Physical Sciences and Mathematics Commons^™

Directed Percolation And The Abstract Tile Assembly Model, Tyler Garrett Moore

Graduate Theses and Dissertations

Self-assembly is a process by which simple components build complex structures through local interactions. Directed percolation is a statistical physical model for describing competitive spreading processes on lattices. The author describes an algorithm which can transform a tile assembly system in the abstract Tile Assembly Model into a directed percolation problem, and then shows simulations of the aTAM which support this algorithm. The author also investigates two new constructs designed for Erik Winfree's abstract Tile Assembly Model called the NULL tile and temperature 1.5. These constructs aid the translation between self-assembly and directed percolation and may assist self-assembly researchers in …

Interactions Between Ions And Lysenin Nanochannels And Their Potential Applications As Biosensors, Radwan Awwad Al Faouri

Graduate Theses and Dissertations

Lysenin is classified as a pore-forming toxin protein that is isolated from the earthworm Eisenia fetida and consists of 297 amino acids [1]. Lysenin inserts large conducting pores (3.0-4.7 nm in diameter) into artificial membranes (BLM) which include sphingomyelin. These pores (channels) are open and oriented upon insertion into the bilayer lipid membrane. Lysenin channels gate at positive voltages (voltage-induced gating), but not at negative voltages. Lysenin pores also exhibit activity modulation in response to changes in ionic strength and pH, indicating that electrostatic interaction is responsible for Lysenin conductance activities. In this line of inquiries, and by modulating Lysenin …

Quantum Resonant Beats And Revivals In The Morse Oscillators And Rotors, Zhenhua Li

Graduate Theses and Dissertations

Analytical eigenfunctions and eigenvalues for the Morse oscillator were applied to investigate the quantum resonant beats and revivals of wave packet propagation. A concise way for exact prediction of the complete revival period of the Morse oscillator was given for the first time. It was suggested that any complete period was made of integer numbers of the minimum or fundamental period. Within the fundamental period, the anharmonicity of this oscillator appeared to cause interesting space-time phenomena that include relatively simple Farey-sum revival structures. In addition, a simple sum of two Morse oscillators led to a double-Morse well whose geometric symmetry …

The Geometry And Sensitivity Of Ion-Beam Sculpted Nanopores For Single Molecule Dna Analysis, Ryan Connor Rollings

Graduate Theses and Dissertations

In this dissertation, the relationship between the geometry of ion-beam sculpted solid-state nanopores and their ability to analyze single DNA molecules using resistive pulse sensing is investigated. To accomplish this, the three dimensional shape of the nanopore is determined using energy filtered and tomographic transmission electron microscopy. It is shown that this information enables the prediction of the ionic current passing through a voltage biased nanopore and improves the prediction of the magnitude of current drop signals when the nanopore interacts with single DNA molecules. The dimensional stability of nanopores in solution is monitored using this information and is improved …

Plasmonic Nanostructures For The Absorption Enhancement Of Silicon Solar Cells, Nathan Matthias Burford

Graduate Theses and Dissertations

In this work, computational investigation of plasmonic nanostructures was conducted using the commercial finite element electromagnetics solver Ansys® HFSS. Arrays of silver toroid nanoparticles located on the surface of an amorphous silicon thin-film absorbing layer were studied for particle sizes ranging from 20 nm to 200 nm in outer diameter. Parametric optimization by calculating an approximation of the photocurrent enhancement due to the nanoparticles was performed to determine optimal surface coverage of the nanoparticles. A comparison was made between these optimized nanotoroid arrays and optimized nanosphere arrays based on spectral absorption enhancement and potential photocurrent enhancement in an amorphous silicon …

Design And Fabrication Of Nanofluidic Systems With Integrated Sensing Electrodes For Rapid Biomolecule Characterization, Taylor Bradley Busch

Graduate Theses and Dissertations

A transparent nanofluidic system with embedded sensing electrodes was designed and fabricated by integrating Atomic Force Microscopy (AFM) nanolithography, Focused Ion Beam (FIB) milling and metal deposition, and standard microfabrication processing. The fabrication process started with the evaporation of chrome/gold (Cr/Au) onto a Pyrex 7740 wafer followed by photolithography and wet etching of the microchannels. The wafer was patterned a second time to form Au microelectrodes with 15-45 micrometer separation gaps in the nanochannel region. Sensing electrodes (up to one micron wide) were then deposited using FIB to bridge the gaps. The nanochannels were realized through both AFM nanolithography and …

Plasmonic And Photonic Designs For Light Trapping In Thin Film Solar Cells, Liming Ji

Graduate Theses and Dissertations

Thin film solar cells are promising to realize cheap solar energy. Compared to conventional wafer cells, they can reduce the use of semiconductor material by 90%. The efficiency of thin film solar cells, however, is limited due to insufficient light absorption. Sufficient light absorption at the bandgap of semiconductor requires a light path more than 10x the thickness of the semiconductor. Advanced designs for light trapping are necessary for solar cells to absorb sufficient light within a limited volume of semiconductor. The goal is to convert the incident light into a trapped mode in the semiconductor layer.

In this dissertation, …

Pulse Sharpening Effects Of Thin Film Ferroelectric Transmission Lines, Robert J. Sleezer

Graduate Theses and Dissertations

Advances in material science have resulted in the development of electrically nonlinear high dielectric thin film ferroelectrics, which have led to new opportunities for the creation of novel devices. This dissertation investigated one such device: a low voltage nonlinear transmission line (NLTL). A finite element simulation of ferroelectric transmission lines showed that NLTLs are capable of creating shockwaves. Additionally, if the losses are kept sufficiently low, it was shown that voltage gain should be possible. Furthermore, a method of accounting for material dispersion was developed. Results from simulations including material dispersion showed that temporal solitons might be possible from a …

An Extension To Particle Polarizability To Predict Coupling Behavior In Periodic Nanoplasmonic Arrays, Drew Dejarnette

Graduate Theses and Dissertations

Plasmonic nanoparticles organized in arrays interact to create spectral patterns which are amplified by individual particle polarizability. It was hypothesized that particle polarizability could be used as a predictor of spectral behavior from far-field interactions within the array. Inter-particle coupling produced an extraordinary peak in extinction efficiency at wavelengths equal to or larger than the single particle plasmon resonance peak. Interactions that produced constructive coupling were found to mimic changes in the particle polarizability model. Testing of the hypothesis was performed using the coupled dipole approximation with parametric characterization of array geometries, giving specific particle size and lattice constant combinations …

Phase Control In Atomic Coherence, Utsab Khadka

Graduate Theses and Dissertations

In this thesis, atomic coherence is used to enhance nonlinear optical processes in multi-level atoms. The multi-photon transitions are driven resonantly, and at the same time without absorptive losses, by using electromagnetically induced transparency (EIT), thereby allowing the study of χ⁽³⁾ and χ⁽⁵⁾ nonlinearities using weak driving fields. The coherently modified probe beam(s) and the atom-radiated signal fields arising from four- and six- wave- mixing (FWM and SWM) processes are measured in the spectral, temporal and spatial domains.

In a three-level ladder-type atomic system, multiple peaks having spectral asymmetries are observed in the EIT window as well as …

Polarization Properties Of Maxwell-Gauss Laser Beams, Jessica Patricia Conry

Graduate Theses and Dissertations

Laser beams are wave-like optical disturbances. They are characterized by a dominant direction of propagation and a finite extent transverse to the direction of propagation. Many characteristics of laser beams can be described in terms of a scalar function multiplied by a constant vector, which can be real (for linear polarization) or complex (for elliptical polarization). The scalar function is a solution to the paraxial scalar wave equation. This scalar description, however, fails to describe the polarization and focusing characteristics of laser beams correctly. For a correct accounting of these characteristics, the electric and magnetic fields associated with laser beams …

Gain Of A Single Gas Electron Multiplier, Mythra Varun Nemallapudi

Graduate Theses and Dissertations

Gas Electron Multiplier (GEM) is a gaseous detector used in particle detection and is

known for its high rate capability. Ever since its invention in 1997, GEM was applied in

many areas and recently has been proposed to be installed in the CMS high η regions for

upgrade at LHC, CERN. A complete understanding of the working and gain behaviour does

not exist. GEM gain is influenced by charging up and this has been variedly interpreted

in literature lacking consensus. I have attempted in this work through simulations and

measurements to achieve a better understanding of single GEM gain and …

Dynamical Properties Of Ferroelectric Perovskites (Ba,Sr)Tio3 And Pb(Zr,Ti)O3 Systems From First Principles, Jeevaka Weerasinghe

Graduate Theses and Dissertations

A first-principles-based effective Hamiltonian scheme which incorporates coupling between ferroelectric (FE) and antiferrodistortive (AFD) motions is applied to Pb(Zr,Ti)O₃ alloys. It validates the existence of two modes of E symmetry (rather than the single E(1TO) soft mode) in the 50-75 cm^-1 range for temperatures smaller than 200 K and for compositions falling within the Rhombohedral R3c phase. Coupling between long-range-ordered FE and AFD motions is shown to be the cause of the additional mode and more insight into its nature is provided. This scheme is further used to reveal a field-induced anticrossing involving FE and AFD degrees of …

Mott Transition And Electronic Structure In Complex Oxide Heterostructures, Jian Liu

Graduate Theses and Dissertations

Strongly correlated electron systems, particularly transition metal oxides, have been a focus of condensed matter physics for more than two decades since the discovery of high-temperature superconducting cuprates. Diverse competing phases emerge, spanning from exotic magnetism to unconventional superconductivity, in proximity to the localized-itinerant transition of Mott insulators. While studies were concentrated on bulk crystals, the recent rapid advance in synthesis has enabled fabrication of high-quality oxide heterostructures, offering a new route to create novel artificial quantum materials.

This dissertation details the investigation on ultrathin films and heterostructures of 3d⁷(t_2g⁶e_g¹) systems with …

Use Of Ultra High Vacuum Plasma Enhanced Chemical Vapor Deposition For Graphene Fabrication, Shannen Adcock

Graduate Theses and Dissertations

Graphene, what some are terming the "new silicon", has the possibility of revolutionizing technology through nanoscale design processes. Fabrication of graphene for device processing is limited largely by the temperatures used in conventional deposition. High temperatures are detrimental to device design where many different materials may be present. For this reason, graphene synthesis at low temperatures using plasma-enhanced chemical vapor deposition is the subject of much research. In this thesis, a tool for ultra-high vacuum plasma-enhanced chemical vapor deposition (UHV-PECVD) and accompanying subsystems, such as control systems and alarms, are designed and implemented to be used in future graphene growths. …

Investigation Of Negative Differential Resistance Phenomena In Quantum Well Heterostructures, Nazariy Andrushchak

Graduate Theses and Dissertations

Increasing interest in entirely new possibilities for quantum mechanical description of carriers transport is becoming more evident with the developing advancements in epitaxial growth technique. Consequently, molecular beam epitaxy (MBE) technique is considered to be the most precise technique that allows the growth of ultra-thin layers of different compositions.

Those structures can be designed to investigate the wave-nature of carriers, which broadens the possibilities in device design and fabrication for a specific area. In this thesis the fundamental study of the real space charge transfer (RST) mechanism that took place in quantum well heterostructures and led to the negative differential …

Symmetry-Based Techniques For Qualitative Understanding Of Rovibrational Effects In Spherical-Top Molecular Spectra And Dynamics, Justin Chadwick Mitchell

Graduate Theses and Dissertations

Using light to probe the structure of matter is as natural as opening our eyes. Modern physics and chemistry have turned this art into a rich science, measuring the delicate interactions possible at the molecular level.

Perhaps the most commonly used tool in computational spectroscopy is that of matrix diagonalization. While this is invaluable for calculating everything from molecular structure and energy levels to dipole moments and dynamics, the process of numerical diagonalization is an opaque one. This work applies symmetry and semi-classical techniques to elucidate numerical spectral analysis for high-symmetry molecules.

Semi-classical techniques, such as the Potential Energy Surfaces, …

Imaging Second-Harmonic Radiation And Scattering Patterns In Zno Micro/Nanostructures, Katrina Marie Geren

Graduate Theses and Dissertations

The optical characteristics of ZnO nanostructures have recently garnered interest due to the inclusion of these structures in many nanoscale optical and optoelectronic devices. This thesis will address several characteristics involving second harmonic generation and scattering in ZnO nano- and microstructures. A method will be presented for determining the nonlinear coefficients of the second order susceptibility in a single ZnO rod. This method uses transmission geometry where previous methods have employed back-reflected irradiation. The nonlinear coefficients found using this new technique were consistent with previous data from similar structures. Models will be presented for predicting the second harmonic scattering patterns …

Modeling Of Compositionally Graded Barium Strontium Titanate From First Principles, Laura Elizabeth Walizer

Graduate Theses and Dissertations

"Barium Strontium Titanate (BaxSr1-xTiO3 or BST) is a Perovskite alloy of interest for both technological and intellectual reasons. Its ferroelectric and piezoelectric properties make it useful in a variety of electric components such as transducers and actuators, and BST in particular is a material of interest for the development of a ferroelectric RAM for computers. The inclusion of SrTiO3, an incipient ferroelectric, and the fact that the properties of a BST system depend strongly on its relative composition of BaTiO3 and SrTiO3 (ST), make also this a material of high interest. Compositionally graded systems are of further interest , partly …