Oil, Gas, and Energy Commons^™

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry Morphology, And Surface Preparation, John Farley, Allen L. Johnson, Dale L. Perry

Transmutation Sciences Materials (TRP)

Advanced nuclear processes such as the transmutation of nuclear waste, fast reactors, liquid-metal-cooled reactors, and spallation neutron sources require advanced materials systems to contain them. The required structural materials must be stable in the presence of nonmoderating coolants. A prime candidate for such a coolant is Lead Bismuth Eutectic (LBE). Materials in these systems must be able to tolerate high neutron fluxes, high temperatures, and chemical corrosion. Unfortunately, LBE corrodes stainless steel.

The corrosive behaviors of structural materials in LBE are not well understood. The Russians have over 80 reactor-years experience with LBE coolant in their Alpha-class submarine reactors. The …

Effect Of Silicon Content On The Corrosion Resistance And Radiation- Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems, Ajit K. Roy

Transmutation Sciences Materials (TRP)

This task is primarily focused on the evaluation of the effect of Si content on the susceptibility of modified 9Cr-1Mo-0.24V steel to stress corrosion cracking (SCC) and localized cracking in both molten lead-bismuth eutectic (LBE) and an aqueous solution of acidic pH.

Further, significant efforts are in progress to characterize the deformation mechanism of modified T91 grade steel as a function of temperature and strain rate. Simultaneously, surface analyses of the tested materials are ongoing using state-of-the-art techniques including scanning electron microscopy (SEM) and transmission electron microscopy (TEM).

Theoretical Modeling Of Protective Oxide Layer Growth In Non-Isothermal Lead Alloy Coolant Systems, Yitung Chen, Jinsuo Zhang, Huajun Chen, Jichun Li

Transmutation Sciences Materials (TRP)

The goal of this research project is to provide a basic understanding of the protective oxide layer behaviors and to develop oxide layer growth models of steels in non-isothermal lead alloys (lead or lead-bismuth eutectic) coolant systems. Precise studies and simulations of all hydrodynamics with thermal conditions encountered in practical coolant loop systems by use of different flowing conditions in the laboratory are difficult and expensive, if not impossible. Therefore it is important and necessary to develop theoretical models to predict the protective oxide layer behaviors at the design stage of a practical lead-alloy coolant system, to properly interpret and …

Corrosion Barrier Development For Lbe Corrosion Resistance: Quarterly Report (April 2006), Biswajit Das

Transmutation Sciences Materials (TRP)

As reported in the last quarterly report, synthesis of Cr nanowires was found to be problematic in terms of uniform coverage. Hence Ni was identified as the alternative metal to form the nanowires. The purpose of the metal nanowires is to provide structural integrity to the nanoporous alumina, as well as a second defense mechanism against corrosion by oxidizing in case the top alumina layer is compromised. Nickel was selected due to its established electrochemical synthesis procedure. While Ni can provide very good structural integrity to the porous alumina, one potential problem is its higher dissolution rate in LBE. However, …

Development Of Nanostructure Based Corrosion-Barrier Coatings On Steel For Transmutation Applications, Biswajit Das

Transmutation Sciences Materials (TRP)

Advanced transmutation systems require structural materials that are able to withstand high neutron fluxes, high thermal cycling, and high resistance to chemical corrosion. The current candidate materials for such structures are ferritic and ferritic-martensitic steels due to their strong resistance to swelling, good microstructural stability under irradiation, and the retention of adequate ductility at typical reactor operating temperatures.

In parallel, lead bismuth eutectic (LBE) has emerged as a potential spallation target material for efficient production of neutrons, as well as a coolant in the accelerator system. While LBE has excellent properties as a nuclear coolant, it is also highly corrosive …

Decoupling And Disturbance Rejection Control For Target Circulation Loop, Xiuju Tan

Reactor Campaign (TRP)

The primary objective is to modify the existing control algorithm of the pilot target circuit (TC-1) loop to achieve precise temperature control. Safety concerns, the alarm system, and a user-friendly design are the secondary objectives.

The decoupling and active disturbance rejection controls are the effective control scheme in this special multivariable control process to TC-1 loop.

The research objectives are:

• To identify the interacting terms between heater inputs and target temperature outputs in each zone experimentally,

• To design of decoupling and active disturbance rejection control (ADRC),

• To monitor system through internet based remote monitoring, automatic alarming and …

Magnetohydrodynamic Simulation Of Electromagnetic Pump In Tc-1, Lillian J. Ratliff

Reactor Campaign (TRP)

The pilot molten lead-bismuth target circuit (TC-1) in university of Nevada Las Vegas (UNLV) was designed for beam power of 1 MW accelerator driven system (ADS). The TC-1 is a liquid lead-bismuth eutectic (LBE) circulation loop. Circulation of the liquid alloy is driven by an annular linear induction pump (ALIP). Experimental measurements of system parameters have yielded a surprisingly low pump efficiency of less than 1%. A numerical study of the pump efficiency is being conducted to determine which operational parameters are responsible for this low efficiency and to give insight into future EM pump design. The numerical study will …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

In this project the chemical bonding and interface formation of metal fission products with the coating materials used in TRISO fuel particles is investigated. The interface formation of Pd, Cs, and Ag with SiC and pyrolytic carbon is studied in detail. Using the SiC single crystals and TRISO coating materials as substrates, interfaces are prepared under controlled conditions in an ultra-high vacuum environment and are studied with a photoelectron spectroscopy, Auger electron spectroscopy, Inverse Photoemission, X-ray emission spectroscopy, and X-ray absorption spectroscopy. Recent additions to the experimental approach include microscopic techniques (Transmission Electron Microscopy, Scanning Tunneling Microscopy, Atomic Force Microscopy) …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 1st Quarterly Report, 2006, Clemens Heske

Fuels Campaign (TRP)

This project is devoted to an in-depth study of the chemical and electronic impact of metal fission products on the coating layers in TRISO nuclear fuel. In particular, there is a focus on the investigation of Pd, Cs, and Ag and their interface formation with SiC and carbon-based substrates. A variety of surface and near-surface bulk sensitive probes that investigate the occupied and unoccupied electronic states of the substrate and the metal overlayer have been utilized. By a controlled and stepwise deposition of the metal overlayer, it is possible to gain substantial insight into the formation of interfaces and their …

Design Concepts And Process Analysis For Transmuter Fuel Manufacturing, Georg F. Mauer

Fuels Campaign (TRP)

The safe and effective manufacturing of actinide-bearing fuels for any transmutation strategy requires that the entire manufacturing process be contained within a shielded hot cell environment. To ensure that the fabrication process is feasible, the entire process must be designed for remote operation. The equipment must be reliable enough to perform over several decades, and also easy to maintain or repair remotely. The facility must also be designed to facilitate its own decontamination and decommissioning. In addition to these design factors, the potential viability of any fuel fabrication process will also be impacted by a number of variables, such as …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project examines inert fuels containing ZrO₂ and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO₂. Reactor physics calculations are used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10% of ²³⁹Pu. Ceramics are synthesized and characterized based on the reactor physics results. The solubility of the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, are investigated in a manner to provide thermodynamic data necessary for …

Impact Of The Synthesis Process On Structure Properties For Afci Fuel Candidates, Thomas Hartmann

Fuels Campaign (TRP)

Advanced Fuel Cycle Initiative research on transmutation fuels includes mono-nitride ceramic fuel forms, and consists of closely coordinated “hot” actinide and “cold” inert and surrogate fuels work. Matrix and surrogate materials work involves three major components: (1) fuel matrix synthesis and fabrication, (2) fuel performance, and (3) fuel materials modeling. The synthesis and fabrication component supports basic material studies, as well as actinide fuel fabrication work through fuel fabrication process development. Fuel performance studies are examining the tolerance of nitride-type fuel to heavy irradiation damage. The fuel materials simulation work involves both atomistic and continuum scale modeling employing first principles, …

Solution-Based Synthesis Of Nitride Fuels, Kenneth Czerwinski, Thomas Hartmann

Fuels Campaign (TRP)

A wide variety of fuel concepts are considered for advanced reactor technology including metals, metal oxides or metal nitrides as solid solutions or composite materials. Nitride fuels have appropriate properties for advanced fuels including high thermal conductivity, thermal stability, solid-state solubility of actinides, fissile metal density, and suitable neutronic properties. A drawback of nitride fuels involves their synthesis. A key parameter for preparing oxide fuels is the precipitation step in the sol-gel process. For nitride fuels, the current synthetic route is carbothermic reduction from the oxide to the nitride. This process step is based on solid phase reactions and for …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Neutronic Evaluation Of Zro2-Mgo Inert Fuels, E. Fridman, A. Galperin, E. Shwageraus

Fuels Campaign (TRP)

Various fuel cycle concepts for plutonium incineration in existing PWR loaded with Inert Matrix Fuel (IMF), in which uranium is replaced by neutron-transparent inert matrix material, are currently under investigation at BGU. Some of the studied designs include ZrO₂-based IMF with annular fuel geometry and ZrO₂-MgO based IMF with the relative amount of MgO varied from 30v/o to 70v/o. These concepts are analyzed via detailed three-dimensional full core simulation of existing PWR including thermal-hydraulic feedback. The whole core simulations are carried out with the SILWER code. The SILWER code, which is a part of the ELCOS …

Here Comes The Sun: The Promise Of Solar Energy, Carmela Amato-Wierda

The University Dialogue

George Harrison, the youngest Beatle, wrote the classic “Here Comes the Sun” in 1969 after spending a glorious day walking around his friend Eric Clapton’s garden. Today, Harrison’s refrain, “And I say, ‘It’s All right’,” accords well with a solar power industry that has grown more than 30 percent in the past six years and received tax-favorable legislative approval in 2006.

Powering Down Technology, Janine Jacques

The University Dialogue

This paper will examine the issue of energy consumption resulting from the use of technology. It will identify and evaluate potential solutions currently being deployed by data center managers. In addition, the paper will recommend guidelines for reducing energy consumption for both the individual and business consumer.

Energy – The Not-So Bottomless Oil Well And The Alternatives, P.T. Vasudevan

The University Dialogue

This essay examines both sides of the “Hubbert’s peak” debate and their implications for energy policy. If there is a strong case for governments to wean their economies of oil, how do they do it? What low-carbon or alternative technologies bear watching? How will these technologies affect the environment? How long will the world remain reliant on oil considering that industries are 98% dependent on petroleum products?

The Analysis Of Core Competence For Chinese Oil Shipping Company, Binmeng. Mo

World Maritime University Dissertations

During the past decade, China’s crude oil import has risen sharply, which demands the immediately matching shipping capacity of the domestic oil shipping companies. Therefore, how to steer the Chinese oil shipping enterprises towards a promising development is a very big problem facing the Chinese entrepreneurs. This paper has tried to provide some practical suggestion to improve Chinese oil shipping companies’ core competence based on the analysis of Chinese Shipping Tanker Company, which is typical representative for this industry. After having studied the measuring methods of the core competence and the index system building principles, the author constructs a complete …

Peak Oil, Geopolitics And The Need For Relocalization: Will Our Magnificent Obsession Become Our Obsolete Obsession?, John E. Carroll

The University Dialogue

This essay will look at the peak oil question, contemporary “oil geopolitics” and their effect not only on energy supplies, but also on transportation, agriculture and food supplies, and population distribution in the United States. While the war in Iraq forms a centerpiece in the geopolitical scene, Russia, China, and other nations will be discussed as well. This essay will also examine the inevitable relocalization which appears to be a necessary result.

Inside Alternatively Powered Vehicles: The Problems And The Possibilities, Roxanne Greitz Miller

Education Faculty Articles and Research

This article explores alternatively powered vehicles.

Uncertainty, Climate Change And Nuclear Power, David M. Hassenzahl

Public Policy and Leadership Faculty Publications

Long time-horizon environmental risks with potential for global impacts have increased in visibility over the past several decades. Such issues as climate change, the nuclear fuel cycle, persistent synthetic chemicals, and stratospheric ozone depletion share some characteristics, including intergenerational impacts, strongly decoupled incidence of risks and benefits, substantial decision stakes and extreme uncertainty. What is not well understood are the similarities and differences among sources and implications of uncertainty among these global environmental threats, especially those associate with current and future human behavior. This describes the uncertainties associated with managing two global concerns: the nuclear (fission) fuel cycle and anthropogenic …