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Environmental Chemistry Commons

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1996

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Articles 1 - 11 of 11

Full-Text Articles in Environmental Chemistry

Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner Dec 1996

Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner

Theses and Dissertations

Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of …


The Biodegradation Characteristics Of Proposed Fuel Systems Icing Inhibitors (Fsii), Charles E. Meshako Dec 1996

The Biodegradation Characteristics Of Proposed Fuel Systems Icing Inhibitors (Fsii), Charles E. Meshako

Theses and Dissertations

The biodegradation characteristics of three fuel system icing ihhibitors (FSII) were evaluated. FSII are jet fuel additives that partition into water readily and are present in the water drained from storage tank bottoms in concentrations approaching 40%. These concentrations raise concerns as to the disposal and handling of these wastes. The current FSII, DiEGME was evaluated along with two new candidates, dipropylene glycol and glycerol formal. DiEGME appeared to be moderately but not completely biodegradable. It is likely that much of it would be removed in a wastewater treatment plant. Dipropylene glycol only showed signs of degradation after more than …


Modeling Marine Exposure To Polychlorinated Biphenyls From Sunken Ships, Charles N. Wendt Dec 1996

Modeling Marine Exposure To Polychlorinated Biphenyls From Sunken Ships, Charles N. Wendt

Theses and Dissertations

In the past, the U.S. Navy has routinely conducted SINKing EXercises (SINKEX) for training, weapon effectiveness tests, and economic disposal of aging assets. Recent concern over polychlorinated biphenyl (PCB) chemicals aboard such target vessels has resulted in a suspension of SINKEX. The U.S. Navy has approximately 200 vessels currently requiring such disposal. Environmental legislation and health concerns preclude selling such vessels to foreign governments or scrapping. This work attempted to model the fate and transport of these PCBs by examining their transport to coastal water and their accumulation in the marine food chain. The model includes biodegradation, upwelling, partitioning of …


Tb162: Red Maple And White Pine Litter Quality: Initial Changes With Decomposition, Mairin T. Delaney, Ivan J. Fernandez, Jeffrey A. Simmons, Russel D. Briggs Nov 1996

Tb162: Red Maple And White Pine Litter Quality: Initial Changes With Decomposition, Mairin T. Delaney, Ivan J. Fernandez, Jeffrey A. Simmons, Russel D. Briggs

Technical Bulletins

The specific objectives of this study were (a) to define the organic and inorganic composition of foliar litter from red maple (Acer rubrum L.) and white pine (Pinus strobus L.), and (b) to determine the shifts in the organic and inorganic composition of these two litter types during the initial stages of decomposition. These two species were chosen because of their prominence in the northeastern U.S. and the contrast they afforded in litter quality characteristics which have a strong influence on litter decomposition.


Rare And Endangered Plants At Gateway National Recreation Area: A Case For Protection Of Urban Natural Areas, Richard Stalter, Michael D. Byer, John T. Tanacredi Ph.D. Jul 1996

Rare And Endangered Plants At Gateway National Recreation Area: A Case For Protection Of Urban Natural Areas, Richard Stalter, Michael D. Byer, John T. Tanacredi Ph.D.

Faculty Works: CERCOM

The diversity of native plant species in urban environments is usually overlooked when biodiversity levels are considered. Inventories of native plants reveal many to be rare species surviving the harsh conditions encountered in urban ecosystems. Knowledge of their existence and an inventory of their distribution will assist in maintaining these populations. Protection strategies for rare plant species are outlined for urban National Parks.


Concentrations, Complexation And Speciation Of Total Dissolved Zinc In The Chesapeake Bay, Charles William Henry Iii Jul 1996

Concentrations, Complexation And Speciation Of Total Dissolved Zinc In The Chesapeake Bay, Charles William Henry Iii

Chemistry & Biochemistry Theses & Dissertations

This is the first research to examine the horizontal, vertical, and temporal variability of total dissolved zinc, organic complexation of zinc, and zinc speciation in the Chesapeake Bay. Filtered (0.45μm) surface and bottom water samples were taken along the salinity gradient of the Chesapeake Bay in October 1993, March 1995, July 1995, and October 1995. Analysis by Differential Pulse Anodic Stripping Voltammetry (DP ASV) indicated that total dissolved zinc concentrations in the Bay ranged from 2.9 ± 0.7nM to 38.8 ± 2nM. Total zinc was highest at the northern end of the Bay (low salinity), approximately 10 times lower at …


Isolation From Soil Microorganisms That Are Inhibitory To Wheat Seeding Pathogens, Kynita Wilson-Humphrey May 1996

Isolation From Soil Microorganisms That Are Inhibitory To Wheat Seeding Pathogens, Kynita Wilson-Humphrey

McCabe Thesis Collection

Many diseases caused by bacteria, viruses, or fungi are responsible for the ruin of a great number of crops annually. At present, many of these crops are being treated for diseases by synthetic or man-made chemicals. Some of the chemicals have been proved to have adverse effects on the environment, including humans and animals. Very few non-chemical means are available to farmers at this time to control these pathogens. This is due to the fact that many of the means of control have little effect against the pathogens or diseases. This research attempts to isolate microorganisms from the soil which …


Epa Overestimates The Benefit Of Biennial Inspection And Maintenance, Donald H. Stedman Jan 1996

Epa Overestimates The Benefit Of Biennial Inspection And Maintenance, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

The United States Environmental Protection Agency (EPA) computer model of mobile source emissions is used to estimate the benefits of future emissions control programs. Four input assumptions are discussed, each of which tends to overestimate the benefits of biennial testing programs. The assumptions are: each model year drives the same number of miles; high/superemitters, absent initially, increase linearly with mileage; inspection and maintenance (I/M) readings are invariant, and I/M repairs last forever. States opting for these programs should be aware that the predicted benefits may not materialize.


Degradation Studies Of The Non-Lethal Bird Repellent, Methyl Anthranilate, Eugeny Aronov, Larry Clark Jan 1996

Degradation Studies Of The Non-Lethal Bird Repellent, Methyl Anthranilate, Eugeny Aronov, Larry Clark

Larry Clark

Methyl anthranilate (MA), a food grade flavor and fragrance additive, has been reported to be an effective non-lethal bird repellent in a variety of situations. Despite the experimental success of MA, field studies have yielded widely differing levels of efficacy. Diminished efficacy in some field trials prob­ ably results from the failure of specific formulations to retain or protect the active ingredient under natural conditions. Therefore, a clearer understanding of the physical and chemical factors affecting the stability of MA is needed. We undertook a series of laboratory studies on hydrolysis, photolysis and microbial degradation of MA, the results of …


Carbon Monoxide Amongst Other Chemicals (Presentation), Donald H. Stedman Jan 1996

Carbon Monoxide Amongst Other Chemicals (Presentation), Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


Flash Pyrolysis Of Anthropogenic And Natural Organic Matter In Polluted Sediments, Sami T. Abdel Bagi, Michael A. Kruge, Gary L. Salmon Jan 1996

Flash Pyrolysis Of Anthropogenic And Natural Organic Matter In Polluted Sediments, Sami T. Abdel Bagi, Michael A. Kruge, Gary L. Salmon

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

INTRODUCTION - Combustion products along with spilled petroleum and industrial chemicals contribute to environmental degradation by contaminating soils and sediments. Such anthropogenic organic matter (OM), if preserved in sediments, can serve an archival function, documenting the local, history of industrial pollution. Christensen and Zhang (1993) determined the sources of polycyclic aromatic hydrocarbons (P AH) to Lake Michigan from sedimentary records, finding that coal combustion was a major source for PAHs in these sediments. Bodzek and Luks-Betlej (1993) reported that atmospheric deposition is the main source of PAH in soils of the heavily industrialized Upper Silesia region of Poland. Smith and …