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Polymer and Organic Materials Commons

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Full-Text Articles in Polymer and Organic Materials

Thermal And Mechanical Numerical Modeling Of Extrusion-Based 3d Printed Reinforced Polymers For Selecting Manufacturing Process Parameters, Sunil Bhandari Dec 2021

Thermal And Mechanical Numerical Modeling Of Extrusion-Based 3d Printed Reinforced Polymers For Selecting Manufacturing Process Parameters, Sunil Bhandari

Electronic Theses and Dissertations

Extrusion-based 3D printing of thermoplastic polymer composites manufactures parts that have nonhomogenous, orthotropic, and process-dependent macro-scale material properties. As a part of the dissertation, research works were carried out to: • improve the interlayer mechanical properties and reduce the orthotropy, • use experimentally homogenized orthotropic material properties to numerically model the mechanical behavior of the non-homogenous orthotropic 3D printed parts, • create an efficient numerical thermal model to predict the process-dependent thermal history of the 3D printed part, and • aid the manufacturing process by selecting a suitable set of processing parameters based on a simplified sequentially coupled thermomechanical model. …


Graphene/Oxide Interactions With Polymer Networks Modeled Using Molecular Dynamics, Matthew Alan Reil Jan 2020

Graphene/Oxide Interactions With Polymer Networks Modeled Using Molecular Dynamics, Matthew Alan Reil

Electronic Theses and Dissertations

Due to its unique physical properties, graphene has shown great promise as an additive to Polymer Matrix Composites (PMCs) for material property enhancement. Achieving homogeneous dispersion of the graphene platelets within a polymeric network is critical to realizing these enhancements. Research has shown that achieving homogeneous dispersion of graphene platelets within PMCs is challenging as graphene is immiscible with most polymeric networks. This work used Molecular Dynamics (MD) simulations to demonstrate dispersion of graphene platelets within PMCs is inhibited by molecular surface charge potentials. Further simulations were conducted to demonstrate functionalized forms of graphene, specifically graphene oxide, have altered surface …