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A Survey Of The Methods Of Gas Analysis, Yadvendra V. Desai

Masters Theses

"The object of this thesis is to survey the different types of gas analyses. Subject concentration will be centered on the general and specific instrumental methods of gas analysis. A general account of continuous automatic gas analyzers will be included. References are included for the use of those who desire a more comprehensive knowledge of a specific method of gas analysis.

During recent years, the importance of gas analysis has been considerably increased with the advancement of science and technology. Gas analysis mainly involves the identification, quantitative evaluation and separation of the components of a gaseous mixture. Thus it includes …

Glass-To-Sapphire End Window Seals, Edward E. Stepp, Richard A. Anderson

Physics Faculty Research & Creative Works

SAPPHIRE windows have been used in laboratory devices where radiation from the ultraviolet through the infrared must be transmitted. Sapphire windows have been valuable in chambers which contain the alkali metals, for the alkali metals are known to react with Pyrex 7740 glass and quartz leaving them pitted and darkened. This paper is a report on an improved glass-to-sapphire end window seal.

A Determination Of Vapor Pressure Of Barium In The Thermal Production Of Barium Metal, Thomas A. Theobald

Masters Theses

The Knudsen effusion method was used to find the equilibrium reaction pressure of barium for the following reactions:
4BaO + 2Al - 3Ba + BaO·Al₂O₃ (l)
4BaO + Si - 2Ba + 2BaO·SiO₂ (2).
The resulting barium pressure for reaction (l) ranged from 0.27 mm. Hg to 1.77 mm. Hg in a temperature range of 940°C to 1086°C. The barium pressures for reaction (2) varied from 0.38 mm. Hg to 1.94 mm. Hg in a temperature range of 1000°C to 1086°C. The free energies of formation of BaO·Al₂O₃ and 2BaO·SiO₂ at 1087°C …

A Model Study Of The Application Of Roof Bolts Under Unsymmetrical Loading Conditions, Friedrich H. K. Esser

Masters Theses

"When coal is extracted by the long wall mining method, two gate-roads on either side of the working face are driven with the advancing operation. In the surroundings of these openings the state of stress which existed prior to mining is not only disturbed by the drifting process of the gate-roads but also by the coal extraction in the long wall, resulting in an "unsymmetrical" stress distribution. Varying incremental pressure components and the high complexity of strata movements make it extremely difficult to control the rock behavior under unsymmetrical conditions by conventional support. Application of roof bolts as an auxiliary …

Dipole Approximation Of The Solution For An Electrode Configuration In Two-Layer Resistivity Problem, Siew Hung Chan

Masters Theses

"An electrode configuration which consists of a pair of current electrodes, spaced at a unit apart, being kept at a great distance r from a pair of potential electrodes also spaced at a unit apart, has been investigated. Two theoretical apparent resistivity formulae were derived by applying Kelvin's theory of images to the problem of two-layer case. One formula is obtained by the exact method of solution, the other being obtained by considering the pair of current electrodes as a single dipole. Results of numerical calculations show that the greater the spacing r in comparison to the spacing a, …

The Removal Of Sub-Structure From Alpha Uranium, Albert E. Bolon

Masters Theses

"The possibility of obtaining larger, perfect single crystals of alpha uranium by a modified strain-anneal method has been investigated. A -196°C tensile deformation was performed on pseudo single crystal rods which had been prepared by the phase transformation method. The specimens were subsequently annealed at 650°C.

It was found that by utilizing pseudo single crystals with a prescribed crystallographic orientation with respect to the tensile axis that recrystallized crystals of comparable size and perfection to those prepared by the grain coarsening method could be produced. Grain coarsening is the presently accepted process for preparing perfect single crystals of alpha uranium. …

Circular Arch Analysis, Aylmer Pao-Sheng Cheng

Masters Theses

"This work presents an analysis of a two-hinged circular arch by both the elastic theory and the deflection theory. The basic assumption made in this analysis was that the moment of inertia of the arch rib and the normal force vary as the secant of the angle with respect to the crown. The increase of maximum moment as found by the deflection theory was in the range of 30%"--Abstract, page 2.

Thermal Conductometer For Liquids, Yuan-Kai Chang

Masters Theses

"The published data pertaining to the thermal conductivity of liquids are of such a character that it is very difficult to determine from them the correct value, or the temperature coefficient for any liquid.

Most of the published values of thermal conductivity for liquids are evaluated at one particular temperature. It is the purpose of this investigation to design, construct and calibrate a thermal conductometer for liquids over a temperature range of 30°F to 200°F.

Since water and glycerol were the only liquids found by this investigator with published data on their conductivities as a function of temperature, they were …

Syntheses And X-Ray Investigations Within The System Fes₂-Cos₂, Samuel Shu Mou Chan

Masters Theses

"Pyrite (FeS₂), cattierite (CoS₂), and various transitional members of the solid solution compounds were prepared. The methods used are as follows:

First, sulfides of cobalt, iron, or cobalt-iron were obtained by precipitation from a mixture of the cobalt chloride and/or ferrous sulfate in an aqueous solution. The dried precipitates were then mixed with an equal weight amount of sulfur and placed into silica glass tubes. After evacuation, they were filled with hydrogen gas of 3/4 of atmospheric pressure and sealed. The samples were then heated up to 500°C (for FeS₂), 650°C (for FeS_{2 …}

Analog Study Of Vibratory Forces In Sorting Machine, Navnit Chhaganlal Mehta

Masters Theses

"This investigation involves the study of the reduction of vibratory forces in a sorting machine. The equivalent masselastic system is shown in Figure 1, in solid lines. In this figure the mass m₁ represents the main structure for the mounting of the machine, the mass m₂ is the main bearing blocks and the mass m₃ is the vibrating basket. The elastic stiffness indicated as k₁ represents the mounting spring for the entire unit, the stiffness k₂ is that of the beam structure by which the bearing block is attached to the main structure, and the stiffness k₃ is that of …

The Effect Of A Continuous Low Temperature On The Operation Of Waste Stabilization Lagoons, Ralston Kennedy Dennis

Masters Theses

"This study was undertaken to determine the effect of a continuous low temperature on the operation of a waste stabilization lagoon and to provide information of value to the sewage treatment field.

The investigation was conducted using two experimental lagoons subjected to a continuous illumination of 550 to 600 foot candles emitted by two fluorescent light fixtures. Of these units, the Cold Room Lagoon was maintained at a controlled temperature of 5° C. and the Warm Room Lagoon was operated at room temperature in the range of 16 to 32° C.

Dissolved oxygen and biochemical oxygen demand determinations were the …

The Influence Of Bench Geometry On Blasting Effects For Vertical Cylindrical Charges, Thomas E. Pearse

Masters Theses

"Blasting phenomena are affected by many factors. Previous investigators have studied many of these factors, however, the influence of charge length and explosive detonation velocity have apparently not been thoroughly examined.

It was found by this investigation that the detonation pressure of a commercial explosive is closely controlled by the detonation velocity. The detonation velocity, in turn, will largely determine the necessary blast geometry that can be successfully employed. Relationships were derived between the detonation velocity, in relation to the rock energy propagation velocity, and blast geometry for both bottom and collar primed blasts.

The resultant force magnitude and direction …

The Application Of Preaeration Of Sewage To The Design And Operation Of Waste Stabilization Lagoons, Richard G. Huber

Masters Theses

"The application of preaeration of sewage on the operation and design of waste stabilization lagoons was investigated and its effect on the permissible BOD loadings was determined to provide original and basic information of value to the sewage treatment field.

The investigation was conducted using two 15 gallon aquariums, one of which was designated as the Control Lagoon and the other as the Test Lagoon. These experimental lagoons were subjected to 12 hour diurnal light and dark cycles, provided by means of fluorescent light fixtures.

Raw sewage and aerated raw sewage were fed daily to the Control and Test Lagoons, …

Application Of Digital Computer To Magnetic Data Interpretation Using Surface Integral Method, Afif Hani Saad

Masters Theses

"A simple method is developed for the calculation of the magnetic effect due to three-dimensional bodies. The method is based on the use of surface integration instead of volume integration. Thus, any three-dimensional body can be considered as having two surfaces, upper and lower, with magnetic pole distributions. Simple equations based on potential theory have been derived for the calculation of the vertical component and total intensity due to these surface distributions of poles. The anomalous field of the body can be obtained by subtracting the effect due to one of the surfaces from that of the other.

The method …

Foraminifera Of The Cenozoic And Recent Genus Sphaerogypsina Galloway, Wayne C. Horton

Masters Theses

"The morphology of Sphaerogypsina as seen in thin section affords various characters useful in classification] 1) arrangement and composition of the wall (calcareous-perforate, radially crystalline); 2) layering of wall (like Gypsina, without layering or black line, having only microlamellae); 3) shape of test (always spherical); and 4) specific characters: size of test, order/unorder ratio, size of chambers, wall thickness, pore diameter, and type of embryonic apparatus.

Correlation of the above characters has allowed recognition of two new species. Comparisons with other genera strongly suggest placing the genus in the Family Gypsinidae (nom. correct.) rather than in the …

A Study Of The Stress Distribution Around Circular Openings Using Multilayered Photoelastic Material, Donald Frank Haber

Masters Theses

"Stress analysis as applied to mine openings ranges from the completely empirical to the completely theoretical. However, it is only through the ultimate utilization of the two methods that a guide to the Interpretation of mine stress phenomenon may be obtained. The bridge between the two approaches lies in the field of model study. Specifically, this is an Investigation into determining the feasibility of using multilayered photoelastic materials in models such that a more exact approximation of the underground stress distribution around mine openings can be made.

The two major objectives in this study for determining the feasibility of using …

Model Analysis By The Moiré Method, David D. Kick

Masters Theses

"This study presents the use of Moiré fringes for model analysis of deflections and strains. Deflection of a beam, strain in a disk, and an Influence diagram for a frame are presented as examples of uses of the Moiré method. The necessary equations for the determination of strain using the Moiré method are also derived and presented in this work"--Abstract, page v.

A Study Of The Chemical Kinetics, Activation Energy And Difference Effect On Beryllium Dissolving In Mineral Acids, Daniel Santhamurthi Gnanamuthu

Masters Theses

"The rate of dissolution of polycrystalline beryllium was studied in hydrofluoric, hydrochloric and sulfuric acids. Two samples of beryllium containing different amounts of beryllium oxide were used. The experiments were performed at temperatures ranging from 20 to 50°C, and at various acid concentrations. The kinetics of these heterogeneous processes conformed to a reaction order of approximately one in all the cases. Since the conditions of the surface were complex during dissolution, these might complicate the reaction. This might be due to the oxide layer, which is present as impurity.

The difference effect was determined at various acid concentrations at 25°C …

Gathering Haunch Design Data By Photoelasticity, Richard B. Heagler

Masters Theses

"The haunching of beams and columns and the haunching of rigid frames is performed by design engineers for the purpose of relieving stress concentrations that might occur at discontinuities in structures. The haunch performs this relieving of stress concentration by increasing the rigidity of the structure at regions of high stress. Usually this design step is one of trial and error; that is, the engineer will select a haunch or method of haunching and then check to see if the result is sufficient for his purpose. This can be a time consuming process and can lead to uneconomical design.

In …

Study Of The Copper-Uranium Deposits At Vilcabamba, Department Of Cuzco, Peru, Oscar Aguilar

Masters Theses

"Uranium has been known in the Vilcabamba district of Cuzco, Peru since 1954. Copper ores of high silver content were worked by the Spaniards during the seventeenth and the early eighteenth centuries, At the beginning of the twentieth century these ores were worked intermittently; during the last fifty years no mining operation has been going on.

The oldest rocks in the thesis area consist of Ordovician phyllites. The presence of Devonian in the area is questionable, but has been recognized 5 km. away from the thesis area. A conglomerate of limited lateral extent of Mississippian age overlies the Devonian (?) …

A Study Of The Colloidal Properties Of Zirconium And Promethium By Electrodialysis And Liquid-Liquid Extraction, James N. Click

Masters Theses

"The purpose of this investigation was to study the solution chemistry of zirconium by investigating the colloidal behavior of natural zirconium and zirconium-95, utilizing electrodialysis and liquid-liquid extraction techniques. Also incorporated into this study was the investigation of optimum conditions for the extraction of the natural zirconium and zirconium-95 with thenoyl trifluoracetone. A limited amount of work was done on the colloidal nature of promethium-147"--Introduction, pages 2-3.

A Study Of A Second-Order Predictive Control System, Tarkeshwar Singh

Masters Theses

"The purpose of this thesis is the study of a predictive control system by simulating it on an analog computer. Logic criteria for step reference inputs are derived by the phase- plane technique, and tie corresponding logic network designed to bring the error and error rate of the controlled system toward zero in the least possible time.

The responses of the predictive control system for step, ramp, sinusoidal and exponential reference inputs are investigated with primary emphasis placed on the rise time and overshoot for several values of step inputs of the reference.

Finally, recommendations are made for further investigations …

A Study Of The Behavior Of Zirconium In Aqueous Solutions And The Separation Of Radioactive Zirconium By Electrodialysis, Charles William Brauer Jr.

Masters Theses

"Nuclear reactor installations designed for power production must of necessity operate at higher energy levels than their experimental precursors. As these facilities increase in number, better solutions must be found for both technical and economic problems.

The disposal of waste materials is of primary importance and will require greater effort if satisfactory disposal methods are to keep pace with the increase of waste materials, produced by the increasing number of new nuclear facilities. The radioactive materials present in this waste material may constitute a valuable by-product from these operations if suitable and economic recovery procedures are developed. If the development …

A Study Of Several Commercial Steels In The Red Short Range, Jorge Alberto Espana

Masters Theses

"The red short phenomenon present in steel, was studied by means of torsion tests at temperatures between 800 and 1200⁰C. Cold drawn bars of different compositions of steels were tested, and the number of turns to failure and maximum twisting torque were plotted versus temperature.

All the steels tested, exhibited to have a certain degree of red shortness. By comparing the curves and the respective chemical analyses, the detrimental effect of sulphur and lead and the beneficial effect of manganese, was established.

Microscopic examinations revealed the intergranular nature of the cracks in the red short range. Sulphur and oxide distribution …

Permeability Of Poly (Ethylene Terephthalate), James G. Harvey

Masters Theses

"Corrosion is a phenomenon which has been the subject of extensive research, in order to find a way to control or completely stop it. Two general methods, either placing the material which corrodes in an anti-corrosive atmosphere or protecting the material which corrodes from the corrosive atmosphere, are the chief means of preventing corrosion today.

The second method is probably most widely used presently. One of the most important methods of protection is by means of organic protective coatings, or paints, but at best these only retard corrosion, due to the fact that corrosive media e.g. water vapor, ions etc. …

A Study Of Heat Transfer Coefficients On Cylindrical Pipe In Turbulent Flow, Dennie Lee Adkins

Masters Theses

"This thesis represents a study of the effects of turbulent motion on heat transfer coefficients on cylindrical pipe.

The turbulent motion was created by cutting transverse slots in a spiral configuration along the pipe length.

An induction heater was used for the heat source and water as the cooling medium. The water was conducted over the pipe surface and through the slots.

This caused the laminar layer along the pipe surface to be broken up and an increase in the heat transfer coefficient was experienced.

The main objective of this test was to find if a relation existed between the …

Investigation And Development Of Ground Water Of Chalone Creek, (Pinnacles National Monument, California), Donald Lee Brown

Masters Theses

"The Pinnacles National Monument is located in San Benito and Monterey Counties about 130 highway miles south of San Francisco, California. Because of unusual patterns in volcanic rocks, the Monument was set aside as a recreation area on January 16, 1908, by President Theodore Roosevelt. It encompasses an area of approximately 12,818 acres.

Water quality and supply problems were experienced at the Monument in the few years prior to 1961. In 1961, a collection trench system was installed to alleviate the water supply condition. A horizontal trench system, 215 feet long and four feet below the dry season water table, …

Ground Water Investigation In The Southern Half Of Franklin County, Missouri, Kemal Piskin

Masters Theses

"Increasing population and industrialization in Franklin County, Missouri, has led to increased demand for water. Much of this demand will be satisfied from ground water resources. Although the general geology of Franklin County has been mentioned in several publications, no detailed study of structure and ground water geology had been done. This thesis consists of study of stratigraphy, lithology, and geologic structure, and analysis of well log data to determine occurrence and availability of ground water, in the southern half of Franklin County.

Stratigraphy and lithology is compiled from previous literature, modified to agree with well log data. Structural geology …

A Study Of The Recrystallization And Polygonization Of High Purity Aluminum, Robert Leon Wright

Masters Theses

"Laue back reflection patterns were used along with visual examination in evaluating the characteristics of the annealed structure of high purity (99.99%) aluminum single crystals which had been deformed by elongation. It was found that the glide strain and annealing temperature are primary factors to be considered with respect to the structural changes occurring during annealing.

It was determined that the glide strain must be above a certain critical value to cause recrystallization; below the critical value polygonization will predominate in the annealed structure regardless of the annealing temperature.

The single crystals used in the investigation were grown by the …

Mineral Paragenesis And Trace Element Distribution In The Tri-State Zinc-Lead District Missouri, Kansas, Oklahoma, Richard D. Hagni

Doctoral Dissertations

"A review of the literature pertaining to the mineral paragenesis and trace element distribution in the Tri-State zinc-lead district of Missouri, Kansas, and Oklahoma revealed inconsistencies in observation and in interpretation and divergent hypotheses regarding the origin of the ores. In an attempt to reconcile the data collected by many investigators over nearly three-quarters of a century, the writer observed working faces in 37 mines, collected over 2,000 specimens for binocular examination and prepared and studied 110 polished surfaces and 60 thin sections of the ores and associated rocks utilizing mineralographic, petrographic, and x-ray techniques. This detailed study resulted in …