Atomic, Molecular and Optical Physics Commons^™

Transition Probabilities In Kr Ii And Kr Iii Spectra, Stevan Djenize, Vladimir Milosavljevic, Milan S. Dimitrijevic

Articles

On the basis of the relative line intensity ratio (RLIR) method, transition probability values of the spontaneous emission (Einstein's A values) of 14 transitions in the singly (Kr II) and 7 transitions in doubly (Kr III) ionized krypton spectra have been obtained relatively to the reference A values related to the 435.548 nm Kr II and 324.569 nm Kr III, the most intensive transitions in the Kr II and Kr III spectra. Our Kr III transition probability values are the first data obtained experimentally using the RLIR method. A linear, low–pressure, pulsed arc operated in krypton discharge was used as …

Dramatic Nondipole Effects In Low-Energy Photoionization: Experimental And Theoretical Study Of Xe 5s, Oliver Hemmers, Renaud Guillemin, E. P. Kanter, B. Krassig, Dennis W. Lindle, S. H. Southworth, R. Wehlitz, J. Baker, A. C. Hudson, M. Lotrakul, D. Rolles, Wayne C. Stolte, I. Tran, A. Wolska, S. Yu, M. Ya Amusia, K. T. Cheng, L. V. Chernysheva, W. R. Johnson, S. T. Manson

Environmental Studies Faculty Publications

The Xe 5s nondipole photoelectron parameter γ is obtained experimentally and theoretically from threshold to ∼200  eV photon energy. Significant nondipole effects are seen even in the threshold region of this valence shell photoionization. In addition, contrary to previous understanding, clear evidence of interchannel coupling among quadrupole photoionization channels is found.

Photofragmentation Dynamics Of Core-Excited Water By Anion-Yield Spectroscopy, Wayne C. Stolte, M. M. Sant'anna, Gunnar Ohrwall, Maria Novella Piancastelli, I. Dominguez-Lopez, Dennis W. Lindle

Chemistry and Biochemistry Faculty Research

Partial-anion and- cation yields from H₂O are presented for photon energies near the oxygen K edge. The O^- yield exhibits a feature above threshold attributed to doubly excited states, in contrast to the H^- and cation yields, which are nearly featureless above threshold. Additionally, the lack of the OH^- fragment indicates radiative decay and provides a negligible amount of anion formation.

The Structures Of Fluorene– (H2o)1,2 Determined By Rotational Coherence Spectroscopy, David M. Laman, Alan G. Joly, Douglas Ray

All Faculty Scholarship for the College of the Sciences

Rotational coherence spectroscopy ~RCS!, via time-correlated single photon counting, and two-color resonant two-photon ionization ~R2PI! time-of-flight mass spectrometry, have been used to characterize fluorene–(water)_1,2[FL– (H₂O)_1,2] van der Waals clusters generated in supersonic jets. Rotational coherence traces have been obtained at excitation energies corresponding to several resonant features in the S₁<-S₀ R2PI spectra of FL– (H₂O)_1,2 . RCS simulations and diagonalization of the moment of inertia tensor have been used to obtain S₁ excited state rotational constants and structures of FL– (H₂O)_1,2 that are consistent with …

Astrophysical Plasma Diagnostics Through Analysis Of Ar Iine Shape Characteristics, Vladimir Milosavljevic, Stevan Djenize

Articles

On the basis of five accurately recorded neutral argon ( ) line shapes (in the 4s-5p transition) we have recovered the basic plasma parameters i.e. electron temperature ( T) and electron density ( N) using our new line deconvolution procedure in the case of three different plasmas created in a linear, low-pressure, pulsed arc discharge. The mentioned plasma parameters have also been measured using independent experimental diagnostic techniques. An excellent agreement has been found among the two sets of obtained parameters. This recommends our deconvolution procedure for plasma diagnostic purposes, especially in astrophysics where direct measurements of the …

Experimental And Calculated Stark Widths Within The Kr I Spectrum, Vladimir Milosavljevic, Stevan Djenize, Milan S. Dimitrijevic

Articles

On the basis of the precisely recorded 20 neutral krypton (Kr I) line shapes (in the 5s−5p and 5s−6p transitions), we have obtained the basic plasma parameters, i.e., electron temperature (T) and electron density (N) using our line deconvolution procedure in a plasma created in a linear, low-pressure, pulsed arc discharge operated in krypton. The mentioned plasma parameters have also been measured using independent experimental diagnostics techniques. Agreement has been found among the two sets of the obtained parameters. This recommends our deconvolution procedure for plasma diagnostical purposes, especially in astrophysics where direct measurements of the …

E1-E2 Interference In The Vuv Photoionization Of He, E. P. Kanter, B. Krassig, S. H. Southworth, Renaud Guillemin, Oliver Hemmers, Dennis W. Lindle, R. Wehlitz, M. Ya Amusia, L. V. Chernysheva, N. L. S. Martin

Environmental Studies Faculty Publications

We have measured the forward-backward asymmetry of photoelectron angular distributions produced in the vacuum ultraviolet photoionization of helium. This asymmetry, a consequence of the breakdown of the dipole approximation, measures the real part of the ratio of the quadrupole and dipole matrix elements. In the autoionization region, the strong energy dependence of the asymmetry permits an experimental separation of the ratio of those magnitudes from their phase difference. We experimentally determined the Fano parameters of the 2p²¹D₂ quadrupole resonance, and report improved values of the width Γ and line profile parameter q from those previously available …

Optical Solitons In A Three-State Medium, Talal Ghannam

Masters Theses

When a beam of light propagates within a typical medium, absorption is a common phenomenon. This happens when the frequency of the light is close to a resonant frequency of the atoms composing the medium. But in the past few decades, it has been shown that in certain circumstances, carefully chosen pulse shapes are able to propagate without significant absorption even when the frequency of the light is close to an atomic resonant frequency. It was called Self Induced Transparency (SIT).

This phenomenon was intensively studied in the two-state systems. On the other hand, the three-state systems seems not to …

Femtosecond Phase-Coherent Two-Dimensional Spectroscopy, Peifang Tian, Dorine Keusters, Yoshifumi Suzaki, Warren S. Warren

Peifang Tian

Femtosecond phase-coherent two-dimensional (2D) spectroscopy has been experimentally demonstrated as the direct optical analog of 2D nuclear magnetic resonance. An acousto-optic pulse shaper created a collinear three-pulse sequence with well-controlled and variable interpulse delays and phases, which interacted with a model atomic system of rubidium vapor. The desired nonlinear polarization was selected by phase cycling (coadding experimental results obtained with different interpulse phases). This method may enhance our ability to probe the femtosecond structural dynamics of macromolecules.

Reply To "Comment On ‘Atomic Spectral Line Free-Parameter Deconvolution Procedure’”, Vladimir Milosavljevic, Goran Poparic

Articles

We do not agree with the authors of the preceding Comment [X. Nikolic, X. Ojurovic, and X. Mijatovic, Phys. Rev. E, 67, 058401, 2003]. Our numerical procedure for the deconvolution of the theoretical asymmetric convolution integral of a Gaussian and a plasma broadened spectral line profile jA,R(λ) for spectral lines enables the determination of all broadening parameters. All broadening parameters can be determined directly from the recorded line profile of a single line, with minimal assumptions or prior knowledge. Additional experimental diagnostics are not required.

Broadening And Shifting Of Atomic Strontium And Diatomic Bismuth Spectral Lines, Jeremy C. Holtgrave

Theses and Dissertations

The objective of this research is to study the effects of noble gases on atomic strontium and diatomic bismuth visible transitions, Specifically, this research seeks to determine if the line broadening and, in the case of atomic strontium, line shifting rates of these transitions in the presence of noble gases depend on the total angular momenta of the energy states involved. It has been known for more than a century that atomic and molecular spectral lines are broadened and shifted by perturbing species. While a considerable body of theoretical work has been accomplished on this topic over the years, only …

The He I 706.52 Nm Line Shape Characteristics In The Plasma Diagnostics, Vladimir Milosavljevic, Stevan Djenize

Articles

On the basis of the precisely recorded 706.52 nm He I line shape we have obtained the basic plasma parameters i.e. electron temperature (T) and electron density (N) using our new line deconvolution procedure in the case of five various plasmas created in a linear, low–pressure, pulsed arc discharge. Plasma parameters have been also measured using independent experimental diagnostical techniques. Excellent agreement was found among the two sets of the obtained parameters. This enables our deconvolution procedure to recommendation for plasma diagnostical purposes, especially in astrophysics where direct measurements of the plasma parameters (T and …

Monte Carlo Simulations Of Surface Phase Transitions In A Modulated Layered Structure, Da Gao, John A. Jaszczak

Department of Physics Publications

A solid-on-solid model of a layered crystal, which has five layers per repeat period in the direction normal to the surface and with only nearest-neighbor interactions, is studied using Monte Carlo simulation to investigate the relationship between crystal structure and the corresponding surface phases. Equilibrium properties, such as the surface specific heat, interface width, and autocorrelation times, are studied as a function of temperature and system size. Results indicate three distinct surface phases exist in this model: a low-temperature flat phase, an intermediate-temperature disordered but flat phase, and a high-temperature rough phase. We suggest the possibility of introducing several intermediate …

Field Emission Based Sensors Using Carbon Nanotubes, Changkun Dong

Physics Theses & Dissertations

A number of sensitive applications would be greatly benefited by the development of better cold cathodes that employ the electron field emission process. Among the many kinds of field emitters that could be tried, carbon nanotubes (CNT) have a number of distinct advantages because of their unique geometrical structure, chemical inertness, mechanical stiffness, and high thermal and electrical conductivities. This dissertation describes research in which CNT cathodes were fabricated and their emission characteristics were measured.

Multi-walled carbon nanotubes (MWNT) were grown by chemical vapor deposition (CVD) on various substrates: Ni and Hastelloy gauze, 304 stainless steel (SS) plates, and Ni-coated …

Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv

Physics Theses & Dissertations

The reaction rate coefficients between the hydronium ion and the molecules ethene (C₂H₄), propene (C₃H₆), 1-butene (C₄H₈) and hydrogen sulfide (H₂S) were measured at 296 K. The measured reaction rates were compared to collision rates calculated using average dipole orientation (ADO) theory. Reaction efficiency depends primarily upon the proton affinity of the molecules. All the measurements were obtained using the newly developed microwave cavity discharge flowing afterglow (MCD-FA) apparatus. This device uses an Asmussen-type microwave cavity discharge ion source that is …

Coherent Backscattering Of Light From An Ultra Cold Gas Of Rubidium-85 Atoms, Pasad B. Kulatunga

Physics Theses & Dissertations

This thesis reports on the experimental study of coherent radiative transport in an ultracold gas of ⁸⁵Rb atoms confined in a magneto-optic trap. Measurements are made of the polarization dependence of the spatial and spectral profile of light backscattered from the sample. The results shows an interferometric enhancement sensitive to coherent multiple scattering in the atomic gas, and strong variations with the polarization of the incident and detected light. Effects due to coherent enhancement of weak non-resonant transitions are also observed. Comparison of the measurements with realistic quantum Monte Carlo simulations of Kupriyanov, et al [1] yield very good …

Detection Of Special Nuclear Material With High Purity Germanium (Hpge) And Mercuric Iodide (Hgi2) Gamma Detectors, Michael B. Nelson

Theses and Dissertations

The Defense Threat Reduction Agency (DTRA) contracted for two gamma radiation detectors: mercuric iodide (HgI₂) and electromechanically cooled (EMC) high purity germanium (HPGe) to support arms control inspection efforts. This project investigated whether these detectors could measure the quality and quantity of special nuclear material (SNM), particularly Pu-239 for the treaty verification mission. The project investigated two areas of detector capabilities: 1) HgI₂ and HPGe detector performance necessary to characterize the quality of plutonium and the presence of shielding materials and 2) HgI₂ and EMC HPGe detector performance degradation by high noise levels and EMC HPGe …

Enhanced Magnetic Quantum Oscillations In The Mixed State Of A Two-Dimensional Organic Superconductor, J. Wosnitza, J. Hagel, P. J. Meeson, D. Bintley, J. A. Schlueter, Javid Mohtasham, Rolf Walter Winter, Gary L. Gard

Chemistry Faculty Publications and Presentations

We report on de Haas–van Alphen (dHvA) oscillations observed in the mixed state of the organic superconductor β″–(BEDT-TTF)₂SF₅CH₂CF₂SO₃ (BEDT-TTF stands for bisethylenedithio-tetrathiafulvalene) utilizing the field-modulation technique and torque magnetometry. At low temperatures (30 mK), the dHvA signal persists down to 1.4 T well below the upper critical field Bc2≈3.6T. Contrary to most theoretical predictions and previous experimental findings, no additional damping of the dHvA-oscillation amplitude, but a reduced damping of the dHvA signal is found. This highly unusual effect might indicate a reduced quasiparticle scattering rate or an additional oscillatory contribution in the superconducting state.

Scattering Of Ultra Wide Band X-Wave Pulses By A Sphere, Maged Fayez Moawad

Archived Theses and Dissertations

No abstract provided.

Superfluorescence Polarization: Signature Of Collisional Redistribution, A. Kumarakrishnan, S. Chudasama, Xianming Han

Scholarship and Professional Work - LAS

We have studied effects of magnetic sublevel degeneracy on the polarization of superfluorescent pulses generated on the Ca 4s4p1P1–3d4s1D2 transition at 5.5μm. These pulses were generated from a cell of length 50 cm by optically pumping calcium vapor on the 4s21S0–4s4p1P1 transition in the presence of Ar gas. The axis of ellipticity of superfluorescence (SF) polarization is oriented parallel to the axis of the pump-laser polarization at large detunings, and undergoes an abrupt rotation through 90° for detunings close to resonance. The distribution of populations in the magnetic sublevels of the 1P1 state can be estimated using a simple model …

Ferroelectric-Field-Induced Tuning Of Magnetism In The Colossal Magnetoresistive Oxide La1Àxsrxmno3, X. Hong, A. Posadas, A. Lin, C. H. Ahn

Xia Hong Publications

A ferroelectric field effect approach is presented for modulating magnetism in the colossal magnetoresistive oxide La_1-xSr_xMnO₃ (LSMO). The ferromagnetic Curie temperature of ultrathin LSMO films was shifted by 35 K reversibly using the polarization field of the ferroelectric oxide Pb(Zr_xTi_1-x)O₃ in a field effect structure. This shift was also observed in magnetoresistance measurements, with the maximum magnetoresistance ratio at 6 T increasing from 64% to 77%. This model system approach does not introduce substitutional disorder or structural distortion, demonstrating that regulating the carrier concentration alone changes the magnetic phase transition …

Infrared-Active Vibron Bands Associated With Substitutional Impurities In Solid Parahydrogen, Robert Hinde

Chemistry Publications and Other Works

We present a model for the line shapes of infrared-active Q₁(0) vibron bands observed in solid parahydrogen doped with low concentrations of spherical substitutional impurities. The line shapes are highly sensitive to the H₂ vibrational dependence of the dopant–H₂ interaction. When this vibrational dependence is strong, the dopant can trap the infrared-active vibron in its first solvation shell; in this case, the trapped vibron manifests itself in the absorption spectrum as a narrow feature to the red of the pure solid’s vibron band.

An Optical Trap For Relativistic Plasma, Ping Zhang, Ned Saleh, Shouyuan Chen, Zhengming Sheng, Donald Umstadter

Donald Umstadter Publications

The first optical trap capable of confining relativistic electrons, with kinetic energy <350 keV was created by the interference of spatially and temporally overlapping terawatt power, 400 fs duration laser pulses (<2.4x10¹⁸ W/cm²) in plasma. Analysis and computer simulation predicted that the plasma density was greatly modulated, reaching a peak density up to 10 times the background density (ne /n0;10) at the interference minima. Associated with this charge displacement, a direct-current electrostatic field of strength of ~2 x 10¹¹ eV/m was excited. These predictions were confirmed experimentally by Thomson and Raman scattering diagnostics. Also confirmed were predictions that the electron density grating acted as a multi-layer mirror to transfer energy between the crossed laser beams, resulting …

Infrared-Active Vibron Bands Associated With Substitutional Impurities In Solid Parahydrogen, Robert Hinde

Robert Hinde

We present a model for the line shapes of infrared-active Q₁(0) vibron bands observed in solid parahydrogen doped with low concentrations of spherical substitutional impurities. The line shapes are highly sensitive to the H₂ vibrational dependence of the dopant–H₂ interaction. When this vibrational dependence is strong, the dopant can trap the infrared-active vibron in its first solvation shell; in this case, the trapped vibron manifests itself in the absorption spectrum as a narrow feature to the red of the pure solid’s vibron band.

Ferroelectricity In Free Niobium Clusters, Ramiro Moro, Xiaoshan Xu, Shuangye Yin, Walt A. De Heer

Xiaoshan Xu Papers

Electric deflections of gas-phase, cryogenically cooled, neutral niobium clusters [Nb_N; number of atoms (N) = 2 to 150, temperature (T) = 20 to 300 kelvin], measured in molecular beams, show that cold clusters may attain an anomalous component with very large electric dipole moments. In contrast, room-temperature measurements show normal metallic polarizabilities. Characteristic energies k_BT_G(N) [Boltzmann constant k_B times a transition temperature T_G(N)] are identified, below which the ferroelectric-like state develops. Generally, T_G decreases [110 > T_G(N) > 10K] as …

Performance Advantages Of Maximum Likelihood Methods In Prbs-Modulated Time-Of-Flight Energy Loss Spectroscopy, Zhongyu Yang

Electronic Theses and Dissertations

This thesis describes the design, experimental performance, and theoretical simulation of a novel time-of-flight analyzer that was integrated into a high resolution electron energy loss spectrometer (TOF-HREELS). First we examined the use of an interleaved comb chopper for chopping a continuous electron beam. Both static and dynamic behaviors were simulated theoretically and measured experimentally, with very good agreement. The finite penetration of the field beyond the plane of the chopper leads to non-ideal chopper response, which is characterized in terms of an "energy corruption" effect and a lead or lag in the time at which the beam responds to the …

Shock Wave Dispersion In Weakly Ionized Gas, Prasong Kessaratikoon

Physics Theses & Dissertations

Electrodeless microwave (MW) discharge in two straight, circular cylindrical resonant cavities in TE_1,1,1 and TM_0,1,2 modes were introduced to perform additional experimental studies on shock wave modification in non-equilibrium weakly ionized gases and to clarify the physical mechanisms of the shock wave modification process. The discharge was generated in 99.99% Ar at a gas pressure between 20 and 100 Torr and at a discharge power density less than 10.0 Watts/cm³. Power density used for operating the discharge was rather low in the present work, which was determined by evaluating the power loss inside the resonant cavity. …

An Experimental And Theoretical Study Of Transient Negative Ions In Mg, Zn, Cd And Hg, J. P. Sullivan, Paul Burrow, D. S. Newman, K. Bartschat, J. A. Michejda, P. Panajotovic, M. Moghbelalhossein, R. P. Mceachran, Stephen J. Busckman

Paul Burrow Publications

A range of experimental and theoretical techniques have been applied to the study of transient negative ions (resonances) formed in electron scattering from the Group II metals Mg, Zn, Cd, and Hg at incident electron energies below the first ionization potential. A wealth of resonance structures have been observed and from the experimental observations and theoretical information, classifications are proposed for some of these negative ion states.

An Information Theoretic Study Of The Ising Antiferromagnet With Quenched Dilution On A Triangular Lattice, Matthew D. Robinson

Electronic Theses and Dissertations

This investigation applies information theoretic techniques to study the ordering and structure of the Ising antiferromagnet with quenched disorder on a triangular lattice. The pure system shows no phase transition due to the high degree of frustration present. However, when quenched vacancies are introduced randomly into this geometrically frustrated system, a phase transition at finite temperature, to an ordered phase, can arise. If the vacancies are introduced on all three sublattices of the triangular lattice, then a two-dimensional spin-glass transition occurs. If dilution takes place on only one sublattice, then the other two sublattices develop magnetiza- tions below the critical …

Measurement Of Correlated Multiple Light Scattering In Utracold Atomic 85Rb, P. Kulatunga, C. I. Sukenik, S. Balik, M. D. Havey, D. V. Kupriyanov, I. M. Sokolov

Physics Faculty Publications

We report an experimental study of correlated multiple light scattering in an ultracold gas of ⁸⁵Rb confined in a magneto-optic trap. Measurements are made of the polarization dependence of the spatial and spectral profile of light backscattered from the sample. The results show an interferometric enhancement sensitive to coherent multiple scattering in the atomic gas, and strong variations with the polarization of the incident and detected light. The spatial width and peak value of the enhancement are found to be dependent on the sample size. Comparison of all the measurements with realistic quantum Monte Carlo simulations yields a very …