Physical Sciences and Mathematics Commons^™

Development Of A Decision Support System Webtool For Historic And Future Low Flow Estimation In The Northeast United States With Applications Of Machine Learning For Advancing Physical And Statistical Methodologies, Andrew F. Delsanto

Doctoral Dissertations

Droughts are a global challenge and anthropogenic climate change is expected to increase the frequency and severity of extreme low flow events. A major challenge for resource managers is how best to incorporate future climate change projections into low flow event estimations, especially in ungaged basins. Using both physically based hydrology models and statistical models, this dissertation contributes novel methodologies to three key challenges associated with 7-day, 10-year low flow (7Q10) estimation in the northeast United States. Chapter 2 builds upon statistically based 7Q10 estimation in ungaged basins by comparing multiple machine learning algorithms to classical statistical methodologies. This chapter’s …

Data For "Density Constrains Environmental Impacts Of Fluid Abstraction In Continental Lithium Brines", Daniel B. Corkran, David F. Boutt, Lee Ann Munk, Brendan J. Moran, Sarah Mcknight, Jordan Jenckes, Alexander Kirshen

Data and Datasets

This dataset contains all data used in the study "Density constrains environmental impacts of fluid abstraction in continental lithium brines." Data include all SEAWAT groundwater-flow model input and output files, which contain all data associated with the parametric modeling study. It also contains NDVI and total annual precipitation datasets used in the study's remote sensing analysis.

Migmatite Formation, Geochronometer Petrogeneisis, And Rare Earth Element Mineralization In The Adirondack Mountains, Ny, Kaitlyn Suarez

Doctoral Dissertations

The Adirondack Mountains in upstate New York contain exposures of complex partially melted rocks, in addition to iron oxide-apatite (IOA) deposits with variable rare earth element (REE) concentrations. Previous workers have suggested that melting occurred during the ca. 1150 Ma Shawinigan and the ca. 1050 Ma Ottawan orogenies. However, there are challenges in determining the timing of melting and the number of partial melt events. Further, tectonic models must be developed to describe the petrogenesis of IOA and REE mineralization. Migmatites are present along Rt. 4/22 near Whitehall, NY. In chapter two, all layers of a single migmatitic rock were …

Sources And Controls Of Carbon Dioxide In Inland Waters At Watershed, Regional, And Continental Scales, Brian Saccardi

Doctoral Dissertations

Inland waters are significant sources of carbon dioxide to the atmosphere, and estimates of emissions are similar in magnitude to those of the carbon dioxide sequestered by the net terrestrial sink. Currently, methods of estimating carbon dioxide emissions are based on statistical approaches and often do not consider landscape attributes such as human development, agriculture, or the hydrologic connectivity of the stream network. The following research addresses these issues in chapter 1 by developing and validating a reactive transport model at the watershed scale, then in chapter 2 by applying the reactive transport model at the continental scale across US …

Heat Flow In The Southern Margin Of Salar De Atacama: Deep Groundwater Temperature Distributions And The Implications For Subsurface Flow And Land Surface Energy Budgets, Graham Thomas

Masters Theses

Salar de Atacama (SdA) located in Northern Chile is home to one of the planet’s largest salar systems and lithium resources. Managing groundwater resources in salars is not obvious due to the lack of scientific understanding on the connectivity between the freshwater and brine systems. Using heat as a tracer in SdA provides a cost-effective method to further investigate groundwater flow in salars. This study employs 372 temperature-depth profiles from 90 boreholes between 2013-18 to understand the distinct thermal zones and flow between them in SdA. Three thermal zones exist within the southern margin of SdA’s thermal regime, at higher …

Architecture Of Extraction: Imagining New Modes Of Inhabitation And Reclamation In The Mining Lifecyle, Erica Dewitt

Masters Theses

Mining is the primary method through which modern society obtains the minerals needed to fuel the global economy, provide for modern energy requirements, and support the built environment. Presently, mining accounts for nearly 1% of the global ice-free land surface, with a dramatic increase anticipated in the coming decades. Mining permanently changes and often destroys the pre-existing topography, hydrology, and ecology of the ground, and efforts to reclaim mining landscapes—with the aim of encouraging reforestation and soil replenishment—are often unsuccessful, rendering the land of abandoned mines both unusable and uninhabitable.

This thesis addresses the current state of mining in the …

Thames River Subwatershed Soil, Sediment, Water Data, Justin B. Richardson, Mark J. Butler

Data and Datasets

Trace element and nutrient data are for riparian soils, suspended sediments, eddy bottom sediments, and river water collected between 2019 and 2020 in the Thames River watershed of Connecticut, USA. Trace elements and nutrients were measured using EPA 3050B digestion method and analyzed by ICP-OES or ICP-MS.

The Use Of Biological Soil Health Indicators To Quantify The Benefits Of Cover Crops, Alexander Wu

Masters Theses

Soils provide many essential functions that support the world. With a decline in soil health, these functions also decrease in efficiency, and can threaten the health of billions of people around the world. Typically, soil health tests do not use biological indicators, however microbes drive and perform vital functions to increase soil health. One way to increase soil health is through the use of cover crops to reduce soil erosion during fallow periods, increasing soil organic matter, as well as collecting nutrients from soil into their biomass. These cover crops are then terminated through various methods such as herbicides, disk …

Modeling Spatial Distributions Of Tidal Marsh Blue Carbon Using Morphometric Parameters From Lidar, Bonnie Turek

Masters Theses

Tidal marshes serve as important “blue carbon” ecosystems that accrete large amounts of carbon with limited area. While much attention has been paid to the spatial variability of sedimentation within salt marshes, less work has been done to characterize spatial variability in marsh carbon density. Driven by tidal inundation, surface topography, and sediment supply, soil properties in marshes vary spatially with several parameters, including marsh platform elevation and proximity to the marsh edge and tidal creek network. We used lidar to extract these morphometric parameters from tidal marshes to map soil organic carbon (SOC) at the meter scale. Fixed volume …

Geomorphology Of Tidal Wetlands: Impacts Of Extreme And Annual Flood Events To Salt Marsh And Mangrove Systems, Frances R. Griswold

Doctoral Dissertations

Tidal wetlands are vital for buffering coastal settings from the threats of accelerated sea level rise and storms. Understanding the factors that are most influential for the maintenance and recovery of tidal wetlands after extreme events compounded by future accelerated sea level rise is of the utmost importance, yet this knowledge is not well established. Two tidal wetland schemas investigated in this dissertation are mangrove systems in Vieques, Puerto Rico (including robust lagoonal-mangrove forest systems and fringing mangrove forests), and salt marshes in New England. While the climatic forcings, vegetation type, and locations are vastly different for these two tidal …

Rainbow Beach Sediment Grain Size Analysis, Northampton, Massachusetts, Brian Yellen

Data and Datasets

This dataset was prepared by Brian Yellen, a research assistant professor in the Department of Earth, Geographic, and Climate Sciences at the University of Massachusetts Amherst. Dr. Yellen worked in conjunction with Melissa Grader of the USFWS and colleagues to conduct the associated field sampling.

This report provides information related to the substrate grain size at surveyed locations on Rainbow Beach on the Connecticut River in Northampton, MA (42.322125, -72.584928). This location is a known breeding site of the endangered puritan tiger beetle (PTB), Ellipsoptera puritana.

Data For "Hydrological Signatures In Wetlands In The Li-Rich Salar Basins Of The Andes, South America", Sarah Mcknight, Jordan Jenckes, David Boutt, Brendan Moran, Lee Ann Munk, Alexander Kirshen

Data and Datasets

Data relevant to regional study of surface water inundation dynamics, vegetative areas, temperature, and precipitation in the Andes of South America.

Enabling An Equitable Energy Transition Through Inclusive Research, Michael Ash, Erin Baker, Mark Tuominen, Dhandapani Venkataraman, Matthew Burke, S. Castellanos, M. Cha, Gabe Chan, D. Djokic, J.C. Ford, Anna P. Goldstein, David Hsu, Matt Lacker, C. Miller, D. Nock, A.P. Ravikumar, Allison Bates, Anna Stefanopoulou, E Grubert, D.M Kammen, M. Pastor, S.Z, Attari, S. Carley, D.L Clark, D. Dean-Ryan, U. Kosar, Kerry Bowie, Tina Johnson

ETI Publications

Comprehensive and meaningful inclusion of marginalized communities within the research enterprise will be critical to ensuring an equitable, technology-informed, clean energy transition. We provide five key action items for government agencies and philanthropic institutions to operationalize the commitment to an equitable energy transition.

Manganese Bioavailability Drives Organic Matter Transformations Across Oxic-Anoxic Interfaces Via Biotic And Abiotic Pathways, Nathan A. Chin

Masters Theses

Soil organic matter decomposition is a critical process that affects nutrient cycling, CO₂ emissions, and carbon storage in terrestrial environments. Recent evidence suggests reactive manganese (Mn) phases, potent oxidants that depolymerize compounds like lignocellulose in soil organic matter, act as critical drivers of organic matter decomposition in soil and sediment environments. Furthermore, oxic-anoxic interfaces (OAIs) have been shown to be crucial hotspots for the formation of reactive Mn(III) species and associated organic matter degradation. However, the extent to which microbially mediated Mn(III) formation and subsequently Mn(III)-driven organic matter oxidation depends on Mn availability remains largely unknown. Additionally, the relative …

Size, Timing, And Landscape Impacts Of Glacial Lake Outburst Floods In The Channeled Scabland Of Eastern Washington, Usa, Karin E. Lehnigk

Doctoral Dissertations

Extreme floods have dramatically altered landscapes on Earth and Mars through bedrock erosion, sediment deposition, and canyon formation. The Channeled Scabland of the Columbia Plateau in eastern Washington, USA, is perhaps the most striking example of such a landscape, where outburst floods from an ice-dammed glacial Lake Missoula eroded immense canyons and transported large volumes of sediment during the late Pleistocene. Despite advances in numerical modeling and geochemical exposure dating methods, it has remained a challenge to untangle the complex interactions between floodwater, bedrock, and glacial ice to link the size of a flood with its impact on the landscape. …

Pre-Agricultural Soil Erosion Rates In The Midwestern U.S., Caroline Lauth Quarrier

Masters Theses

Soil erosion undermines agricultural productivity, limiting the lifespan of civilizations. For agriculture to be sustainable, soil erosion rates must be low enough to maintain fertile soil, as was present in many agricultural landscapes prior to the initiation of farming. However, there have been few measurements of long-term pre-agricultural erosion rates in major agricultural landscapes. We quantified geological erosion rates in the Midwestern U.S., one of the world’s most productive agricultural areas. We sampled soil profiles from 14 native prairies and measured concentrations of the cosmogenic nuclide 10Be and chemically immobile elements to calculate physical erosion rates. We used the erosion …

Remote Sensing Of High Latitude Rivers: Approaches, Insights, And Future Ramifications, Merritt E. Harlan

Doctoral Dissertations

High latitude rivers across the pan-Arctic domain are changing due to changes in climate and positive Arctic feedback loops. Understanding and contextualizing these changes is challenging due to a lack of data and methods for estimating and modeling river discharge, and mapping rivers. Remote sensing, and the availability of satellite imagery can provide ways to overcome these challenges. Through combining various forms of fieldwork, modeling, deep learning, and remote sensing, we contribute methodologies and knowledge to three key challenges associated with better understanding high latitude rivers. In the first chapter, we combine field data that can be rapidly deployed with …

Antarctic Ice Sheet Stability During Warm Periods: Integrating Numerical Modeling With Geologic Data, Anna Ruth W. Halberstadt

Doctoral Dissertations

Sea level rise is one of the major social and environmental challenges that threatens modern civilization, yet the response of polar ice sheets to future warming is deeply uncertain. Mass loss from the Antarctic Ice Sheet is projected to dominate global sea level rise in the near future, but how much, and when, remains a key unknown. The challenges associated with projecting Antarctica’s future sea level contribution are derived from a knowledge gap of physical ice sheet processes in a world warmer than today, and a lack of understanding of climatic thresholds that drive potentially irreversible retreat. Future and even …

Perceptions Of Historical Climate Change And Park Policy: The Impact On The Fremont Cottonwood In Zion National Park, Kathleen Kavarra Corr

Doctoral Dissertations

Despite its “natural” appearance and the Organic Act 1916 mandate for preservation of the natural environment in National Parks, the Virgin River as it flows through Zion National Park’s Zion Canyon was transformed through massive flood control re-engineering projects in the 1930s. The armoring of the river has had significant impacts on riparian vegetation, particularly on the stands of native Fremont Cottonwood trees that once filled the narrow valley. What was the motivation for this massive flood control project carried out in an arid region with less than 15 inches of rain per year? This dissertation explores the motivations which …

Improving The Hydrological Analysis Of Groundwater Flow Paths By Integrating Geochemical And Physical Characteristics Of A Highly Fractured Aquifer System To Create Sustainable Use Of Groundwater In A Climate With Projected Drying Trends., Marsha K. Allen

Doctoral Dissertations

Improving the hydrological analysis of groundwater flow paths by integrating geochemical and physical characteristics of a highly fractured aquifer system to create sustainable use of groundwater in a climate with projected drying trends. Precipitation over Caribbean islands has decreased steadily since the 1950's, which has led to severe drought conditions. The most recent Pan-Caribbean Drought occurred from 2013 to 2016. Climate models predict that drying trends are expected to continue and become more severe over time as precipitation decreases and temperatures rise. In addition, evaporation rates on these islands are expected to increase by ~15-17%, contributing to the drought. Though …

Fundamental Controls On The Water Cycle In Arid Environments: A Mechanistic Framework For Spatiotemporal Connectivity Between Hydroclimate And Groundwaters In The Dry Andes, Brendan J. Moran

Doctoral Dissertations

There remain many persistent uncertainties regarding fundamental aspects of natural water cycles in arid mountainous regions, the Dry Andes of South America represents one of the most extreme examples of these environments on the Planet. Deep water tables (>100 meters), long groundwater transit times and distances (>100 years, 10-100 kilometers), limited and infrequent rainfall, remote and difficult to access terrain, and complex salar/evaporite hydrogeology common in these environments make reliable monitoring of these hydrological systems particularly difficult. As a result, major gaps remain in our understanding of critical aspects of the water cycle such as recharge and evaporation …

New England Foliar Spectral Reflectance And Nutrient Concentrations Data, Wenxiu Teng, Qian Yu, Ivan Mischenko, Alexandrea Rice, Justin Richardson

Data and Datasets

No abstract provided.

Data For "Distinct Hydrologic Pathways Regulate Perennial Surface Water Dynamics In An Arid Basin", Sarah Mcknight, David F. Boutt, Lee Ann Munk, Brendan Moran

Data and Datasets

In water-stressed arid basins, questions continue to mount over the compounding impacts of anthropogenic groundwater extraction and climate-driven perturbations on groundwater-surface water interactions and the resulting resilience of ecosystem-critical surface waters. Coupling groundwater and surface water level observations with surface water extents from Sentinel-2 data provides an unprecedented opportunity to evaluate surface water connectivity with local aquifers following intense, sporadic precipitation events in arid basins. Surface water area, surface water level, and groundwater level data were analyzed for trends following precipitation, including peak lag time, post-peak decline rates, and changes in hydraulic gradients. Results indicate variable connectivity following precipitation events …

Data For "Relic Groundwater And Mega Drought Confound Interpretations Of Water Sustainability And Lithium Extraction In Arid Lands", Brendan J. Moran, David F. Boutt, Sarah V. Mcknight, Jordan Jenckes, Lee Ann Munk, Daniel Corkran, Alexander Kirshen

Data and Datasets

This repository contains raw data from this publication including hydrogeochemistry, model calculations, groundwater levels, and remotely sensed data compiled and extracted using Google Earth Engine.

Magnitude And Rates Of Agriculturally-Induced Soil Erosion In The Midwestern United States, Evan Thaler

Doctoral Dissertations

Fertile, agricultural productive soils are essential for producing food for a growing global population. Soil erosion diminishes soil quality, threatens food security by decreasing crop productivity, and degrades ecosystem health through increased rates of sedimentation and runoff. Despite decades and thousands of soil erosion studies, robust scalable methods for estimating the magnitude and rates of soil erosion have been elusive. In this dissertation, we develop a remote sensing method for quantifying the areal extent of historical loss in an agricultural landscape and provide a method for estimating the total thickness of soil loss and rates of historical soil loss in …

Hydrologic Controls On Phosphorus Speciation And Mobilization In A Subalpine Watershed (East River, Colorado), Lucia Isobel Arthen-Long

Masters Theses

The cycling of phosphorus (P) through floodplain environments is critical to ecosystem productivity and has significant implications on both water quality and soil fertility. P export from soils in response to saturation has been well documented, but the relative vulnerability of specific P pools to mobilization remains poorly constrained, as do the mechanisms mediating its release. The prediction of P availability in and export from mountainous floodplain soils is of great importance as global climate change is projected to significantly alter precipitation regimes in alpine systems. This study combined a thorough characterization of P distribution across a hillslope to floodplain …

Sedimentary Processes Influencing Divergent Wetland Evolution In The Hudson River Estuary, Kelly Mckeon

Masters Theses

Consistent shoreline development and urbanization have historically resulted in the loss of wetlands. However, some construction activities have inadvertently resulted in the emergence of new tidal wetlands, with prominent examples of such anthropogenic wetlands found within the Hudson River Estuary. Here, we utilize two of these human-induced tidal wetlands to explore the sedimentary and hydrologic conditions driving wetland development from a restoration perspective. Tivoli North Bay is an emergent freshwater tidal marsh, while Tivoli South Bay is an intertidal mudflat with vegetation restricted to the seasonal growth of aquatic vegetation during summer months. Using a combination of sediment traps, cores, …

Testing The Impact Of A Freshwater Wetland Restoration On Water Table Elevation And Soil Moisture Using A Parametric Groundwater Modeling Approach, Erika T. Ito

Masters Theses

Wetlands are now recognized for the many social, environmental, ecological, and economic benefits they provide. They improve water quality, support biodiversity, abate floods and storms, and provide local recreational areas. Historically, many wetlands have been drained or altered for residential, commercial, or agricultural use. Effective wetland restoration projects reestablish ecosystem services and mitigate legacy effects of land use change to create self-sustaining systems. However, a persisting lack of scientifically-vetted methodological and evaluation guidelines in the field of restoration ecology has caused many restoration efforts to fail to restore natural wetland hydrologic conditions. By definition, wetlands must be saturated, permanently or …

Algorithm Performance On The Estimation Of Cdom And Doc In The North Slopes Of Alaska, Monica Weisenbach

Masters Theses

Use of satellite imagery makes environmental monitoring easy and convenient with little of the logistics involved in planning sampling campaigns. Colored dissolved organic matter (CDOM) is an important component to track as a proxy for the large pool of dissolved organic carbon (DOC). In a world contending with the looming issue of global climate change, the ability to investigate the carbon cycle of inland to coastal environments allows for examination of the magnitude of carbon flowing through the system and potential changes over years. The Arctic region is a critical area for climate change impacts but is a difficult landscape …

Benjamin Smith Lyman: Geologist At The Intersection Of Hokkaido, Japan, And The United States, Benjamin Ashby

Masters Theses

Benjamin Smith Lyman was a geologist from Northampton, Massachusetts, who was contracted by the Japanese government in 1872 to carry out coal surveys on the island of Hokkaidō 北海道. What started out as a standard geological survey, quickly evolved into a lifelong interest in Japan for Lyman. The large collection of letters, books, photographs, and other documents housed under the Benjamin Smith Lyman Collection at the University of Massachusetts Amherst, serve as a primary source on both early relations between the Japanese and the West and the beginnings of the large network of academic writings which today can be classified …