Fresh Water Studies Commons^™

Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee

Department of Biological Systems Engineering: Dissertations and Theses

With a growing human population, urbanization is impeding a plethora of natural waterways. Of these, urban ponds play a vital role in nutrient sequestration, flood prevention, and habitat sanctuaries. However, nutrient loading can reduce habitat effectiveness and promote harmful algae blooms. To reduce internal nutrient loads, a biological-chemical treatment strategy consisting of floating treatment wetlands (FTWs) and lanthanum were applied to two urban retention ponds, Densmore and Wilderness Ridge Ponds. To measure effectiveness, chlorophyll-a samples were collected and correlated with Sentinel-2. A novel band algorithm termed 3BR1 produced a strong correlation (R² = 0.72) to physical chlorophyll-a …

Small Community Water Systems Have The Highest Prevalence Of Mn In Drinking Water In California, Usa, Miranda Aiken, Samantha C. Ying

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Manganese (Mn) is currently regulated as a secondary contaminant in California, USA; however, recent revisions of the World Health Organization drinking water guidelines have increased regulatory attention of Mn in drinking water due to increasing reports of neurotoxic effects in infants and children. In this study, Mn concentrations reported to California’s Safe Drinking Water Information System were used to estimate the potentially exposed population within California based on system size. We estimate that between 2011 and 2021, over 525,000 users in areas with reported Mn data are potentially exposed to Mn concentrations exceeding the WHO health-based guideline (80 μg L …

Chromophoric Dissolved Organic Matter And Dissolved Organic Carbon In Lakes Across An Elevational Gradient From The Mountains To The Sea, Kyle Juetten, Angela L. Strecker, Aaron Harrison, Zachary Landram, Warren J. De Bruyn, Catherine D. Clark

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Dissolved organic matter (DOM) in lakes across elevation gradients is a complex function of topography, climate, vegetation coverage, land use, and lake properties. To examine sources and processing of DOM from sea level to mountain lakes (3–1,574 m), we measured dissolved organic carbon (DOC) concentrations and chromophoric dissolved organic matter (CDOM) optical properties, lake characteristics, and water quality parameters in 62 freshwater lakes in the Pacific Northwest, USA. Higher elevation lakes had lower DOC concentrations and absorbance. These lakes had higher forest cover and minimal wetlands in their watershed, in addition to low nutrients, water temperatures, and chlorophyll a in …

Tools For Predicting Emulsification Capacity Of Crude Oil Exposed To Sunlight: Impact Of Photoproduced Carboxylic Acids On Emulsion Stability, Chaka Nacaya Brown

University of New Orleans Theses and Dissertations

The role of acids in the formation of emulsions from sunlight exposed petroleum is not well understood. To elucidate the impact of sunlight on the formation of emulsions from petroleum, Macondo, its surrogate and NIST 1619b and 2717a were separately exposed to simulated sunlight for up to 48 hours as a film dispersed into a quartz dish, or a film spread on water. Emulsion stability was scored from 0-5. All exposures demonstrated a correlation between emulsion stability and sunlight exposure with no observable emulsification in absence of photoproduction due to sunlight exposure. Aqueous studies of DOC_HC (dissolved organic carbon …

The Quantitative Assessment Of Pond Scum: An Examination Of The Biogeochemistry Of Phosphorus Cycling In The Belgrade Lakes, Abbey M. Sykes

Honors Theses

The internal recycling phosphorus in freshwater lake bottom sediments represents a significant source of hypolimnetic phosphorus (P) release for many of Maine’s lakes. In summer months, Maine lakes often thermally stratify and the lake hypolimnion develops anoxia, leading to a reduction in redox potential at the sediment-water interface. These reducing conditions facilitate the reductive dissolution of ferric iron, and, since phosphorus is often present in freshwater lake sediments as solid FeOOH-PO₄ complexes, results in release of soluble phosphorus into the water column. Our current study presents field and laboratory data from sediment fractionation extractions designed to quantify concentrations of …

Phosphorus Variability In The Area Of Influence Of The Mid-Barataria Sediment Diversion, Peter Mates

LSU Master's Theses

Man-made levees along the lower Mississippi River prevent delivery of sediment from building and maintaining Louisiana’s coastal wetlands. The Mid-Barataria sediment diversions is designed to reintroduce Mississippi River water, sediment, and nutrients into the sediment-starved Barataria Basin. Phosphorus (P) is an important macronutrient for regulating primary production in coastal marine ecosystems. Wetlands can serve as a sink or source for phosphorus to the overlying water column through various retention and release processes, dependent on concentration. Louisiana coastal systems can be phosphorus limited due to much higher concentrations of bioavailable Nitrogen in river water. The high soluble molar N:P ( >50:1) …

Surveillance Of Microplastic Pollution In Central Virginia Freshwater Ecosystems, Alexandra Reddy

Senior Honors Theses

Aquatic organisms often mistake microplastic particulates (MP) as food and inadvertently ingest the particulates, which can biomagnify through the food chain. While MP ingestion is well-researched in the marine environment, little is known about microplastics in freshwater  ecosystems. This project explores MP occurrence in an ecologically significant freshwater invertebrate: crayfish. Crayfish from two Central Virginia streams are collected to identify MP in the digestive tracts and gill filaments, and characterize the MP using analytical chemistry techniques. It was determined that MP were present in the digestive tracts and gill filaments of crayfish collected from both streams, and that MP frequency …

Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber

Theses and Dissertations (Comprehensive)

The Peace-Athabasca Delta (PAD) in northern Alberta, Canada, is recognized internationally for its ecological, historical, and cultural significance. The delta is mostly within Wood Buffalo National Park, a UNESCO World Heritage Site, and is a Ramsar Wetland of International Importance. The construction of the WAC Bennett Dam (1967) and the Site C Dam (ongoing, 2024) on the Peace River, and expansion of the Alberta Oil Sands industry along the Athabasca River have raised concerns over water quantity and quality in the delta. When industry operations began, effective monitoring had not been implemented. Consequently, pre-industrial reference conditions are unknown and can …

Global Sinusoidal Seasonality In Precipitation Isotopes, Scott T. Allen, Scott Jasechko, Wouter R. Berghuijs, Jeffrey M. Welker, Gregory R. Goldsmith, James W. Kirchner

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Quantifying seasonal variations in precipitation δ²H and δ¹⁸O is important for many stable isotope applications, including inferring plant water sources and streamflow ages. Our objective is to develop a data product that concisely quantifies the seasonality of stable isotope ratios in precipitation. We fit sine curves defined by amplitude, phase, and offset parameters to quantify annual precipitation isotope cycles at 653 meteorological stations on all seven continents. At most of these stations, including in tropical and subtropical regions, sine curves can represent the seasonal cycles in precipitation isotopes. Additionally, the amplitude, phase, and offset parameters of …

The Effects Of Reactant Concentration And Air Flow Rate In The Consumption Of Dissolved O2 During The Photochemistry Of Aqueous Pyruvic Acid, Alexis J. Eugene, Marcelo I. Guzman

Chemistry Faculty Publications

The sunlight photochemistry of the organic chromophore pyruvic acid (PA) in water generates ketyl and acetyl radicals that contribute to the production and processing of atmospheric aerosols. The photochemical mechanism is highly sensitive to dissolved oxygen content, [O₂(aq)], among other environmental conditions. Thus, herein we investigate the photolysis (λ ≥ 305 nm) of 10–200 mM PA at pH 1.0 in water covering the relevant range 0 ≤ [O₂(aq)] ≤ 1.3 mM. The rapid consumption of dissolved oxygen by the intermediate photolytic radicals is monitored in real time with a dissolved oxygen electrode. …

Seasonal Origins Of Soil Water Used By Trees, Scott T. Allen, James W. Kirchner, Sabine Braun, Rolf T. W. Siegwolf, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Rain recharges soil water storages and either percolates downward into aquifers and streams or is returned to the atmosphere through evapotranspiration. Although it is commonly assumed that summer rainfall recharges plant-available water during the growing season, the seasonal origins of water used by plants have not been systematically explored. We characterize the seasonal origins of waters in soils and trees by comparing their midsummer isotopic signatures (δ2H) to seasonal isotopic cycles in precipitation, using a new seasonal origin index. Across 182 Swiss forest sites, xylem water isotopic signatures show that summer rain was not the predominant water source …

Spatial Variation In Throughfall, Soil, And Plant Water Isotopes In A Temperate Forest, Gregory R. Goldsmith, Scott T. Allen, Sabine Braun, Nadine Engbersen, Clara Romero González-Quijano, James W. Kirchner, Rolf T. W. Siegwolf

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Studies of stable isotopes of water in the environment have been fundamental to advancing our understanding of how water moves through the soil‐plant‐atmosphere continuum; however, much of this research focuses on how water isotopes vary in time, rather than in space. We examined the spatial variation in the δ¹⁸O and δ²H of throughfall and bulk soil water, as well as branch xylem and bulk leaf water of Picea abies (Norway Spruce) and Fagus sylvatica (Beech), in a 1 ha forest plot in the northern Alps of Switzerland. Means and ranges of water isotope ratios varied considerably …

Predicting Spatial Patterns In Precipitation Isotope (Δ2h And Δ18o) Seasonality Using Sinusoidal Isoscapes, Scott T. Allen, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding how precipitation isotopes vary spatially and temporally is important for tracer applications. We tested how well month‐to‐month variations in precipitation δ18O and δ2H were captured by sinusoidal cycles, and how well spatial variations in these seasonal cycles could be predicted, across Switzerland. Sine functions representing seasonal cycles in precipitation isotopes explained between 47% and 94% of the variance in monthly δ18O and δ2H values at each monitoring site. A significant sinusoidal cycle was also observed in line‐conditioned excess. We interpolated the amplitudes, phases, and offsets of these sine functions across the landscape, using multiple linear …

A Model To Predict Concentrations And Uncertainty For Mercury Species In Lakes, Ashley Hendricks

Dissertations, Master's Theses and Master's Reports

To increase understanding of mercury cycling, a seasonal mass balance model was developed to predict mercury concentrations in lakes and fish. Results indicate that seasonality in mercury cycling is significant and is important for a northern latitude lake. Models, when validated, have the potential to be used as an alternative to measurements; models are relatively inexpensive and are not as time intensive. Previously published mercury models have neglected to perform a thorough validation. Model validation allows for regulators to be able to make more informed, confident decisions when using models in water quality management. It is critical to quantify uncertainty; …

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Studies On Hydroxyl Radical Formation And Correlated Photoflocculation Process Using Degraded Wood Leachate As A Cdom Source, Luni Sun, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

In this study, we examined hydroxyl radical (•OH) formation with respect to photoreactivity of colored dissolved organic matter (CDOM), the Fenton reaction, and photoflocculation using leachate from decaying wood. The relationship between •OH photoproduction rate and leachate optical properties (UV-visible absorption and fluorescence excitation-emission matrices (EEMS)) was studied during irradiation using a UV solar simulator. The results showed that the •OH photochemical formation rate is strongly related to humic-like fluorescence as characterized by parallel factor analysis (PARAFAC), and that these fluorescence components are more photolabile than most of the other CDOM components. Fourier transform infrared spectroscopy (FT-IR) indicated the photodegradation …

Measurement Of Antioxidant Activity Toward Superoxide In Natural Waters, D. Whitney King, Emma Berger, Zachary Helm, Eleanor Irish, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

Antioxidants are a class of molecules that provide a protective function against reactive oxygen species (ROS) in biological systems by out competing physiologically important molecules for ROS oxidation. In natural waters, the reactivity of antioxidants gives an estimate of oxidative stress, and may determine the reactivity and distribution of reactive oxidants. We present an analytical method to measure antioxidant activity in natural waters through the competition between ascorbic acid, an antioxidant, and MCLA, a chemiluminescent probe for superoxide. A numerical kinetic model of the analytical method has been developed to optimize analytical performance. Measurements of antioxidant concentrations in pure and …

Optical Characterization And Distribution Of Chromophoric Dissolved Organic Matter (Cdom) In Soil Porewater From A Salt Marsh Ecosystem, Catherine D. Clark, Paige Aiona, Jason K. Keller, Warren J. De Bruyn

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

To characterize chromophoric dissolved organic matter (CDOM) in marsh porewaters and its contribution as a carbon source, optical properties (absorbance, fluorescence indices, 3-dimensional excitation-emission matrices [EEMs]) of soil porewater and surface water were measured in a southern Californian salt marsh. Absorption coefficients and fluorescence intensities were higher in porewater than in overlying surface waters, consistent with higher CDOM concentration at depth. Humic-type peaks A and C were observed in EEMs in all samples, and peak M was observed in surface waters and shallow porewater to -5 cm depth. Fluorescence:absorbance (flu:abs) ratios and spectral slopes (S) decreased across the surface interface, …

A Review Of The Hyporheic Zone, Stream Restoration, And Means To Enhance Denitrification, Leanne Merill, David J. Tonjes

Technology & Society Faculty Publications

The hyporheic zone is the subsurface area below and adjacent to a stream where groundwater mixes with stream water, through vertical, lateral, and longitudinal flows. The hyporheic zone connects the stream to uplands and other terrestrial environments. It is a zone of distinct faunal communities, high biological diversity and ecological complexity, and is the site of chemical processing and transformations of ground- and stream waters. The hyporheic zone is important to the overall ecosystem ecology of the stream, and it can influence stream water chemistry. Flows, reactions, and biota in the hyporheic zone are heterogeneous and patchy, making it difficult …

Compositions And Constituents Of Freshwater Dissolved Organic Matter Isolated By Reverse Osmosis, Yulong Zhang, Wen Huang, Jingdong Mao

Chemistry & Biochemistry Faculty Publications

Dissolved organic matter (DOM) from riverine and lacustrine water was isolated using a reverse osmosis (RO) system. Solid-state ¹³C nuclear magnetic resonance (¹³C NMR) was used to quantitatively evaluate the compositions and constituents of DOM, which are compared with previous investigations on marine DOM. Results indicated that concentration factor (CF) was a key metric controlling yield and sorption of DOM on the RO system. The sorption was likely non-selective, based on the ¹³C NMR and δ¹³C analyses. Carbohydrates and lipids accounted for 25.0–41.5% and 30.2–46.3% of the identifiable DOM, followed by proteins (18.2–19.8%) and …

Tb207: A Manual For Remote Sensing Of Maine Lake Clarity, Ian M. Mccullough, Cynthia S. Loftin, Steven A. Sader

Technical Bulletins

The purpose of this manual is to support use of satellite-based remote sensing for statewide lake water-quality monitoring in Maine. The authors describe step-by-step methods that combine Landsat and MODIS satellite data with field-collected Secchi disk data for statewide assessment of lake water clarity. Landsat can be simul­taneously used to assess more than Maine 1,000 lakes ≥ 8 ha, whereas MODIS can be used to assess a maximum of 364 lakes ≥ 100 ha (250-m image resolution) or 83 lakes ≥ 400 ha (500-m image resolution). Although the methods were specifically developed for Maine, other states or non-Maine agen­cies may …

Organic Geochemical Analysis Of Late-Glacial And Early-Holocene Ecosystem Changes: A Case Study From Northern New England Lakes, Michael A. Kruge, Andrea Lini

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lacustrine sedimentary archive of organic remains provides important evidence for the reconstruction of the environmental histories of lakes and their watersheds, recording the response of the Earth's biota to changes on scales varying from the local to the global. The last Glacial-Interglacial transition presents an opportunity to investigate how, and at what rates, watershed and lake ecosystems were established on once glaciated, carbon and nutrient-poor landscapes. The small lakes of northern Vermont (USA) provide an appropriate setting in which to investigate such changes.

As part of a multidisciplinary study of three Vermont lake sediment cores, samples ranging in age …

Empirical Model For The Variarion In Concentration Of Metal Ions During A Precipitation Event, David M. Chittenden Ii, Julie D. Chittenden

Journal of the Arkansas Academy of Science

The concentration of a pollutant in an air mass and the concentration of that pollutant in a series of rain water samples from a single event within that air mass, fluctuate during the course of the event. This the result of scavenging, diffusion, and advection processes. A simple mathematical model, containing only a scavenging term has had limited success in describing changes of concentration in rain water. To date, no attempt has been made to include diffusion or advection terms in the model. In this study, a two factor model was developed after determining that (1) the exponential scavenging term …

Moisture Determination By Thermal Titrimetry Using The Enthalpy Of Reaction Of 2,2-Dimethoxypropane With Water, Edmond W. Wilson Jr., Reagan Baber

Journal of the Arkansas Academy of Science

Assays for water content can be readily and simply carried out using the technique of thermal titrations. The method is based on measuring the endothermic heat of reaction exhibited when 2,2-dimethoxypropane is brought into contact with water in the presence of an acid catalyst. The apparatus is simple, requiring a constant delivery rate buret, a recording thermistor thermometer, and a stirred, thermally insulated reaction container. The 2,2-dimethoxypropane reagent used for the water assays is environmentally friendly ("green"). It is stable, pleasant smelling and economical. Working curves in three solvents, acetonitrile, tetrahydrofuran and 1,4-dioxane, show excellent precision and linearity with increasing …

Interagency Lake Mead And Las Vegas Wash Monitoring Program: Standard Operating Procedures Manual, Bureau Of Reclamation, City Of Henderson Water Reclamation Facility, City Of Las Vegas Water Pollution Control Facility, Clark County Sanitation District, Nevada, Southern Nevada Water Authority

Publications (WR)

A number of agencies sample Lake Mead and the Las Vegas Wash on a routine basis at several locations. In order to share and properly interpret the data, the Bureau of Reclamation, Southern Nevada Water Authority and the three Wastewater Treatment Facilities (City of Las Vegas, Clark County Sanitation District and City of Henderson) formed a committee to examine sampling and analytical protocols and to share information with the goal of maximizing the data quality. The group first met in April 1997.

It was agreed that an effort should be made to discuss and compare specific sampling and analytical techniques …

Estimation Of Groundwater Velocities From Yucca Flat To The Amargosa Desert Using Geochemistry And Environmental Isotopes, Ronald L. Hershey, Steve Y. Acheampong

Publications (WR)

Geochemical modeling techniques were applied to groundwater flowpaths from Yucca Flat on the Nevada Test Site (NTS) to the Amargosa Desert, south of the NTS to estimate groundwater flow velocities for independent comparison to velocities calculated by other methods. The groundwater flowpaths examined considered flow in the carbonate aquifer beneath Yucca and Frenchman flats mixing with flow from carbonate aquifers east and southeast of the NTS and discharging at wells south of the NTS border. The approach used the computer codes WATEQ4F and NETPATH to calculate chemical speciation, determine the saturation state of mineral phases, and simulate mixing and the …

Nutrient Limitation In A Southwestern Desert Reservoir: Eutrophication Of Las Vegas Bay, Lake Mead, Nevada, Davine M. Lieberman

Publications (WR)

Algal bioassay tests were conducted with Selenastrum capricornutum and natural algae on inner Las Vegas Bay, Lake Mead, Nevada, from December 1992 through September 1993, to identify any nutrient limitation in an area of the reservoir that has experienced problems associated with severe nutrient enrichment. Three areas were sampled based on a gradient of water quality conditions that existed in Las Vegas Bay (LVB). Disodium ethylenedinitrilotetraacetate (EDTA) significantly stimulated algal growth compared to non-EDTA treatment. Algal bioassays indicated that phosphorus (P) was the primary limiting nutrient at all stations for most of the test dates. Chl a response with EDTA …

Baseline Water Quality Data Inventory And Analysis: Lake Mead National Recreation Area, Volume Ii Of Ii, National Park Service

Publications (WR)

This document presents the results of surface-water-quality data retrievals for Lake Mead National Recreation Area (LAME) from five of the United States Environmental Protection Agency's (EPA) national databases: (1) Storage and Retrieval (STORET) database management system; (2) River Reach File (RF3); (3) Industrial Facilities Discharge (IFD); (4) Drinking Water Supplies (DRINKS); and (5) Flow Gages (GAGES). This document is one product resulting from a cooperative contractual endeavor between the National Park Service's Servicewide Inventory and Monitoring Program, the National Park Service's Water Resources Division (WRD), and Horizon Systems Corporation to retrieve, format, and analyze water quality data for all units …

Baseline Water Quality Data Inventory And Analysis: Lake Mead National Recreation Area, Volume I Of Ii, National Park Service

Publications (WR)

This document presents the results of surface-water-quality data retrievals for Lake Mead National Recreation Area (LAME) from five of the United States Environmental Protection Agency's (EPA) national databases: (1) Storage and Retrieval (STORET) database management system; (2) River Reach File (RF3); (3) Industrial Facilities Discharge (IFD); (4) Drinking Water Supplies (DRINKS); and (5) Flow Gages (GAGES). This document is one product resulting from a cooperative contractual endeavor between the National Park Service's Servicewide Inventory and Monitoring Program, the National Park Service's Water Resources Division (WRD), and Horizon Systems Corporation to retrieve, format, and analyze water quality data for all units …

Total Maximum Daily Loads And Waste Load Allocations For Las Vegas Bay: Rationale And Calulations, State Of Nevada: Division Of Environmental Protection

Publications (WR)

In September 1987 the Nevada Division of Environmental Protection revised Water Quality Standards for Las Vegas Wash (LVW) and Lake Mead. Standards were set for chlorophyll-a and unionized ammonia in Las Vegas Bay (LVB) (NDEP 1987). The 1986 and 1987 LVB data showed non-achievement of both the chlorophyll-a and unionized ammonia standard which triggered an analysis of total phosphorus and total ammonia Total Maximum Daily Loads and Waste Load Allocations which are presented in this report.

This report is separated into three sections:

1. 1987 Las Vegas Bay Water Quality Conditions and Seasonal Periodicity.

2. Concentration Estimates at Northshore Road …