Physical Sciences and Mathematics Commons^™

Freshwater Endmembers Impacting Carbonate Chemistry In The Mississippi Sound, Allison Savoie

Master's Theses

Coastal ecosystems are highly dynamic areas for carbon cycling and are likely to be negatively impacted by increasing ocean acidification. This research focused on dissolved inorganic carbon (DIC) and total alkalinity (TA) in the Mississippi Sound in order to understand the influence of local rivers that supply alkalinity to the area and buffer against ocean acidification. This area receives large fluxes of freshwater from local rivers, in addition to episodic inputs from the Mississippi River through a human-built diversion, the Bonnet Carré Spillway. Sites in the Mississippi Sound were sampled monthly during August 2018 to November 2019 and at weekly …

A Groundwater Model Of The San Luis Obispo Valley Basin Using Comsol Multiphysics, Brian Whetsler

Master of Science in Environmental Sciences and Management Projects

A groundwater model of a subsection of the San Luis Obispo Valley basin was pro- duced using COMSOL Multiphysics 5.5 software. The goal of this project was to create a general model using forward modeling techniques which would serve as the foundation for a more refined, complete, and calibrated groundwater hydrology model. The San Luis Obispo and Edna Valley basins are characterized as high-priority by the California Sustainable Groundwater Management Act because of historic overdrafting of groundwater reserves during periods of drought in the early 1990's. Natural resource managers must use tools such as computer models to help forecast trends …

Modeling The Evolution Of A Coupled Barrier-Marsh-Lagoon System : Insights From The New Jersey Coastline, Christopher Tenebruso

Theses, Dissertations and Culminating Projects

Barriers and their associated backbarrier environments protect populated centers and infrastructure from storm impacts, support biodiversity, and provide a number of ecosystem services. Despite their socio-economic and ecological importance, the response of coupled barrier-backbarrier environments to sea-level rise is yet poorly understood. Undeveloped barrier-backbarrier systems typically respond to sea level rise through the process of landward migration, driven by storm overwash, tidal fluxes, and inland marsh upland expansion. Such response, however, can be largely affected by development and engineering activities such as dredging and shoreline stabilization techniques (e.g., seawalls, groins, beach replenishment). To better understand the difference in the response …

Joint Use Of Advanced Oxidation Process (Aop) And Advanced Reduction Process (Arp) For Alleviation Of Leachate Organic Matter (Lom), Ali Albalgane

Theses, Dissertations and Culminating Projects

Landfilling is the dominant municipal solid waste (MSW) management option in the United States and many other countries. Leachate management and treatment represent an essential component in sustainable management of landfills. However, leachate organic matter (LOM) present in landfill leachate challenges existing treatment practices. The long-term goal of this study is to develop innovative treatment technologies for mitigation of LOM impacts for supporting sustainability in waste management and wastewater treatment. The overall objective of this thesis research aimed to investigate technical performance of the joint use of advanced oxidation process (AOP) and advanced reduction process (ARP) for treatment of mature …

The Behavior Of The Baltic Sea Ice Stream During The Deglaciation Of The Baltic Ice Lake, Recorded In The Particle Size And Geochemistry Within Bornholm Basin, Iodp Site M0065, Mathew Lucas Sandefur

Theses, Dissertations and Culminating Projects

IODP 347 Site M0065 was drilled to assess the last deglaciation of the Scandinavian Ice Sheet (SIS) within the southern Baltic Sea Basin (BSB) from ~20 ka BP. Site M0065 was drilled in the Baltic Sea within the Bornholm Basin in a water depth of 87m. It provided the opportunity to study the development of the Baltic Ice Lake (BIL), which occupied the southern BSB between ~17 and 11 ka. Previous studies in this area looking at glacial till and surface exposure dates have dated the deglaciation of Bornholm Island, and consequently Site M0065, at ~16.3 ka BP. A visual …

Paleoenvironment Reconstruction Of The Eocene Southeastern Tethys Using Geochemistry Of Sedimentary Rocks, Liliana CalderóN Convers

Theses, Dissertations and Culminating Projects

The Early Eocene hyperthermals are a series of transient global warming events that occurred between 54.09 and 52.63 Ma, and are considered as ancient analogues for future climate change. These hyperthermal events are well studied in the deep sea sites, but have not been investigated in the eastern Tethys Ocean. Here, we report new major and trace element geochemistry and stable carbon isotope data of the Early Eocene strata deposited in a shallow marine foreland basin prior to the main stage of India-Asian continent collision at Qumiba section in the Tingri County, southern Tibet. These geochemical data are used to …

Water Quality And Management Challenges In Urban New Jersey, Alessandra Rossi

Theses, Dissertations and Culminating Projects

Exacerbation of extreme weather events and increasing urbanization are facilitating the pathway of pollutants towards the waterbodies with freshwater ecosystems being impacted more than terrestrial and marine ecosystems by anthropogenic stressors. We addressed here the three major threats to freshwater ecosystems, pathogens, litter, and eutrophication, integrating scientific findings with management inputs at the watershed level. We evaluated the relationship between environmental variables measurements and Escherichia coli counts with the intent to develop equations capable of predicting near-real-time E. coli concentrations in two riverine ecosystems to help decision makers in assessments of recreational safety. Results showed that the cumulative rainfall for …

Utilizing The Public On Public Lands: The Application Of Community Science To Monitor And Model Erosion In National Forests, Jacob L. Hansen

Electronic Theses and Dissertations

Unpaved forest roads are adversely affecting coldwater streams through excessive erosion and the subsequent sedimentation of adjacent waterways. To help identify areas of concern, Trout Unlimited (TU) in the Southern Appalachian region developed a Community Science initiative to gather data on sediment sources and stream-road crossings. Volunteers were recruited and trained to monitor road and trail conditions and collect and submit data using a Survey123 application on their cell phones. Analysis of the contributed data reveals statistical connections between drainage type and both erosion level and stream sedimentation. The contributed data were also included as a calibration for the lite …

Three-Dimensional (3d) Characterization Of The Middle Ordoovician (Darriwilian) Strata In The Southern Great Basin, Western United States, Uday Mohamed Baheej Kara Ali

UNLV Theses, Dissertations, Professional Papers, and Capstones

Carbonates are mostly produced in shallow-marine environments and their deposition is sensitive to water depth changes on carbonate platforms. The water depth in depositional environments of a particular carbonate platform is controlled by the interplay of eustatic sea-level change, tectonic subsidence, platform morphology, and depositional rate. Due to the morphological variations of carbonate platforms in different tectonic settings, facies distribution across carbonate platforms varies significantly even during a single eustatic sea-level cycle. Carbonate platforms developed on passive continental margins are thought to be the most stable platforms and their facies distribution is commonly taken as examples in textbook depositional models. …

Experimental Polycrystal Stress Mapping Using Raman Spectroscopy, Genevieve C. Kidman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Stress conditions leading to rock deformation influence how a rock will ultimately deform. However, the internal distribution of stress in an elastically anisotropic rock under load, a precursor to rock deformation, is not well understood. Two models that may describe the distribution of stress in polycrystals include the Reuss bound and stress percolation. The Reuss bound, when applied to a polycrystal, describes isostress on each grain resulting in homogeneous intragranular strain and heterogeneous intergranular strain. The stress percolation model involves a network of strong contacts or force chains containing domains of high stress interwoven through areas of lower stress that …

Structural Characterization Of Organic Matter In Oil Shales Using Multiple Nuclear Magnetic Resonance Spectroscopic Techniques, Wenying Chu

Chemistry & Biochemistry Theses & Dissertations

Oil shale is a promising source of hydrocarbon fuel that is distributed throughout the world. The petroleum generating potential of oil shale is related to the molecular structure of the organic matter in source rock. The major fraction of organic matter of oil shale is termed kerogen, and due to its insolubility in organic solvents, ¹³C solid-state nuclear magnetic resonance (NMR) spectroscopy is one of the best ways to directly measure the insoluble organic matter without changing its chemical structures. This dissertation investigated oil shale samples using advanced solid-state ¹³C NMR spectroscopy techniques and high resolution magic angle …

Geology, Soils And Climate Of The Margaret River Wine Region, Peter J. Tille, Angela Stuart-Street, Peter S. Gardiner

All other publications

This report is an extract from the broader description and analysis of the Geology, soils and climate of Western Australia's wine regions. It expands on the brief descriptions in the second edition of 'Viticulture' (Coombe & Dry 2004) concerning the soils and landscapes of Western Australia’s main wine growing regions. We have tailored this report extract to the specific needs of the Margaret River wine region. It contains local soil names and soil-landscape zones and systems maps.

The wine industry recognises the importance of giving customers an understanding of the vines’ environment and how that may influence wine character …

Influence Of Living Plant Roots And Mycorrhizal Hyphae On Soil Hydraulic Properties, Katelyn M. Marcacci

Masters Theses

The interrelationships between vegetation, soil, and water are fundamental in evaluating the projected impacts of global climate change. Many predictive models require soil hydraulic parameters as inputs. As most hydraulic parameter datasets are for repacked soil, the influence of vegetation on hydraulic parameters is not thoroughly understood. Living roots and mycorrhizal fungi cause physicochemical alterations in soils. Quantifying how vegetation influences soil hydraulic parameters is necessary to more accurately simulate soil water dynamics in climate models.

Laboratory experiments were conducted to test if the presence of roots and roots inoculated with mycorrhizal fungi have a significant effect on the saturated …

Geomorphic History Of The Grand Staircase Region Of The Colorado Plateau: Understanding Arroyo Cut-Fill Dynamics, Erosion Rates, And Wildfire, Kerry E. Riley

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Most streams in the southwestern United States do not flow all year, and given their delicate balance of sediment and water flow, they are sensitive to climate change. At the turn of the 20th century, many streams in the Southwest rapidly incised into their floodplains, forming arroyos with a channel entrenched into near-vertical channel banks mostly composed of sand and mud. This dissertation investigates past changes in watersheds draining the Grand Staircase region in southern Utah with the goal of understanding how changes in climate and sediment influence these types of streams. Results show sediment supply is highly variable across …

Greening-Induced Runoff Loss In The Western United States, Xueyan Zhang

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This study assessed how vegetation will influence long-term runoff trends across the western United States (western US) in the future. I used a land surface model with improved dynamic vegetation root processes to better quantify regional runoff trends across five regions (Upper and Lower Colorado, Great Basin, Pacific Northwest, and California). The model was driven by statistically downscaled and bias-corrected outputs from three global climate models under the Representative Concentration Pathway 4.5 and 8.5 scenarios. Vegetation greening dominated significant transpiration increases that contributed most to increasing evapotranspiration across the western US, especially during spring and summer. Consistent with these trends, …

Boron In The Pariette Wetlands, Uinta Basin, Ut, Palak Vasudeva

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Boron is a naturally occurring mineral in shale and coal beds formed in marine environments, as found in the Uinta Basin. Mining activity and the application of excess irrigation water on agricultural lands in the Pariette watershed lead to mobilization of B via surface run off. Water quality monitoring records from 2006- 2009 reported violations of Utah B standard for irrigation water 43-100% of the time, for water flowing through the Pariette Wetlands. This study aims to determine B distribution in abiotic (water, sediments) and biotic samples (macroinvertebrates, aquatic vegetation, fish, bird eggs), and to establish correlations between B concentrations …

Nitrogen Fertilizer Needs Of First-Year Small Grains Following Alfalfa, Collin Pound

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Wheat, barley, triticale, and oats, are small grains commonly grown as hay and grain following alfalfa in Utah and the Intermountain West, especially during drought years as they require less irrigation than corn. Several studies in many parts of the world have shown that first-year corn following alfalfa rarely needs nitrogen (N) fertilizer, yet relatively few have evaluated the N needs of small grains, especially small grains grown for hay. Objectives of this research were to determine whether N fertilizer is needed to economically optimize the yield and quality of first-year small grains following alfalfa, develop N guidelines, and whether …

A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega

MSU Graduate Theses

The Big Four Springs region hosts four major first-order magnitude springs in southern Missouri and northern Arkansas. These springs are Big Spring (Carter County, MO), Greer Spring (Oregon County, MO), Mammoth Spring (Fulton County, AR), and Hodgson Mill Spring (Ozark County, MO). Based on historic dye traces and hydrogeological investigations, these springs drain an area of approximately 1500 square miles and collectively discharge an average of 780 million gallons of water per day. The rocks from youngest to oldest that are found in Big Four Springs region are the Cotter and Jefferson City Dolomite (Ordovician), Roubidoux Formation (Ordovician), Gasconade Dolomite …

Connections Between Hydrothermal System Geochemistry And Microbiology: Traversing Tectonic Boundaries In The South-Central Peruvian Andes, Heather Upin

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Geochemistry and microbiology are inherently tied in the natural world. The study of geomicrobiology has historically taken place in extreme systems, like hot springs of Yellowstone National Park and deep-sea hydrothermal vents, because the organisms that exist there have deep lineages on the tree of life and provide insight into early life on Earth. These microbes use chemical energy from nutrients available in their environment rather than relying on photosynthesis, energy obtained from the sun, to support their metabolism. The goal of this study is to improve our understanding of geological controls (for example the tectonic setting) on hot spring …

Effect Of Plant Derived Tannins On Nitrogen And Carbon Cycling In Pasture Soils, Kathryn A. Slebodnik

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Pasture-finished beef has become increasingly popular, but nitrogen losses from these pastures are of concern. Legumes containing condensed tannins such as birdsfoot trefoil (Lotus corniculatus) and sainfoin (Onobrychis viciifolia) may serve as environmentally and economically viable alternative forages in pasture finishing systems while reducing soil nitrogen loss. The goal of this project was to understand how tannin type and concentration affects soil nitrogen cycling both in the lab and the field. This thesis: 1) compared the physical, chemical, and biological characteristics of soil samples obtained from grazed grass and tannin and non-tannin containing legume pastures, 2) …

Soil Health Assessment On Arid Rangeland Soils Impacted By Oil And Gas Exploration, Development, And Extraction, Justin Allred

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Oil and gas well pad reclamation in arid environments such as in the Uinta Basin of Utah, presents unique challenges, including remote locations, limited water, and elevated soil salinity and sodicity. Successfully reclaimed Plugged and Abandoned (P&A) well pads should resemble the surrounding rangeland once fully reclaimed. Revegetation of native species is the primary indicator of successful reclamation, but the lack of water makes it challenging to re-seed native plants, while trying to prevent the encroachment of invasive plant species such as Bromus tectorum (cheatgrass), Salsola tragus (Russian thistle), and Halogeton glomeratus (halogeton). Could successful reclamation be reflective of good …

Distribution Of First Row Transition Elements In Eclogites, Natalie Harmon

Honors College

Surficial materials are recycled back into the deep Earth at subduction zones. The oxidation state of subducted materials affects the oxidation state of major geochemical reservoirs in the Earth, such as the mantle and the crust. First row transition elements (FRTEs), such as V and Sc, are highly redox sensitive and thus have the potential to track important redox processes in subduction zones. In this project, concentrations of FRTEs in garnet, omphacite, and rutile were determined for a global suite of oceanic eclogites, which represent exhumed subducted materials. Data were collected by LA-ICP-MS using an ESI NWR193UC laser ablation system …

Meteoroid Impacts As A Source Of Bennu's Particle Ejection Events, W. F. Bottke, A. V. Moorhead, Harold Connolly Jr., C. W. Hergenrother, J. L. Molaro, P. Michel

School of Earth & Environment Faculty Scholarship

Asteroid (101955) Bennu, a near‐Earth object with a primitive carbonaceous chondrite‐like composition, was observed by the Origins, Spectral Interpretation, Resource Identification, and Security‐Regolith Explorer (OSIRIS‐REx) spacecraft to undergo multiple particle ejection events near perihelion between December 2018 and February 2019. The three largest events observed during this period, which all occurred 3.5 to 6 hr after local noon, placed numerous particles <10 cm on temporary orbits around Bennu. Here we examine whether these events could have been produced by sporadic meteoroid impacts using the National Aeronautics and Space Administration's (NASA) Meteoroid Engineering Model 3.0. Most projectiles that impact Bennu come from nearly isotropic or Jupiter‐family comets and have evolved toward the Sun by Poynting‐Robertson drag. We find that 7,000‐J impacts on Bennu occur with a biweekly cadence near perihelion, with a preference to strike in the late afternoon (~6 pm local time). This timing matches observations. Crater scaling laws also indicate that these impact energies can reproduce the sizes and masses of the largest observed particles, provided the surface has the cohesive properties of weak, porous materials. Bennu's ejection events could be caused by the same kinds of meteoroid impacts that created the Moon's asymmetric debris cloud observed by the Lunar Atmosphere and Dust Environment Explorer (LADEE). Our findings also suggest that fewer ejection events should take place as Bennu moves further away from the Sun, a result that can be tested with future observations.

Geophysical And Social Influences On Evacuation Decision-Making: The Case Of Hurricane Irma, Robin Ersing, Christianne Pearce, Jennifer M. Collins, Michelle E. Saunders, Amy Polen

School of Geosciences Faculty and Staff Publications

Understanding the factors that influence evacuation decision-making among local residents is of critical importance to those involved in monitoring and managing weather-related hazards. This study examined both geophysical and social variables that we believe influenced individual decision-making on whether to stay home, seek out a public shelter, or leave the area entirely during Hurricane Irma. A 23-item survey was administered to a convenience sample of adults (n = 234) who resided within a coastal Florida county that received an evacuation warning during Hurricane Irma in 2017. Results suggested sources of information relied on through media, government, family, and social networks …

Statistical Downscaling Techniques To Enhance The Spatial Resolution Of The Grace Satellite Data And To Fill Temporal Gaps, Hossein Sahour

Dissertations

The Gravity Recovery and Climate Experiment (GRACE) has been successfully used to monitor variations in terrestrial water storage (GRACE_TWS ) and groundwater storage (GRACE_GWS) across the globe, yet such applications are hindered on local scales by the limited spatial resolution of GRACE data. Using the Lower Peninsula of Michigan as a test site, I developed optimum procedures to downscale GRACE Release-06 monthly mascon solutions. A four-fold exercise is conducted. Cluster analysis is performed to identify the optimum number and distribution of clusters (areas) of contiguous pixels of similar geophysical signals (GRACE_TWS time series); three clusters are …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Detrital Zircon Petrochronology For Sedimentary Provenance Analysis: Source To Sink Of The Mississippi/Missouri River Drainage Basin, Sage Denali Muttel

MSU Graduate Theses

Detrital petrochronology can provide a detailed look into sedimentary provenance through integrated mineral radioisotopic ages with corresponding mineral chemistry. By combining U-Pb ages and Th/U values of detrital zircon from 13 samples collected from Quaternary sand deposits in the Upper Missouri, Yellowstone, Bighorn, Platte, Kansas, Arkansas, Mississippi, Red and Brazos Rivers, an interpretation of detailed signatures that record evidence of the evolution of the Mississippi/Missouri River drainage and the tectonic events that shaped it were observed. Low Th/U values in zircon correlate temporally to convergent magmatism, whereas, higher and more variable Th/U zircon are coeval with known extensional tectonism. Using …

Stream Bank And Bar Erosion Contributions And Land Use Influence On Suspended Sediment Loads In Two Ozark Watersheds, Southeast Missouri, Kayla Ann Coonen

MSU Graduate Theses

In-channel sources and storages of fine-sediment such as in banks and bars can influence sediment loads and overall geomorphic activity in stream systems. However, in-channel processes and effects on sediment load are rarely quantified in geomorphic or water quality studies. This study uses a sediment budget approach to assess the influence of bank erosion and bar deposition on fine sediment loads in Mineral Fork (491 km²) and Mill Creek (133 km²) watersheds located in the Ozark Highlands in Washington County, Missouri. These watersheds were disturbed by historical lead and barite mining which included the construction of …

Field Measurements Of Bed-Load Transport Distances Using Painted Sediment Tracers In An Urban Stream In The Missouri Ozarks, Kristen E. Breckenridge

MSU Graduate Theses

Predictions of bed-load mobility and transport in stream channels are useful for restoration and management purposes. This study uses native gravel tracers to determine transport distances for bed-load in an urban stream in the Ozark Highlands. The objectives of this project are to: (i) determine downstream transport distances of painted tracers of different sizes over a range of flow conditions; (ii) evaluate the influence of channel morphology and thalweg location on transport; and (iii) compare field results to those predicted by mobility equations. The study site is located on South Creek, which drains Springfield, Missouri. The study reach is 132 …

The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan

MSU Graduate Theses

The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …