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Full-Text Articles in Mechanical Engineering
Microstructure Correlation With Formability For Biaxial Stretching Of Magnesium Alloy Az31b At Mildly Elevated Temperatures, David T. Fullwood, Isaac Chelladurai, Michael P. Miles, John E. Carsley, Raj K. Mishra, Irene J. Beyerlein, Marko Knezevic
Microstructure Correlation With Formability For Biaxial Stretching Of Magnesium Alloy Az31b At Mildly Elevated Temperatures, David T. Fullwood, Isaac Chelladurai, Michael P. Miles, John E. Carsley, Raj K. Mishra, Irene J. Beyerlein, Marko Knezevic
Faculty Publications
Magnesium AZ31B sheets of 2 mm thickness were stretch formed using a 101.6 mm diameter punch at temperatures from 25°C - 150°C, in 25°C increments. Surface strains were measured using a digital image correlation (DIC) method. The punch height vs load curve was found to be the same for temperatures of 25°C and for 50°C, while at 75°C and above the load for a given punch height started to decrease, indicating a potential change in deformation mechanism. Electron Backscatter Diffraction (EBSD) was used to quantify features of the microstructure in the tested specimens. In particular, the gradual decrease in twinning …
Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen
Redox Stable Anodes For Solid Oxide Fuel Cells, Guoliang Xiao, Fanglin Chen
Faculty Publications
Solid oxide fuel cells (SOFCs) can convert chemical energy from the fuel directly to electrical energy with high efficiency and fuel flexibility. Ni-based cermets have been the most widely adopted anode for SOFCs. However, the conventional Ni-based anode has low tolerance to sulfur-contamination, is vulnerable to deactivation by carbon build-up (coking) from direct oxidation of hydrocarbon fuels, and suffers volume instability upon redox cycling. Among these limitations, the redox instability of the anode is particularly important and has been intensively studied since the SOFC anode may experience redox cycling during fuel cell operations even with the ideal pure hydrogen as …
Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao
Influence Of Crystal Structure On The Electrochemical Performance Of A-Site-Deficient Sr1-SNb0.1Co0.9O3-Δ Perovskite Cathodes, Yinlong Zhu, Ye Lin, Xuan Shen, Jaka Sunarso, Wei Zhou, Shanshan Jiang, Dong Su, Fanglin Chen, Zongping Shao
Faculty Publications
The creation of A-site cation defects within a perovskite oxide can substantially alter the structure and properties of its stoichiometric analogue. In this work, we demonstrate that by vacating 2 and 5% of Asite cations from SrNb0.1Co0.9O3-δ (SNC1.00) perovskites (Sr1-sNb0.1Co0.9O3-δ,s = 0.02 and 0.05; denoted as SNC0.98 and SNC0.95, respectively), a Jahn–Teller (JT) distortion with varying extents takes place, leading to the formation of a modified crystal lattice within a the perovskite framework. Electrical conductivity, electrochemical performance, chemical compatibility and microstructure of Sr1-sNb0.1Co …
The Effect Of Isostatic Pressing On The Dielectric Properties Of Screen Printed Ba0.5Sr0.5Tio3 Thick Films, Siwei Wang, Lingling Zhang, Jiwei Zhai, Fanglin Chen
The Effect Of Isostatic Pressing On The Dielectric Properties Of Screen Printed Ba0.5Sr0.5Tio3 Thick Films, Siwei Wang, Lingling Zhang, Jiwei Zhai, Fanglin Chen
Faculty Publications
Ba0.5Sr0.5TiO3 thick films with B2O3–Li2O glass sintering aid were prepared by the screen printing method on Al2O3 substrates. A 200 MPa isostatic pressure was applied to the films before sintering. After being sintered at 950∘C, lower porosity and denser microstructure was obtained compared with the films without isostatic pressing. The dielectric constant and dielectric loss were 238 and 0.0028, respectively. A tunability of 61.7% was obtained for the isostatic pressed films, a 27.8% enhancement compared to unpressurized films. These results suggest that isostatic pressing …
Recovery Of The Grain Boundary Character Distribution Through Oblique Double-Sectioning, Brent L. Adams, David T. Fullwood, E. R. Homer
Recovery Of The Grain Boundary Character Distribution Through Oblique Double-Sectioning, Brent L. Adams, David T. Fullwood, E. R. Homer
Faculty Publications
This work was supported primarily by the MRSEC program of the National Science Foundation under DMR-0079996. A method for the retrieval of the complete grain boundary character distribution by oblique double-sectioning is proposed. The method, which is similar to the recovery of the orientation distribution from sets of incomplete pole-figures, is efficient and provides many advantages as compared to calibrated serial sectioning. As compared to standard stereological approaches, the new methodology retains the advantage of direct measurement of the grain boundary inclination parameters. Solutions to the fundamental equation of oblique double-sectioning are provided in the Fourier space, and some specifics …
Two-Dimensional Grain Boundary Percolation In Alloy 304 Stainless Steel, Brent L. Adams, John A. Basinger, David T. Fullwood, E. R. Homer
Two-Dimensional Grain Boundary Percolation In Alloy 304 Stainless Steel, Brent L. Adams, John A. Basinger, David T. Fullwood, E. R. Homer
Faculty Publications
This work was supported by the MRSEC program of the National Science Foundation under Award Number DMR-0079996. An experimentally-obtained percolation threshold for high-angle random grain boundary networks in alloy 304 stainless steel is compared to thresholds predicted by percolation theory. A discrepancy occurs in the two values (0.46 experimental and 0.65 theoretical). Possible reasons for the discrepancy are explored. The grain boundary network appears to be composed of two distinct sub-networks, with the 'outer' network acting as the dominant contributor to the percolating paths.
New Stereology For The Recovery Of Grain-Boundary Plane Distributions In The Crystal Frame, Brent L. Adams, Ryan J. Larsen
New Stereology For The Recovery Of Grain-Boundary Plane Distributions In The Crystal Frame, Brent L. Adams, Ryan J. Larsen
Faculty Publications
One of the authors (RJL) is grateful to the Office of Naval Research for fellowship support. BLA acknowledges the support of the NSF through the Materials Research Science and Engineering Center, Carnegie Mellon University (Grant No. DMR-0079996). A new experimental method is given for recovering the probability-distribution function Sv(ns/g). The function Sv(na/g) is the grain-boundary area per unit volume as a function of grain-boundary plane orientation (na), given a lattice misorientation (g) between the adjoining grains. The grain-boundary normal (na) is expressed in the crystal frame in which the misorientation g originates. The proposed method recovers the three-dimensional Sv(na/g) function …
Microstructures By Design: Linear Problems In Elastic-Plastic Design, Brent L. Adams, B. Henrie, M. Lyon
Microstructures By Design: Linear Problems In Elastic-Plastic Design, Brent L. Adams, B. Henrie, M. Lyon
Faculty Publications
Materials microstructure is considered to be a design variable in the methodology called microstructure sensitive design (MSD). Based upon existing homogenization relations, relating the first-order representation of microstructure (the local state distribution function) to elastic and yield properties, the paper describes the construction of properties closures. These establish the theoretically-possible combinations of properties achievable by the set of all possible microstructures, which is called the microstructure hull. Exemplary homogenization relations are shown to be, typically, hypersurfaces (often hyperplanes) in the Fourier space in which the microstructure hull resides. All points lying on (or to one side of) the hypersurface, that …
Microstructure Design Of A Two Phase Composite Using Two-Point Correlation Functions, Brent L. Adams, H. Garmestani, G. Saheli
Microstructure Design Of A Two Phase Composite Using Two-Point Correlation Functions, Brent L. Adams, H. Garmestani, G. Saheli
Faculty Publications
This work has been funded under the AFOSR Grant no. F49620-03-1-0011 and Army Research Lab contract no. DAAD17-02-P-0398 and DAAD 19-01-1-0742. Two-point distribution functions are used here as to introduce "Microstructure Sensitive Design" in two-phase composites. Statistical distribution functions are commonly used for the representation of microstructures and also for homogenization of materials properties. The use of two-point statistics allows the composite designer to include the morphology and distribution in addition to the properties of the individual phases and components. Statistical continuum mechanics is used to make a direct link between the microstructure and properties (elastic and plastic) in terms …
A Texture Evolution Model In Cubic-Orthotropic Polycrystalline System, Brent L. Adams, H. Garmestani, D. S. Li
A Texture Evolution Model In Cubic-Orthotropic Polycrystalline System, Brent L. Adams, H. Garmestani, D. S. Li
Faculty Publications
This work has been funded under the AFOSR Grant # F49620-03-1-0011 and Army Research Lab Contract # DAAD17-02-P-0398 and DAAD 19-01-1-0742. B.L. Adams acknowledges support of Army Research Office, Proposal No. 42566-MS. The authors express their sincere gratitude to Professor Surya Kalidindi, for helpful suggestions and correspondence for the derivation of the processing path functions. A new methodology based on a conservation principle in the orientation space is developed to simulate the texture evolution in a cubic-orthotropic polycrystalline system. A least squares error method was used to improve the accuracy of the simulation results obtained from the texture evolution function. …
Spectral Integration Of Microstructure And Design, Brent L. Adams, B. Henrie, M. Lyon, H. Garmestani, Surya R. Kalidindi
Spectral Integration Of Microstructure And Design, Brent L. Adams, B. Henrie, M. Lyon, H. Garmestani, Surya R. Kalidindi
Faculty Publications
Support of the Army Research Office is greatly appreciated. Mechanical design can be conducted in a framework where consideration of microstructure as a continuous design variable is facilitated by the use of a Fourier space. Selection of the mechanical framework for the problem (e.g., mechanical constitutive model and homogenization relations) dictates the dimensionality of the pertinent microstructure representation. Microstructure is comprised of basic elements that belong to the local state space. Local state includes crystallographic phase and orientation, and other parameters such as composition. The local state space is transformed into an isomorphic set in Fourier space. The universe of …
Extracting The Relative Grain Boundary Free Energy And Mobility Functions From The Geometry Of Microstructures, Brent L. Adams, D. Kinderlehrer, W. W. Mullins, Anthony D. Rollett, Shlomo Ta'asan
Extracting The Relative Grain Boundary Free Energy And Mobility Functions From The Geometry Of Microstructures, Brent L. Adams, D. Kinderlehrer, W. W. Mullins, Anthony D. Rollett, Shlomo Ta'asan
Faculty Publications
This work was supported primarily by the MRSEC Program of the National Science Foundation under Award Number DMR-9632556. This paper describes a method for extracting, from measurements of a polycrystal, the relative excess free energy and the relative mobility of the grain boundaries as functions of the crystallographic type (five degrees of freedom) and relevant thermodynamic variables. The method requires the simultaneous measurement of both the geometry and the crystallography of a large number of grain boundary intersections; the crystallographic information may be obtained from orientation imaging microscopy (OIM). For simplicity, the intersections will be assumed to be triple junctions …