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Articles 1 - 30 of 50
Full-Text Articles in Engineering Science and Materials
Fatigue Behavior Of A Quasi-Isotropic Graphite/Epoxy Laminate Embedded With A Piezoelectric Sensor, Jon M. Coleman
Fatigue Behavior Of A Quasi-Isotropic Graphite/Epoxy Laminate Embedded With A Piezoelectric Sensor, Jon M. Coleman
Theses and Dissertations
This study primarily investigated the mechanical effects of embedding piezoelectric sensors on the tensile and fatigue strength of a quasi-isotropic, carbon-epoxy laminate. A secondary focus was the investigation of the sensor degradation under tensile loading. A [0 | ±45 | 90]s laminate was fabricated from Hercules AS4/3501-6 pre-preg tape. Specimens were first tested monotonically to obtain an average ultimate tensile strength and to detail the progression of damage. The fatigue tests were tension-tension, R=0.1, 10 Hz, constant amplitude. Results indicated that the embedded piezoelectric sensors did not have a significant effect on the tensile strength of the laminate. Specimens …
Study On The Oxygen Electrodes Of Alkaline Fuel Cells Effect Of Dopant On The Activity Of Ag/C Catalyst, Jiawei Teng
Study On The Oxygen Electrodes Of Alkaline Fuel Cells Effect Of Dopant On The Activity Of Ag/C Catalyst, Jiawei Teng
Journal of Electrochemistry
A new kind of nonnoble catalyst for the oxygen electrodes of Alkaline Fuel Cells was investigated. The AgNiBiHg/C catalyst, which was prepared by chemical reduction, was active for the cathodic reduction of oxygen in alkaline fuel cells. It was found that the catalytic activity was improved by adding Ni, Bi, Hg to Ag/C catalyst, and the maximum activity was observed at Ag50%Ni2%Bi3%Hg3%C42%(wt%). XRD inconjunction with SEM indicated that the crystalline silver turned into amorphous in the presence of doping agents and the grain size of silver was reduced. No dramatic deactivation of the catalyst occured after 5200 hours of service.
Preparation Of High Rate Discharge Foamed Nicd Battery, Yuming Wang
Preparation Of High Rate Discharge Foamed Nicd Battery, Yuming Wang
Journal of Electrochemistry
A novel device of SC type foamed NiCd battery is presented, in which, the innerresistance of battery is appeared to be reduced, and the electrode performance is gained to very improved, and so, this battery can be suited to using of the powerdrive pistol drill.
Mechanism Of Electrodeposition Of Cu/Co Multilayer Thin Films, Jiangyun Xue, Jixun Wu, Dejun Yang
Mechanism Of Electrodeposition Of Cu/Co Multilayer Thin Films, Jiangyun Xue, Jixun Wu, Dejun Yang
Journal of Electrochemistry
The mechanism of electrodeposition of Cu/Co multilayer thin films has been studied by means of potentodynamic sweep, cyclic voltammetry sweep and AC impendance. The results indicated that the copper deposition is mass transfer controlled process and the cobalt deposition is related to the absorbed intermediate species such as Co(OH)ads. The cobalt ions first form Co(OH)ads, then was deoxygenated to cobalt on the electrode surface.
Study On Perchlorate Produced By Electrolysis With Oxygen Cathode, Zhigang Shao, Baolian Yi, Naichao Li, Ming Han
Study On Perchlorate Produced By Electrolysis With Oxygen Cathode, Zhigang Shao, Baolian Yi, Naichao Li, Ming Han
Journal of Electrochemistry
A new method of measuring the flow capacity of cell gas in the perchlorate cell process equipped with an oxygen cathode is applided to investigate the influence of changes in the concentration of solution (chloride, chlorate, perchlorate and metal ion) and changes in the operation parameters (current density, temperature and pH) on perchlorate current efficiency. The main abstacle that the oxygen cathode is used in the perchlorate cell process is put forward and a method is provided to resolve it.
Photoluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang
Photoluminescence Of Photoelectrochemically Etched N+-Si, Guozheng Li, Chengqian Zhang, Xiumei Yang
Journal of Electrochemistry
PS layer on n+Si with (111) orientation prepered by means of photoelectrochemically etched has photoluminescent (PL) ability like PS layer on usual nSi. The data of PL spectra and quenching are given.
Development Of A New Type Ni-S Evolution Hydrogen Electrode For Water Electrolysis, Xiaoyou Yuan
Development Of A New Type Ni-S Evolution Hydrogen Electrode For Water Electrolysis, Xiaoyou Yuan
Journal of Electrochemistry
A new type evolution hydrogen electrode NiS(N) has been made from nickel plating electrode in NiSO4CS(NH2)2 bath by electrodeposition. It is analyzed by SEM and Xray energy spectrum. The NiS(N) electrode is different from the NiS(O) electrode (which is used in plant at present time) in surface metallograph configuration and surfer content. The results of measurement polarization curves and water electrolysis 480 hours at 5 000 A·m-2 show that the evolution hydrogen overpotential of NiS(N) electrode is decreased at least 160 mV relative to NiS(O) electrode and the stablisum of NiS(N) electrode is better than that of NiS(O) electrode.
Molten Carbonate Fuel Cell Materials And Technology, Naichao Li, Baolian Yi
Molten Carbonate Fuel Cell Materials And Technology, Naichao Li, Baolian Yi
Journal of Electrochemistry
Molten Carbonate Fuel Cell materials are reviewed, and the technology of Molten Carbonate Fuel Cell are discussed.
The Effect Of Solution Composition On The Corrosion Behavior Of Electrodeposited Zinc Powder, Qingwen Li, Qin Yang, Xi Xia
The Effect Of Solution Composition On The Corrosion Behavior Of Electrodeposited Zinc Powder, Qingwen Li, Qin Yang, Xi Xia
Journal of Electrochemistry
Zinc powder as a widely anode material can be electrowon from ZnCl2 or ZnO+KOH media. The properties of zinc powder are likely to be modified with electrolytic conditions such as the composition of bath solution, electrolysis manner, current density and additives etc.. In this paper, we have discussed the effect of the compositions of bath solution on the microstructure and corrosion resistance of zinc powder.
The Activity Of Alloy CuNi Electrode In Electroreduction Of Aromatic NitroCompounds, Chunan Ma, Shaoping Tong, Xiaojun Cheng, Hui Wang
The Activity Of Alloy CuNi Electrode In Electroreduction Of Aromatic NitroCompounds, Chunan Ma, Shaoping Tong, Xiaojun Cheng, Hui Wang
Journal of Electrochemistry
CuNi alloy on the basis of copper at different ratio Cu/Ni are prepared by codepostion. The cathode activtiy of film are studied by steadystate polarization for electroreduction nitrobenzene (NB) and 1,5dinitroanthraquinone (1,5DNA) to paminophenol and 1,5diamino4,8dihydroanthraquinone respectly. The results show that the alloy cathodes at different ratio Cu/Ni have different exchange current density (io) and apparent activition energy (EA). The alloy (CN30) has maximal io and minimal EA by codeposition at the following conditions: electrolyte: 0.05 mol/L CuSO4·5H2O+0.6 mol/L NiSO4·6H2O+0.25 mol/L Na3Cit·2H2O; current density: 0.6 A/dm2 , pH=6, temperature at 50 ℃. Compared with the common cathodes such as …
Fiber Volume Fraction Effects On Fatigue Response Of A Scs-6/Ti-15-3 Metal Matrix Composite At Elevated Temperature, Sean C. Coghlan
Fiber Volume Fraction Effects On Fatigue Response Of A Scs-6/Ti-15-3 Metal Matrix Composite At Elevated Temperature, Sean C. Coghlan
Theses and Dissertations
The purpose of this study was to determine the effects of fiber volume fraction on the fatigue behavior of Silicon Carbide fiber-reinforced Titanium alloy, SCS-6/Ti-15-3. Three fiber volume fractions were investigated; 15%, 25%, and 42%. The tests were performed under fully-reversed, strain-controlled conditions at 427 °C. The primary objectives of this study were to develop a fatigue life diagram and to document the damage and failure mechanisms. Compressive loads on the slender specimens were kept from buckling the specimens through the use of a buckling guide. This device allows unrestricted axial movement of the composite, while preventing any out-of-plane motion. …
The Electrode Process Of Some Organic Dyes Studied By Spectroelec Tro Chemical Technique In Situ, Yinxuan Tang, Hangsheng Yang, Baoen Shen
The Electrode Process Of Some Organic Dyes Studied By Spectroelec Tro Chemical Technique In Situ, Yinxuan Tang, Hangsheng Yang, Baoen Shen
Journal of Electrochemistry
Spectroelectrochemistry especially with in situ measurement in a cell provides a very useful mthodology for measuring the parameters of electrode process. In this paper, we report the determination of formal potentials, the number of electron transfer, the diffusion coefficient, the heterogeneous electron transfer rate constant and the transfer coefficient of some organic dyes (Methyelene blue, Neutral red, Indigo carmine) using spectroelectro chemical technique in situ.
Corrosion Behaviour Of Copper Covered With Ion Selective Phenolic Coatings By Eis, Zhoucheng Wang, Yingzhou Zhang, Shaomin Zhou
Corrosion Behaviour Of Copper Covered With Ion Selective Phenolic Coatings By Eis, Zhoucheng Wang, Yingzhou Zhang, Shaomin Zhou
Journal of Electrochemistry
Electrochemical impedance spectroscopy(EIS) technique was employed to study the corrosion behaviour of copper painted with the anion selective、 cation selective and bipolar phenolic coatings in 3% NaCl solution. From the impedance spectrum characteristics, the models of equivalent circuit for these different coating systems were established,and the methods for the analysis of experimental impedance diagrams in terms of coating and interface properties were discussed. The research results show that the composition and structure of ion selective coatings have significant influence on corrosion behaviour of copper. The bipolar coating consisting of an anion selective inner layer and a cation selective outer layer …
Studies On The Failure Modes Of Stationary Vrla Batteries, Yibo Tong, Xiangming Qiu
Studies On The Failure Modes Of Stationary Vrla Batteries, Yibo Tong, Xiangming Qiu
Journal of Electrochemistry
In order to improve the reliability and the quality of stationary valve regulated lead acid (VRLA) batteries, the failure modes of the stationary VRLA batteries which caused by the water loss and the thermal runaway are studied. The water loss may be solved by increasing the Oxygen recombination efficiency, choosing the suitable grid material and the additives of megative paste, decreasing the corrosion of the positive plates. The thermal runaway may be solved by decreasing the inner ohmic resistance of VRLA batteries, improving the outside condition of batteries such as putting into the absorbing heat material between the abtteries etc..
Behavior Of Copper In Hydrogen Storage Alloy Microencapsulated By Copper, Dawei Zhang, Huatang Yuan, Huabin Yang, Zuoxiang Zhou, Yunshi Zhang
Behavior Of Copper In Hydrogen Storage Alloy Microencapsulated By Copper, Dawei Zhang, Huatang Yuan, Huabin Yang, Zuoxiang Zhou, Yunshi Zhang
Journal of Electrochemistry
Negative electrode made from Cu microencapsulated hydrogen storage alloy was studied by using cyclic voltammetry method. The results showed that copper as a coating material was of a certain stability in 5 mol/L KOH solution within the range of charge and discharge voltage. But when expanding the sweep voltage, the CV curve showed a pair of distinct oxidation reduction current peaks of Cu 2O formation at E =-0.3 V and Cu 2O reduction at E =-0.6 V. With charging discharging cycles, copper is liable to be oxidized to Cu 2O and further oxidized into CuO 2- 2. When charged again, …
Electrocatalytic Oxidation Of Methanol On The Stearate Nickel L B Film, Benzeng Hua, Wenyan Hu, Yanzhen Chen
Electrocatalytic Oxidation Of Methanol On The Stearate Nickel L B Film, Benzeng Hua, Wenyan Hu, Yanzhen Chen
Journal of Electrochemistry
The stearate nickel L B films is good electroacatlyst for the oxidation of methanol MeOH in alkaline. The electrochemical behaviors of stearate nickel L B films is affected by the concentration of KOH. The rate of quantity of mickel ion and stearic acid in L B films is 1∶1, which means that the nickel ion may exist in -COONi(OH) form. The electrocatalytic process is influenced by the concentration of OH - , it involves the penetration of MeOH into the films. The oxidative currents of MeOH are linearly dependent on the bulk concentration.
The Electrochemical Behavior And Deposited Mechanism Of Zn Ni Alloy Codeposition, Jixun Wu, Yongqin Liu, Huimin Meng
The Electrochemical Behavior And Deposited Mechanism Of Zn Ni Alloy Codeposition, Jixun Wu, Yongqin Liu, Huimin Meng
Journal of Electrochemistry
The electrochemical behavior of Zn Ni alloy codeposition and concomitant hydrogen evolution have been studied in the chloride ammonia solution through the d c electroplating method. Under the condition of the applied cathodic current density of 2A/dm 2 , the AC impedance spectra have been measured. An equivalent circuit has been presented for the impedance study on the alloy codeposition.
Study On The Diffusion Of Electroactive Molecules In Polymer Electrolyte By Microelectrode Voltammetry, Liming Ding, Shaojun Dong, Erkang Wang
Study On The Diffusion Of Electroactive Molecules In Polymer Electrolyte By Microelectrode Voltammetry, Liming Ding, Shaojun Dong, Erkang Wang
Journal of Electrochemistry
The ten years study on the diffusion of electroactive molecules in polymer electrolyte by microelectrode voltammetry was reviewed by considering the development background of polymer electrolyte materials. The classification, fabrication, applications and electrochemical measurements of microelectrode were introduced concisely. The several important factors influencing the diffusion of electroactive molecules were stressed. In the final part of this paper, some new reports on the diffusion of labeled molecules were introduced. 52 references were quoted.
Preparation Of Pbo 2/Ti Plate Electrode, Zhigang Shao, Baolian Yi, Xinge Zhang, Enjun Zhang
Preparation Of Pbo 2/Ti Plate Electrode, Zhigang Shao, Baolian Yi, Xinge Zhang, Enjun Zhang
Journal of Electrochemistry
The perchlorate was made up of a lead dioxide plate elcetrode and an oxygen cathode. By measuring the flow capacity of cell gas in the cell, and by means of CV、SEM、XRD, the performances of the lead dioxide plate electrodes are evaluated. The influence of changes in the concentrations of electroplating solutions (F 、HNO 3、Bi 3+ 、Ni 2+ 、Fe 3+ and surface active agent) is investigated. The results show that the concentrations of Fe 3+ in the solutions must be lower 0.01 g/l, and the concentrations of HNO 3 in the solutions are about 20 g/l, in order to get better …
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅲ. Improvement Of Artificially Imposed Solid Electrolyte Film On Cell Performance, Shuhua Ma, Xiabin Jing, Fosong Wang
Surface Modifications Of Carbon Materials Used As Anode Of Lithium Ion Battery Ⅲ. Improvement Of Artificially Imposed Solid Electrolyte Film On Cell Performance, Shuhua Ma, Xiabin Jing, Fosong Wang
Journal of Electrochemistry
The improving effect of solid electrolyte film artificially imposed on carbon electrode was investigated. The result showed that both the charge/discharge capacity and first charge/discharge efficiency, to a certain extent, were enhanced, and the result also suggested the effectiveness of the substitution of the artificially imposed solid electrolyte film for the inherent passivating film which was formed on the surface of the carbon electrode while inserted in the electrolyte during charging or discharging. The Scanning Electron Microscope result displayed the compact and well defined morphology of the artificially imposed crystalline film.
Investigation On Electro Reduction Behaviour Of Copper Anodic Products In Concentrated Naoh Solutions Ⅱ. Electro Reduction Of Cu(Ⅱ) Products, Jianbo He, Hanhe Chen, Jianxin Lin
Investigation On Electro Reduction Behaviour Of Copper Anodic Products In Concentrated Naoh Solutions Ⅱ. Electro Reduction Of Cu(Ⅱ) Products, Jianbo He, Hanhe Chen, Jianxin Lin
Journal of Electrochemistry
Potentiostatic oxidation potentiodynamic or galvanostatic reduction methods have been used to study the cathodic reduction behaviour of various products anodically formed on the second stage of copper oxidation in concentrated NaOH solutions. Seven cathodic current peaks and the corresponding cathodic potential plateaus are observed on the potentiodynamic E/i curves and the galvanostatic E/t curves, respectively. In the negative potential scan, there are three couples of voltammetric peaks which have been attributed to the formation and reduction of CuO, Cu(OH) 2 and Cu(Ⅱ) ion, respectively. The complicated mechanism for the electro formation of the three Cu(Ⅱ) species are discussed.
Preparation And Examination Of Planar Type Solid Oxide Fuel Cells, Yi Jiang, Jingwang Yan, Shizhong Wang, Chunying Yu, Wenzhao Li
Preparation And Examination Of Planar Type Solid Oxide Fuel Cells, Yi Jiang, Jingwang Yan, Shizhong Wang, Chunying Yu, Wenzhao Li
Journal of Electrochemistry
The solid oxide fuel cells of planar type(SOFC) have been developed after successfully preparing La 0.8 Sr 0.2 MnO 3 cathodes and Ni YSZ ceramic anodes on YSZ plates and solving the high temperature sealing technical problem. Examination of the single cells fabricated showed that the maximum power output at 950 ℃ for H 2 as fuel and air as oxidant reached 0.12 W/cm 2. It was found that the large polarization overpotential of the Ni YSZ anode and the Ohmic losses of the cells were two main factors responsible for the relative low output power density.
Thickness Effects On A Cracked Aluminum Plate With Composite Patch Repair, Joel J. Schubbe
Thickness Effects On A Cracked Aluminum Plate With Composite Patch Repair, Joel J. Schubbe
Theses and Dissertations
Post-repair fatigue crack growth was investigated in 3.175, 4.826, and 6.35 mm thick aluminum panels asymmetrically repaired with boron/epoxy composite patches bonded to the plates with FM73 sheet adhesive. Patches were uniaxial with patch to panel stiffness ratios ranging from 0.46 to 1.3. Experimental fatigue tests were carried out at 120 MPa, R=0.1, and 10 Hz (sinusoidal) to measure patched and unpatched face crack lengths, center crack opening displacements, and selected strains. Crack growth data was acquired using optical, eddy current, and post-test analysis methods. Crack growth rates were calculated using the incremental polynomial method. A three-layer Mindlin plate finite …
Studies On Electrodeposition Of Rare Earth Metals And Their Alloys In Molten Salts, Qiqin Yand
Studies On Electrodeposition Of Rare Earth Metals And Their Alloys In Molten Salts, Qiqin Yand
Journal of Electrochemistry
The cyclic voltammetry, convolution voltammetry, potentiostatic electrolysis and open circuit potential time curve after electrolysis, current time curve at potential step, potential time curve at current step, X ray diffraction, EDAX, electron probe microanalysis were used to investigate the electrode processes of the reduction of rare earth ions on inert electrodes and alloying electrodes in molten chlorides and fluorides. The free energies of formation for the intermetallic compounds, the diffusion coefficients of rare earth ions in the melt, the diffusion coefficients of rare earth atoms in the alloy phases were determined. The alloys of rare earth with iron, cobalt, nickel, …
Polymer Electrolyte Fuel Cell Powered Vehicles, Naichao Li, Baolian Yi
Polymer Electrolyte Fuel Cell Powered Vehicles, Naichao Li, Baolian Yi
Journal of Electrochemistry
The background, status and commercialization prospect of polymer electrolyte fuel cell vehicles are surveyed in this paper. The technology of this cell and system used in vehicles is discussed.
Mechanism And Texture Of Ni Mo Alloy Electrodeposition, Ling Huang, Shukai Xu, Jaoning Tang, Fangzu Yang, Shaomin Zhou
Mechanism And Texture Of Ni Mo Alloy Electrodeposition, Ling Huang, Shukai Xu, Jaoning Tang, Fangzu Yang, Shaomin Zhou
Journal of Electrochemistry
Ni Mo alloy deposits with (111) preferred orientation was obtained in a solution of 0.22 mol/L NiSO 4·6H 2O, 0.06 mol/L Na 2MoO 4·2H 2O and 0.3 mol/L Na 3C 6H 5O 7·2H 2O in temperature from 25℃ to 50℃,and current densities ranged from 10 mA·cm -2 to 30 mA·cm -2 . The electrodeposition of Ni Mo alloy was studied by cylic voltammetry and potential step experiment. It was shown that Ni Mo alloy is formed by mechanism involving progressive nucleation followed by three dimensional growth of the metal centres. The complex plane impedance plots indicate codeposition of Ni Mo …
Electroluminescence Of Photoelectrochemically Etched N + Si, Guozheng Li, Chengqian Zhang, Xiumei Yang
Electroluminescence Of Photoelectrochemically Etched N + Si, Guozheng Li, Chengqian Zhang, Xiumei Yang
Journal of Electrochemistry
Porous silicon with micrometer size pores, which is made on n + Si by photoelectrochemically etched, has electroluminescent property. Each monochromic intensity and wavelength range of luminescent spectra depend on polarized potential. The intersity and the stability of cathodic electroluminescence is high than those of anodic one. Voltammetric behavior before quenching indicated that the electrochemical reactions of some surface species are involved in except the reduction of S 2O 2- 8, which leads to radiative recombination. The energy band diagram based on n + Si (E g=1.1 eV)/PS(E g=1.8 eV) junction is proposed.
Study On The Preparation, Properties And Applications Of The Polymer/Graphite Composite Electrode, Guohua Chen, Jinrui Xu
Study On The Preparation, Properties And Applications Of The Polymer/Graphite Composite Electrode, Guohua Chen, Jinrui Xu
Journal of Electrochemistry
The graphite AS composite electrodes, which show high electric conductivity, high mechanical strength and operationl stability, were prepared by filling and extruding the AS copolymer with graphite powder. It exhibited a substantial hydrogen overvoltage and small residual current in different electrolytes, as compared with glassy carbon electrode. The electrode was applied to the determination of traces of Pb 2+ in mineral water, Ag + in waste water and In 3+ , Cu 2+ , Pb 2+ , Cd 2+ in zinc ore, and showed high stability, reproducibility and selectivity. Owing to the existence of abundant polar functioal groups on the …
Studies Of Electrocatalytic Properties Of Electrode Of Dispersed Pt On Gc Support In Ethylene Glycol Oxidation, Shengpei Chen, Shigang Lu Guoqiang Sun, Zhiyou Zhou, Shuanjing Hong
Studies Of Electrocatalytic Properties Of Electrode Of Dispersed Pt On Gc Support In Ethylene Glycol Oxidation, Shengpei Chen, Shigang Lu Guoqiang Sun, Zhiyou Zhou, Shuanjing Hong
Journal of Electrochemistry
The structures and properties of electrocatalyst of dispersed Plutinum(Pt) on glassy carbon(GC) support under different conditions were studied using cyclic voltammetry,potential step technique,x ray diffraction(XRD) and scanning Electron microscopy(SEM). The results indicated that after having been treated in high temperature,the dispersed Pt on GC support was recrystallised with preferented orientation,and the grain of Pt microcrystal become large and regular.It was illustrated that the dispersed Pt on GC support after high temperature treatment exhibited better stability and high activity for ethylene glycol oxidation.
Study Of Electrodepositing Bright Tin Cobalt Zinc Alloy From Weak Acid Solution, Zhengzhong Zuo, Runxiang Hou, Shaochun Xia
Study Of Electrodepositing Bright Tin Cobalt Zinc Alloy From Weak Acid Solution, Zhengzhong Zuo, Runxiang Hou, Shaochun Xia
Journal of Electrochemistry
A new process of electrodeposting bright Tin Cobalt Zinc alloy from weak acid solution is proposed in this paper. The solution compositions and operating conditions are Na 3C 6H 5O 7·2H 2O 100~150,Na 2EDTA·2H 2O 20~30,SnCl 2·2H 2O 15~20,CoSO 4·7H 2O 25~35,ZnCl 2 15~20 g·L -1 ;stabilizer WDZ 1 60~100, brightener WDZ 2 15~20 mL·L -1 ; pH=4~6, D K = 0.5~5.0 A·dm -2 , T= 5~35 ℃. A bright Sn Co Zn deposit having Co about 0.5~3.5% and Zn about 1~10% is produced. The effects of bath compositions on Co or Zn content in deposit is also discussed.