Inorganic Chemistry Commons^™

Characterization Of Uranium, Lead, And Rare Earth Element Pollution In Natural Soils And Sediments, Hope Rasmussen

Civil and Environmental Engineering Theses and Dissertations

Heavy metals in the environment add to the global burden of pollution, negatively impacting public health and ecosystem resilience. This study included projects regarding uranium (U), lead (Pb), and rare earth elements (REE) in natural samples, due to their known toxicity, ubiquity, and relevance in context to recent pollution trends. The first project focused on testing the potential of using a hydroxyapatite product as a remediation solution for U-contaminated groundwater and soil at an EPA Superfund site. The results showed that the U was sequestered in a highly crystalline mineral form within the solids, guiding the EPA to specify the …

Coastal Watershed Monitoring And Management: Geomorphology, Geochemistry, And Hydrologic Modeling Of Los Peñasquitos Creek, Ca, Ravleen Khalsa-Basra

Theses

Rivers in semi-arid climates are directly influenced by local geographic and hydrologic conditions and impacted by modifications to hydrology via urbanization. Changes can influence erosion, morphology, habitat sustainability, and watershed health. In highly urbanized southern California coastal regions, these rare open spaces provide vital ecosystem services. Los Peñasquitos Creek in San Diego County is one such watershed. Using stream surveying and laboratory methods we quantified channel characteristics, grain size distribution, total metal concentration [M], organic carbon (%OC), and phosphate to longitudinally characterize the creek for improved management. Results identified three distinct reaches in the watershed (upper, middle, lower). Downstream, depth …

Seasonal Transport Of Dissolved Inorganic Carbon And Total Alkalinity Across The Louisiana Shelf, Michelle M. Anderson

LSU Master's Theses

Rivers and wetlands are a major source of terrestrial derived carbon for coastal ocean margins. Unfortunately, Louisiana’s wetlands are threatened by ongoing high rates of erosion, deterioration, and unprecedented rates of river water discharge that changes seasonally, leading to a net loss of terrestrial carbon into the northern Gulf of Mexico (nGOM). There exists a current lack of understanding about the distribution of dissolved inorganic carbon (DIC) and total alkalinity (TAlk) within the shallowest regions of the Louisiana shelf. Even less is known about how the transport of DIC alters seasonally with changes in river outflow and shelf currents. Quantifying …

Lithological And Geochemical Responses To Abrupt Global And Regional Paleoenvironmental Changes During The Aptian In A Hemipelagic Setting Of The Eastern Iberian Peninsula: A Multi-Proxy Approach, Jander Socorro

FIU Electronic Theses and Dissertations

Intense episodes of environmental perturbations and regionally to globally distributed, oxygen-deprived marine facies characterize the Cretaceous sedimentary record. The Organyà Basin in the Spanish Pyrenees chronicles this period in expanded stratigraphic sequences that enabled high-resolution sampling and detailed analysis of disturbances poorly recorded in more lithologically condensed sections. Here, I present an integrated multi-proxy study aimed at understanding the Basin’s response to changing paleoenvironmental conditions during the early Aptian stage of the Cretaceous.

Results from the El Pui section indicate that large-scale (> 1‰), negative carbon isotope excursions (CIEs) that show no corresponding shifts in local sources of organic matter …

Desalination Concentrate Disposal: Ecological Effects And Sustainable Solutions, Ryan Hanley

Global Honors Theses

Freshwater availability is a growing global concern, and desalination is often presented as the solution, but from this important technology comes issues of toxic waste. Ecosystems are delicate areas that contain species adapted to that specific location, and any chemical or physical changes can disrupt the fitness of species. The concentrate byproduct waste from desalination plants is toxic to species if the concentrate is not compatible with the receiving water body. A critical review of scientific articles, industry-leading books, conversations with industry experts, and information from the American Membrane Technology Association conference was used to analyze the current knowledge. Species …

Depletion Of Ozone And Reservoir Species Of Chlorine And Nitrogen Oxide In The Lower Antarctic Polar Vortex Measured From Aircraft, T. Jurkat, C. Voigt, S. Kaufmann, J.-U. Grooß, H. Ziereis, A. Dörnbrack, P. Hoor, H. Bozem, A. Engel, H. Bönisch, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Novel airborne in situ measurements of inorganic chlorine, nitrogen oxide species, and ozone were performed inside the lower Antarctic polar vortex and at its edge in September 2012. We focus on one flight during the Transport and Composition of the LMS/Earth System Model Validation (TACTS/ESMVal) campaign with the German research aircraft HALO (High-Altitude LOng range research aircraft), reaching latitudes of 65°S and potential temperatures up to 405 K. Using the early winter correlations of reactive trace gases with N₂O from the Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS), we find high depletion of chlorine reservoir gases up to ∼40% …

The Role Of Sulfur Dioxide In Stratospheric Aerosol Formation Evaluated By Using In Situ Measurements In The Tropical Lower Stratosphere, A. W. Rollins, T. D. Thornberry, L. A. Watts, P. Yu, K. H. Rosenlof, M. Mills, E. Baumann, F. R. Giorgetta, T. V. Bui, M. Höpfner, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Stratospheric aerosols (SAs) are a variable component of the Earth's albedo that may be intentionally enhanced in the future to offset greenhouse gases (geoengineering). The role of tropospheric-sourced sulfur dioxide (SO₂) in maintaining background SAs has been debated for decades without in situ measurements of SO₂ at the tropical tropopause to inform this issue. Here we clarify the role of SO₂ in maintaining SAs by using new in situ SO₂ measurements to evaluate climate models and satellite retrievals. We then use the observed tropical tropopause SO₂ mixing ratios to estimate the global flux of …

Nitrous Oxide In The Atmosphere: First Measurements Of A Lower Thermospheric Source, Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, Peter F. Bernath, Bernd Funke

Chemistry & Biochemistry Faculty Publications

Nitrous oxide (N₂O) is an important anthropogenic greenhouse gas, as well as one of the most significant anthropogenic ozone-depleting substances in the stratosphere. The satellite-based instrument Atmospheric Chemistry Experiment-Fourier Transform Spectrometer has been observing the Earth's limb since 2004 and derives profiles of N₂O volume mixing ratios in the upper troposphere to the lower thermosphere. The resulting climatology shows that N₂O is continuously produced in the lower thermosphere via energetic particle precipitation and enhanced N₂O is present at all latitudes, during all seasons. The results are consistent with an N₂O …

Conversion Of Iodide To Hypoiodous Acid And Iodine In Aqueous Microdroplets Exposed To Ozone, Elizabeth A. Pillar, Marcelo I. Guzman, Jose M. Rodriguez

Chemistry Faculty Publications

Halides are incorporated into aerosol sea spray, where they start the catalytic destruction of ozone (O₃) over the oceans and affect the global troposphere. Two intriguing environmental problems undergoing continuous research are (1) to understand how reactive gas phase molecular halogens are directly produced from inorganic halides exposed to O₃ and (2) to constrain the environmental factors that control this interfacial process. This paper presents a laboratory study of the reaction of O₃ at variable iodide (I^–) concentration (0.010–100 μM) for solutions aerosolized at 25 °C, which reveal remarkable differences in the reaction intermediates …

Experimental Validation Techniques For The Heleeos Off-Axis Laser Propagation Model, John D. Haiducek

Theses and Dissertations

The High Energy Laser End-to-End Operational Simulation (HELEEOS) off-axis scattering algorithm is designed to predict the irradiance that will be detected at a given off-axis location due to atmospheric scattering of a high-energy laser. The HELEEOS system models the propagation of the laser through the atmosphere, accounting for such effects as turbulence, thermal blooming, and atmospheric absorption. The HELEEOS off-axis scattering algorithm uses the scattering phase functions of the Mie scattering models to predict the amount of radiation that will be scattered toward a particular observation location from each point along the beam path, and the total irradiance that will …

Copper Complexation And Speciation In The Western South And Equatorial Atlantic Ocean, John A. Consolvo

Chemistry & Biochemistry Theses & Dissertations

Presented here are the first data on copper complexation and speciation in the South Atlantic Ocean. Samples were collected at six vertical profile stations and along the surface (1m) transect during the 1996 IOC Baseline Contaminant Survey. Copper complexation measurements were made for the surface transect (1m) samples and three of the six vertical profile stations (1m - ~500m) using differential pulse anodic stripping voltammetry (DPASV) with a thin mercury film, rotating glassy carbon disk electrode (TMFRGCDE).

A strong organic copper complexing ligand (L₁; log K' _cuL1/cu2+ > 11. 8 ± 0 .4) was detected in 57% of all …

Trace Elements In Estuarine And Coastal Waters: U.S. Studies From 1986-1990, Gregory A. Cutter

OES Faculty Publications

The use of specialized analytical techniques, field studies, controlled laboratory experiments, and geochemical modeling have allowed U.S. investigators to expand our understanding of trace element cycling in coastal waters and estuaries. Considerable emphasis has been placed on quantifying the flux of trace elements within and through the coastal zone. In addition, substantial progress has been made in identifying the chemical speciation of many trace elements, providing a linkage between the geochemical and biochemical behavior of these elements. Another significant advance has been the use of trace elements as tracers of geochemical processes and water masses in the coastal environment.

Hydrogen Sulfide And Radon In And Over The Western North Atlantic Ocean, T. W. Andreae, Gregory A. Cutter, N. Hussain, J. Radford-Knoery, M. O. Andreae

OES Faculty Publications

Atmospheric measurements of radon and hydrogen sulfide, and seawater measurements of total sulfide, free sulfide, and carbonyl sulfide, were made on a cruise in the western North Atlantic Ocean (October 24 to November 9, 1989). Measured values for ²²²Rn ranged from 3 to 70 pCi m⁻³, those for atmospheric hydrogen sulfide from 1 to 85 parts per trillion, and those for dissolved total and free sulfide in seawater from 33 to 930 pmol L⁻¹ and 0 to 73 pmol L⁻¹, respectively. A positive correlation between ²²²Rn and atmospheric H₂S was observed. …

Cranola Rapseed Variety Assessment. Cranola Agronomy. Linseed. Tillage., J. D. Warren

Experimental Summaries - Plant Research

Trial 90AB15. 90N68, 90EB39

Canola : assessment of early maturing Stage 2 lines.

Location: Katanning, Newdegate Research Station, East Beverley Annex

Production of Canola in medium rainfall zones offers the opportunity for a rapid expansion of the industry. However presently recommended varieties take too long to mature for the area's shorter growing season. The Stage 2 trials assess Canola lines selected on the basis of earliness from the remnants of Dr Roy's now defunct rapeseed breeding programme as well as selections from Eastern States breeding programmes. The trials arc conducted at three sites to account for environmental effects on cultivar …

Phosphorus And Sulphur Nutrition Of Pastures In High Rainfall Areas., M. D. Bolland, M. F. Clarke

Experimental Summaries - Plant Research

J.S.Yeates and M.F.Clarke started these experiments. In January 1990 M.D.A. Bolland replaced J.S. Yeates (who became Regional Manager of the Northern Agricultural Region) as the Research Officer responsible for the management of the long-term experiments, and to continue the research on the topic.

In the experiments the fertilizers wee applied in autumn (March-April) in the years listed in the tables.

Trial 80AL4

Location: Cuthbert.

A new experiment was started in 1989 to compare two partially acidulated rock phosphate (PARP) fertilizers with ordinary (single) superphosphate (OSP).

Trial 84AL32

Location: Denmark

The fertilizers compared are ordinary (single) superphosphate (OSP). New (pre 1990) …

Leaf Diseases Of Wheat, R. Loughman, Geoff Thomas, J. A. Bathgate, W. R. Smith

Experimental Summaries - Plant Research

Trial 90PE10

Strategic variety mixtures to reduce septoria diseases of wheat. Evaluation of wheat lines for suitability to mixing for septoria control.

Location: Mt. Barker Research Station

To determine components of partial resistance to both Septoria species to ensure that lines with components that are complimentary are chosen for evaluation as mixtures for Septoria control.

Trial 90MT12 and 90ME10

Assessing effects of a paired variety mixture to reduce Septoria.

Location: Borden and Mt Barker Research Station.

To assess the effects of a variety mixture on Septoria diseases.

Trial 90MT11 and 90JE9

Evaluating variety mixtures to reduce septoria, using a range …

Agronomic Practices To Improve Or Maintain The Protein Content Of High Yielding, Long Season Wheats., Wayne Smith

Experimental Summaries - Plant Research

Trial 90SG8, 90SG9, 90ES9, 90ES11, 90MT8, 90KO2

Wheat variety * Time of sowing

Location: Salmon Gums Research Station, Mt. Ridley, East Gibson, Mt Barker Research Station, Kojaneerup Research Station

The aim is to define the optimum heading/flowering date on the South Coast. This trial also provides information on the performance of the varieties and new cross-breds at various sowing times.

Trial 90E10, 90ES12, 90ES13, 90ES14, 90ES15, 90ES16, 90SG10, 90SG11, 90MT10, 90KO3, 90KO4

Wheat protein on the South Coast

Location: Esperance Downs Research Station, Gibson, Neridup, Mt Ridley, Salmon Gums Research Station, Mt Barker Research Station, Kojaneerup Research Station

The Australian …

Weed Control In Crops And Pasture., J. Buckley

Experimental Summaries - Plant Research

Trial 90WH74

Crop establishment trial

Location: Wongan Hills Research Station.

To assess the effect of timing of roundup and sprayseed application and cultivation on crop growth.

Trial 90AB19

Ryegrass control in wheat using slow release trifluralin.

Location: Katanning.

To compare 2 experimental formulations of controlled release trifluralin at 4 rates and 2 timings with some commonly used herbicides for the control of ryegrass in wheat.

Trial 90ME84

Early application of 2, 4-D to wheat.

Location: Corrigin.

To assess the use of 2,4-D.amine at early times of application for the control of broadleaf weeds in wheat.

Trial 90WH92

Early application of …

Investigating Poor Pasture Productivity., J. W. Bowden, R. J. Lunt, C. Broun

Experimental Summaries - Plant Research

Trial 90N06

Location: West Dale

To determine the reason for poor pasture productivity in medium rainfall zone. Specifically why the pastures are dominated by the poorly productive species Trifolium suffocatum and why there was a large response to phosphorous fertilizer at 50 ppm P in the soil.

Pasture Agronomy., C. K. Revell

Experimental Summaries - Plant Research

Trial 89ME82

a. Medic establishment.

Establishing burr medic pastures with cereal cover.
Merredin

Trial 89SC19

b. Serradella - Potash response.

Response of serradella to potash fertilizer.
South Carrabin

Trial 89M44

c. Serradella/Grass competition

Effect of grass competition on production of serradella.
Merredin Research Station.

Trial 89SC HERB

d. Herbicide tolerance of Serradella.

Herbicide tolerance of Madeira serradella.
South Carrabin

Tactical Nitrogen Decisions For Wheat (And N Rates Trials), J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89NO77 (89NO76)

Location: Grass Valley.

History: 1984 Lupins.

1985/86 pasture legumes and about 100 kg super/ha.

1987 Wheat yield of 2.8 t/ha using 45 kg DAP/ha and 60 of urea 2-4 WAS.

1988 Gungurru lupins (27 kg/ha seed) yielding 1.9 t/ha using 80 kg super/ha.

Tactical nitrogen trials - summary of treatments required.

Trial 89NO77

Location: Meckering

Treatments existed of nitrogen and urea. Nitrogen was not applied at seeding. Urea was applied at seeding.

Trial 88No77

Tactical nitrogen trials. - summary of observations.

Location: Grass Valley.

Trial 89NO76

Hand harvest 23/11/1989.
Yield components for copper sufficient plots reps. I …

Tactical Nitrogen Decisions For Wheat (And Nitrogen Sources Rates And Times On Wheat), J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89MO49

Location: Tenderloin, Brand Highway, Regan's Ford.

History:

1987 Aroona wheat with 70 kg DAP and 3 kg CuSO4 at seeding followed by 60 urea at 3WAS and another 40 urea at 6WAS. Yield was about 1.7 to 1.8 t/ha;
1988 Gungurru lupins with 120 kg super and manganese/ha yielded 1.9 t/ha. 350-400 ml Roundup/ha and one cultivation prior to seeding.

New Block Badgingarra Rs Late Time Of Seeding., J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89BA33,

Location: Badgingarra

Based on a 1.5 t/ha potential yield, the strategic treatment was planned to be 120 kg urea/ha 4WAS. However, the crop was poorly established and so NH4NO3 was used in the hope of getting better tillering than would be possible with the slower release urea source. Gambling on equal dollars to urea for 2/3 N, but believe that twice as effective.

DAP was used to place nitrogen with the seed in case there was no rain of significance after seeding. This nitrogen (only 5 kg/ha) was probably lost with the rains of 20-28/7/89 (50 mm). Urea …

Dryland Pasture Legume Programme, C. K. Revell, G. Croker, J. Simmons, L. Heinrich

Experimental Summaries - Plant Research

1. Medic variety evaluation

a. Row Evaluation - 88ME122 - Merredin.
This method of assessment was used to test a range of new medic material originating from the South Australian Department of Agriculture.

b. Evaluation of burr medics on Morrel soils. - 88ME84 - Nokaning.

c. Evaluation of burr medics on Whitegum soils. 88ME85 - North Kellerberrin.

d. Evaluation of Santiago in low rainfall areas - 88ME86 - Mukinbudin.

e. Selection of early maturing M. murex. 88SC30 - Merredin.

f. Medic species evaluation - large plots. 88NO88 - Tammin.

g. Medic species evaluation - large plots. 85M43 - Merredin Research …

N X P X Irrigation On Wheat - South Carabin, J W. Bowden

Experimental Summaries - Plant Research

Trial 87M7.

Nx P x irrigation on wheat

Although no major effects of fertilizer on average seed size were noted, it was found that phosphate level had an effect on the distribution of seed sizes.

Location: South Carrabin.

Trial 87WH51

1987 rainfall.

Location: Wongan Hills Research Station.

Development, Verification And Use Of Methods To Model Chemical And Thermal Processes For Lakes Mead And Powell, John Eric Edinger, Edward M. Buchak, Joseph S. Norton, Bureau Of Reclamation

Publications (WR)

Analysis and development of carbonate-bicarbonate chemical subroutine.

Lake Mead And Lake Powell Salinity Reports, Cathy Lee, Steve Gazafy

Publications (WR)

The enclosed reports were compiled for the Colorado River Water Quality Office based on salinity data for Lake Mead and Lake Powell. According to the regional director of the office, the reports are not considered "polished" documents for public distribution. However, he considers them to be "interesting, rough appraisals of general trends that may be very important In our understanding the hydro-salinity system in the Colorado River."

Water Chemistry Survey Of Boulder Basin, Lake Mead, P. R. Tramutt, Bureau Of Reclamation

Publications (WR)

The survey results indicate that the impoundment of water behind Hoover Dam has not adversely affected the dissolved oxygen (DO) content and that water quality and DO content were uniform regardless of depth. The study made in April-May 1964 will provide water quality data of Lake Mead prior to releases from Lake Powell as a basis for evaluating Lake Powell's effect on water quality and limnology of Lake Mead. The performance of a DO analyzer was tested and found unsatisfactory at depths below 150 ft. Parameters tested by standard chemical analyses of water samples in the Denver Laboratory and by …