant disease diagnostics but remains largely overlooked in nutrient quantification-- could provide a feasible means for quantifying the …

Prioritizing Amd Impaired Watersheds For Watershed-Scale Restoration Using Multi-Criteria Decision Analysis, James Nicholas Marino

Graduate Theses, Dissertations, and Problem Reports (ETD)

Acid Mine Drainage (AMD) remains a significant environmental challenge in coal-mining and hard rock regions like West Virginia, degrading water quality and ecosystem health. Traditional site-specific remediation efforts often prove inefficient in addressing AMD at large scale. This study explores watershed-scale restoration as a more effective solution, leveraging centralized treatment facilities and multi-source pollution management. This study will follow Multi-criteria Decision Analysis (MCDA), specifically the Analytical Hierarchy Process (AHP), to develop a structured rubric for grading watersheds. The process involves identifying critical criteria, organizing them into a hierarchy, and generating weights for clusters of criteria through collaboration with decision makers. …

Using Visual Prompts To Analyze Ejection Fraction In Echocardiograms, Kevin Reisch

Graduate Theses, Dissertations, and Problem Reports (ETD)

Left ventricular ejection fraction (LVEF) is a critical biomarker for heart failure, but manual estimation from echocardiograms is time-consuming. Artificial intelligence can be used to accelerate this process, allowing clinicians to focus on other critical tasks. Current methods typically train models from scratch on echocardiogram datasets; however, this approach is limited by the scarcity of large medical imaging datasets, which are expensive and difficult to acquire. We present a transfer learning approach that leverages pretrained models from massive datasets, enabling continuous improvement as foundation models advance. Our method employs visual prompting to generate trainable masks for echocardiogram videos, transforming the …

Thermal Inactivation Of E. Faecium On Ground Poultry, Joseph Katz

Graduate Theses, Dissertations, and Problem Reports (ETD)

Chicken products in grocery stores are contaminated with Salmonella that is ranked number one as a foodborne pathogen, and causes about 1.35 million cases of foodborne illness, 26,500 hospitalizations, and 420 deaths annually. The objective of this study is to determine thermal kinetic parameters of Salmonella surrogate bacteria E. faecium in ground poultry as affected by different temperatures and salt concentrations. The raw chicken was sliced up into a 500 g batch with a total of 6 batches per replicate, ground up in the meat grinder followed by inoculation with E. faecium resistant to 200 ppm Nalidixic Acid. NaCl …

Academic Agency Within The Curricular Reform Of Gateway Stem Courses: A Faculty Perspective, Katie Beck

Graduate Theses, Dissertations, and Problem Reports (ETD)

The research regarding faculty agency during curricular reform is a burgeoning field within higher education as the faculty perspective within the current research concerning curriculum reform is limited. This study seeks to illuminate the faculty perspective of the curricular reform process of gateway STEM courses and how faculty experienced the reform process through a qualitative case study. The site of the case study is a public four-year institution on the eastern coast of the United States that has undergone and continues to undergo significant academic restructuring. The research utilized a structured survey and semi-structured interviews with seven total participants from …

Closing Racial And Ethnic Disparity Gaps In Pediatric Asthma Follow Up Care - A Quality Improvement Initiative, Ayodele Ayeko

Graduate Theses, Dissertations, and Problem Reports (ETD)

ABSTRACT

Closing racial and ethnic disparity gaps in pediatric asthma follow up care - A quality improvement initiative

Ayodele Ayeko

Introduction/Background: Inadequate management of asthma significantly contributes to poor asthma control, poor quality of life (QOL), and high hospitalization rates among pediatric patients. The Global Initiative for Asthma (GINA) guidelines offer recommendations designed to enhance asthma control and improve the quality of life for those affected (2015), including recommendations for close follow up care. At WVU Medicine Children’s Hospital (WVUMCH), insufficient asthma control has been associated with lower clinic follow-up rates and an increase in hospitalization. Although educational initiatives …

Reuse Of Calcium Carbonate (Caco3) Recovered From Discarded Carpets As Filler In Fiber-Reinforced Polymer (Frp) Composites, Roshan Devkota

Graduate Theses, Dissertations, and Problem Reports (ETD)

Over four billion pounds of carpet are discarded annually in the United States, making carpet waste a significant environmental concern. Calcium carbonate (CaCo₃) constitutes up to 45% of the mass of most synthetic carpets. Reusing this CaCo₃ as a filler in the rapidly growing fiber-reinforced polymer (FRP) industry, which is projected to reach USD 10.38 billion, presents a low-cost, practical approach to developing a market-based solution to post-consumer carpet waste.

This study investigates the reuse of CaCo₃ recovered from discarded carpet backing as a filler in FRP composites, focusing on its mechanical viability in comparison to virgin CaCo₃. The methodology …

Exploring Long-Term Patterns: Black Bass Tournament Fishery And Population Trends In West Virginia's Navigable Rivers, Alex J. Benecke

Graduate Theses, Dissertations, and Problem Reports (ETD)

Black bass Micropterus spp. are popular sport fish in West Virginia’s navigable rivers. In recent years, anglers have expressed concerns about a potential decline in fishery quality. To investigate these claims, we evaluated whether fishery quality has declined compared to earlier periods and whether population trends correspond to angler catch rates. Specifically, we aimed to (1) examine changes in species catch over time and during key periods, such as tournament and spawning seasons; (2) describe the distribution of black bass species across pools and habitat types; and (3) assess the outcomes of previous stocking efforts. To address these objectives, we …