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Full-Text Articles in Materials Chemistry
Fabrication Of Polyvinyl Alcohol Arrays And The Direct Electrochemistry Of Adsorbed Cytochrome C, Yu-Hua Qin, Ruo-Kun Jia, Qing-Juan Wei, Li Ma, Xiao-Hui Guan, Nan Lv
Fabrication Of Polyvinyl Alcohol Arrays And The Direct Electrochemistry Of Adsorbed Cytochrome C, Yu-Hua Qin, Ruo-Kun Jia, Qing-Juan Wei, Li Ma, Xiao-Hui Guan, Nan Lv
Journal of Electrochemistry
Regular polyvinyl alcohol arrays were prepared with porous polystyrene films by a self-assembly method. Cyt c immobilized on PVA microlens arrays modified glassy carbon electrodes gave a pair of stable,well-defined and quasi-reversible cyclic voltammetric peaks at about 0.072 V (vs. Ag/AgCl) in 0.1 mol/L PBS buffer (pH = 6.89) solution. The effects of scan rate,pH and concentration of buffers on the electrochemical behaviors of Cyt c were studied in detail. The apparent heterogeneous electron transfer rate constant (k0) was evaluated to be 2.98×10-6 cm·s-1.
Immobilization Of Cytochrome C On The Surface Of Single-Wall Carbon Nanotube And Its Direct Electron Transfer And Electrocatalysis, Ya-Jing Yin, Ya-Fen Lv, Ping Wu, Pan Du, Yan-Mao Shi, Chen-Xin Cai
Immobilization Of Cytochrome C On The Surface Of Single-Wall Carbon Nanotube And Its Direct Electron Transfer And Electrocatalysis, Ya-Jing Yin, Ya-Fen Lv, Ping Wu, Pan Du, Yan-Mao Shi, Chen-Xin Cai
Journal of Electrochemistry
Cytochrome c(Cyto c) was immobilized on the surface of the single-wall carbon nanotube(SWNT) by using the method of adsorption.Infrared spectroscopy indicated that the Cyto c remained in its original structure and did not undergo structural change after its immobilization on the SWNT.The direct electrochemistry of cyto c,which was adsorbed on the surface of the SWNT,was studied by cyclic voltammetry.The voltammetric results demonstrated that the SWNT had promoting effects on the direct electron transfer of Cyto c and also indicated that the immobilized Cyto c retained its bioelectrocatalytic activity to the reduction of H_(2)O_(2).This modified electrode might be used in development …
Direct Electrochemical Reaction Of Cytochrome C At The Poly (Ethylene Oxide) Film Modified Gold Electrodes, Xiaogang Qu, Gongquan Sun
Direct Electrochemical Reaction Of Cytochrome C At The Poly (Ethylene Oxide) Film Modified Gold Electrodes, Xiaogang Qu, Gongquan Sun
Journal of Electrochemistry
In this paper, the direct electrochemical reaction of cytochrome c was sudied at the poly (ethylene oxide) film modified gold electrodes. It was found the PEO is a good promoter for the electrochemical reaction of cytochrome c, and the reversibility of reaction of cytochrome c was found to depend on the molecular weight of PEO and the morphology of the PEO films.
Studies Of Electrochemical Behaviors Of Cytochrome C On Pretreated Gold Electrodereceived 16 May, 1996, Jin Luo, Lingling Wu, Shaohua Huang, Zhonghua Lin
Studies Of Electrochemical Behaviors Of Cytochrome C On Pretreated Gold Electrodereceived 16 May, 1996, Jin Luo, Lingling Wu, Shaohua Huang, Zhonghua Lin
Journal of Electrochemistry
The quasi reversible responses of both adsorbed and bulk cytochrome c at the pretreated gold electrode are observed. The adsorption behaviors and reaction kinetics have been studied using in situ FTIR spectroscopy, UV/Vis reflection spectroscopy, voltammetry, AC impedance and potential step methods. The results show that the cytochrome c can irreversibly adsorb on the gold surface in a complete monolayer and the adsorbed layer can mediate the redox reaction of the cytochrome c in the solution in the absence of promoter.
Effects Of Ph,Ligand Cn-,Metallic Ions Hg￣(+2),Cd￣(+2) And Pb￣(2+) On Electroactivity Of Cytochrome C, Jin Luo, Lingling Wu, Jintain Wu, Shaohua Huang, Zhonghua Lin
Effects Of Ph,Ligand Cn-,Metallic Ions Hg￣(+2),Cd￣(+2) And Pb￣(2+) On Electroactivity Of Cytochrome C, Jin Luo, Lingling Wu, Jintain Wu, Shaohua Huang, Zhonghua Lin
Journal of Electrochemistry
The effects of pH, ligtlnd CN￣-,metallic ions,Hg￣(+2), Cd￣(+2) and Pb￣(2+) on electroactivity of cytochrome c have been studied with cyclic voltammetry and UV/Vis spectroseopy.In the phosphate buffer solution containing 5 mg/mL cytochrome c, cytochrome c is electroactive at a glod electrode with suitable pretreatment if the pH value is equal to 7.0, but it is electroinactive at the gold electrode if the pH value is equal to 2. 0 or 10.0. The existence of CN- ions in the solution would cause deactivation of cytochrome c in the bulk sulurion, and would not affect the electroactivity of cytochrome c adsorbed on …