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Full-Text Articles in Engineering Science and Materials

Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira Jun 2009

Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

New applications for polymer composite materials are occurring at a rapid pace today. These include structural components in the energy, transportation, and biomedical fields. Many if not all of these new applications will require that part performance is insured with some degree of sustainable damage. With the growth in the use of composite structures comes the necessity of improved methodologies that can predict more accurately the life and serviceability conditions of composite parts. Damage mechanics in two-phase composite materials is a very complex problem that has challenged researchers for many years. However, most of the available models perform only a …


Multiscale Modeling Of Impact On Heterogeneous Viscoelastic Solids With Evolving Microcracks, Flavio V. Souza Apr 2009

Multiscale Modeling Of Impact On Heterogeneous Viscoelastic Solids With Evolving Microcracks, Flavio V. Souza

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Multiscale computational techniques play a major role in solving problems related to viscoelastic composite materials due to the complexities inherent to these materials. In the present work, a numerical procedure for multiscale modeling of impact on heterogeneous viscoelastic solids containing evolving microcracks is proposed in which the (global scale) homogenized viscoelastic incremental constitutive equations have the same form as the local scale viscoelastic incremental constitutive equations, but the homogenized tangent constitutive tensor and the homogenized incremental history dependent stress tensor depend on the amount of damage accumulated at the local scale. Furthermore, the developed technique allows the computation of the …


Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn Jan 2000

Modeling The Effect Of Plasticizer On The Viscoelastic Response Of Crosslinked Polymers Using The Tube-Junction Model, P. P. Simon, Harry J. Ploehn

Faculty Publications

Plasticizers modify the mechanical properties of polymericmaterials. The effects of plasticizers on glass transition temperatures can be most clearly observed in isochronal temperature sweep profiles of viscoelastic dynamic moduli. However, no simple mathematical models of plasticization are available to those who wish to design and employ plasticized materials in specific applications. We extend a phenomenological, molecular-level model (known as the tube–junction model) for crosslinked polymers to describe the effect of plasticizers on dynamic moduli. We show that the increase in free volume fraction due to the presence of the plasticizer can account for the shift in the glass transition in …


Molecular-Level Modeling Of The Viscoelasticity Of Crosslinked Polymers: Effect Of Time And Temperature, P. P. Simon, Harry J. Ploehn Jan 1997

Molecular-Level Modeling Of The Viscoelasticity Of Crosslinked Polymers: Effect Of Time And Temperature, P. P. Simon, Harry J. Ploehn

Faculty Publications

We present a new molecular-level picture of chain dynamics for describing the viscoelasticity of crosslinked polymers. The associated mathematical model consists of a time-dependent momentum balance on a representative polymer segment in the crosslinked network, plus phenomenological expressions for forces acting on the segments. These include a cohesive force that accounts for intermolecular attraction, an entropic force describing the thermodynamics governing chain conformations, and a frictional force that captures the temperature dependence of relative chain motion. We treat the case of oscillatory uniaxial deformation. Solution of the model equations in the frequency domain yields the dynamic moduli as functions of …