Digital Commons Network^™

Metal-Free Photoredox Catalysis For The S-Trifluoromethylation Of Thiols, Raheemat Rafiu, Puspa Aryal, V. Prakash Reddy

Chemistry Faculty Research & Creative Works

The S-trifluoromethylation of thiols is accomplished using a simple and cost-effective organic catalyst (diacetyl) along with a bench-stable and environmentally friendly trifluoro methylating reagent (Langloi's reagent). Under optimized conditions (2.5 equivalents of Langlois reagent, Blue LED irradiation, 48-h reaction time at room temperature), the reaction yielded up to 81% S-trifluoro methylated product. This method's high yields, compatibility with a broad substrate scope (aliphatic, heteroaromatic, and aromatic thiols), and environmentally friendly conditions demonstrate its potential for broader synthetic applications. In contrast to traditional methods that rely on organometallic catalysts and environmentally hazardous reagents, this novel photoredox catalysis method offers a more …

Gfrp Reinforced Bridge Barriers: Experiment Testing, Manish Kumar Gadhe

Masters Theses

This study focused on evaluating the performance of concrete bridge barriers reinforced with Glass Fiber Reinforced Polymer (GFRP) compared to those reinforced with conventional mild steel. Four full-scale barriers were constructed, three using GFRP bars as the reinforcement and one with mild steel reinforcement. These were cast on two concrete slabs to ensure consistent support conditions. The use of GFRP aims to address durability concerns associated with steel reinforced concrete (RC), particularly corrosion of these bars in harsh environments.

To simulate real-world impact scenarios, a weighted cart was launched at each barrier using a guided sled system. Sensors, including load …

Students’ Perceptions Of Self And Peers Predict Self-Reports Of Cheating, Amber M. Henslee, Luke Settles, Sara E. Johnson, Gayla R. Olbricht

Psychological Science Faculty Research & Creative Works

Academic dishonesty and how to address it are common concerns across higher education disciplines, but engineering students admit to higher rates of academic dishonesty than other students. However, first-year students may be particularly receptive to prevention efforts. Considering self-perception, social norming, and behavioral choice theories, we hypothesized that 1.) Students who perceived themself as ethical and more knowledgeable of the consequences for misconduct would be less likely to self-report cheating and 2.) Students who perceived cheating and plagiarism to be common would be more likely to self-report cheating. For this study, freshmen engineering students (N=703) reported their self-perception, perception of …

How Do Human And Ai Gender Bias Interact In Hiring Decisions?, Eyuel Getahun, Daniel Burton Shank, Casey I. Canfield, Jessica L. Cundiff, Jenny L. Davis, Celia Freed

Psychological Science Faculty Research & Creative Works

The hiring process is crucial for organizational success but has long been troubled by human biases. Many organizations now include AI in their hiring protocols to mitigate these biases and increase efficiency. However, AI itself can have biases baked-in. Human biases and AI biases are distinct but related; here, we examine how human and AI biases interact to affect hiring outcomes. Through an online experiment, we examine this question in the context of gendered hiring for a male-dominated leadership position in electrical engineering. The study tests how elevated and depressed AI recommendations for male and female job candidates affect participant …

Comparison Of Cnn And Lstm Networks On Human Intention Prediction In Physical Human-Robot Interactions, Khosro Ghorbani Zadeh, Niloofar Zendehdel, George L. Holmes, Keyri Moreno Bonnett, Amy Costa, Devin Michael Burns, Ming-Chuan Leu, Yun Seong Song

Psychological Science Faculty Research & Creative Works

Advancements in robotics and AI have increased the demand for interactive robots in healthcare and assistive applications. However, ensuring safe and effective physical human-robot interactions (pHRIs) remains challenging due to the sophistication of human motor communication and intent recognition. Traditional physics-based models struggle to capture the dynamic nature of human force interactions, limiting robot adaptability. To address these limitations, neural networks (NNs) have been explored for force-movement intention prediction. While multi-layer perceptron (MLP) networks show potential, they struggle with temporal dependencies and generalization. Long Short-Term Memory (LSTM) networks effectively model sequential dependencies, while Convolutional Neural Networks (CNNs) enhance spatial feature …

Popular Music And Movies As Autobiographical Memory Cues, Julien Hanson, Jessica Frame, Elena Bai, Kendra Mehl, Kelly Jakubowski, Amy M. Belfi

Psychological Science Faculty Research & Creative Works

Research on music-evoked autobiographical memories has grown rapidly in recent years, suggesting that music can be an effective stimulus for cueing memories from one's life. One challenging aspect of this type of research is creating a stimulus set that is effective at cueing autobiographical memories in a wide range of individuals. The present work sought to address this issue by creating a normed stimulus set of popular music and popular movie cues. In addition to this methodological aim, we had an empirical aim to identify differences between autobiographical memories cued by music and movies. Participants (N = 248) either listened …

Apocalyptic Technical Communication From Clockface To Briefcase: Revealing The Spurious Coin Of Nuclear-Security Rhetoric, Ryan Cheek

English and Technical Communication Faculty Research & Creative Works

This article the Doomsday Clock and the Nuclear Football as interconnected technical communication artifacts that function as two sides of a "spurious coin" in the securitization of nuclear deterrence. While the Clock externalizes existential risk through apocalyptic rhetoric, the Football internalizes it within exclusive military command structures—together legitimizing perpetual nuclear crisis. Drawing on technical communication scholarship and critical security studies, the analysis argues that both artifacts sustain nuclearist ideology by reinforcing deterrence as common sense. The Clock's ominous countdown and the Football's ever-present launch capability are mutually validating and together normalize nuclear brinkmanship as the price of global security.

Balance Assistance Without Mechanical Support Using A Virtual Cane With Haptic Feedback, Sindhu Reddy Alluri, Sambad Regmi, Fazlur Rashid, Devin Michael Burns, Yun Seong Song

Psychological Science Faculty Research & Creative Works

Light Touch (LT) has been known to improve standing balance without mechanical support by providing sensory information about the movement of the body. Inspired by this, this work developed a Virtual Cane (VC) which gives no physical support but provides other sensory information that a physical cane would. The VC is developed with a distance sensor and vibration actuators to provide cane tip-to-ground distance information to the user. The extent to which this haptic feedback improves standing balance was assessed in a human experiment. 10 healthy young participants underwent a standing balance experiment with tandem stance and eyes closed, using …

Elucidating The Role Of Hydrogen At C-In2o3/A-In2o3−X Interface, Julia E. Medvedeva, Mariana I. Bertoni

Physics Faculty Research & Creative Works

Ab initio molecular dynamics simulations and hybrid functional electronic structure calculations are employed to determine the formation, the structural and electronic properties, and the dynamics of covalent (In-OH) and ionic (In-H-In) hydrogen defects at crystalline-In2O3/amorphous-In2O3−x interface. This comprehensive computational study considers (i) various interstitial and substitutional hydrogen site locations within the crystalline, amorphous, and interfacial regions; (ii) several oxygen-to-hydrogen ratios; and (iii) possible defect charged states. The results reveal hydrogen's inability to fully passivate the undercoordinated under-shared in atoms in amorphous highly substoichiometric oxide, giving rise to the formation of deep electron traps even in net-charge neutral structures. These trap …

Nonlinear Control Of Buck-Type Converters For Micro-Wind Generators, Noah Wilding, Shuzan Kumar Sarkar, Shruti Pandey, Michael L. Mcintyre

Electrical and Computer Engineering Faculty Research & Creative Works

Small-scale wind turbines offer a promising solution for distributed renewable energy generation. However, this approach often leads to wasted energy when battery capacity is reached, as excess energy is typically dissipated into resistors. The reliance on batteries further increases the cost and complexity of such systems. This paper presents a nonlinear control algorithm for regulating buck-type converters, providing a more efficient energy management solution. By employing a grid-connected inverter, excess energy is utilized rather than dissipated, potentially eliminating the need for batteries and reducing micro-wind turbine installation costs. The proposed control strategy manages the DC-link voltage for the inverter by …

Filter Based Motor Control For Robotic Applications, Shuzan Kumar Sarkar, Noah Wilding, Shruti Pandey, Nicholas Hawkins, Michael L. Mcintyre

Electrical and Computer Engineering Faculty Research & Creative Works

Controlling coreless DC motor in the field of humanoid robotic application involves considering various surrounding electromagnetic environment interference and sudden change of load with parameters variation of motor dynamics which makes the system complex. This paper presents a filter-based control scheme for a coreless DC motor drive system using an H-bridge inverter as the input circuit of the motor which is easy to implement and cost effective. From the electromagnetic characteristics, the dynamic model of the motor along with the control scheme is implemented in the commercial software PLECS. Then the effectiveness of this approach is validated through simulations demonstrating …

Nutrient Fate, Mass Balance, Species Selection, And Plant Management Strategies With Floating Treatment Wetlands, Carla Campbell

Doctoral Dissertations

Excess nutrients in shallow urban ponds can lead to harmful algal blooms, low dissolved oxygen, and internal phosphorus cycling. These effects can compromise municipal water supplies and cause negative impacts on fisheries and recreation. Floating treatment wetlands (FTWs) show promise to mitigate surface water nutrient pollution. However, despite recent research, many aspects of FTWs remain poorly characterized. The contribution of FTW components to nutrient removal, local species selection, and plant management strategies were the focus of this dissertation. Mesocosm experiments revealed that the combination of plants and coir fiber growth media in FTWs appeared to positively affect plant biomass gain …

Radio Frequency Wave Propagation Modeling Within Obstructed Underground Mining Environments For Effective Miner Localization During Mine Emergencies, Emmanuel Atta Antwi

Doctoral Dissertations

The reliability of underground wireless communication systems remains a significant challenge, particularly during emergencies when the mine environment becomes severely obstructed by debris, dust, and humidity. These environmental and geometric conditions result in significant attenuation of electromagnetic (EM) waves and multipath effects that undermine miner localization and rescue operations. Existing Vector Parabolic Equation (VPE) models are efficient for straight or mildly curved tunnels but fail to account for the random and obstructive conditions typically encountered during underground emergencies. This research develops a novel radio propagation model for EM wave behavior in underground mine drifts under geometrically obstructed conditions. The model …

The Organization Of Serotonergic Fibers In The Pacific Angelshark Brain: Neuroanatomical And Supercomputing Analyses, Skirmantas Janušonis, Ralf Metzler, Thomas Vojta

Physics Faculty Research & Creative Works

Serotonergic axons (fibers) are a universal feature of all vertebrate brains. They form meshworks, typically quantified with regional density measurements, and appear to support neuroplasticity. The self-organization of this system remains poorly understood, partly because of the strong stochasticity of individual fiber trajectories. In an extension to our previous analyses of the mouse brain, serotonergic fibers were investigated in the brain of the Pacific angel shark (Squatina californica), a representative of a unique (ray-like) lineage of the squalomorph sharks. First, the fundamental cytoarchitecture of the angel shark brain was examined, including the expression of ionized calcium-binding adapter molecule 1 (Iba1, …

Mitigating Frost Heave And Thaw Weakening In Roads Using Wicking Geotextile, Javad Galinmoghadam

Doctoral Dissertations

"Excess water is known to be the primary cause of soil and foundation problems. In cold regions, water-related problems are exacerbated by seasonal freezing and thawing cycles. Frost heave and thaw weakening is the leading cause of premature pavement failure and consume considerable budgets of the Department of Transportations in cold regions. The first step to designing mitigation measures is the ability to predict frost heave under different conditions. This study aims to introduce a new method for quantifying frost heave using a prediction model based on the state surface approach. This proposed model addressed many inconsistencies and limitations of …

Development Of Ligands And Metal Complexes With Weakly Coordinating Apical Elements And Their Application To Nitrene Insertion And Addition To C‒H And C=C Bonds, Meenakshi Sharma

Doctoral Dissertations

"We present a family of triangular coinage metal M₃Cl₃ complexes [M = Cu (I), Ag (I)] supported by antimony [Sb (III)], and bismuth [Bi (III)]-centered highly basic tetramethyl-guanidinyl [TMG₃trphen-E] (E = Sb, Bi) ligand frameworks with their applications as catalysts toward the construction of C‒N bond through aziridination and amination reaction methodologies.

The [(TMG₃trphen-Sb)Cu₃(µ-Cl)₃] catalyst gives better yields of aziridines with styrenes than [(TMG3trphen-Bi)Cu₃(µ-Cl)₃] with PhINTs as a nitrene source. However, the catalytic reactivity of both catalysts is enhanced by an electrophilic nitrene, PhINTces for …

Applying Human System Integration Principles To The Investigation, Design And Validation Of Interventions For Self-Escape In Underground Mines, Eugene Adubofour Gyawu

Doctoral Dissertations

This dissertation investigates the use of human systems integration (HSI) to develop technologies for miners’ self-escape during a mine emergency, addressing barriers that compromise miner safety during emergencies.

Recognizing the inherently hazardous nature of underground mining, this study has three core objectives: (1) assessing miners' perceptions of proposed self-escape interventions, (2) designing interventions based on these insights, and (3) validating their effectiveness using experimental testing. This work evaluates self-escape interventions for both coal and metal/non-metal miners using scenario-based surveys, information design reviews, label designs and experimental testing methods varying across three distinct studies.

Results reveal that miners identified improvements to …

Mid-Field Shock And Impulse Estimation Methods For Blast Loading On Tall Targets, Ethan Allan Steward

Doctoral Dissertations

Blast resistant structural design continues to be a major research area for governments around the world due to explosive threats from both state and non-state actors. Many of the typical targets of explosive attacks, such as government buildings, commercial high rise office buildings, and apartment complexes are mid to high-occupancy buildings that present a tall profile relative to the charge size and are often clad in curtain walls. In blast resistant structural design, the origin of a shock wave is typically assumed to be in the far-field, creating a wave that is nearly planar and parallel to at least one …

Supporting Human-Ai Interaction From User Expectations To Mental Models, Harishankar Vasudevanallur Subramanian

Doctoral Dissertations

Explainable AI (XAI) aims to unravel the "black box" nature of AI systems and provide insights into the inner workings that lead to a prediction. However, the best XAI communication varies depending on the individual, task, and broader context. It is challenging to anticipate the best XAI for a particular use case. One strategy is for users to build an appropriate mental model of AI with both prediction and system level XAI. To date, little research has focused on quantitatively measuring users interacting with system-level XAI. This dissertation has three primary contributions. The first contribution is a scoping review paper …

Testing The Life-History Dependence Of Dietary Restriction Effects On Oxidative Molecular Damage In Hornworms, Fahime Taheri

Masters Theses

DR and ambient temperature are two environmental factors widely implicated in shaping organismal maintenance and longevity through effects on metabolic rate and oxidative damage. This study tests whether DR and reduced body temperature independently or interactively reduce oxidative protein damage in the gut of tobacco hornworm larvae, a short-lived ectotherm whose life history may constrain typical DR responses. Larvae hatched from eggs were allocated to two feeding regimes (AL and DR) and to 20 °C and 30 °C. At a defined endpoint, guts dissected and homogenized, and analyzed for protein carbonyl content and total protein. Protein damage was expressed as …

Extraction And Separation Of Metal Cations From Synthetic Acidic Solutions Using Emulsion Liquid Membrane, Nouhaila Filali

Masters Theses

The work is organized into two main papers supported by experimental and comparative studies using Emulsion Liquid Membrane (ELM) systems. The first paper explores the individual extraction of heavy metals (Cd, Cr, As, Ni) from synthetic phosphoric acid using Alamine 336 and D2EHPA as carriers. Alamine 336 achieved the highest extraction efficiency (>90%) and stability, offering a promising route to reduce toxic impurities in fertilizer-grade acid. The second paper examines the selective separation of Ni2+ and Co2+ from various acidic solutions using the ELM configuration. Systematic variation of carriers, stripping agent and feed acidity, clarified transport mechanisms and stability, …

Application Of Edge-Enhanced Phase Analysis To Active Microwave Thermographic Measurements, Douglas Blaine Fleetwood

Masters Theses

Nondestructive testing and evaluation (NDT&E) encompasses a range of inspection techniques that assess materials, components, and structures while maintaining their integrity and performance. Among these techniques, thermography is particularly attractive due to its non-contact imaging approach with easy-to-interpret results. Active Microwave Thermography (AMT) has emerged as a promising NDT&E inspection technique that utilizes electromagnetic energy to heat materials through dielectric and magnetic absorption, with subsequent infrared imaging used to detect subsurface defects. While AMT offers significant advantages including material-specific heating optimization and lower power requirements compared to conventional thermographic methods, the technique faces a persistent challenge related to the thermal …

Biological Computing From Microscopic To Macroscopic Evolution, Xiaofeng Ding

Masters Theses

A unified theory from microscopic to macroscopic DNA-based biological systems is explained in terms of the rule components used when the system size is increased. Even though the eight female rules in each ruleset are provided with an equal probability of the computation-state outcomes, the initial ensemble of the computation states will exponentially settle into one dominant rule that supports the nutrition needed for growth. The remaining seven rules form into two minority groups to provide the biological characteristics of the system's growth from a micro to macroscopic evolution. The object of this study is to prove that such a …

From Normal To Disaster Response Mode: How Can Virtual Communities Reconfigure Themselves To Respond Effectively To A Disaster?, Mahmudul Hasan, Cecil Eng Huang Chua, Michael David Myers, Varqa Shamsi Bahar

Business and Information Technology Faculty Research & Creative Works

During a disaster, many people seek information from virtual communities. However, information overload, falsehoods and unrelated topics hinder information flow in virtual communities, putting disaster victims at risk. Given many disasters are generally of a short duration, we explore how virtual communities can quickly reconfigure themselves to respond effectively to a disaster. Drawing on risk society theory, our findings suggest reconfiguration is done via a series of cycles initially involving community members and subsequently featuring both community members and moderators working together to mitigate risks. We contribute to virtual community discourse on disaster response by showing how a virtual community …

A Tribute To The Life And Work Of Jess Chua, James J. Chrisman, Zhenyu Wu, Alfredo De Massis, Pramodita Sharma, Lloyd P. Steier, Franz W. Kellermanns, Josip Kotlar, Emanuela Rondi, Bingbing Ge, Chevy-Hanqing Fang

Business and Information Technology Faculty Research & Creative Works

Jess Chua was a leading scholar in the field of family business and a major contributor to Entrepreneurship Theory and Practice both as an author and editor. His significant contributions to the field were acknowledged by the Web of Science, which listed him among the world's most highly cited researchers in Economics and Business in 2017, 2019, and 2020. In this memorial editorial, we pay tribute to him by discussing his influence on the field through his academic work, mentoring, long-term collaborations with other scholars, and the kindness he and his wife, Eva Kan, showed to his colleagues and students.

Managing Digital Transformation With Blockchain: Distributed Ledger Innovation Platforms, Nobuyuki Fukawa, Gregory J. Fisher

Business and Information Technology Faculty Research & Creative Works

Realizing its overarching potential in achieving digital transformation, leading organizations, such as Air New Zealand, have recently employed blockchain technology to manage 3D printing innovation. Despite the potential benefits, including the key role of blockchain as a supporting technology in Industry 5.0, these applications of blockchain technology in 3D printing are still at a nascent stage in practice and mostly limited to producer innovation. Additionally, 3D printing and blockchain technologies are often independently revolutionizing value capture and value creation, whereas the theoretical implications of their combined impacts on innovation management remain an underexplored domain. Limited digital transformation efforts have been …

Modeling Ion-Specific Effects In Polyelectrolyte Brushes: A Modified Poisson-Nernst-Planck Model, William J. Ceely, Marina Chugunova, Ali Nadim, James D. Sterling

Business and Information Technology Faculty Research & Creative Works

Polyelectrolyte brushes consist of a set of charged linear macromolecules, each tethered at one end to a surface. An example is the glycocalyx which refers to hair-like negatively charged sugar molecules that coat the outside membrane of all cells. We consider the transport and equilibrium distribution of ions and the resulting electrical potential when such a brush is immersed in a salt buffer containing monovalent cations (sodium and/or potassium). The Gouy-Chapman model for ion screening at a charged surface captures the effects of the Coulombic force that drives ion electrophoresis and diffusion but neglects non-Coulombic forces and ion pairing. By …

The Antibiofilm Efficacy Of Copper And Zinc-Enhanced Borate Bioactive Glasses On Polymicrobial Biofilms, Sarah Fakher, David J. Westenberg

Biological Sciences Faculty Research & Creative Works

Healthcare-acquired infections (HAIs) are a significant global challenge driven by biofilm-forming pathogens. Polymicrobial biofilms, involving interactions between multiple microbial species, exacerbate treatment difficulties due to their enhanced resistance to antimicrobial therapies. Borate bioactive glasses (BBGs) are an emerging class of biomaterials that have attracted significant interest in infection control. The incorporation of copper and zinc into the BBG matrix can effectively disrupt biofilm formation and bacterial colonization. This study investigates the antibiofilm efficacy of copper and zinc-doped BBGs against polymicrobial biofilms formed by S. epidermidis, E. coli, and P. aeruginosa. Using static and dynamic biofilm models, BBGs were applied through …

Tintin: A Unified Hardware Performance Profiling Infrastructure To Uncover And Manage Uncertainty, Ao Li, Marion Sudvarg, Zihan Li, Sanjoy Baruah, Chris Gill, Ning Zhang

Computer Science Faculty Research & Creative Works

Hardware performance counters (HPCs) enable the measurement of microarchitectural events, which are crucial for tracking and predicting program behavior. High-fidelity measurement and precise attribution are essential for accurate profiling. However, existing profiling tools have fundamental challenges in both aspects. In measurement, numerous events compete for limited hardware monitoring resources; while for attribution, applications have diverse requirements, but systems provide limited support. Existing tools mitigate the former limitation through event multiplexing, but this approach introduces non-trivial errors. The latter limitation, however, remains largely unaddressed. This paper introduces Tintin, an HPC profiling infrastructure with a modular three-component design that addresses both challenges. …

Reflections On Linear B, (Part 7): Sign 75, Which Looks Like A Backwards Letter S, Might Derive From The Ancient Egyptian Uraeus Figure, Gerald Leonard Cohen

Arts, Languages and Philosophy Faculty Research & Creative Works

Linear B sign 75 is evidently of unknown origin, both with respect to its intended portrayal and a rationale for its pronunciation /we/. And yet, like several other signs of Linear B, I believe this one too derives from ancient Egyptian, viz., the mythological cobra figure poised to spit fire to protect the god/goddess or sovereign on whose crown or headdress the cobra stands guard.