Cosmochemistry Commons^™

Stable Isotope Chemistry In Titan Haze Aerosol, Allison Wold, Thomas Gautier, Jennifer Stern, Joshua Sebree, Melissa Trainer

Research in the Capitol

Titan, a moon of Saturn, has a thick atmosphere made up of nitrogen and a few percent methane, with a surface pressure of 1.5x that of Earth. Titan’s atmosphere is believed to be that similar to that of early Earth before the rise of O2. One significant source of information on the history and evolution of the atmosphere is the measurement of stable isotopes of elements in the molecules of major gases such as nitrogen, methane, and higher order hydrocarbons. The fractionation associated with the formation of Titan aerosol analogs are explored in the laboratory as a function of environmental …

Photocatalytic Reduction Of Fumarate To Succinate On Zns Mineral Surfaces, Ruixin Zhou, Marcelo I. Guzman

Chemistry Faculty Publications

The reductive tricarboxylic acid (rTCA) cycle is an important central biosynthetic pathway that fixes CO₂ into carboxylic acids. Among the five reductive steps in the rTCA cycle, the two-electron reduction of fumarate to succinate proceeds nonenzymatically on the surface of photoexcited sphalerite (ZnS) colloids suspended in water. This model reaction is chosen to systematically study the surface photoprocess occurring on ZnS in the presence of [Na₂S] (1–10 mM) hole scavenger at 15 °C. Experiments at variable pH (5–10) indicate that monodissociated fumaric acid is the primary electron acceptor forming the monoprotic form of succinic acid. The following …

40ar/39ar Ages Of Lunar Impact Glasses: Relationships Among Ar Diffusivity, Chemical Composition, Shape, And Size, John W. Delano Phd, Nicolle Zellner

Atmospheric and Environmental Science Faculty Scholarship

Lunar impact glasses, which are quenched melts produced during cratering events on the Moon, have the potential to providenot only compositional information about both the local and regional geology of the Moon but also information about the impact flux over time. We present in this paper the results of 73 new 40Ar/39Ar analyses of well-characterized, inclusion-free lunar impact glasses and demonstrate that size, shape, chemical composition, fraction of radiogenic 40Ar retained, and cosmic ray exposure (CRE) ages are important for 40Ar/39Ar investigations of these samples. Specifically, analyses of lunar impact glasses from the Apollo 14, 16, and 17 landing sites …

Insights Into Planetesimal Evolution: Petrological Investigations Of Regolithic Howardites And Carbonaceous Chondrite Impact Melts, Nicole Gabriel Lunning

Doctoral Dissertations

Asteroidal meteorites are the only available geologic samples from the early part of our solar system’s history. These meteorites contain evidence regarding how the earliest protoplanetary bodies formed and evolved. I use petrological and geochemical techniques to investigate the evolution of these early planetesimals, focusing on two meteorite types: Howardites, which are brecciated samples of a differentiated parent body (thought to be the asteroid 4 Vesta), and CV chondrites, which are primitive chondrites that have not undergone differentiation on their parent body.

Quantitative petrological analysis and characterization of paired regolithic (solar wind-rich) howardites indicate that this large sample of the …

Exploring Martian Magmas: From The Mantle To The Regolith, Arya Sigrid Waltraud Udry

Doctoral Dissertations

The planet Mars is geologically more similar to Earth than to other planets of the solar system. For the past 50 years, new rovers, orbital spacecraft, and new martian meteorites have helped us to understand the geological processes that occurred on Mars. In this dissertation, I investigate a wide range of martian igneous compositions, such as shergottite and nakhlite meteorites, Gusev and Gale surface basalts, and the Northwest Africa (NWA) 7034 breccia. I attempt to better understand magmatic processes that occurred in the martian mantle and crust as well as surficial processes using various petrologic and geochemical tools.

As shown …

Hunting Starstuff: Searching For Calcium-Aluminum-Rich Inclusions In Cometary Dust, Christian Engelbrecht

STAR Program Research Presentations

NASA’s Stardust mission (1999 - 2006) returned physical samples of the particles ejected by the comet 81P/Wild 2, collected in ultralight and extremely low density aerogel. These samples have been extensively analyzed using X-Ray Fluorescence (XRF), among other techniques, to determine the elemental, chemical and mineralogical composition of Wild 2. Because comets are thought to be formed in the icy outer regions of the solar system, billions of years ago, the Stardust data gives us details of the composition of the ancient solar system and its subsequent evolution. One of the surprises to come out of the data is the …

The Stardust Interstellar Dust Collector Crater Origins And Hypervelocity Cratering At Oblique Angles In Aluminum Foil, Harison Wiesman

Undergraduate Theses—Unrestricted

From 1999 to 2006 the NASA Stardust mission collected cometary particles from the Wild 2 comet and interstellar dust from the interstellar medium in two collectors made from aerogel tiles and aluminum foil. By studying their isotopic compositions, these particles can provide us with information about nucleosynthetic processes in stars. Both collector trays are being studied for traces of these particles, though a number of challenges have arisen in doing so. Identifying impact craters in the aluminum foil on the interstellar collector tray has been incredibly difficult. In addition to being only a few micrometers or less in diameter, many …

Survey Of ‘Low-Z’ Particles From The Interplanetary Dust Collection In Search Of Idps, Harison Wiesman

Undergraduate Theses—Unrestricted

Micrometeorites are one of the most common types of extraterrestrial material that fall to the Earth, beside meteorites and interplanetary dust particles (IDPs). All of these materials are known to contain presolar grains that, when studied in the laboratory, provide information about the origin of the solar system and help to constrain models of nucleosynthesis in stars. Recent studies of micrometeorites revealed the presence of a group of particles with very high C contents. These ultra-carbonaceous Antarctic micrometeorites (UCAMMs) are fine-grained, fluffy particles dominated by highly disordered carbonaceous matter. The presence of H and N isotopic anomalies, abundant presolar grains, …

Landsat-8: Science And Product Vision For Terrestrial Global Change Research, David P. Roy, M. A. Wulder, T. R. Loveland, C. E. Woodcock, R. G. Allen, M. C. Anderson, D. Helder, J. R. Irons, D. M. Johnson, R. Kennedy, T. A. Scambos, C. B. Schaaf, J. R. Schott, Y. Sheng, E. F. Vermote, A. S. Belward, R. Bindschadler, W. B. Cohen, F. Gao, J. D. Hipple, P. Hostert, Desert Research Institute, Reno, Nv, C. O. Justice, Ayse Kilic, V. Kovalskyy, Z. P. Lee, L. Lymburner, J. G. Masek, J. Mccorkel, Y. Shuai, R. Trezza, J. Vogelmann, R. H. Wynne, Z. Zhu

School of Natural Resources: Faculty Publications

Landsat 8, a NASA and USGS collaboration, acquires global moderate-resolution measurements of the Earth's terrestrial and polar regions in the visible, near-infrared, short wave, and thermal infrared. Landsat 8 extends the remarkable 40 year Landsat record and has enhanced capabilities including new spectral bands in the blue and cirrus cloud-detection portion of the spectrum, two thermal bands, improved sensor signal-to-noise performance and associated improvements in radiometric resolution, and an improved duty cycle that allows collection of a significantly greater number of images per day. This paper introduces the current (2012–2017) Landsat Science Team's efforts to establish an initial understanding of …

Petrography, Stable Isotope Compositions, Microraman Spectroscopy, And Presolar Components Of Roberts Massif 04133: A Reduced Cv3 Carbonaceous Chrondrite, Jemma Davidson, Devin L. Schrader, Conel M. Alexander, Dante S. Lauretta, Henner Busemann, Ian A. Franchi, Richard C. Greenwood, Harold Connolly Jr., Kenneth J. Domanik, Alexander Verchovsky

School of Earth & Environment Faculty Scholarship

Here, we report the mineralogy, petrography, C-N-O-stable isotope compositions, degree of disorder of organic matter, and abundances of presolar components of the chondrite Roberts Massif (RBT) 04133 using a coordinated, multitechnique approach. The results of this study are inconsistent with its initial classification as a Renazzo-like carbonaceous chondrite, and strongly support RBT 04133 being a brecciated, reduced petrologic type >3.3 Vigarano-like carbonaceous (CV) chondrite. RBT 04133 shows no evidence for aqueous alteration. However, it is mildly thermally altered (up to approximately 440 °C); which is apparent in its whole-rock C and N isotopic compositions, the degree of disorder of C …

Ballistics Analysis Of Volcanic Ejecta: Miter Crater, Ice Springs Volcanic Field, Black Rock Desert, Utah, William Cary

Senior Independent Study Theses

Ice Springs Volcanic Field, located in the Black Rock Desert west of Fillmore, Utah, is composed of three large craters, Crescent, Miter, and Terrace, and several smaller craters. Concern over the hazards of the volcanic field, ±660 years old, reactivating prompted the creation of a hazards model. This study focuses on Miter Crater in order to conduct a ballistic analysis of the blocks and bombs observed along the crater rim. Data analysis of Miter Crater ejecta was then used to create a hazards model for ballistic volcanic ejecta. Thirty-four blocks and bombs were recorded along the rim of Miter Crater. …

Crystal Structure And Al/Si Cation Ordering In "Fassaite": A Combined Single Crystal, 27al And 29si Nmr Study, Monika M. Haring

Electronic Thesis and Dissertation Repository

Al-,Ti-rich diopside, referred to herein as fassaite, occurs in both terrestrial and extraterrestrial environments. The composition of fassaite, Ca(Mg,Al)(Si,Al)₂O₆, makes it ideal for Al/Si cation ordering studies. In this study, crystal XRD, ²⁷Al and 29Si MAS NMR as well as ²⁷Al 3QMAS NMR is used to study cation ordering in extraterrestrial fassaite from Allende CAIs and a terrestrial analogue from Fassa Valley Italy. From ²⁷Al and ²⁹Si spectroscopy, fassaite from Allende CAIs is found to have more local Al/Si cation ordering than terrestrial Fassaite. Both terrestrial and extraterrestrial have C2/c …

Identification Of An Unknown Meteorite Found In North Africa, Carroll C. Rigler

Chancellor’s Honors Program Projects

No abstract provided.

Geochemical And Field Relationships Of Pillow And Dike Units In A Subglacial Pillow Unit Undirhliđar Quarry, Southwest Iceland, Lindsey J. Bowman

Senior Independent Study Theses

Undirhlíðar quarry is located on the Sveifluhals ridge, a Pleistocene subglacial pillow ridge within the NE-SW trending Krísuvík fissure swarm on the Reykjanes peninsula in Southwest Iceland. The walls of Undirhlíðar quarry provide excellent exposures of the internal architecture of the pillow ridge, yielding insights into the sequence of eruptive and intrusive events that construct subglacial ridges. In particular, the south and east walls expose at least 5 different pillow units and 3 dikes. Also seen in the east wall is a black, glassy breccia unit that appears on both the north and south sections of the east wall. Preliminary …

Laboratory Astrophysics: Using Ebit Measurements To Interpret High Resolution Spectra From Celestial Sources, Carey Scott, Joshua Thompson, N. Hell, Greg V. Brown

STAR Program Research Presentations

Astrophysicists use radiation to investigate the physics controlling a variety of celestial sources, including stellar atmospheres, black holes, and binary systems. By measuring the spectrum of the emitted radiation, astrophysicists can determine a source’s temperature and composition. Accurate atomic data are needed for reliably interpreting these spectra. Here we present an overview of how LLNL’s EBIT facility is used to put the atomic data on sound footing for use by the high energy astrophysics community.

Serpentinite Weathering And Implications For Mars, Valerie Tu, Julie Baumeister, Rodney Metcalf, A. Olsen, Elisabeth Hausrath

Festival of Communities: UG Symposium (Posters)

In the search for life on Mars near-surface soil environments may be important habitats for life accessible to future missions. Serpentinite rocks have been documented on Mars, as well as other clay minerals including smectite and kaolinites. Previous studies of soils formed on serpentinites on Earth have documented the formation of extensive clays. Serpentinites are additionally of interest as habitats for life such as methanogens. Here we examine weathering of serpentinites from bedrock to soil surface, as a potential route for the formation of clay minerals on Mars from abundant ultramafic minerals. We additionally test for the presence of Fe-oxidizing …

Thermodynamic Properties Of Neutron-Rich Matter, Matt Tilley, Bao-An Li

Journal of the Arkansas Academy of Science

The mechanism of supernova explosion and properties of neutron stars are uniquely determined by the equation of state of neutron-rich matter. Using a phenomenological equation of state within a thermal model, we study thermodynamic properties of neutron-rich matter. In particular, we investigate chemical (diffusive) and mechanical (isothermal) instabilities of neutron-rich matter and their dependence on the nuclear equation of state. Both instabilities are found to be heavily dependent upon the isospin asymmetry, temperature, and density of neutron-rich matter. We show that the boundary of the chemical instability extends farther out into the density-isospin symmetry plane than that of the mechanical …

Analysis Of Lunar Basalt Flows In Oceanus Procellarum Using Clementine Data, Noel William Jackson

OES Theses and Dissertations

Remote sensing analyses of data set taken by Clementine in 1994 permit new observations about mineral distribution on the lunar surface, basalt flow stratigraphy, and thus the geologic evolution of the Moon. The northern section of Oceanus Procellarum contains numerous impact craters which penetrated the basalt and thus can be used as natural probes to estimate the number and thicknesses of flows.

I constructed a mosaic taken in three frequencies ( 415 nm, 750 nm, 950 nm), and a Ratio Image (750/415 = red, 750/950 = green, 415/750 = blue). On such an image, red indicates the iron-poor mature highland …