Environmental Chemistry Commons^™

Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

With a growing human population, urbanization is impeding a plethora of natural waterways. Of these, urban ponds play a vital role in nutrient sequestration, flood prevention, and habitat sanctuaries. However, nutrient loading can reduce habitat effectiveness and promote harmful algae blooms. To reduce internal nutrient loads, a biological-chemical treatment strategy consisting of floating treatment wetlands (FTWs) and lanthanum were applied to two urban retention ponds, Densmore and Wilderness Ridge Ponds. To measure effectiveness, chlorophyll-a samples were collected and correlated with Sentinel-2. A novel band algorithm termed 3BR1 produced a strong correlation (R² = 0.72) to physical chlorophyll-a …

Speciation Of Elements Via A Sequential Extraction Procedure In Municipal Wastewater Biosolids From Three Rural Wwtp In East Texas (Usa), Kefa K. Onchoke

Faculty Publications

In this data article, the bioavailability of elements in municipal wastewater sludge (also known as biosolids) in samples collected from three treatment plants in East Texas, USA was evaluated. Although detailed speciation of the metals were assessed by using inductively coupled plasma optical spectroscopy (ICP-OES), and were discussed in the research article titled “Evaluating bioavailability of elements in municipal wastewater sludge (Biosolids) from three rural wastewater treatment plants in East Texas (USA) by a sequential extraction procedure” [1], this report presents the absolute raw concentrations and fractionations of the 26 metals from the biosolids (Nacogdoches Wastewater Sludge, Lufkin Wastewater Sludge, …

Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley

Florida DOT

Much of Earth’s nutrient cycling takes place in soils. Characteristics of soils control physical, chemical, and biological processes that determine rates of nutrient fluxes, storage, or transformation. As remediation of excess nutrients in stormwater runoff is one function of stormwater Best Management Practices (BMPs), the soil profile constitutes one of the most important factors of BMP design. Variation observed in BMP effectiveness (e.g., why one BMP design works effectively in one place and not another) can often be explained by variations in the soil profile, either through direct means or by a soil’s influence on hydraulics of stormwater flow through …

Small Community Water Systems Have The Highest Prevalence Of Mn In Drinking Water In California, Usa, Miranda Aiken, Samantha C. Ying

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Manganese (Mn) is currently regulated as a secondary contaminant in California, USA; however, recent revisions of the World Health Organization drinking water guidelines have increased regulatory attention of Mn in drinking water due to increasing reports of neurotoxic effects in infants and children. In this study, Mn concentrations reported to California’s Safe Drinking Water Information System were used to estimate the potentially exposed population within California based on system size. We estimate that between 2011 and 2021, over 525,000 users in areas with reported Mn data are potentially exposed to Mn concentrations exceeding the WHO health-based guideline (80 μg L …

Contrasting Seasonal Cycling Of Arsenic In A Series Of Subarctic Shield Lakes With Different Morphometric Properties, Jeremy Harbinson

Theses and Dissertations (Comprehensive)

The subarctic shield near Yellowknife, Northwest Territories (NWT), is populated with thousands of small lakes (<1.5 km²) and several large lakes. Historic mining activities in the region have left a legacy of environmental impacts and widespread arsenic (As) contamination in both aquatic and terrestrial environments. In particular, several small subarctic lakes near Yellowknife have been previously documented to be contaminated with high levels of As. Subarctic lakes are characterized by seasonal ice-cover that can persist for more than half of the year, yet little is known about the under-ice spatial and seasonal dynamics of As cycling. The objective of …

The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin

Dissertations, Theses, and Capstone Projects

An artificial urban shallow lake, Prospect Park Lake (PPL), is situated on a terminal moraine in Brooklyn New York, and supplied with municipal water treated with ortho-phosphates. The constant input of the phosphate nutrient is the primary source of eutrophication in the lake. The numerous pools along the water course houses various aquatic phototrophs, which influence the water quality and the state of the system, driving conditions into favoring the survival of their species. In the first half of the dissertation, the focus of the project is on analyzing how the different primary producers in different regions of PPL affect …

Phosphorus And Metal Cycling In A Drinking Water Source, Amanda Modica

Senior Theses and Projects

This project sought to investigate the cycling of phosphorus and metals in Lake Auburn, a drinking water source, specifically to analyze the impacts of an alum treatment on the lake for the purpose of decreasing concentrations of eutrophication-promoting phosphorus. The alum addition was performed in the summer of 2019 in two phases. Water samples were collected from the surface to the deepest point at five sites around the lake from February 2019 to November 2021. Data showed that the added alum slowly sank to the bottom of the lake. Total and dissolved metals data showed increased metals concentrations at sampling …

Ligands For Complexation, Extraction, And Sensing Of Mercury(Ii) For Application To High-Level Waste (Hlw) At The Savannah River Site (Srs), Adenike O. Fasiku

FIU Electronic Theses and Dissertations

Mercury (Hg) separation and sensing is of high significance due to Hg^(II) environmental mobility and toxicity. Furthermore, the use of Hg in nuclear applications has resulted in its accumulation in several DOE sites, such as in Oak Ridge and Savannah River reservations. Organic mercury species have been found in low activity waste (LAW) streams resulting from high-level waste (HLW) processing at the Savannah River Site (SRS), therefore posing a threat to humans and the environment. Mercury, being a soft Lewis acid, has a strong affinity for softer Lewis bases, such as S- or N-donor ligands. Therefore, we focus on …

Impacts Of Oil And Gas Wastes On Landfill Leachate, Sewage Treatment Plants, And The Environment, Lauren Badertscher

Electronic Theses and Dissertations

Between January 2011 and March 2021 oil and gas wells in Pennsylvania produced

305,637,795 barrels of liquid waste and 6,992,957 tons of solid waste with the majority from

Marcellus Shale unconventional wells. This waste is not considered hazardous and over 89% of

the solid waste generated by unconventional and conventional oil and gas extraction has been

disposed of in landfills over the past decade. This study examined trends in the quantity of waste

produced and methods of disposal. Landfills accepting this waste were identified and their

general method of leachate treatment, using onsite facilities or offsite at wastewater treatment

plants, …

Dissolved Organic Carbon And The Potential Role To Stream Acidity In The Great Smoky Mountains National Park, Jason R. Brown

Masters Theses

A substantial societal shift towards environmental awareness has focused research efforts on the impacts of pollution on natural landscapes. Improvements to pollutant regulations and technology have resulted in sizeable reductions of atmospheric deposition of anthropogenic acids, especially nitrates and sulfates, which has altered the role of these ions in the environment. As such, understandings of environmental chemistry dynamics have required regular updating.

Through the National Park Service Vital Signs monitoring program, increases in precipitation pH observed in Great Smoky Mountains National Park (GRSM) has been attributed to the reduction of inorganic acid concentrations. Unfortunately, these improvements have not been uniformly …

Laboratory Investigation Of Cyanide Evolution During Reaction Between Hypochlorous Acid And Glycine, Luz Chavez

Electronic Theses, Projects, and Dissertations

Fresh water treatment and conservation is of great importance in a society with a growing population. Ensuring water safety is a crucial task for water treatment plants. Advances in science and technology have allowed for the testing and study of potentially harmful side substances produced by water sanitation methods, one of those substances is cyanide (-CN). Previous research correlated a significant increase of cyanide levels in effluent water sanitized with a chlorination method. Research has also proposed a mechanism for the formation of cyanogen chloride (CNCl) from reactions with amino acids during the chlorination process. Flow injection analysis was chosen …

Engineered Nanostructured Nitrogen-Doped Carbon Network (Ndc) Electrodes With Unprecedented Cycling Stability For Water Capacitive Deionization In Harsh Conditions, Soha Essam Anwar

Theses and Dissertations

Capacitive deionization (CDI) is a feasible low-cost desalination technique for low-to-medium (brackish) salinity water. However, cycling stability and regeneration of the CDI electrodes are the bottlenecks hindering the practical application of the technology on large scale. Oxidation of the electrodes during the sequential adsorption-desorption processes is one of the most challenging problems hindering their long-term cycling performance. Herein, we demonstrated the ability to design and fabricate exceptionally stable CDI electrodes via a one-pot pyrolysis protocol. The optimized pyrolysis of nitrogen-carbon precursors at different temperatures enabled the fabrication of carbon materials with a controlled amount nitrogen dopant (NDCs) with exceptional cycling …

Effects Of Environmental Change On Ancestral Pueblo Fishing In The Middle Rio Grande, Jonathan W. Dombrosky Dr.

Anthropology ETDs

It has long been assumed that fishes were unimportant in the diet of past Pueblo people in the U.S. Southwest. Yet, small numbers of fish remains are consistently recovered from Late pre-Hispanic/Early Historic archaeological sites in the Middle Rio Grande of New Mexico. The end of drought conditions may have impacted food choice and fishing decisions during this time. I use behavioral ecology to understand how fishing could have been an optimal food-getting strategy for Ancestral Pueblo farmers. Stable isotope analysis offers a way to account for environmental change. I provide a refined ¹³C Suess correction model to support …

Coastal Watershed Monitoring And Management: Geomorphology, Geochemistry, And Hydrologic Modeling Of Los Peñasquitos Creek, Ca, Ravleen Khalsa-Basra

Theses

Rivers in semi-arid climates are directly influenced by local geographic and hydrologic conditions and impacted by modifications to hydrology via urbanization. Changes can influence erosion, morphology, habitat sustainability, and watershed health. In highly urbanized southern California coastal regions, these rare open spaces provide vital ecosystem services. Los Peñasquitos Creek in San Diego County is one such watershed. Using stream surveying and laboratory methods we quantified channel characteristics, grain size distribution, total metal concentration [M], organic carbon (%OC), and phosphate to longitudinally characterize the creek for improved management. Results identified three distinct reaches in the watershed (upper, middle, lower). Downstream, depth …

The Quantitative Assessment Of Pond Scum: An Examination Of The Biogeochemistry Of Phosphorus Cycling In The Belgrade Lakes, Abbey M. Sykes

Honors Theses

The internal recycling phosphorus in freshwater lake bottom sediments represents a significant source of hypolimnetic phosphorus (P) release for many of Maine’s lakes. In summer months, Maine lakes often thermally stratify and the lake hypolimnion develops anoxia, leading to a reduction in redox potential at the sediment-water interface. These reducing conditions facilitate the reductive dissolution of ferric iron, and, since phosphorus is often present in freshwater lake sediments as solid FeOOH-PO₄ complexes, results in release of soluble phosphorus into the water column. Our current study presents field and laboratory data from sediment fractionation extractions designed to quantify concentrations of …

Province Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Province Lake (Wakefield, NH and Parsonsfield, ME) for 2021.

Lake Ivanhoe 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Lake Ivanhoe (Wakefield, NH) for sampling efforts in 2021.

Belleau Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Belleau Lake in Wakefield, NH for 2021.

Bow Lake (Station 1 - Ledges) 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Bow Lake, Station 1 Ledges (Barrington and Northwood, NH) for 2021.

Lovell Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Lovell Lake (Sanbornville, NH) for sampling efforts in 2021.

Bow Lake (Station 3 - Bennett) 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Bow Lake, Station 3 Bennett (Barrington and Northwood, NH) for 2021.

Baboosic Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Baboosic Lake (Amherst and Merrimack, NH) for 2021.

Balch Pond 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Balch Pond (Wakefield, NH; Acton and Newfield, ME) for sampling efforts up to 2021.

Pine River Pond 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft

UNH Cooperative Extension

No abstract provided.

Eelgrass (Zostera Marina) Population Decline In Morro Bay, Ca: A Meta-Analysis Of Herbicide Application In San Luis Obispo County And Morro Bay Watershed, Tyler King Sinnott

Master's Theses

The endemic eelgrass (Zostera marina) community of Morro Bay Estuary, located on the central coast of California, has experienced an estimated decline of 95% in occupied area (reduction of 344 acres to 20 acres) from 2008 to 2017 for reasons that are not yet definitively clear. One possible driver of degradation that has yet to be investigated is the role of herbicides from agricultural fields in the watershed that feeds into the estuary. Thus, the primary research goal of this project was to better understand temporal and spatial trends of herbicide use within the context of San Luis …

Corn And Soybean Response To Wastewater-Recycled Phosphorus Fertilizers, Shane Ylagan

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

The ability to recycle phosphorus (P) from wastewaters could provide a sustainable, continuous source of P that might also help protect surface water quality from P enrichment. The mineral struvite (MgNH4PO4·6H2O) is an understudied material that can be created from Pcontaining wastewater and has been shown to have agricultural fertilizer value. The objective of this study was to evaluate the effects of electrochemically precipitated struvite (ECST), chemically precipitated struvite (Crystal Green; CG), diammonium phosphate (DAP), monoammonium phosphate (MAP), rock phosphate (RP), and triple super phosphate (TSP) on corn (Zea mays) and soybean (Glycine max) response in a 79-day greenhouse pot …

The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan

MSU Graduate Theses

The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …

Phosphorus Variability In The Area Of Influence Of The Mid-Barataria Sediment Diversion, Peter Mates

LSU Master's Theses

Man-made levees along the lower Mississippi River prevent delivery of sediment from building and maintaining Louisiana’s coastal wetlands. The Mid-Barataria sediment diversions is designed to reintroduce Mississippi River water, sediment, and nutrients into the sediment-starved Barataria Basin. Phosphorus (P) is an important macronutrient for regulating primary production in coastal marine ecosystems. Wetlands can serve as a sink or source for phosphorus to the overlying water column through various retention and release processes, dependent on concentration. Louisiana coastal systems can be phosphorus limited due to much higher concentrations of bioavailable Nitrogen in river water. The high soluble molar N:P ( >50:1) …

Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber

Theses and Dissertations (Comprehensive)

The Peace-Athabasca Delta (PAD) in northern Alberta, Canada, is recognized internationally for its ecological, historical, and cultural significance. The delta is mostly within Wood Buffalo National Park, a UNESCO World Heritage Site, and is a Ramsar Wetland of International Importance. The construction of the WAC Bennett Dam (1967) and the Site C Dam (ongoing, 2024) on the Peace River, and expansion of the Alberta Oil Sands industry along the Athabasca River have raised concerns over water quantity and quality in the delta. When industry operations began, effective monitoring had not been implemented. Consequently, pre-industrial reference conditions are unknown and can …

Evaluation Of The Mechanisms And Effectiveness Of Nano-Hydroxides, Wood And Dairy Manure-Derived Biochars To Remove Fluoride And Heavy Metals From Water, Anna Rose Wallace, Wenjie Sun Dr, Chunming Su Dr

Civil and Environmental Engineering Theses and Dissertations

The development of effective treatment processes for the removal contaminants, such as fluoride and heavy metals, from polluted water have been urgently needed due to serious environmental health and safety concerns. In this dissertation, a variety of materials including various (hydro)oxide nanomaterials, biochars and surface modified biochar were studied to evaluate their effectiveness and mechanism on removing fluoride or mixed heavy metals from water.

In the Chapter 2, this study investigated the adsorptive removal of fluoride from water using various (hydro)oxide nanomaterials, focusing on ferrihydrite, hydroxyapatite (HAP) and brucite, which have the potential to be used as sorbents for surface …