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Full-Text Articles in Analytical Chemistry
Raman And Surface Enhanced Raman Spectroscopy For Forensic Analysis: Case Studies On The Identification Of Illicit Substances And Artist Pigments, Abed Haddad
Dissertations, Theses, and Capstone Projects
Raman spectroscopy is an effective tool for detecting trace amounts of material by fingerprint-like vibrational spectra. At times, the weak intensity of Raman scattering can make it difficult to distinguish trace materials. This shortcoming is addressed by surface‐enhanced Raman spectroscopy (SERS), which produces strong signal enhancements when target compounds are near metal nanoparticles. For the first part of this thesis, the identification of fentanyl and carfentanil, main culprits in the opioid epidemic, was done using normal Raman and the SERS spectroscopy. As an aid in the assignment of the spectral lines, a computational model was built using Density Functional Theory …