Polymer and Organic Materials Commons^™

Structural Design And Application Of Polymeric Silicon Elastomers, Jacob Wyant

Williams Honors College, Honors Research Projects

The purpose of this project was to determine how the polymeric structure and mechanical properties of this elastomer are affected by the ratio between the polydimethylsiloxane macromolecular chains and the crosslinkers. These were determined via tensile and compression testing. Then, spiropyran was added to observe how this fluorescence and crosslinking agent affected the elastomer. Also, the elastomer’s fluorescent and icephobic nature were tested. The elastomers with a higher ratio of crosslinker to macromolecular chain could withstand higher tensile and compressive strains but failed at lower stresses than their counterparts with lower concentrations of crosslinkers. The elastomers were also found to …

Silicone Tadpole: Research Into Soft Bodies, Danielle Fernandez

Mechanical Engineering Undergraduate Honors Theses

In this thesis, research is conducted in the area of soft robotics by building a soft tadpole that can deform with a specific air pressure. The goal is to mimic the motion of an organic tadpole in respect to its S-shaped tail movement. The angle of deformation, derived from material mechanic theories, ranges from 45 to 80 degrees for this type of movement. The design includes a head compartment which acts as a tank to transfer nitrogen pressure and a tail section that receives the said pressure and bends as a result. The tail section was designed with two rows …

Analysis Of The Low-Cycle Fatigue Behavior Of Silicone Rubber For Biomedical Balloons, Chase Cooper

Materials Engineering

The development of a medical drug delivery device that allows for the deployment drugs into the adventitial tissue of blood vessels requires the inflation of a silicone elastomer. The inflated silicone must be able to consistently endure multiple loading cycles without failing so that the device can operate reliably. There are multiple methods of processing the silicone for the device and the goal of this study is to examine the effect of the various processing methods on the characteristics of the silicone. The Dynamic Mechanical Analysis Machine (DMA) is used to model the conditions of the device’s application by performing …

Deformation And Adhesion Of Soft Composite Systems For Bio-Inspired Adhesives And Wrinkled Surface Fabrication, Michael Imburgia

Doctoral Dissertations

The study of soft material deformation and adhesion has broad applicability to industries ranging from automobile tires to medical prosthetics and implants. When a mechanical load is imposed on a soft material system, a variety of issues can arise, including non-linear deformations at interfaces between soft and rigid components. The work presented in this dissertation embraces the occurrence of these non-linear deformations, leading to the design of functional systems that incorporate a soft elastomer layer with application to bio-inspired adhesives and wrinkled surface fabrication. Understanding the deformation of a soft elastomer layer and how the system loading and geometry influence …

Effect Of Processing History And Material Properties On The Growth Of Wrinkle Amplitude, Yu-Cheng Chen

Doctoral Dissertations

Wrinkling has been employed by many organisms to form unique topography, such as fingerprints, gut villi, and surface of flower petal cells. The wavy wrinkle structure provides friction enhancement, surface area increase, optical, and wetting properties improvement. Inspired by Nature, scientists have created wrinkles synthetically and proposed numerous uses for them. However, wrinkling surfaces encounters limitations on achieving massive area and high amplitude-to-wavelength ratio (aspect ratio). The three phase contact line wrinkling technique creates well-defined wrinkles in a continuous fashion, and has great potential to scale-up for massive production. In addition to the velocity dependent adhesion force, we find the …

Surface Instabilities For Adhesion Control, Chelsea Simone Davis

Open Access Dissertations

Controlling the specific adhesive properties of surfaces is a technologically complex challenge that has piqued the interest of many research groups around the world. While many scientists have used complex topographic and chemically altered surfaces to tune adhesion, others have shown that naturally occurring phenomena, such as elastic instabilities, can impact adhesion. We provide a thorough investigation into the effects of periodic surface buckling instabilities, or wrinkles, on adhesion. Wrinkles are an attractive surface patterning alternative as they form spontaneously over large areas and their dimensions, namely wavelength and amplitude, can be controlled on length scales relevant for adhesion control. …

Artificial Muscle Project: Process Development Of Polydimethyl Siloxane Thin Films For Use In Dielectric Electroactive Polymer Artificial Muscle Actuators, Vincent J. Gayotin, Richard W. Morrison, Paul A. Preisser

Materials Engineering

An artificial muscle design was created founded on the principles of a dielectric electroactive polymer (DEAP), which is fundamentally similar to a capacitor. A polydimethyl siloxane (PDMS)-based elastomer, Sylgard 184 from Dow Corning, was chosen for the design and spun coat onto polystyrene (PS) Petri dishes at varying speeds to create a thin film, using speeds of 2000 rpm, 3000 rpm, 4000 rpm, 5000 rpm, and 6000 rpm. The film thicknesses were measured optically through use of a microscope with coupled computer imaging software to generate a characteristic curve of film thickness to spin speed, achieving a minimum film thickness …

Equi-Biaxial Fatigue Of Elastomers: The Effect Of Oil Swelling On Fatigue Life, Stephen Jerrams, John Hanley, Niall Murphy, Ali Hassan

Articles

The effect of oil swelling on the fatigue life of ethylene propylene diene monomer rubber (EPDM) has been studied under conditions of equi-biaxial cycling using dynamic bubble inflation. Specimens were subjected to varying degrees of swelling in reference mineral oils and fatigued at constant engineering stress amplitudes. The reference oils used for swelling the EPDM had known aniline points, allowing the rubber-oil compatibility to be determined. The inflation fluid for fatigue testing was selected with a solubility parameter that would produce a desired level of incompatibility with the test specimens, thereby limiting the amount of additional swelling during cycling. Wöhler …

Friction And Adhesion In Rigid Surface Indentation Of Nitrile Rubber, Stephen Jerrams

Articles

When a rigid body in the form of a plane strain indentor is forced into an elastomer, the asperities on the surface of the indentor are filled by the softer material. As depth of ingress increases, the rubber displaced into the indentor asperities exhibits stick-slip behaviour. The rubber adheres to the rigid body and if the depth of ingress is held at a maximum, the level of adhesion remains constant despite short-term load relaxation occurring in the rubber.

This text describes the influence of a range of factors on indentation forces and adhesion in rigid indentation of hydrogenated nitrile rubbers. …