Digital Commons Network^™

Process Intensification Of Fuel Synthesis And Electrolysis, Jeremy Lee Hartvigsen

Doctoral Dissertations

”As more renewable energy is added to the electric grid, energy storage becomes a high priority. Suggestions have been made for energy storage in the form of fuel and chemicals. Currently, Solid Oxide Electrolysis systems can operate in endothermic mode and reduce the electrical requirement by supplying heat. Fuel synthesis from syngas is exothermic and can supply heat. However, the temperature mismatch in the normal operation of the electrolysis step and fuel synthesis step makes the direct utilization of this heat impossible. This work explores possibilities of alternate arrangements of coupling electrochemical systems and chemical synthesis. This work also explores …

Development Of Lightweight Materials By Meso- And Microstructure Control, Myranda Shea Spratt

Doctoral Dissertations

”In this work, two lightweight structures – lattice structures and metal matrix syntactic foams (MMSF) – were studied. Honeycomb lattices were manufactured by powder bed selective laser melting (SLM) from 304L stainless steel. The wall thicknesses of these structures ranged from 0.2 to 0.5 mm. Surface roughness was the primary cause of dimensional mismatch between the expected and as-built structures with an average wall thickness increase of 0.12 mm. The strength of the honeycombs increased with increasing wall thickness. A feature of the SLM microstructure, the melt pool boundary, was also studied as a part of this work. 3D models …

Experimental Study On A Novel Eor Method -- Polymeric Nanogel Combined With Surfactant And Low Salinity Water Flooding To Enhance Oil Recovery, Mustafa M. Almahfood

Doctoral Dissertations

“Extracting higher amounts of oil from current reservoirs is a necessity for the oil industry to enhance their profitability and sustainability. The desire to recover more oil from the existing reservoirs has led to a growing interest of nanoparticle application in enhanced oil recovery (EOR). However, most researchers have focused on the evaluation and surface modification of non-deformable nanoparticles. This dissertation evaluates the potential of deformable nanogel particles as an EOR material when they are combined with two other promising technologies - surfactant and low salinity water floodings. The particle size distribution, ζ-potential and interfacial tension were measured for a …

Decoupled Finite Element Methods For General Steady Two-Dimensional Boussinesq Equations, Lioba Boveleth

Masters Theses

"This work presents two kinds of decoupled finite element methods for the steady natural convection problem in two dimensions. Firstly, the standard Galerkin finite element method is derived in detail stating algorithms needed for the realization in MATLAB. A numerical example verifies the error convergence. Secondly, using iteration, the Boussinesq equations are decoupled into the Navier-Stokes equations and a parabolic problem. The resulting problems are solved either in parallel or sequentially. Finally, the same numerical example as before is used to confirm the convergence and analyze the methods in terms of iteration performance. In addition to a higher flexibility and …

Analysis Of Energy Economy In Muon Catalyzed Fusion Considering External X-Ray Reactivation, Nishant Raghav Pillai

Masters Theses

"An analysis of the energy economy of a theoretical muon-catalyzed nuclear fusion system has been made by invoking the use of point kinetic equations, Monte Carlo radiation transport simulations, and from a review of existing literature on muon-catalyzed fusion. An external X-ray reactivation source is proposed as a novel way to increase the number of fusions per muon and thereby overcome the so-called alpha sticking problem that has long been considered the primary impediment to breakeven muon-catalyzed fusion power. Free electron lasers, synchrotrons and Wakefield accelerators are discussed as possible bright X-ray photon sources. The addition of an intense external …

Design And Development Of Power Processing Units For Applications In Electrically-Propelled Satellite Systems, Kartikeya Jayadurga Prasad Veeramraju

Masters Theses

"Electrospray technology provides a way to ionize specialized liquids by applying high voltages across a sharp porous tip and a metallic mesh. This technology is widely used in the field of mass spectroscopy for generating ions for testing purposes. The dawn of nano-satellites posed new challenges in the miniaturization of many conventional satellite sub-systems. One significant challenge faced in such a process was the miniaturization of the propulsion system. Electrosprays have started to find their application in the field of Aerospace Engineering and now are formally known as Electrospray Thrusters. These thrusters provide high specific impulse and are attractive substitutes …

Experimental Evaluation Of A Honeycomb Structure In Open Channel Flows, Kyle David Hix

Masters Theses

“Designing and controlling open channel flows presents many challenges. One such challenge is energy dissipation. This challenge is currently addressed by several means, including the use of honeycomb structures. Energy dissipation by honeycomb structures has been studied for pressurized conduit flows; however, their ability to dissipate energy in free-surface flows remains largely unexamined. This work introduces a comprehensive experimental study designed to estimate the energy dissipation through a honeycomb structure in a free-surface flow.

This work examined the energy dissipation for a range of flows, pipe lengths, and pipe diameters in two flumes. PVC pipes ranging from 6 inches to …

Modeling And Control Of Cascaded Bridgeless Multilevel Rectifier Under Unbalanced Load Conditions, Sai Hemanth Kankanala

Masters Theses

“The goal of this project is to model and control a novel unidirectional cascaded multilevel bridgeless rectifier as an active front end in medium and high voltage applications. This topology has many advantages over a conventional cascaded H-bridge rectifier, such as lower implementation cost, higher reliability, and greater flexibility with similar power quality. The complete design process of the proposed converter is developed step by step in order to meet all the desired objectives. The steady-state mathematical model is used to develop a method for the voltage balancing of dc cells. Power factor analysis is discussed to mathematically derive requirements …

Computer Vision Based Deep Learning Models For Cyber Physical Systems, Muhammad Monjurul Karim

Masters Theses

“Cyber-Physical Systems (CPSs) are complex systems that integrate physical systems with their counterpart cyber components to form a close loop solution. Due to the ability of deep learning in providing sensor data-based models for analyzing physical systems, it has received increased interest in the CPS community in recent years. However, developing vision data-based deep learning models for CPSs remains critical since the models heavily rely on intensive, tedious efforts of humans to annotate training data. Besides, most of the models have a high tradeoff between quality and computational cost. This research studies deep learning algorithms to achieve affordable and upgradable …

Intrinsic Mechanical Properties Of Zirconium Carbide Ceramics, Nicole Mary Korklan

Masters Theses

“This research focuses on the processing and mechanical properties of zirconium carbide ceramics (ZrC_x). The first goal of this project was to densify near stoichiometric (i.e., x as close to 1 as possible) and nominally phase pure ZrC_x. The maximum stoichiometry achieved for the ZrC_x (C/Zr ratio of 0.92) was measured using gas fusion analysis. Hot pressing was used to obtain dense ZrC_x. Archimedes was used to determine the relative density of hot pressed ZrC_x at > 95%. Scanning electron microscopy (SEM) was used to determine the overall microstructure of the hot pressed …

Microgel Placement And Plugging Performance In Sand Filled Fracture For Conformance Control, Baihua Lin

Masters Theses

“Preformed particle gels (PPG) has been widely applied for conformance control in heterogeneous reservoirs with fractures and super-K channels. As a plugging agent, PPG could plug the fractures or high permeability streaks and divert the displacing fluid into low permeability matrix. Many studies have been conducted to investigate the potential of PPGs as a water cut reduction and improved oil recovery agent using homogeneous sandpacks or heterogeneous core samples with man-made open fractures. However, no research has been carried out to understand how PPG injection and plugging performance will be changed if the fractures are filled with sands. Herein, the …

Inclusion Control In Steel Castings, Koushik Karthikeyan Balasubramanian

Masters Theses

“Non-metallic inclusions are mainly comprised of oxides, sulfides, and nitrides, and are formed in liquid steel during the melting and refining process, as a result of reoxidation, worn-out refractories, or entrained slag. The notch toughness of high strength steels is particularly susceptible to the type, number, size, and distribution of non-metallic inclusions. High manganese and aluminum austenitic steels, or Fe-Mn-Al steels, have gained much interest in the military and automotive sector because of their excellent combinations of high strength and toughness. However, these steels are subject to both oxide bifilms and aluminum nitride, AlN, inclusions which form during melting and …

Therapeutic Dna: Delivery And As A Delivery Vehicle, Natalie J. Holl

Masters Theses

"A review of gene delivery methods and gene editing methods, as well as original research utilizing DNA as a delivery vehicle is presented in the following thesis. Thousands of diseases have been linked to genes. Gene therapy, either delivering therapeutic genes or editing DNA bases, has arisen as a treatment option with the potential to cure diseases, rather than just ease symptoms. Genes and editing tools need to be delivered to cells for these therapies to be effective and many techniques have been developed to address the issue of delivery. Nonviral and viral methods have been used to deliver nucleic …

On The Investigation Of Hot Tearing Behavior Of Continuous Cast Steel, Yanru Lu

Masters Theses

”Hot tearing has long been recognized as a major problem that plagues the development of the continuous casting process and results in low-quality products. Understanding of the mechanisms and the required conditions for the hot tearing formation is important for industries but has not been well-established yet. Thus, this research focuses on the hot tearing issue observed in continuous cast steel, by providing a summary of the current research progress and then introducing a new laboratory method to determine the thermo-mechanical properties relevant to hot tearing of different steel grades under different solidification conditions. In this method, an apparatus was …

Aquatic Plants And Their Application To Successful Floating Treatment Wetlands, Katherine May Mazanec

Masters Theses

“This research aims to mitigate eutrophication of freshwater habitats affected by urban stormwater runoff. Two highly impacted urban ponds near the Missouri S&T campus in Rolla were the focus of this research on the application of floating treatment wetlands (FTWs). An FTW consists of a man-made floating mat that is planted with emergent or floating macrophytes. The plants grow on the mat and their roots extend into the water column below the mat. Plant tissues, especially roots in direct contact with the water, take up nutrients, act as biofilm growth sites, and may facilitate precipitation of nutrients. With urbanization, ponds …

Micro-Analysis Of Contaminants In Suspended Load And Bank Deposits From The Mineral Fork Creek Watershed In Potosi, Missouri, 2019-2020, William Joseph Miller

Masters Theses

”There are rising concerns pertaining to water contamination produced by toxic heavy metal contaminants such as lead and zinc. For this study, lead, zinc, and barite are three identified contaminants currently threatening Missouri water supplies. A microanalysis of the amounts of lead, zinc, and barite in the water of Mineral Fork Creek was conducted, involving both field and laboratory work. The purpose of the study was to determine the levels of lead, zinc, and barite contaminants, contributing to Big River, by Mineral Fork Creek, in Potosi Missouri, Washington County.

This research study uses a quantitative micro-analysis approach to determine the …

Evaluation Of The Symbiotic Relation Between Endophyte And Poplar Trees Exposed To Landfill Leachate, Catalina Vega Hurtado

Masters Theses

“The contamination of soil and groundwater from leachate leakage from landfill has turned, nowadays, into a global public issue. One of the main concerns about this pollutant is the potential threat to human and ecosystem health. The current research studied endophyte bacteria in association with poplar trees (Populus sp.), as a method of bioremediation of landfill leachates. The objective of the project was to identify treatment strategies that may improve plant performance (survival rates, plant fitness, and degradation efficacy) with the purpose of being implemented in phytoremediation plots, aimed to intercept and treat landfill leachate, before the contamination of watershed. …

Quantifying Effects Of Sleep Deprivation On Cognitive Performance, Quang Nghia Le

Masters Theses

“The most commonly used metric for evaluating alertness and vigilance is the Psychomotor Vigilance Test (PVT), previous studies have indicated that alertness and vigilance can be affected by the lack of sleep as a function of sleep loss. This study explores methods to predict median psychomotor vigilance reaction times. The data used in this study comes from a series of tests and surveys conducted on volunteer students. The data set contains many potential predictors of PVT and one aspect of the study was to identify variables that are useful in prediction. The performances of various prediction methods that allow for …

Strain Partitioning Across The Polochic-Motagua Fault System In Guatemala: Insight From Kinematic Modeling, Qiaoqi Sun

Masters Theses

”The Polochic-Motagua Fault System in Guatemala is the on-land segment of the sinistral transform plate boundary between the North American Plate and the Caribbean Plate. Three major seismically active strike-slip faults in this fault system pose significant earthquake threats to surrounding populated cities. The assessment of seismic hazard requires a better understanding of the kinematics of the fault system. GPS monitoring indicates that seventy-five percent of the ~20 mm/yr. plate motion is accommodated by the Motagua Fault and less than twenty-five percent is accommodated by the Polochic Fault. However, the Polochic Fault documents a lateral offset of ~132 ± 5 …

Design And Comparison Of Unoptimized And Optimized Gray Code Multi-Level Systems, Shirly Adams Gamliel

Masters Theses

“As the conventional binary MOS-based VLSI technology is reaching limitations in chip area, speed, and power, new technologies are being researched. Some such technologies relate to multi-level logic design. This thesis explores the process and benefits of applying and optimizing multi-level design techniques to an existing Gray code binary system. Specifically, the multi-level system is designed using CoreMem technology and is optimized using Indira Dugganapally’s optimization techniques.

The first step is generating the n-bit binary and quaternary truth tables for an encoder’s Gray code output and additional desired data. Then, the data for each n-bit system is arranged in multi-level …

Modal Analysis As Non-Destructive Testing Technique For Additively Manufactured 304l Stainless Steel Parts, Tristan N. Cullom

Masters Theses

“Non-Destructive Testing (NDT) methods for Additively Manufactured (AM) parts is an ongoing field of research in the additive community due to its ability to determine if a part can be deemed viable for field usage. This study presents modal analysis as a NDT method for AM parts. For production builds that have multiple copies of the same part, a correcting technique can be used such that the frequencies of the parts under test can be reliably compared against each other, which saves both time and money compared to other traditional NDT methods. This study was able to develop a novel …

3d Printing Reinforced Concrete Structures, Bryce Tyler Tafolla

Masters Theses

"This study aims to investigate a 3D printing method to directly incorporate continuous reinforcement into concrete structures. The ability to design and produce complex structures with optimized topographical configuration can be used to reduce potential material waste while maintaining the required structural strength. Furthermore, the ability to actively incorporate reinforcement into printed members substantially reduces potential labor requirements and eliminates the need to set up formwork.

The study began its initial approach with a manual extrusion process containing reinforcement to observe the necessary constraints required to achieve a printing system with this functionality. The second stage of development was designing …

Simulation And Modeling Of Cold-Wall Hypersonic Turbulent Boundary Layers On Flat Plate, Junji Huang, Gary L. Nicholson, Lian Duan, Meelan M. Choudhari, Rodney D.W. Bowersox

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Direct numerical simulations (DNS) of flat-plate, zero-pressure-gradient turbulent boundary layers are presented for nominal freestream Mach numbers of 11 and 14 and a highly cooled wall (wall-to-recovery temperature of approximately 0.2). The flow conditions of the DNS are representative of the experimental data for a Mach 11.1 turbulent boundary layer on a flat plate that was tested at Calspan–University of Buffalo Research Center (CUBRC) and the operational conditions of the AEDC Hypervelocity Tunnel No. 9 at Mach 14. The wall shear stress and turbulent heat flux predicted by DNS show good comparisons with those measured at CUBRC and those modeled …

Erratum: Minimization Of The Kullback-Leibler Divergence For Nonlinear Estimation (Journal Of Guidance, Control, And Dynamics, (2017), 10.2514/1.G002282), Jacob E. Darling, Kyle J. Demars

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Erratum Notice In the original article [https://doi.org/10.2514/1.G002282], Eqs. (16b) and (18b) were typeset as (Formula Presented) which incorrectly show that the posterior covariance at time tk, denoted by Pk, is calculated about the prior mean, m−k. The correct forms of these equations are given by (Formula Presented) which show that Pk is calculated about the posterior mean, mk. All resulting analyses and simulations reported in the article were performed using the correct forms of the equations.

Information-Based Particle Flow For High Uncertainty Estimation, Kari C. Ward, Kyle J. Demars

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This work presents a new formulation of the Gaussian particle flow filter derived using an information theoretic approach. The developed information flow addresses two problems with Gaussian particle flow: the lack of inherent meaning in the flow parameters and the inability to easily include modifications for a non-Bayesian update. Equivalency between Gaussian particle flow and information flow is established using a linear, Gaussian example. An orbit determination simulation with high initial uncertainty is used to demonstrate the consistent, robust performance of the information flow filter in situations where the extended Kalman filter fails.

Robots On Blockchain: Emergence Of Robotic Service Organizations, Nobuyuki Fukawa

Business and Information Technology Faculty Research & Creative Works

Radical changes in the technological environment have been forcing service providers to consider whether, if so, how to automate any aspects of their services with robots and other emerging technologies. Some service providers have been adopting robotic service assistants, and even creating organizations partially or fully automated by robots. However, some service providers have not been able to fully take advantage of RSAs’ benefits in a way that enhances customer service experiences. We review those challenges of RSAs and discuss the potential application of blockchain technology in governing a robotic service organization, the concept we propose in this study. …

Pseudospin-Polarized Topological Line Defects In Dielectric Photonic Crystals, Menglin L.N. Chen, Li (Lijun) Jun Jiang, Zhihao Lan, Wei E.I. Sha

Electrical and Computer Engineering Faculty Research & Creative Works

Electromagnetic (EM) topological insulators have been extensively explored due to the robust edge states they support. In this work, we propose a topological EM system based on a line defect in topologically nontrivial photonic crystals (PCs). With a finite-difference supercell approach, modal analysis of the PC structure is investigated in detail. The topological line-defect states are pseudospin polarized and their energy flow directions are determined by the corresponding pseudospin helicities. These states can be excited by using two spatially symmetric line-source arrays carrying orbital angular momenta. The feature of the unidirectional propagation is demonstrated, and it is stable when disorders …

Attack Detection And Mitigation In Mobile Robot Formations, Arnold Fernandes

Masters Theses

"A formation of cheap and agile robots can be deployed for space, mining, patrolling, search and rescue applications due to reduced system and mission cost, redundancy, improved system accuracy, reconfigurability, and structural flexibility. However, the performance of the formation can be altered by an adversary. Therefore, this thesis investigates the effect of adversarial inputs or attacks on a nonholonomic leader-follower-based robot formation and introduces novel detection and mitigation schemes.

First, an observer is designed for each robot in the formation in order to estimate its state vector and to compute the control law. Based on the healthy operation of the …

Erratum: Causal Knowledge Promotes Behavioral Self-Regulation: An Example Using Climate Change Dynamics (Plos One (2017) 12:9 (E0184480) Doi: 10.1371/Journal.Pone.0184480), David K. Sewell, Peter J. Rayner, Daniel Burton Shank, Sophie Guy, Simon D. Lilburn, Saam Saber, Yoshihisa Kashima

Psychological Science Faculty Research & Creative Works

In the Task overview: Managing a dynamic human-climate system subsection of the Introduction, there is an error in equation 4. There is a factor of τ that is missing from the denominator of the first term that appears on the right-hand side of the equation. Please view the complete, correct equation here [Formula Presented].

Measurement Of Sub-2 Nm Stable Clusters During Silane Pyrolysis In A Furnace Aerosol Reactor, Miguel Vazquez-Pufleau, Yang Wang, Pratim Biswas, Elijah Thimsen

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The initial stages of particle formation are important in several industrial and environmental systems; however, the phenomenon is not completely understood due to the inability to measure cluster size distributions. A high resolution differential mobility analyzer with an electrometer was used to map out the early stages of Si particle formation from pyrolysis of SiH4 in a furnace aerosol reactor. We detected for the first time subnanometer stable clusters from silane pyrolysis, and the diameter was measured to be about 0.7 nm. This diameter is within the range of probable sizes that the reported families of critical silane clusters could …