Physics Commons^™

Relevancy Of Pulsed Electroacoustic Measurements For Investigating Spacecraft Charging, Zachary Gibson, J. R. Dennison

Journal Articles

The magnitude and spatial distribution of charge embedded in dielectric materials and the evolution of the charge distributions with time are paramount for the understanding and mitigation of spacecraft charging. Spacecraft materials are charged primarily by incident fluxes of low-energy electrons, with electron fluxes in the 10–50 keV range often responsible for the most deleterious arcing effects. While the pulsed electroacoustic (PEA) method can provide sensitive nondestructive measurements of the internal charge distribution in insulating materials, it has often been limited for spacecraft charging applications by typical spatial resolutions of ≤ 10 μm , with a 10- μm …

Effects Of Exposure To Atmospheric Humidity On Breakdown Field Strength Measurements Of Polymers, Megan Loveland Dewaal

Physics Capstone Projects

This study investigates the effects of absorbed water introduced via exposure to atmospheric humidity on electrostatic breakdown field strength measurements of polymers. Conducting breakdown tests under sample conditions appropriate for different applications is essential. If the breakdown field strength is overestimated for an application, an insulator may be used inappropriately in high electric fields where they are more likely to break down. Comparisons are made between: sets of pristine samples, samples that underwent a thorough vacuum bake out to remove absorbed water, and samples subject to subsequent incremental prolonged atmospheric exposure. These investigated the effects of absorbed water and determined …

Nondestructive Evaluation Of 3d Printed, Extruded, And Natural Polymer Structures Using Terahertz Spectroscopy And Imaging, Alexander T. Clark

Dissertations

Terahertz (THz) spectroscopy and imaging are considered for the nondestructive evaluation (NDE) of various three-dimensional (3D) printed, extruded, and natural polymer structures. THz radiation is the prime candidate for many NDE challenges due to the added benefits of safety, increased contrast and depth resolution, and optical characteristic visualization when compared to other techniques. THz imaging, using a wide bandwidth pulse-based system, can evaluate the external and internal structure of most nonconductive and nonpolar materials without any permanent effects. NDE images can be created based on THz pulse attributes or a material’s spectroscopic characteristics such as refractive index, attenuation coefficient, or …

A Molecular Dynamics Study Of Polymer Chains In Shear Flows And Nanocomposites, Venkat Bala

Electronic Thesis and Dissertation Repository

In this work we study single chain polymers in shear flows and nanocomposite polymer melts extensively through the use of large scale molecular dynamics simulations through LAMMPS. In the single polymer chain shear flow study, we use the Lattice Boltzmann method to simulate fluid dynamics and also include thermal noise as per the \emph{fluctuation-dissipation} theorem in the system. When simulating the nanocomposite polymer melts, we simply use a Langevin thermostat to mimic a heat bath. In the single polymer in shear flow study we investigated the margination of a single chain towards solid surfaces and how strongly the shear flow …

Materials Science And Mechanosensitivity Of Living Matter, Alison E. Patteson, Merrill E. Asp, Paul A. Janmey

Physics - All Scholarship

Living systems are composed of molecules that are synthesized by cells that use energy sources within their surroundings to create fascinating materials that have mechanical properties optimized for their biological function. Their functionality is a ubiquitous aspect of our lives. We use wood to construct furniture, bacterial colonies to modify the texture of dairy products and other foods, intestines as violin strings, bladders in bagpipes, and so on. The mechanical properties of these biological materials differ from those of other simpler synthetic elastomers, glasses, and crystals. Reproducing their mechanical properties synthetically or from first principles is still often unattainable. The …

Establishing Independent Tunability Of The Mechanical And Transport Properties Of Polymer Gels, Lucas Rankin

Master’s Theses

Polymer gels can be used in the fabrication of materials for filtering liquid and gaseous media, solid-state electrolytes, and transdermal medical patches. This diverse range of applications primarily relies on the transport and mechanical properties of polymer gels. Both sets of properties have shown excellent tunability, but typically in a coupled fashion. Establishing the independent tunability of the transport and mechanical properties of polymer gels (using simple, cost-effective methods) is paramount if polymer gels are to be used to their full potential. Specifically, block copolymer gels self-assemble into organized nanoscale networks within the gel solvent, which allows for facile control …

Optical Relaxation Of Defects In Kapton Caused By Irradiation, Ashlan Keeler Swainston

Physics Capstone Projects

Radiation can create atomic-scale defect states in polymers, leading to changes in their optical, electrical and mechanical properties. Recent studies of polymers have shown that these defect states are sensitive to oxygen or air exposure. It is believed that air cause the number of defect states to decrease and the polymers to revert to their original states. However, the time scale of this regression is not known. This experiment quantified the time that it takes one polymer to recover and the extent of said recovery; polymide (PI). In order to study the regression, optical transmission data were taken using a …

Thermoelectric Porous Mof Based Hybrid Materials, Engelbert Redel, Helmut Baumgart

Electrical & Computer Engineering Faculty Publications

Porous hybrid materials and MOF (Metal-Organic-Framework) films represent modern designer materials that exhibit many requirements of a near ideal and tunable future thermoelectric (TE) material. In contrast to traditional semiconducting bulk TE materials, porous hybrid MOF templates can be used to overcome some of the constraints of physics in bulk TE materials. These porous hybrid systems are amenable for simulation and modeling to design novel optimized electron-crystal phonon-glass materials with potentially very high ZT (figure of merit) numbers. Porous MOF and hybrid materials possess an ultra-low thermal conductivity, which can be further modulated by phonon engineering within their complex porous …

Relaxation Of Radiation Effects In Polymers, Alexandra Hughlett Nelson

Physics Capstone Projects

Radiation can create atomic-scale defect states in polymers, leading to changes in their optical, electrical and mechanical properties. Recent studies of polymers have shown that these defect states are sensitive to oxygen or water exposure. It is believed that oxygen cause the number of defect states to decrease and the polymers to revert to their original states. However, the time scale of this regression is not known. This experiment quantified the time that it takes five polymers to recover and the extent of said recovery; polypropylene (PP), low density polyethylene (LDPE), fluorinated ethylene propylene (FEP), polymide (PI), and poly ether …

Erratum: "Imaging The Three‐Dimensional Orientation And Rotational Mobility Of Fluorescent Emitters Using The Tri‐Spot Point Spread Function", Oumeng Zhang, Jin Lu, Tianben Ding, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

In the original paper, a calibration error exists in the image-formation model used to analyze experimental images taken by our microscope, causing a bias in the orientation measurements in Figs. 2 and 3. The updated measurements are shown in Fig. E1. We have also updated the supplementary material for the original article to discuss the revised PSF model and estimation algorithms (supplementary material 2) and show the revised model and measurements (Figs. S1, S3, S7, S8, and S10–S13).

Wireless Antenna Detection Of Electrostatic Discharge Events, Allen Andersen, Jr Dennison

Journal Articles

Wireless intraspacecraft communication technology is being developed for signal transfer on space missions to save weight and simplify the design. One consideration for this new technology is its interaction with space environmentinduced electrostatic discharges (ESDs). The short time scales of spacecraft ESD events result in broad frequency band signals that can interact with high-frequency wireless antennas. These interactions present a source of signal noise. However, they also present a possibility of in-flight wireless ESD monitoring. We present laboratory measurements of arcing on common spacecraft insulators using commercially available single-band 2.4-GHz and dual-band 2.4-/5.8-GHz Wi-Fi antennas. These wireless detections are shown …

Polymer Gels With Tunable Ionic Seebeck Coefficient For Ultra-Sensitive Printed Thermopiles, Dan Zhao, Anna Martinelli, Andreas Willfahrt, Thomas Fischer, Diana Bernin, Zia Ullah Khan, Maryam Shahi, Joseph W. Brill, Magnus P. Jonsson, Simone Fabiano, Xavier Crispin

Physics and Astronomy Faculty Publications

Measuring temperature and heat flux is important for regulating any physical, chemical, and biological processes. Traditional thermopiles can provide accurate and stable temperature reading but they are based on brittle inorganic materials with low Seebeck coefficient, and are difficult to manufacture over large areas. Recently, polymer electrolytes have been proposed for thermoelectric applications because of their giant ionic Seebeck coefficient, high flexibility and ease of manufacturing. However, the materials reported to date have positive Seebeck coefficients, hampering the design of ultra-sensitive ionic thermopiles. Here we report an “ambipolar” ionic polymer gel with giant negative ionic Seebeck coefficient. The latter can …

Diffusion Of Gold Nanoparticles Within Polymer Solutions And Gels, Kavindya Kumari Senanayake R W H

Wayne State University Dissertations

Soft matter is a subfield of condensed matter physics including systems, such as polymers, colloidal dispersions, liquid crystals, surfactants. Understanding their interaction and dynamics is essential for many interdisciplinary fields of study as well as important for technological advancements. We used gold nanoparticles (AuNPs) to investigate the length-scale dependent dynamics in dilute, semidilute, entangled polymer solutions and gels. Two-photon fluctuation correlation spectroscopy (FCS) technique was used to investigate the translation diffusion coefficient of AuNPs. For polymer solutions, we found that existing hydrodynamic and obstruction models are inadequate to describe the size dependence of the particle diffusion coefficient. Within entangled Poly …

Imaging The Three-Dimensional Orientation And Rotational Mobility Of Fluorescent Emitters Using The Tri-Spot Point Spread Function, Oumeng Zhang, Jin Lu, Tianben Ding, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

Fluorescence photons emitted by single molecules contain rich information regarding their rotational motions, but adapting single-molecule localization microscopy (SMLM) to measure their orientations and rotational mobilities with high precision remains a challenge. Inspired by dipole radiation patterns, we design and implement a Tri-spot point spread function (PSF) that simultaneously measures the three-dimensional orientation and the rotational mobility of dipole-like emitters across a large field of view. We show that the orientation measurements done using the Tri-spot PSF are sufficiently accurate to correct the anisotropy-based localization bias, from 30 nm to 7 nm, in SMLM. We further characterize the emission anisotropy …

Wireless Antenna Detection Of Electrostatic Discharge Events, Allen Andersen, Jr Dennison

Conference Proceedings

Wireless intra-spacecraft communication technology is being developed as a weight-saving and design-simplifying measure for signal transfer on space missions. One consideration for this new technology is its interaction with space-environment induced electrostatic discharges (ESD). The short time scales of spacecraft ESD events results in broad frequency signals that can interact with wireless antennae. These interactions present a source of signal noise. However, they may also present a possibility of in-flight wireless ESD monitoring.

We present laboratory measurements of arcing on common spacecraft insulators using commercially available single band 2.4 GHz and dual band 2.4/5.8 GHz Wi-Fi antennas. These wireless detections …

Electrostatic Alignment Of Electrospun Peo Fibers By The Gap Method Increases Individual Fiber Modulus In Comparison To Non-Aligned Fibers Of Similar Diameter, Christopher Fryer, Meghan Scharnagl, Christine C. Helms

Physics Faculty Publications

Studies on the alignment, physical and mechanical properties of individual electrospun fibers provide insight to their formation, production and optimization. Here we measure the alignment, diameter and modulus of individual fibers formed using the electrostatic gap method. We find electrostatic alignment produces fibers with a smaller diameter than their nonaligned counterparts have. Therefore, due to the dependence of fiber modulus on diameter aligned fibers have a higher modulus. Furthermore, we show that aligned and nonaligned fibers of the similar diameter have different moduli. Aligned fibers have a modulus 1.5 to 2 times larger than nonaligned fibers of the similar diameter.

The Role Of Recoverable And Non-Recoverable Defects In Dc Electrical Aging Of Highly Disordered Insulating Materials, Allen Andersen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Electrical insulation under high voltage can eventually fail, causing critical damage to electronics. Such electrostatic discharge (ESD) is the primary source of anomalies or failures on spacecraft due to charged particles from the Sun or planetary radiation belts accumulating in spacecraft insulators. High-voltage direct current power distribution is another example of a growing industry that needs to estimate the operational lifetime of electrical insulation. My research compares laboratory tests of ESD events in common insulating materials to a physics-based model of breakdown. This model of breakdown is based on the approximation that there are two primary types of defects in …

Conducting Polyelectrolyte Complexes: Assembly, Structure, And Transport, Michael A. Leaf

Doctoral Dissertations

Decades of progress have yielded a tremendous variety of organic electronics, with great strides in the development of photovoltaics, thermoelectrics and other flexible devices. Ubiquitous in these research areas are films of poly(3,4-ethylenedioxythiophene): poly(styrenesulfonic acid) (PEDOT: PSS), a complex of oppositely-charged polyelectrolytes initially suspended in water before film formation. This material has high electronic conductivity and good water processability. Pristine film conductivity is somewhat low, but is dramatically enhanced through simple treatments like ionic liquid addition or shear. Can this enhancement be understood so that further optimization might render PEDOT: PSS commercially viable? PEDOT: PSS is a complicated material, with …

Planar Granular Shear Flow Under External Vibration, Brian Utter, Eric P. Hoppmann

Faculty Journal Articles

We present results from a planar shear experiment in which a two-dimensional horizontal granular assembly of pentagonal particles sheared between two parallel walls is subjected to external vibration. Particle tracking and photoelastic measurements are used to quantify both grain scale motion and interparticle stresses with and without imposed vibrations. We characterize the particle motion in planar shear and find that flow of these strongly interlocking particles consists of transient vortex motion with a mean flow given by the sum of exponential profiles imposed by the shearing walls. Vibration is applied either through the shearing surface or as bulk vertical vibration …

Perspectives On The Distributions Of Esd Breakdowns For Spacecraft Charging Applications, Allen Andersen, Krysta Moser, Jr Dennison

Journal Articles

Electrostatic discharge (ESD) continues to pose significant risks to space missions despite decades of intense study. Tabulated values of material breakdown strength used in spacecraft charging models are often based on cursory measurements that may not be fully relevant to a given mission. Materials physics offers insight into the pertinent variables that affect breakdown and how to address them experimentally for spacecraft applications. We present measured distributions of ESD data across several test configurations for three polymeric materials that, taken together, begin to provide an understanding of how to estimate the likelihood of ESD events over a spacecraft’s mission lifetime. …

Dependence Of Electrostatic Field Strength On Voltage Ramp Rate For Spacecraft Materials, Krysta Moser, Allen Andersen, Jr Dennison

Journal Articles

This work investigated the dependence of electrostatic field strength for spacecraft materials on voltage ramp rate, by applying an increasing incremental electrostatic field until electrostatic breakdown occurred. Tests on Kapton E found that at ramp rates two or three orders of magnitude lower than the maximum recommended rate, the electrostatic breakdown field, FESD was lower by a factor of two or more. This suggests that tabulated values of FESD, which have been used by the spacecraft charging community, could substantially overestimate FESD in common slowly evolving spacecraft situations. This study expanded these ramp rate tests to include a wider range …

Measurement Of The Temperature Dependence Of Radiation Induced Conductivity In Polymeric Dielectrics, Jodie Corbridge Gillespie

Jodie Corbridge Gillespie

This study measures Radiation Induced Conductivity (RIC) in five insulating polymeric materials over temperatures ranging from ~110 K to ~350 K: polyimide (PI or Kapton HNTM and Kapton ETM), polytetraflouroethylene (PTFE or TeflonTM), ethylene-tetraflouroethylene (ETFE or TefzelTM), and Low Density Polyethylene (LDPE). RIC occurs when incident ionizing radiation deposits energy and excites electrons into the conduction band of insulators. Conductivity was measured when a voltage was applied across vacuum-baked, thin film polymer samples in a parallel plate geometry. RIC was calculated as the difference in sample conductivity under no incident radiation and under an incident ~4 MeV electron beam at …

Kinetics And Dynamics Of Electrophoretic Translocation Of Polyelectrolytes Through Nanopores, Harshwardhan Katkar

Doctoral Dissertations

The idea of sequencing a DNA based on single-file translocation of the DNA through nanopores under the action of an electric field has received much attention over the past two decades due to the societal need for low cost and high-throughput sequencing. However, due to the high speed of translocation, interrogating individual bases with an acceptable signal to noise ratio as they traverse the pore has been a major problem. Experimental facts on this phenomenon are rich and the associated phenomenology is yet to be fully understood. This thesis focuses on understanding the underlying principles of polymer translocation, with an …

The Effect Of Attractive Polymer-Nanoparticle Interactions On The Local Segmental Dynamics Of Polymer Nanocomposites, Adam Prillaman Holt

Doctoral Dissertations

Considerable progress has been made in understanding the miscibility and morphology of polymer nanocomposites (PNCs). However, to date, there is little understood concerning the modification of segmental mobility at the polymer-nanoparticle interface, which due to prevalence of interfaces in PNCs, will predominately control the viscoelastic and mechanical properties of these materials.

In this dissertation, static and dynamic experimental techniques are combined to identify the specific parameters controlling the modification of segmental dynamics at the polymer-nanoparticle interface in the model system of poly(2-vinyl pyridine)/silica nanocomposites. In general, the experimental results clearly demonstrate that the segmental dynamics at the polymer-nanoparticle interface are …

Electrostatic Discharge And Endurance Time Measurements Of Spacecraft Materials: A Defect-Driven Dynamic Model, Allen Andersen, Jr Dennison, Alec Sim, Charles Sim

Journal Articles

Electrostatic breakdown leads to the majority of anomalies and failures attributed to spacecraft interactions with the plasma space environment. It is therefore critical to understand how electrostatic field strength (F_ESD) of spacecraft materials varies due to environmental conditions such as duration of applied electric field, rate of field change, history of exposure to high fields, and temperature. We have developed a dual-defect, thermodynamic, mean-field trapping model in terms of recoverable and irrecoverable defect modes to predict probabilities of breakdown. Fits to a variety of measurements of the dependence of F_ESD of insulating polymers on endurance time, voltage …

Advances In The Analysis And Prediction Of Turbulent Viscoelastic Flows, T. B. Gatski, L. Thais, G. Mompean

CCPO Publications

It has been well-known for over six decades that the addition of minute amounts of long polymer chains to organic solvents, or water, can lead to significant turbulent drag reduction. This discovery has had many practical applications such as in pipeline fluid transport, oil well operations, vehicle design and submersible vehicle projectiles, and more recently arteriosclerosis treatment. However, it has only been the last twenty-five years that the full utilization of direct numerical simulation of such turbulent viscoelastic flows has been achieved. The unique characteristics of viscoelastic fluid flow are dictated by the nonlinear differential relationship between the flow strain …

Plasma Processes And Polymers Special Issue On: Plasma And Cancer, Mounir Laroussi, Michael Keidar

Electrical & Computer Engineering Faculty Publications

During the last two decades, research efforts on the application of low temperature plasmas in biology and medicine have positioned nonequilibrium lowtemperature plasmas as a technology that has the potential of revolutionizing healthcare.[1,2] Low temperature plasmas can be applied in direct contact with living tissues to inactivate bacteria,[3] to disinfect wounds and accelerate wound healing,[4] and to induce damage in some cancer cells.[5–11]

Enhancing The Performance Of Organic Thin Film Transistors By Cross-Linking The Organic Gate Dielectric, Soheila Naderi Gohar

Electronic Thesis and Dissertation Repository

Amongst various surface modification techniques, hyperthermal hydrogen induced cross-linking (HHIC) has been used to modify the surface of polymeric samples. In this novel and innovative technique neutral hydrogen projectiles with appropriate kinetic energy are produced to generate carbon radicals on the impacted surface through the collision-induced C-H bond breaking. Subsequently, this phenomenon results in cross-linking hydrocarbon chains in the treated polymeric samples.

Verifying the validity of cross-linking process through experiments is the target of first part of presented dissertation. Spin-coated poly(methyl methacrylate) (PMMA) films on silicon wafer were exposed to hydrogen projectiles for different durations, while the other conditions related …

Highly Piezoelectric Biocompatible And Soft Composite Fibers, J. Morvan, E. Buyuktanir, John L. West, Antal Jakli

Antal Jakli

We report the fabrication of highly piezoelectric biocompatible soft fibers containing barium titanate ferroelectric ceramic particles dispersed in electrospun poly lactic acid (PLA). These fibers form mats that have two orders of magnitude larger piezoelectric constant per weight than single crystal barium titanate films. We propose that the observed apparent piezoelectricity results from the electrospinning induced polar alignment of the ferroelectric particles that pole the fibers similar to ferroelectret polymer foams that are poled by corona discharge. Due to the biocompatibility of PLA that encases the ferroelectric particles, these mats can be used in biological applications such as bio-sensors, artificial …

Large Flow Birefringence Of Nematogenic Bent-Core Liquid Crystals, C. Bailey, Katalin Fodor-Csorba, Rafael Verduzco, Jim T. Gleeson, Samuel N. Sprunt, Antal Jakli

Antal Jakli

We have found that bent-core liquid crystalline materials show exceptionally large intrinsic flow birefringence in their isotropic liquid phase. This effect is more than 100 times larger than typical values measured for low molecular weight liquid crystals. The specific flow birefringence (i.e., normalized by the flow viscosity) is an order of magnitude larger than in both side-chain polymeric as well as low molecular weight liquid crystals. We propose that this large enhancement for bent-core compounds may be attributed to nanoscale smecticlike clusters that persist above the nematic-isotropic transition temperature, and shear align under shear flow; however, this mechanism has not …