Geology Commons^™

Dispersion Of Artificial Tracers In Ventilated Caves, Claudio Pastore, Eric Weber, Frédéric Doumenc, Pierre-Yves Jeannin, Marc Lütscher

International Journal of Speleology

Artificial CO₂ was used as a tracer along ventilated karst conduits to infer airflow and investigate tracer dispersion. In the karst vadose zone, cave ventilation is an efficient mode of transport for heat, gases and aerosols and thus drives the spatial distribution of airborne particles. Modelling this airborne transport requires geometrical and physical parameters of the conduit system, including the cross-sectional areas, the airflow and average air speed, as well as the longitudinal dispersion coefficient which describes the spreading of a solute. Four gauging tests were carried out in one mine (artificial conduit) and two ventilated caves (natural conduits). …

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti

International Journal of Speleology

A new sub-type of folia named “reverse pseudo-gour” has been observed and described in the Nerja Cave, southern Spain. It consists of fairly vertical, thin barriers (about 5 mm high and 2 mm thick) that develop on the underside of a sub-horizontal surface (shelfstone) and grow in the opposite direction to normal gours (rimstone dams), generating sinuous shapes. Their mineral composition is essentially calcium carbonate, although globular aggregates composed of clay and phosphate minerals have also been identified. The genesis and evolution of these reverse pseudo-gours occur just at the air-water interface and are controlled by (1) the sub-horizontality of …

Seasonal Dynamics Of Karst Surface Dissolution Based On A Limestone Tables Experiment (Slovak Karst), Alena Gessert, Zdenko Hochmuth

International Journal of Speleology

Chemical denudation in karst is the basic process of karst relief formation. However, it is influenced by many factors of varying intensity that depend on the climatic conditions and characteristics of each given location. Based on measurable results of weight loss of limestone tablets, we monitored the intensity of chemical denudation in two areas of the Slovak Karst, Silica Plateau and Jasov Plateau that are situated in the most developed karst plateau region of Slovakia. Both experimental sites are similar in terms of geographical conditions, thus comparable between them. In each locality, we placed three sets of standardized tablets at …

An Attempt To Identify Source Areas Of Clastic Deposits From Selected Caves Of The Prokletije Mountains (Montenegro): A Mineralogical And U-Series Geochemistry Approach, Ditta Kicińska, Jacek Pawlak, Jacek Stienss

International Journal of Speleology

The Prokletije Mountains/Albanian Alps are the highest part of the Dinaric Mountains. Paradoxically, these mountains and their cave areas remain among the most enigmatic in Europe, having only recently become subjects of scientific research and cave exploration. This paper focuses on the Kolata and Greben massifs, where the highest, and thus the oldest, cave systems are located. Through the analysis of heavy mineral composition, the apatite-tourmaline index, and cluster analysis for mineralogical composition and uranium isotopic data, it becomes possible to identify the source areas for the cave clastic deposits. It also allow to distinguish multiple paleoflow directions, each corresponding …

Preliminary Data Of Potentially Hazardous Radon Concentrations In Modrič Cave (Croatia), Robert Lončarić, Vanja Radolić, Maša Surić, Igor Miklavčić, Matea Šatalić, Dalibor Paar, Lukrecija Obšivač

International Journal of Speleology

Instigated by relatively high cave-air CO₂ concentrations in Modrič Cave (Croatia) recorded for the purpose of speleothem-based paleoclimate research, we established preliminary monitoring of radon (²²²Rn) concentrations within the cave for a 4.5-year period (2018–2022). As radioactive geogenic gas, radon, which often correlates with cave-air CO₂ concentrations, presents a potential health hazard in cases of longer exposure time in high concentration conditions. Since the Modrič Cave is open to tourists and long-term scientific research has been performed within, a safety assessment for radon concentrations was essential. The integrated measurements of radon concentrations were performed by passive …

4d Flow Pattern Of The Longest Cave In The Eastern Alps (Schönberg-Höhlensystem, Totes Gebirge), Lukas Plan, Eva Kaminsky, Pauline Oberender, Clemens Tenreiter, Maximilian Wimmer

International Journal of Speleology

The Schönberg-Höhlensystem (SBH) is not only the longest cave system in the Eastern Alps (length 156 km, depth 1061 m), but a significant proportion of the passages have developed on or just below two surfaces that dip 1.7° to the NE. These so-called "speleogenetic phases" are rarely developed in caves of the Northern Calcareous Alps and have not yet been confirmed by detailed morphological mapping. Furthermore, the deep parts of the cave offer the possibility to study the active epiphreatic zone for a distance of 1.6 km. Detailed morphological mapping shows that the main level at about 1500 m a.s.l. …

Sub-Recent Microfauna Within Allogenic Sediments At The Bottom Of A Deep Cave, Njemica (Biokovo Mt., Croatia), Tomislav Kurečić, Valentina Hajek Tadesse, Lara Wacha, Marija Horvat, Nina Trinajstić, Ivan Mišur

International Journal of Speleology

Clastic sediments deposited at the bottom of the vertical, nearly 1000 m deep Njemica Cave (Biokovo Mountain, Croatia) were analysed. Owing to the vertical morphology of the cave, the occurrences of clastic sediments are sparse. Small, up to decimetre-thick, undisturbed sediment accumulations situated near the siphon lake revealed interesting palaeontological and mineralogical data. These data are used as a useful proxy for discussing depositional processes, the provenance of the sediments and paleo-habitats of the subterranean fauna.

The sub-recent assemblages of ostracods were discovered within the sediment, and they were shown to be correlative to the known endemic species in the …

Flow Regime Evolution Of A Major Cave System In The Eastern Alps (Hirlatzhöhle, Dachstein), Lukas Plan, Gottfried Buchegger, Eva Kaminsky, Gabriella Koltai, Tanguy Racine, Jacek Szczygieł

International Journal of Speleology

The 116 km-long and 1560 m-deep Hirlatzhöhle is one of the major cave systems in the Northern Calcareous Alps (NCA; Austria). It is located in the NW part of the Dachstein, an extensive karst massif encompassing 576 km² with its highest point at 2995 m a.s.l. In contrast to most other caves in the NCA, Hirlatzhöhle comprises old (epi)phreatic passages located up to 1 km above the base level as well as two modern major drainage systems. The aim of this study is to define the palaeo- and the active flow conditions in combination with speleogenesis, and the age of …

Airflow Dynamics In Wind Cave And Jewel Cave: How Do Barometric Caves Breathe?, Annika K. Gomell, Andreas Pflitsch

International Journal of Speleology

Recent research on air pressure propagation through barometric caves has revealed various speleoclimatological processes, which cause a more complex relationship between surface air pressure changes and resulting pressure gradients between cave and surface air than previously assumed. So far, however, studies on barometric cave airflow have only been based on surface air pressure measurements. Thus, this study investigates and compares airflow at the openings of Wind Cave and Jewel Cave – two major barometric cave systems in South Dakota, USA – as a response to surface air pressure changes and air pressure gradients. Based on high-resolution long-term air pressure measurements …

Speleothems In Sandstone Crevice And Boulder Caves Of The Elbe River Canyon, Czech Republic, Jiří Adamovič, Jaroslav Kukla, Michal Filippi, Roman Skála, Noemi Mészárosová

International Journal of Speleology

A variety of speleothems are present in crevice and boulder caves developed in Cretaceous sandstones of the Elbe River Canyon in northern Czech Republic. A set of complementary instrumental mineralogical methods was applied to characterize the speleothems and cave dripwaters, including X-ray powder diffraction, scanning electron microscopy and microanalysis, Raman spectroscopy and optical emission spectrometry. Four morphological types were distinguished and characterized in terms of their mineral and chemical composition: 1, rusty brown mud-dominated coatings with micro-gours, composed of a mixture of clay minerals; 2, white “chalky” coatings (moonmilk) composed of calcite with minor gypsum; 3, cauliflower-shaped coralloids composed of …

Sulfuric Acid Speleogenesis And Surface Landform Evolution Along The Vienna Basin Transfer Fault: Plavecký Karst, Slovakia, Pavel Bella, Helena Hercman, Šimon Kdýr, Petr Mikysek, Petr Pruner, Juraj Littva, Jozef Minár, Michal Gradzinski, Wojciech Wróblewski, Marek Velšmid, Pavel Bosak

International Journal of Speleology

Hypogene caves in the Plavecký hradný vrch Hill (Western Slovakia, Central Europe) were formed by waters ascending along faults in fractured Triassic carbonates related to the horst-graben structure at the contact of the Malé Karpaty Mountains and the NE part of the Vienna Basin. The Plavecká jaskyňa and Pec caves mostly contain horizontal passages and chambers with flat corrosion bedrock floors, fissure discharge feeders, wall water-table notches, replacement pockets, as well as a few other speleogens associated with sulfuric acid speleogenesis. The low-temperature sulfuric acid development phases of the Plavecká Jaskyňa are also indicated by the presence of sulfate minerals …

Speleogenesis In A Lens Of Metamorphosed Limestone And Ankerite: Ochtiná Aragonite Cave, Slovakia, Pavel Bella, Pavel Bosák, Petr Pruner, Helena Hercman, Katarína Pukanská, Karol Bartoš, Ľudovít Gaál, Dagmar Haviarová, Peter Tomčík, Šimon Kdýr

International Journal of Speleology

The Ochtiná Aragonite Cave (Western Carpathians) represents an unique natural phenomenon. It originated under particular lithological and hydrogeological conditions of the Ochtiná Karst in which several isolated lenses of Paleozoic crystalline limestone (marbles), partly metasomatically altered to ankerite, are enclosed by phyllites. Meteoric water seepage through non-carbonate rocks dissolved limestone and caused the oxidation of ankerite to Fe oxyhydroxides. Carbon dioxide produced during ankerite oxidation enhanced limestone dissolution. The maze cave consists of parallel fault-controlled linear passages and chambers interconnected by transverse horizontal passages. Phreatic and epiphreatic solution morphologies resulted from slowly moving or standing water. These include flat ceilings …

Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll

International Journal of Speleology

Because they can archive a variety of geochemical proxies and be precisely and accurately dated with the U-Th decay series chronometer, stalagmites are widely used for paleoclimate reconstructions. However, limitations in the use of this chronometer arise because U-Th dating is analytically time consuming, expensive, and requires a relatively large sample size. These limitations restrict the number of absolute dates usually obtained, which can result in significant uncertainties in the age model and inhibit the ability to archive high resolution records of environmental variability, particularly in those stalagmites where there are variations in growth rate not constrained by U-Th dates. …

Geochemistry Of Phosphatic Nodules As A Tool For Understanding Depositional And Taphonomical Settings In A Palaeolithic Cave Site (San Teodoro, Sicily), Gerlando Vita, Vittorio Garilli, Mirko Andrea Vizzini, Renato Giarrusso, Angelo Mulone, Massimiliana Pinto Vraca, Valeria La Parola, Pierluigi Rosina, Laura Bonfiglio, Luca Sineo

International Journal of Speleology

Interpreting depositional settings of cave sites is generally problematic, especially in absence of paleontological/archaeological evidence. This is the case of some deposits at San Teodoro Cave (Sicily), a key site for the Mediterranean Palaeolithic. In a stratigraphic level interrupted by a carbonatic concretion, phosphatic nodules are present only in the part enclosed between the concretion and the cave wall. The discovery of these nodules combined with the punctual lack of fossils had initially suggested an erosion phenomenon and subsequent formation of nodules at a vadose level. Here we show the usefulness of an integrated, geochemical-paleoecological approach in defining stratigraphy and …

Bat Guano Minerals And Mineralization Processes In Chameau Cave, Eastern Morocco, Philippe Audra, Vasile Heresanu, Lionel Barriquand, Mohamed El Kadiri Boutchich, Stephane Jaillet, Edwige Pons-Branchu, Pavel Bosak, Hai Cheng, R Lawrence Edwards, Michel Renda

International Journal of Speleology

The decay of bat guano deposits in caves produces mineral accumulations, mainly phosphates and secondary sulfates. Chameau Cave, Eastern Morocco, is located in the semi-arid Bni Snassen Mountains. It is composed of semi-active and dry passages, and is featured by strong condensation-corrosion on the walls, presence of fluvial sediments, and old corroded flowstones. Due to forced and convective airflow, the cave is generally very dry, with some damp sites related to condensation. Samples collected on the surface of different passages and along two sediment profiles yielded minerals related to bat guano decay. On recent or fresh guano, precursor minerals correspond …

Application Of The Global Srtm And Aw3d30 Digital Elevation Models To Mapping Folds At Cave Sites, Mark J. Abolins, Albert E. Ogden

International Journal of Speleology

A novel method to map and quantitatively describe very gentle folds (limb dip <5^o) at cratonic cave sites was evaluated at Snail Shell and Nanna Caves, central Tennessee, USA. Elevations from the global SRTM digital terrain model (DTM) were assigned to points on late Ordovician geologic contacts, and the elevations of the points were used to interpolate 28 m cell size natural neighbor digital elevation models (DEM’s) of the contacts. The global Forest Canopy Height Dataset was subtracted from the global 28 m cell size AW3D30 digital surface model (DSM) to create a DTM, and that DTM was applied …

Hydrometeorological Factors Determining The Development Of Water Table Cave Patterns In High Alpine Zones. The Ordesa And Monte Perdido National Park, Ne Spain, Antonio González-Ramón, Jorge Jódar, José M. Samsó, Sergio Martos-Rosillo, Javier Heredia, Ane Zabaleta, Iñaki Antigüedad, Emilio Custodio, Luis J. Lambán

International Journal of Speleology

This study is focussed on the geomorphological characterization and the processes driving the evolution of the highest karst system in Western Europe, which is located in the Ordesa and Monte Perdido National Park (PNOMP), in the central-southern Pyrenees. The karst system does not seem to have a well-developed epikarst. The studied area shows a karst network of polygenic branchwork type in the vadose zone. Additionally, the explored karst conduits in the epiphreatic zone show a water table cave pattern that is different to the looping one, which is the expected cave pattern development for a karst located in a mountain …

Bubble Trail And Folia In Cenote Zapote, Mexico: Petrographic Evidence For Abiotic Precipitation Driven By Co2 Degassing Below The Water Table, Rafael López-Martínez, Fernando Gázquez, José M. Calaforra, Philippe Audra, Jean Y. Bigot, Teresa Pi Puig, Rocío J. Alcántara-Hernández, Ángel Navarro, Philippe Crochet, Liliana Corona Martínez, Raquel Daza Brunet

International Journal of Speleology

Folia are speleothems that resemble bells, inverted cups, or bracket fungi, and whose origins are still controversial. Cenote Zapote (an underwater cave) in the Yucatán Peninsula (México), is home to some of the largest folia reported to date. These speleothems are currently growing in an active underwater system, meaning this site offers an excellent opportunity to constrain the different formation models proposed for folia, which have traditionally relied on inactive examples. In Cenote Zapote, folia are closely related to bubble trails and cupolas, suggesting an underwater CO₂-degassing process. In thin section, they display a succession of columnar-open and …

Speleothems In Quartz-Sandstone Caves Of Ponta Grossa Municipality, Campos Gerais Region, Paraná State, Southern Brazil, Henrique S. Pontes, Luiz A. Fernandes, Mário S. De Melo, Gilson B. Guimarães, Laís L. Massuqueto

International Journal of Speleology

The present communication characterizes and discusses the genesis of cave speleothems developed in Furnas Formation (Silurian-Devonian) and Vila Velha sub-unit (Campo Mourão Formation, Upper Carboniferous) quartz-sandstones, in southern Brazil. The research, which involved stratigraphic and petrographic studies, was conducted to identify the faciological context of occurrence of these features, and to determine, through different analytical methods, their mineralogical composition and porosity, and also the action of microbial markers on the genesis of these secondary mineral deposits. The speleothems were classified into six types based on form, composition and genesis: (1) arborescent (coral), (2) mushroom-shaped, (3) stalactitic, (4) stalagmitic, (5) columnar …

Cave Airflow Mechanism Of A Crevice-Type Cave: A Case Study From Czechia, Martin Kašing, Jan Lenart

International Journal of Speleology

At present, crevice-type caves are investigated mainly by means of geomorphic and geophysical methods. Microclimatic research of this type of caves is underrepresented and is often limited to temperature and humidity measurement only. Yet, microclimatic research of such caves can significantly help in the management and conservation of caves, speleological exploration or analysis of speleothems. Being the first ever research of ventilation within a crevice-type cave, a complex analysis of cave ventilation was performed within the Velká Ondrášova Cave, a crevice-type cave in the Outer Western Carpathians, Czechia. Long-term temperature recording, airflow tracing within the cave, and a total of …

Active Growth Of Non-Hydrothermal Subaqueous And Subaerial Barite (Baso4) Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Hazel A. Barton, Katey E. Bender, Harvey R. Duchene

International Journal of Speleology

Barite (BaSO₄) speleothems have been reported from caves around the globe and interpreted to have chiefly formed in phreatic, hypogene, hydrothermal settings. Here we report two contrasting types of barite speleothems (bluish tabular crystals in a shallow pool and actively dripping greenish stalactites), which today form at lower temperatures in the non-hydrothermal and vadose environment of Lechuguilla Cave, New Mexico, USA. Scanning electron microscopy analysis, along with energy- and wavelength-dispersive X-ray spectroscopy (EDS, WDS), as well as X-ray diffraction (XRD), characterize the habit and chemical composition as barite. Fractionation of the minor element calcium is related to growth …

The Lampenflora In Show Caves And Its Treatment: An Emerging Ecological Problem, Carlos Baquedano Estévez, Luis Moreno Merino, Almudena De La Losa Román, Juan J. Durán Valsero

International Journal of Speleology

The artificial lighting of caves adapted for touristic visits, leads to the appearance and propagation of a complex community of phototrophic organisms known as “lampenflora”. Formed mainly by algae and cyanobacteria, they produce the degradation of the colonized substrates and decrease the show value of the caves. This phenomenon became famous worldwide in the 1960s due to the damage caused to the paintings in the Lascaux Cave (France). Since then it has become an issue of serious concern to both managers of show caves and to the international scientific community. Over time, the problem has been approached following two complementary …

Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska

International Journal of Speleology

Zoloushka Cave is one of the largest maze gypsum caves in the world. Mining of the gypsum bedrock and lowering of the water level due to the pumping of groundwater led to exposure of the cave passages to vadose conditions and changed the hydrochemistry of the karst water. As a result, large quantities of Fe and Mn hydroxides were deposited in the passages. It was found that at least two groups of various organisms were involved in depositing ferrous and manganese sediments. In order to establish the mechanism of deposition, we conducted chemical analyses of the sediments and isotopic analyses …

Multi-Phased Hypogene Speleogenesis In A Marginal Horst Structure Of The Malé Karpaty Mountains, Slovakia, Pavel Bella, Pavel Bosák, Petr Mikysek, Juraj Littva, Helena Hercman, Jacek Pawlak

International Journal of Speleology

The Plavecká jaskyňa Cave on the western fault edge of the Malé Karpaty Mountains (western Slovakia) is a result of multi-phased hypogene speleogenesis. It formed in fractured Triassic carbonates by waters ascending along the Vienna Basin Transform Fault between Malé Karpaty Mountains and Záhorská nížina Lowland (the north-eastern part of the Vienna Basin) and/or the N–S-trending faults that intersect it in the cave vicinity. Morphologically, the cave is featured by (1) phreatic chimneys, cupolas, ceiling pockets, enlarged fissures with spongework cavities, upward wall channels and upward oriented large scallops, (2) epiphreatic flat corrosion bedrock floors, feeding fissures and wall water-table …

Breakdown Mechanisms In Iron Caves. An Example From Brazil, Marcelo R. Barbosa, Allan D.F. Da Silva, Rafael G. De Paula, Georgete M. Dutra, Airton Barata, Iuri V. Brandi, Chrystophe R.P. Da Silva, Robert A. Osborne

International Journal of Speleology

An iron cave in the vicinity of a mine in Carajás, Brazil, was selected to be mined within an assisted elimination project, planned to control all mine advancement operations towards the cave along with a strict speleological physical monitoring. It allowed, in a pioneering way, the recording of events in the cave from the first signs of damage until to the total collapse of the cave. The project lasted four years and it was possible to identify and describe four breakdown mechanisms in iron caves: Fragment downfall, Block downfall, Controlling structure reactivation, and Open discontinuity movement. The mechanisms occurred independently …

Interpreting The Origin And Evolution Of ‘Karst’ Features From A Siliceous Hydrothermal Terrane: A Case Study From The Upper Geyser Basin In Yellowstone National Park, Usa, Kevin W. Blackwood, Lainee A. Sanders, Stacy I. Gantt-Blackwood

International Journal of Speleology

The Upper Geyser Basin in Yellowstone National Park occurs over a siliceous hydrothermal terrane containing numerous hot springs and geysers. The pool and vent-conduit geometries of these hydrothermal features share a resemblance to conventional karst features known from other rock types, suggesting karst processes could be responsible for their origin and/or evolution. Hypogene speleogenesis is a cave-forming process in which the formation of caves is decoupled from and occurs independently of surface recharge. The geologic setting for hypogene speleogenesis typically occurs at the distal end of regional groundwater systems wherein the hydrogeology is manifested by ascending fluids and/or by geochemical …

Sulfur (34S/32S) Isotope Composition Of Gypsum And Implications For Deep Cave Formation On The Nullarbor Plain, Australia, Matej Lipar, Mateja Ferk, Sonja Lojen, Milo Barham

International Journal of Speleology

Large deep caves with little relation to surface topography are distinctive karst features on the Nullarbor Plain of Australia. The presence of gypsum deposits and chemoautotrophic bacteria within the caves have been suggested as evidence for cave formation and (or) enlargement via sulfuric acid speleogenesis. To test this hypothesis, the stable sulfur isotope compositions (δ³⁴S) of both cave gypsum and surface gypsum were measured. Analyses yielded relatively high, positive δ³⁴S values from both cave gypsum and surface gypsum, arguing against gypsum genesis via microbial chemoautotrophy, and more broadly, sulfuric acid speleogenesis. Instead, the gypsum is interpreted …

Old And Recent Processes In A Warm And Humid Desert Hypogene Cave: ‘A’Rak Na‘Asane, Israel, Amos Frumkin, Shlomi Aharon, Uri Davidovich, Boaz Langford, Yoav Negev, Micka Ullman, Anton Vaks, Shemesh Ya‘Aran, Boaz Zissu

International Journal of Speleology

Recent environmental processes are studied in ʻA’rak Naʻasane Cave at the northern Judean Desert, Israel. The outer zone of the cave is heavily influenced by the outside environment through a large entrance, facilitating entry of air flow, fauna and humans, with minor cave-forming modifications. Conversely, the inner cave sustains humid and warm conditions, favoring modifications by condensation corrosion of convective air flow, associated with deposition of popcorn speleothems at the lower parts of dissolution pockets. The warm humid air of the inner cave may be associated with an underlying thermal water table. Active condensation corrosion is decreasing, possibly because of …

New Insights On Secondary Minerals From Italian Sulfuric Acid Caves, Ilenia M. D'Angeli, Cristina Carbone, Maria Nagostinis, Mario Parise, Marco Vattano, Giuliana Madonia, Jo De Waele

International Journal of Speleology

Sulfuric acid minerals are important clues to identify the speleogenetic phases of hypogene caves. Italy hosts ~25% of the known worldwide sulfuric acid speleogenetic (SAS) systems, including the famous well-studied Frasassi, Monte Cucco, and Acquasanta Terme caves. Nevertheless, other underground environments have been analyzed, and interesting mineralogical assemblages were found associated with peculiar geomorphological features such as cupolas, replacement pockets, feeders, sulfuric notches, and sub-horizontal levels. In this paper, we focused on 15 cave systems located along the Apennine Chain, in Apulia, in Sicily, and in Sardinia, where copious SAS minerals were observed. Some of the studied systems (e.g., …

Extremely High Diversity Of Sulfate Minerals In Caves Of The Irazú Volcano (Costa Rica) Related To Crater Lake And Fumarolic Activity, Andrés Ulloa, Fernando Gázquez, Aurelio Sanz-Arranz, Jesús Medina, Fernando Rull, José María Calaforra, Guillermo E. Alvarado, María Martínez, Geoffroy Avard, J. Maarten De Moor, Jo De Waele

International Journal of Speleology

The caves of the Irazú volcano (Costa Rica), became accessible after the partial collapse of the NW sector of the Irazú volcano in 1994, offering the opportunity to investigate active minerogenetic processes in volcanic cave environments. We performed a detailed mineralogical and geochemical study of speleothems in the caves Cueva los Minerales and Cueva Los Mucolitos, both located in the northwest foothills of the main crater. Mineralogical analyses included X-ray diffraction (XRD) and Raman spectroscopy, while geochemical characterization used Energy Dispersive X-ray spectroscopy (EDX) coupled to Scanning Electron Microscopy (SEM). In addition, measurements of environmental parameters in the caves, …