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Full-Text Articles in Physics
Polymer Gels With Tunable Ionic Seebeck Coefficient For Ultra-Sensitive Printed Thermopiles, Dan Zhao, Anna Martinelli, Andreas Willfahrt, Thomas Fischer, Diana Bernin, Zia Ullah Khan, Maryam Shahi, Joseph W. Brill, Magnus P. Jonsson, Simone Fabiano, Xavier Crispin
Polymer Gels With Tunable Ionic Seebeck Coefficient For Ultra-Sensitive Printed Thermopiles, Dan Zhao, Anna Martinelli, Andreas Willfahrt, Thomas Fischer, Diana Bernin, Zia Ullah Khan, Maryam Shahi, Joseph W. Brill, Magnus P. Jonsson, Simone Fabiano, Xavier Crispin
Physics and Astronomy Faculty Publications
Measuring temperature and heat flux is important for regulating any physical, chemical, and biological processes. Traditional thermopiles can provide accurate and stable temperature reading but they are based on brittle inorganic materials with low Seebeck coefficient, and are difficult to manufacture over large areas. Recently, polymer electrolytes have been proposed for thermoelectric applications because of their giant ionic Seebeck coefficient, high flexibility and ease of manufacturing. However, the materials reported to date have positive Seebeck coefficients, hampering the design of ultra-sensitive ionic thermopiles. Here we report an “ambipolar” ionic polymer gel with giant negative ionic Seebeck coefficient. The latter can …
Nonequilibrium Processes In Polymers Undergoing Interchange Reactions. Part 2: Reaction-Diffusion Processes, Alejandro Garcia, J. Pojman, D. Kondepudi, C. Van De Broeck
Nonequilibrium Processes In Polymers Undergoing Interchange Reactions. Part 2: Reaction-Diffusion Processes, Alejandro Garcia, J. Pojman, D. Kondepudi, C. Van De Broeck
Faculty Publications
A reactiodffusion system of polymers undergoing interchange reactions is studied. The equation that describes the dynamics of the system is similar to the Boltzmann equation for a gas of hard spheres. We consider a one-dimensionsl system in which the average length and the concentrations at the boundaries are fixed. The resulting steady states are obtained analytically and with numerical integration of equations obtained by using a local equilibrium approximation. Monte Carlo simulations of experimentally realizable conditions were performed and compared. The results reveal a nonlinear distribution of molecular concentration and mass. The entropy of the polymer distributions is calculated as …
Nonequilibrium Processes In Polymers Undergoing Interchange Reactions. Part 2: Reaction-Diffusion Processes, Alejandro Garcia, J. Pojman, D. Kondepudi, C. Van De Broeck
Nonequilibrium Processes In Polymers Undergoing Interchange Reactions. Part 2: Reaction-Diffusion Processes, Alejandro Garcia, J. Pojman, D. Kondepudi, C. Van De Broeck
Alejandro Garcia
A reactiodffusion system of polymers undergoing interchange reactions is studied. The equation that describes the dynamics of the system is similar to the Boltzmann equation for a gas of hard spheres. We consider a one-dimensionsl system in which the average length and the concentrations at the boundaries are fixed. The resulting steady states are obtained analytically and with numerical integration of equations obtained by using a local equilibrium approximation. Monte Carlo simulations of experimentally realizable conditions were performed and compared. The results reveal a nonlinear distribution of molecular concentration and mass. The entropy of the polymer distributions is calculated as …