Digital Commons Network^™

A Preliminary Study Of The Effect Of Heat Treatment On The Strength And Microstructure Of A Glass-Ceramic Material, P. D. Ownby

Masters Theses

"The strength and microstructure of a glass-ceramic material of the composition 53 percent SiO₂, 19 percent Al₂O₃, 15 percent MgO, and 13 percent Li₂O were studied. Cylindrical specimens of glass were formed and heat-treated to six different temperature levels for various time periods. The method of strength testing used was a diametral compression loading technique. It was found that the strength of this material increased initially with heat-treatment but then decreased. The strength characteristics of the completely crystallized glass ceramic material were found to be dependent on the initial nucleation period. Some factors which influenced anomalous crystal growth are described. …

The Separation Of Germanium From Lead, Cadmium, And Zinc By Ion Exchange, Myra Sue Anderson

Masters Theses

"The object of this study was to investigate the ion exchange behavior of germanium in order to find a quantitative separation method applicable to the analysis of germanium in zinc ores.

Germanium had been predicted and described as eka-silicon by Mendeleeff, and was discovered by Winkler in 1886. The importance of the metal has increased very much since World War II because of its use as a semiconductor in diodes and transistors.

All commercial scale germanium is now produced as a by-product of base metal processing. Although the United States Bureau of Mines is conducting a program for the recovery …

K₂O/Na₂O Content As A Possible Index To The Chronological Sequence Of Some Precambrian Igneous Rocks Of Missouri, Erwin Joseph Mantei

Masters Theses

"Flame photometric analyses for K₂O and Na₂O were run on 31 samples of the Precambrian igneous rocks of Missouri. Samples were collected from the field, physically prepared and dissolved by a standard method and a modified standard method of rapid silicate analyses. The K₂O, Na₂O values obtained are averages between two methods of analyses. The modified method reduces by 80% the time required to chemically digest a rock sample. The results for both methods are not significantly different. Curtin and Company Advanced Flame Photometer was used.

Results have been plotted on graphs and a chronological sequence for the named Precambrian …

Experimental Evaluation Of Thermal Strains And Stresses, T. F. Lehnhoff

Masters Theses

"This investigation is the study of a method for the experimental measurement of thermal strains. Using four electric strain gages (two of one type and two of another) the method will yield the normal and shear strains as well as the temperature change in any biaxial stress field. The gage types must be chosen for the range of temperature in which it is desired to measure the thermal stresses. The method described eliminates the need for extra resistors, thermocouples, unrestrained dummy gages at the same temperature as the active gages, special alloy gages for each type of metal and special …

Transpiration Cooling Of A Heat Generating Porous Plate, M. K. A. Hameed

Masters Theses

"This investigation is a continuation of a thesis by T. S. Purewal. Several of the simplifying assumptions made by the above author are either ignored or the justifiability of such assumptions is probed into in order to obtain a more rigorous solution. Effects of the assorted grain size, non-Newtonian cooling, direction of coolant flow, thickness of the porous heat generating plate, specific heat of the coolant, and compressibility of the coolant are investigated in this thesis. Variation of maximum temperature of both coolant and the solid material for different types of heat source distribution are also studied.

As the grain …

An Investigation Of Lehmer's Method For Finding The Roots Of Polynomial Equations Using The Royal-Mcbee Lgp-30, James W. Joiner

Masters Theses

“The solution of the general polynomial equation f (x) = O, where f(x) = a_nxⁿ + a_n-1x^n-1 + … + a₁x = a_o, has received the attention of many mathematicians for hundreds of years and is at present in a very highly developed state. Even a cursory examination of the literature will reveal many volumes on this subject. However, this study is concerned primarily with the numerical methods for solving polynomial equations, hence the classical methods will be treated here only as they contribute to this field.

Virtually all of …

A Survey Of The Influence Of Selected Sulfides On The Thermal Decomposition Rate Of Zinc Sulfate, L. G. Twidwell

Masters Theses

"The influence which ZnS, CdS, Cu₂S, PbS, and FeS has on the thermal decomposition rate of ZnSO₄ was studied by measuring the SO₂ gas evolved per unit of time for various ZnSO₄-MeS mixtures at 600°C, and analyzing the solid phases by means of X-ray diffraction patterns.

The SO₂ gas evolved upon heating the pellets was analyzed as a function of time by absorbing the gas in a solution of distilled water, H₂O₂, and NaOH, and measuring the time required for the SO₂ to neutralize the NaOH. The gas …

Preliminary Investigation Of The Effects Of Seeding Fusion Cast Refractories, Thomas Spencer Montgomery

Masters Theses

"The crystallization process in a zirconia-alumina- silica melt of high viscosity was studied, A system was used of the same composition found in commercial electrocast glass tank refractories. Artificial nucleation was tried in an attempt to control the process of crystallization; the method involved the addition of suitable "seeding" material.

It was found that introduction of nucleation agents consisting of the major component oxides of the system had noted effect upon the course of crystallization. Preferred orientation normally found in unseeded electrocast refractories was diminished with the addition of zirconia grains and amplified with particles of tabular alumina.

Results obtained …

Effect Of The Mixed Liquor Suspended Solids Concentration On The Treatment Of Dairy Wastes By Activated Sludge Process, Meredith Hambleton Saxer

Masters Theses

"The effect of the mixed liquor suspended solids concentration on the treatment of dairy wastes by the activated sludge process was investigated to provide original and basic information of value to the waste water treatment field.

The studies were conducted using a continuous flow activated sludge laboratory unit. Two different synthetic dairy waste systems were used in this investigation, the 0.05 Percent Skim Milk Waste System and the 0.1 Percent Skim Milk Waste System. These wastes provided BOD loadings of 43.9 and 91.1 lb. BOD per day per 1000 cu. ft., respectively, at the 12 hour detention period employed. Mixed …

A Study Of The Electro-Chemical Injection Of Ca(Oh)₂ Into Pure Kaolin Clay, Sam Michael Savas Jr.

Masters Theses

"The work presented in this thesis is the investigation and study of a possible and successful means of injecting an electrolyte solution into a fine grain soil mass with the use of electric current and to measure some of the changes of its physical properties. A NoKarb Georgia Kaolin Clay was treated by passing a preferential electrolyte solution of Ca(OH)₂ using direct current for a period of one and six days. The tests performed during this investigation included the following: (a) tri-axial tests, (b) atterberg limits, (c) pH determination, (d) moisture content change (from treatment), (e) visual settling of treated …

Investigation Of Flow Rates Through A Rockfill Dam With An Internal Spillway, Jerry R. Bayless

Masters Theses

"Tests were performed on a model of a rockfill dam with an internal spillway for the purpose of developing a method of predicting the flow rate through the dam. The flow rate depends upon the head but is affected by the rock size and the height of the impervious core; there- fore, these factors were varied in the study. A relation for flow rate in terms of head was found for each combination of rock size and core height used and was compared to the general weir equation to find the coefficient of contraction; thus the effect of changing core …

An Evaluation Of State Mineral Taxation In Missouri, Jerry Wayne Huffman

Masters Theses

"A study was made to evaluate the present taxes levied on the mineral industry in the State of Missouri. The corporate income tax, corporate franchise tax, and general property taxes were examined, in addition to the mine inspection fees and methods of local assessment of mineral properties.

It is suggested that the State of Missouri revise the method of application of the general property tax to mineral properties. Utilization of the principle of taxation of future profits and employment of qualified appraisers would provide a more equitable application of the general property tax.

It is recommended that the present mine …

An Evaluation Of The Resistance Element Method For Measuring Detonation Velocity Of An-Fo Mixtures Confined In Small Diameter Boreholes, William Stewart Breakey

Masters Theses

"Instrumentation and techniques employing a constant current in a 4 ft. length of Nichrome resistance wire embedded in an explosive mixture were developed to measure detonation velocity in small diameter boreholes.

The resistance element technique was evaluated by detonating mixtures in iron and clay pipes, and it was shown that the current in the circuit was not constant. Velocity measurements varied from 8,000 fps to 16,000 fps. Low velocity material provided poor time - voltage traces.

The resistance element method was compared to a pin oscillograph technique, and an explanation was offered for observed differences in velocity. The standard deviation …

A Study Of The Problems Of Design Of Optimum Vibration Absorbers For Multi-Mass Systems, James C. Villegas

Masters Theses

"The purpose of this investigation was to continue the preliminary work of Burrows on the application of tuned and damped vibration absorbers to the reduction of vibratory stresses in a multi-mass torsional vibration system. A hypothetical engine system was chosen for both investigations because it had many complicating factors and gave an eminently practical subject for study.

Attention was centered on the reduction of stresses resulting at higher speeds of the machine system and on developing methods and criteria for the designing of effective absorbers where several modes of vibration exist in the operating speed range of the machine"--Abstract, page …

A Tunnel Diode Parametric Down Converter, Leland Lovell Long

Masters Theses

"The problem, as presented, is to derive analytical expressions for the conversion gain, bandwidth, and noise figure of a self excited tunnel diode converter and to verify, if possible, the validity of these express- ions by building such a converter. These analytical results are presented and discussed. The converter circuit is shown along with the resulting intermediate frequency output. Gain and bandwidth measurements are also given. It is concluded that the self excited converter could very definitely be of value as a low noise pre-amplifying device in the ultra-high frequency and microwave frequency ranges"--Abstract, page ii.

Seismic Investigation Of Flint Clay Deposits In East Central Missouri, Roland D. Dayley

Masters Theses

"Seismic refraction surveys were conducted in several localities within the east central Missouri clay districts in order to determine the applicability and economy of this method as a clay exploration tool. Results of these surveys revealed that the sink-type clay deposits possess lithologic and structural characteristics that lend themselves favorably to this method of exploration.

Seismic records obtained from profiles shot across known deposits indicate that several factors other than velocity contrast serve to produce apparent seismic anomalies.

Some unforeseen time loss and expense was encountered because of malfunctions of the seismic equipment employed, which necessitated the purchase and installation …

The Experimental Determination And Prediction Of Ternary-Liquid Equilibria Data, Risdon William Hankinson

Masters Theses

"Although the field of liquid extraction is of increasing importance in today's chemical industry, the ternary-liquid data so necessary to the design and study of extraction operations are available in the literature only to a limited extent. During the twentieth century, approximately 120 ternary-liquid systems have been studied. However, limiting solubility data have been reported for approximately one-third of these systems, and about 30 per cent of the equilibria data reported for the remainder of these systems are incomplete or inaccurate.

Within limits, liquid equilibria data may be calculated for a ternary system from the properties of its constituents which …

Study Of The Design Of Reinforcement For Prestressed Concrete And Blocks, Charles Robert Hoffman

Masters Theses

"This thesis is an analysis of the transverse tensile stress condition in an end block of a prestressed concrete beam. A stress analysis was made by photoelasticity and compared to the mathematical solutions and experimental solutions performed by others on concrete models. The photoelastic model was made from a piece of Columbia Resin, 39.

Whatever method is chosen to determine the stress condition, there is no exact code that can be established to fit the various type problems which arise"--Abstract, page 1.

Fractionation Of Fission Elements By Electrodialysis, George Joseph Bub

Masters Theses

"The development of nuclear power has presented countless problems to the scientists and engineers of today. A problem of extreme importance is the disposal of radioactive wastes. Another is the recovery of some of the useful radioisotopes from fission product waste solutions. This investigation is concerned with the recovery of some of the fission elements for use in radiochemical and medical research and in industry.

At present little effort is made to recover useful fission elements. The fission product waste solutions are treated to reduce the volume and are stored until the radiological hazard is reduced and are then disposed …

Refrigeration Heat Transfer Characteristics Of An Artificially Cooled Trout Pond, Richard G. Murray

Masters Theses

"In many locations natural summer lake and pond temperatures are too great for the practical production of trout for fishing purposes.

The purpose of this thesis is to investigate the refrigeration capacity required to maintain a pond of water at a temperature that provides a healthful environment for trout.

The over-all refrigeration load for this application was sub-divided into four categories; conduction, convection, evaporation and radiation. Each type was solved by analytical means using suitable boundary conditions and simplifications. It was necessary to determine one boundary condition for the conduction heat transfer by an empirical method.

The results of this …

Porous Cooling Of A Pile, Tarsem Singh Purewal

Masters Theses

"In this investigation the problem of a limiting case of steady state one dimensional solid-fluid Newtonian heat transfer is examined in which an incompressible non-heat generating coolant fluid is flowing through a heat generating porous plate.

The effect of grain size on the Newtonian heat transfer in the porous plate with various kinds of internal heat generations is determined analytically. The temperature difference between the solid and the coolant fluid through the porous plate is determined. All the previous studies assume that in the porous plate, coolant fluid temperature and solid temperatures are approximately equal. This analysis eliminates this simplifying …

The Dissolution Of Magnesium In Strong Acids, Baldev K. Bhatia

Masters Theses

"The rapidly growing demand for magnesium and magnesium-base alloys in the manufacture of aircraft has led to a great amount of research into the corrosion characteristics of these materials. The result of such research has been the development of suitable magnesium alloys and protective coatings to retard corrosion.

The standard electrode potential of magnesium lies between -2.35 volts and -2.54 volts at 25⁰C (hydrogen scale). Thus, magnesium lies next to aluminium in the electrochemical series of elements. The atmospheric corrosion of magnesium has been studied under conditions of indoor and outdoor exposure. Under these conditions the initial attack is formation …

A Study Of Small Watersheds Within The State Of Missouri, Terence E. Harbaugh

Masters Theses

"The present status of data from watersheds in the under 10 square mile drainage area classification, pages much to be desired. However, this study of 45 small watersheds within the State of Missouri gives an indication that surface runoff from these basins may be predicted with a fair degree of accuracy. The inclusion of a shape factor AL² and its use as a portion of the "basin index" (AL²S^1/2) gives accurate results as a predictor of the "mean annual flood". The mean annual flood may be adequately computed by the formula, MAF = 113(AL^{2 …}

A Theoretical Study Of The Mechanism For The Haeffner Effect, David Charles Jacobs

Masters Theses

"In 1953, E. Haeffner reported that when he had passed a direct electric current through a length of capillary filled with liquid mercury, the lighter mercury isotopes were enriched at the positive terminal and the heavier mercury isotopes were enriched at the negative terminal. This phenomenon is referred to as the Haeffner Effect. Since Haeffner’s original experiment, other investigators have obtained similar results in other liquid metal systems.

When a direct electric current passes through a metallic conductor a free energy gradient is established. The direction of the negative free energy gradient is in the direction of the positive terminal. …

Shear Stress Distribution In Haunched Beam Models, Manyu K. Mehta

Masters Theses

"The purpose of this thesis has been to give the distribution of shear stress inside a haunch. A haunch is generally provided to relieve high stress concentrations at the face of the column. However the nature of shear stress distribution inside the haunch is not known.

This stress distribution was determined from a photo- elastic study on a CR-39 model. It is noted that the haunch reduces the stress concentration at the face of the column but at the same time somewhere near the point where the haunch meets the beam there is a high stress concentration.

Shear stress changes …

Velocity Distribution Induced By Free Jet Impact On A Stilling Basin, Sedat Özkol

Masters Theses

"At present, the use of the free jet impacting on a stilling basin as an energy dissipator is not very common, as there is very little information available concerning this particular field. However, if conditions are favorable, this type of energy dissipator will be quite economical to construct.

In this paper it was found that the hydraulic behavior of the free jet impacting on a stilling basin can be determined to a degree which may be considered accurate for practical purposes. It was also shown that given the free jet velocity, the magnitudes of the velocities at the critical points …

Linear Feedback Control System Compensator Design Under Specified Constraints, Keikhosrow Irani

Masters Theses

"The purpose of this thesis is to find the necessary and sufficient conditions for the design of compensators, following the concepts developed by Ross, Warren, Hsu and Sanden.

The main object that motivates this investigation is to design the lead or lag compensator networks for a given linear feedback system when there are these constraints.

1. Gain of the system is constant.
2. The steady-state error is invariant.
3. The dominant poles of the closed-loop transfer function are specified.

Consideration of the problem is in two parts:

• a. Derivation of necessary and sufficient conditions of compensator design that fulfill the three constraints.
• b. …

Stylolites And Sedimentary Structures In The Cave-In-Rock Fluorspar District, Southern Illinois, Won Choon Park

Masters Theses

"This thesis deals with stylolites, slump structures, sulfides in the oolitic limestone, and geometry of the bedded fluorite deposits in the Cave-In-Rock fluorspar district, southern Illinois. Stratigraphic zones studied were: 1) the upper part of the lower Fredonia limestone member, 2) the upper part of the upper Fredonia limestone member,,and 3) the upper part of the Renault formation.

Geometry of the ore rocks and related structures was investigated. Most of the ore is layered and constitutes part of the sedimentary strata.

Slump structures were observed and studied in detail. Most of the slump structures show evidence which indicates a sedimentary …

Mechanics Of The Voussoir Arch As Applied To Block Caving, Christopher Haycocks

Masters Theses

"The theories of ground failure in massive rock with special reference to the problem of the mechanics of block caving were studied and evaluated.

The mechanics of arch or dome formation underground were studied quantitatively using the Voussoir arch theory. The effect of shear stress on the arch stability was considered and found to affect the system only when the arch height increased beyond certain limits.

A theory of the mechanism of ground failure in an undercut block using the dome theory was advanced. Photo- elastic model studies were used to support the conclusions reached"--Abstract, page i.

The Dielectric Strength Of Some Anti-Corrosive Paints, George Albert Chappell Iii

Masters Theses

"Corrosion has been one of the costly problems to industry because each year losses due to corrosion are in excess of six billion dollars. Corrosion is caused by the tendency of all metals to become oxidized and return to their natural state. Oxidation may be suppressed by restraining the flow of electrons from the system, thereby inhibiting corrosion.

One effective means to prevent rusting is by applying a barrier of paint between the system and the corrosive atmosphere. Not all paints, however, are equally effective as corrosion inhibitors. At present, the only effective means of determining the corrosion resistant ability …