Physics Commons^™

Strain-Enhanced Coherent Exciton-Polaron States In 1d Phthalocyanine Crystalline Thin Films, Libin Liang

Graduate College Dissertations and Theses

Organic semiconductors are at the forefront of materials research, due to their desired electric and mechanical properties. They offer the unique opportunity to modify material properties during synthesis process, opening an avenue to the development of novel flexible and wearable electronic and photonic devices.Molecular excitons are of importance in organic semiconductor properties. While majority of research studies are centered on achieving good control of amorphous or polycrystalline thin film properties, the static disorder effect leads to poor device performance when compared to inorganic semiconductors with superior crystalline ordering. On the other hand, the macroscopic molecular long-range ordering can enhance device …

Structural, Electrical And Optical Properties Of Copper Oxide Phase Mixture: An Active Layer Of Solar Cell, Rifat Ara Shams

MSU Graduate Theses

Both CuO and Cu2O have been well studied and implemented individually as an active layer of a solar cell from early age of manufacturing. A mixture of these two-phase contents at different ratios can bring variance in absorbance which can present new and diverse aspect in solar cell fabrication with added efficiency. Previous works were successful to vary the phase mixture, and the nanostructures provided very high absorption co-efficient but poor optical response on electrical conductivity. The goal of this research is to find out the optimum parameter for the phase mixture of copper oxide with high absorption coefficient as …

Wave Excitation And Dynamics In Disordered Systems, Yiming Huang

Dissertations, Theses, and Capstone Projects

This thesis presents studies of the field and energy excited in disordered systems as well as the dynamics of scattering.

Dynamic and steady state aspects of wave propagation are deeply connected in lossless open systems in which the scattering matrix is unitary. There is then an equivalence among the energy excited within the medium through all channels, the Wigner time delay, which is the sum of dwell times in all channels coupled to the medium, and the density of states. But these equivalences fall away in the presence of material loss or gain. In this paper, we use microwave measurements, …

Understanding The Effects Of Water Vapor And Temperature On Aerosol Using Novel Measurement Methods, Tyler Jacob Capek

Dissertations, Master's Theses and Master's Reports

Aerosol and water are inexorably linked, and both are ubiquitous within our atmosphere and required components for cloud formation. Relative humidity (RH), a temperature dependent quantity, can have a significant influence on the size, shape, and ultimately, the optical properties of the aerosol. RH can vary substantially on small spatial and short temporal scales in turbulent conditions due to rapid fluctuations in temperature and water vapor mixing ratio. Accurate assessment of optical enhancements due to an increase in RH is key for determining the particles’ impact on the climate and visibility.

A humidity-controlled cavity attenuated phase-shift albedometer (H-CAPS-PM_SSA) …

Lasers, Noah B. Caro

Physics

No abstract provided.

Transient Transmission Oscillations In Doped And Undoped Lithium Niobate Induced By Near-Infrared Femtosecond Pulses, Bryan J. Crossman, Gregory J. Taft

Physics Faculty Publications

Transient transmission oscillations in X-cut and Z-cut congruent, iron-doped, and magnesium-doped lithium niobate samples were measured using 50 fs, 800 nm, 0.5 nJ pulses from a self-mode-locked Ti:sapphire laser in an optical pump–probe system. Several Raman-active oscillation modes excited by these pulses were observed as changes in the transmitted probe intensity versus time delay between the pump and probe pulses. The samples were rotated to determine how the incident polarization of the pump pulses affects the mode excitations. The observed Raman-active oscillations correspond to previously reported symmetry modes measured with traditional, continuous-wave, Raman spectroscopy using the same scattering …

Photo Stability Of Solutions Of Some Rodamine Dyes With Carboxyl Group, N. Nizomov, A.A. Jamalova, A.Sh. Yarmuxamedov

Scientific Journal of Samarkand University

The effect of light irradiation on the spectral-luminescent characteristics of some rhodamine dyes with a carboxyl group in solvents of various natures was studied. It has been established that under the influence of light irradiation in aqueous solutions of selected dyes, a decrease in the intensity of absorption and fluorescence with a simultaneous hypsochromic shift of the electronic spectra is observed.Under the same conditions, discolored solutions of rhodamine dyes in a binary solvent mixture of 1% water + 99% DMSO are reduced in color and, accordingly, absorbing and fluorescent capacity. The observed phenomenon is explained by the transition of molecules …

Progress Towards Terahertz Acoustic Phonon Generation In Doping Superlattices, Thomas E. Wilson

Thomas E. Wilson

Progress is described in experiments to generate coherent terahertz acoustic phonons in silicon doping superlattices by the resonant absorption of nanosecond-pulsed far-infrared laser radiation. Future experiments are proposed that would use the superlattice as a transducer in a terahertz cryogenic acoustic reflection microscope with sub-nanometer resolution.

Interactive Physics And Characteristics Of Photons And Photoelectrons In Hyperbranched Zinc Oxide Nanostructures, Garrett Edward Torix

Graduate Theses and Dissertations

As is commonly known, the world is full of technological wonders, where a multitude of electronic devices and instruments continuously help push the boundaries of scientific knowledge and discovery. These new devices and instruments of science must be utilized at peak efficiency in order to benefit humanity with the most advanced scientific knowledge. In order to attain this level of efficiency, the materials which make up these electronics, or possibly more important, the fundamental characteristics of these materials, must be fully understood. The following research attempted to uncover the properties and characteristics of a selected family of materials. Herein, zinc …

Sensitive And Ultra-Fast Species Detection Using Pulsed Cavity Ringdown Spectroscopy, Et-Touhami Es-Sebbar

Dr. Et-touhami Es-sebbar

Pulsed cavity ringdown spectroscopy (CRDS) is used to develop a novel, ultra-fast, high-sensitivity diagnostic for measuring species concentrations in shock tube experiments. The diagnostic is demonstrated by monitoring trace concentrations of ethylene in the mid-IR region near 949.47 cm−1. Each ringdown measurement is completed in less than 1 μs and the time period between successive pulses is 10 μs. The high sensitivity diagnostic has a noise-equivalent detection limit of 1.08 x 10−5 cm−1 which enables detection of 15 ppm ethylene at fuel pyrolysis conditions (1845 K and 2 bar) and 294 ppb ethylene under ambient conditions (297 K and 1 …

Progress Towards Terahertz Acoustic Phonon Generation In Doping Superlattices, Thomas E. Wilson

Thomas E. Wilson

Progress is described in experiments to generate coherent terahertz acoustic phonons in silicon doping superlattices by the resonant absorption of nanosecond-pulsed far-infrared laser radiation. Future experiments are proposed that would use the superlattice as a transducer in a terahertz cryogenic acoustic reflection microscope with sub-nanometer resolution.

Measurements Of Ultracold Neutron Upscattering And Absorption In Polyethylene And Vanadium, Eduard I. Sharapov, Charles L. Morris, Mark Makela, Andy Saunders, Evan R. Adamek, Yelena Bagdasarova, Leah J. Broussard, Chris Cude-Woods, Deon E. Fellers, Peter Geltenbort, Siraj I. Hasan, Kevin P. Hickerson, Gary Hogan, Anthony T. Holley, Chen-Yu Liu, Michael P. Mendenhall, Jose Ortiz, Robert W. Pattie Jr., David G. Phillips, John Ramsey, D. J. Salvat, Susan J. Seestrom, E. Shaw, Sky Sjue, Walter E. Sondheim, Brittany Vorndick, Zhehui Wang, Tanner L. Womack, Andrew R. Young, B. A. Zeck

Robert W. Pattie Jr.

Electrical And Optical Characterization Of Si-Ge-Sn, Merle D. Hamilton

Theses and Dissertations

The electrical characterization of boron-doped p-Si_0.08Ge_0.90Sn_0.02/p-Ge(100) and p-Si_0.112Ge_0.86Sn_0.028/n-Si(100) with various epilayer thicknesses was measured using the Hall effect. The room temperature sheet carrier concentration ranged from 1.21 x 10¹³ – 1.32 x 10¹⁶ cm^-2. The room temperature mobilities were measured to be between 166 and 717 cm²/V·s, depending on sample composition. In the low temperature regime, the mobility was mainly affected by ionized impurity scattering. In the high temperature regime, the mobility was mainly affected by …

Characterization Of Wave Transport In Non-Conservative Media With Random And Correlated Disorder, Benjamin Henry Payne

Doctoral Dissertations

"Passive quasi-one-dimensional random media exhibit one of the three regimes of transport - ballistic, diffusive, or Anderson localization - depending on system size. The ballistic and diffusion approximations assumes particle transport, whereas Anderson Localization occurs when wave self-interference effects are dominant. When the system contains absorption or gain, then how the regimes can be characterized becomes unclear. By investigating theoretically and numerically the ratio of transmission to energy in a random medium in one dimension, we show this parameter can be used to characterize localization in random media with gain. Non-conservative media implies a second dimension for the transport parameter …

Modeling Free-Carrier Absorption And Avalanching By Ultrashort Laser Pulses, Jeremy R. Gulley

Faculty and Research Publications

In the past decade it was demonstrated experimentally that negatively-chirped laser pulses can lower the surface LIDT for wide band-gap materials by decreasing the number of photons required for photoionization on the leading edge of the pulse. Similarly, simulations have shown that positively-chirped pulses resulting from selffocusing and self-phase modulation in bulk dielectrics can alter the onset of laser-induced material modifications by increasing the number of photons required for photoionization on the leading edge of the pulse. However, the role of multi-chromatic effects in free-carrier absorption and avalanching has yet to be addressed. In this work a frequency-selective model of …

Modeling Free-Carrier Absorption And Avalanching By Ultrashort Laser Pulses, Jeremy Gulley

Jeremy R. Gulley

In the past decade it was demonstrated experimentally that negatively-chirped laser pulses can lower the surface LIDT for wide band-gap materials by decreasing the number of photons required for photoionization on the leading edge of the pulse. Similarly, simulations have shown that positively-chirped pulses resulting from selffocusing and self-phase modulation in bulk dielectrics can alter the onset of laser-induced material modifications by increasing the number of photons required for photoionization on the leading edge of the pulse. However, the role of multi-chromatic effects in free-carrier absorption and avalanching has yet to be addressed. In this work a frequency-selective model of …

Energy Scaling Of Nanosecond Gain-Switched Cr2+:Znse Lasers, Vladimir V. Fedorov, Igor S. Moskalev, M. S. Mirov, S. B. Mirov, Torrey J. Wagner, Matthew J. Bohn, Patrick A. Berry, K. L. Schepler

Faculty Publications

In this paper, we report record nanosecond output energies of gain-switched CrZnSe lasers pumped by Q-switched CrTmHoYAG 100 ns at 2.096 microns and Raman shifted NdYAG lasers 7 ns at 1.906 microns. In these experiments we used Brewster cut CrZnSe gain elements with a chromium concentration of 8x10¹⁸cm^-3. Under CrTmHoYAG pumping, the first CrZnSe laser demonstrated 3.1 mJ of output energy, 52 slope efficiency and 110 nm linewidth centered at a wavelength of 2.47 microns. Maximum output energy of the second CrZnSe laser reached 10.1 mJ under H₂ Raman shifted NdYAG laser pumping. The slope …

Optical Properties Of In1-Xgaxn Epilayers Grown By Hpcvd, Jielei Wang Ms

Physics and Astronomy Theses

Optical absorption spectroscopy has been applied to study properties such as the fundamental absorption edge and defect absorption centers of group III-nitride compound semiconductor epilayers. The investigation in this thesis focused on analyzing the band gap of indium-rich In1-xGaxN epilayers, which where grown by the high-pressure chemical vapor deposition (HPCVD) technique. Our results - together with literature data for gallium-rich In1-xGaxN alloys indicate that the shift of the fundamental band gap of In1-xGaxN with composition x can be described with a bowing parameter of b = 2.2eV. Temperature dependent transmission measurements show that the band gap variation with temperature follows …

Structure And Mechanism Of Copper- And Nickel-Substituted Analogues Of Metallo-Β-Lactamase L1, Zhenxin Hu, Lauren J. Spadafora, Christine E. Hajdin, Brian Bennett, Michael W. Crowder

Physics Faculty Research and Publications

In an effort to further probe metal binding to metallo-β-lactamase L1 (mβl L1), Cu- (Cu-L1) and Ni-substituted (Ni-L1) L1 were prepared and characterized by kinetic and spectroscopic studies. Cu-L1 bound 1.7 equiv of Cu and small amounts of Zn(II) and Fe. The EPR spectrum of Cu-L1 exhibited two overlapping, axial signals, indicative of type 2 sites with distinct affinities for Cu(II). Both signals indicated multiple nitrogen ligands. Despite the expected proximity of the Cu(II) ions, however, only indirect evidence was found for spin−spin coupling. Cu-L1 exhibited higher k_cat (96 s⁻¹) and K_m (224 μM) values, as …

Effective Medium Theory, Rough Surfaces, And Moth’S Eyes, David D. Allred, Zephne Larsen, Joseph Muhlestein, R. Steven Turley, Anthony Willey

Faculty Publications

Optics in the extreme ultraviolet (XUV) have important applications in microelectronics, microscopy, space physics, and in imaging plasmas. Because of the short wavelengths involved in these applications, it is critical to account for interfacial roughness to accurately predict the reflection and absorption of XUV optics. This paper examines two possible effects of roughness on optical absorption, non-specular reflection and enhanced transmission and compares these to measured experimental data on a rough Y2O3 thin film.

Implementation Of Optical Spectra Calculations In Fireball: A Local-Orbital Density Functional Theory Approach, Ivan Grigoryevich Okhrimenko

Theses and Dissertations

We have expanded the capabilities of the ab initio tight-binding molecular dynamics package FIREBALL to include calculations of optical properties. Basic zero order approximation is based on transitions between Kohn-Sham states. Corrections for electron-electron interactions are based on time dependant density functional theory (TDDFT). Consistent with the FIREBALL approach, we use precalculated integrals and approximations to make the program faster.

Optical And Physical Properties Of Ceramic Crystal Laser Materials, Jed Simmons

Electronic Theses and Dissertations

Historically ceramic crystal laser material has had disadvantages compared to single crystal laser material. However, progress has been made in the last decade and a half to overcome the disadvantages associated with ceramic crystal. Today, because of the promise of ceramic crystal as a high power laser material, investigation into its properties, both physical and optical, is warranted and important. Thermal expansion was measured in this thesis for Nd:YAG (yttrium aluminum garnet) ceramic crystal using an interferometric method. The interferometer employed a spatially filtered HeNe at 633 nm wavelength. Thermal expansion coefficients measured for the ceramic crystal samples were near …

Black Hole Particle Emission In Higher-Dimensional Spacetimes, Vitor Cardoso, Marco Cavaglia, Leonardo Gualtieri

Physics Faculty Research & Creative Works

In models with extra dimensions, a black hole evaporates both in the bulk and on the visible brane, where standard model fields live. The exact emissivities of each particle species are needed to determine how the black hole decay proceeds. We compute and discuss the absorption cross sections, the relative emissivities, and the total power output of all known fields in the evaporation phase. Graviton emissivity is highly enhanced as the spacetime dimensionality increases. Therefore, a black hole loses a significant fraction of its mass in the bulk. This result has important consequences for the phenomenology of black holes in …

Variational Approach To The Volume Viscosity Of Fluids, Allan J. Zuckerwar, Robert L. Ash

Mechanical & Aerospace Engineering Faculty Publications

The variational principle of Hamilton is applied to develop an analytical formulation to describe the volume viscosity in fluids. The procedure described here differs from those used in the past in that a dissipative process is represented by the chemical affinity and progress variable (sometimes called "order parameter") of a reacting species. These state variables appear in the variational integral in two places: first, in the expression for the internal energy, and second, in a subsidiary condition accounting for the conservation of the reacting species. As a result of the variational procedure, two dissipative terms appear in the Navier-Stokes equation. …

Progress Towards Terahertz Acoustic Phonon Generation In Doping Superlattices, Thomas E. Wilson

Physics Faculty Research

Progress is described in experiments to generate coherent terahertz acoustic phonons in silicon doping superlattices by the resonant absorption of nanosecond-pulsed far-infrared laser radiation. Future experiments are proposed that would use the superlattice as a transducer in a terahertz cryogenic acoustic reflection microscope with sub-nanometer resolution.

Progress Towards Terahertz Acoustic Phonon Generation In Doping Superlattices, Thomas E. Wilson

Physics Faculty Research

Progress is described in experiments to generate coherent terahertz acoustic phonons in silicon doping superlattices by the resonant absorption of nanosecond-pulsed far-infrared laser radiation. Future experiments are proposed that would use the superlattice as a transducer in a terahertz cryogenic acoustic reflection microscope with sub-nanometer resolution.

Thorium-Based Thin Films As Highly Reflective Mirrors In The Euv, David D. Allred, William R. Evans, Jed E. Johnson, Richard L. Sandberg, R. Steven Turley

Faculty Publications

As applications for extreme ultraviolet (EUV) radiation have been identified, the demand for better optics has also increased. Thorium and thorium oxide thin films (19 to 61 nm thick) were RF-sputtered and characterized using atomic force microscopy (AFM), spectroscopic ellipsometry, low-angle x-ray diffraction (LAXRD), x-ray photoelectron spectroscopy (XPS), and x-ray absorption near edge structure (XANES) in order to assess their capability as EUV reflectors. Their reflectance and absorption at different energies were also measured and analyzed at the Advanced Light Source in Berkeley. The reflectance of oxidized thorium is reported between 2 and 32 nm at 5, 10, and 15 …

Multiple Scattering Of Light In Inhomogeneous Media And Applications, Claudia Mujat

Electronic Theses and Dissertations

Light scattering-based techniques are being developed for non-invasive diagnostics of inhomogeneous media in various fields, such as medicine, biology, and material characterization. However, as most media of interest are highly scattering and have a complex structure, it is difficult to obtain a full analytical solution of the scattering problem without introducing approximations and assumptions about the properties of the system under consideration. Moreover, most of the previous studies deal with idealized scattering situations, rarely encountered in practice. This dissertation provides new analytical, numerical, and experimental solutions to describe subtle effects introduced by the properties of the light sources, and by …

Complete Measurement Of Three-Body Photodisintegration Of 3He For Photon Energies Between 0.35 And 1.55 Gev, H. Bagdasaryan, M. Bektasoglu, K. V. Dharmawardane, G. E. Dodge, T. A. Forest, G. Gavalian, N. Guler, C. E. Hyde-Wright, A. Klein, S. E. Kuhn, L. M. Qin, S. Stepanyan, L. B. Weinstein, J. Yun, Et Al., The Clas Collaboration

Physics Faculty Publications

The three-body photodisintegration of ³He has been measured with the CLAS detector at Jefferson Lab, using tagged photons of energies between 0.35 GeV and 1.55 GeV. The large acceptance of the spectrometer allowed us for the first time to cover a wide momentum and angular range for the two outgoing protons. Three kinematic regions dominated by either two- or three-body contributions have been distinguished and analyzed. The measured cross sections have been compared with results of a theoretical model, which, in certain kinematic ranges, have been found to be in reasonable agreement with the data.

Substrate Specificity, Metal Binding Properties, And Spectroscopic Characterization Of The Dape-Encoded N-Succinyl-L,L-Diaminopimelic Acid Desuccinylase From Haemophilus Influenzae, David L. Bienvenue, Danuta M. Gilner, Ryan S. Davis, Brian Bennett, Richard C. Holz

Physics Faculty Research and Publications

The catalytic and structural properties of divalent metal ion cofactor binding sites in the dapE-encoded N-succinyl-l,l-diaminopimelic acid desuccinylase (DapE) from Haemophilus influenzae were investigated. Co(II)-substituted DapE enzyme was 25% more active than the Zn(II)-loaded form of the enzyme. Interestingly, Mn(II) can activate DapE, but only to ∼20% of the Zn(II)-loaded enzyme. The order of the observed k_cat values are Co(II) > Zn(II) > Cd(II) > Mn(II) >Ni(II) ∼ Cu(II) ∼ Mg(II). DapE was shown to only hydrolyze l,l-N-succinyl-diaminopimelic acid (l,l-SDAP) and was inactive toward d,l-, l,d-, and d,d-SDAP. DapE was also inactive toward several acetylated amino acids as …