Engineering Science and Materials Commons^™

Failure Analysis And Materials Characterization Of Hip Implants, Amanda Marie Bastidos

Open Access Theses & Dissertations

This research focused on the microstructural characterization and failure analysis of hip implant components. The main hip components analyzed were the femoral heads and the ultra-high molecular weight polyethylene (UHMWPE) liners. Previous research has shown that hip implants tend to fail by the PE liners due to adhesive and abrasive wear, delamination, and third body particles (metals, ceramics, and PE). The methods and procedures for analyzing the said failures consisted of non-destructive and destructive evaluations. Non-destructive evaluations included of techniques such as visual characterization and dye penetrant inspection (DPI)-which displayed macroscopic surface details and presented initial clues as to the …

Additive Layer Manufacturing Of Ti-6al-4v By Electron Beam Melting From Powder Particles: Solid, Mesh And Foam Components Study, Sara M. Gaytan

Open Access Theses & Dissertations

Additive Manufacturing by Electron Beam Melting Rapid Manufacturing is a technology that consists of the fabrication of a CAD design by melting powder particles in a layer by layer fashion. In this study, Ti-6Al-4V has been utilized to fabricate solid, mesh and foam components by EBM technologies. Powder analysis of Ti-6Al-4V was performed to obtain a better understanding of the porosity obtained by the system. After proper optimization of the machine, and porosity control, microstructural analysis was performed to the components already mentioned and correlated by transmission electron microscopy. Besides the microstructural analysis, tensile and hardness testing was performed to …

Observed Superspin-Glass Behavior In Ni0.5zn0.5fe2o4 Nanoparticles, Antony Adair

Open Access Theses & Dissertations

In this investigation we seek to identify the magnetic behavior of Ni0.5Zn0.5Fe2O4 nanoparticles though AC-susceptibility and DC-magnetization measurements. Powder x-ray diffraction was performed to determine the purity and average diameter ( ~ 9nm) of the particles. Aditionally, structure was confirmed by comparison through the International Centre for Diffraction Data's Powder Diffraction File [52] (PDF # 08-0234).

Zero-field cooled and field cooled DC magnetization measurements (bifurcation and blocking temperature), as well as M(H) hysteresis (below and above the blocking temperature) lead us to initially suggest that the material may in fact be superparamagnetic. However, further investigation of the real AC susceptibility …

Spectroscopic Characterizations Of Organic/Inorganic Nanocomposites, Jayesh Rasikalal Govani

Open Access Theses & Dissertations

Inorganic potassium dihydrogen phosphate (KDP) is widely known for its value as a nonlinear optical material. In this study, pure and l-arginine-doped KDP single crystals were grown by the slow solvent evaporation technique and further subjected to infrared absorption and Raman studies for the confirmation of chemical group functionalization and possible bonding between the organic and inorganic materials. The appearance in the infrared absorption spectra of additional vibrational lines, which mostly originate from disturbed N-H, C-H, and C-N bonds of the l-arginine-doped salt, confirm the interaction between KDP and the organic material. This affirmation is supported by more evidence from …

Effects Of Build Orientation, Aging, And Pre-Conditioning On Mechanical Properties For Stereolithography-Manufactured Astm Type I Specimens Using A Design Of Experiments Approach, Karina Puebla

Open Access Theses & Dissertations

With industry's growing focus on the rapid manufacturing (RM) of end-use products, rapid prototyping (RP) or layered manufacturing (LM) machines that were originally designed to build prototypes may now be required to build functional end-use products. To successfully accomplish the transition, the available materials utilized in RP must provide the performance required for RM. The specific technology used must also be capable of producing repeatable and reproducible parts in regards to mechanical and dimensional properties.

A design of experiments approach was performed to determine the effects of build orientation, aging, and pre-conditioning on the mechanical properties. To perform the investigations, …

Computational Modeling Studies Of The Structures And Properties Of Organotin(Iv) And Stannyl-Thioether Systems With Comparisons To X-Ray Crystallography, Michelle R. Stem Joseph

Open Access Theses & Dissertations

Controlling the toxic effects of organotin(IV) compounds involves engineering the structure of the molecules to optimize their properties. Molecular engineering, coupled with improved capabilities to generate reliable computational optimization models (COMs), will enable researchers to have greater success at harnessing the highly specific cytotoxicity of organotins. For example, as the thio_n ligand phenyl groups were replaced with Cl atoms, the S-Sn intramolecularity was strengthened, the bond distance decreased, and the stannyl tetrahedral structure was deformed from its triphenyl conformation. With each substitution, conformation deformations lowered the damaging bioactivity levels of thio_n. Bonding various ligands to organotin(IV) compounds …

Experimental Study Of The Response Of Semiconductor Detectors For Edxrf Analysis., Sunil Kumar Valaparla

Open Access Theses & Dissertations

This present work relates to the study and characterization of the response function of an energy-dispersive x-ray spectrometer. The problems of energy, efficiency and resolution calibration of the system operating in the energy (5-60 keV) range are discussed. We present the operation characteristics of the portable pyro-electric x-ray generator (COOL-X) and the application of the calibrated response spectrum in the elemental analysis using X-ray Fluorescence (XRF).

We study the response of the Si(Li)-Pin XR-100CR semiconductor detector to low energy photons. The photopeak efficiency was determined experimentally by using radioisotopes and compared against a theoretical efficiency curve. The efficiency for gamma …

High Temperature Oxidation Behavior Of Nb-20mo-15si-5b-20cr Alloy, Julieta Angelica Ventura

Open Access Theses & Dissertations

Materials for high temperature applications, such as jet engines, gas turbines and turbine blades, require a balanced combination of physical and chemical properties to withstand the aggressive environments in which they are utilized. Some of the properties required are high strength, low density, high melting point and good oxidation resistance at elevated temperatures [1-3]. For this reason, the microstructure and oxidation behavior of the Nb-20Mo-15Si-5B-20Cr alloy (at.%) has been studied as a potential candidate to replace Nickel-based alloys currently used in the aerospace industry.

Short term oxidation (STO) and long term oxidation (LTO) studies have been performed in air for …

Exploring Poly(Ethylene Glycol) As A Suitable Material For Peripheral Nerve Regeneration Scaffolds Manufactured By Stereolithography, Nubia Zuverza

Open Access Theses & Dissertations

One of the challenges in tissue engineering is to have spatial and temporal control over the biological elements within a scaffold used to guide regeneration for example of transected nerves. Some of the physical and chemical characteristics to regulate include incorporation of bioactive domains and release of chemical signals. This study presents the use of stereolithography (SL) to incorporate localized domains for cell adhesion in addition to include releasable nerve growth factor (NGF) in the process of building poly(ethylene glycol)diacrylate (PEGda) hydrogel scaffolds. Besides providing sites for cell attachment, an ideal nerve guidance conduit (NGC) should be able to release …

Impacting Testing Of High Temperature Ceramics Through The Use Of A Vitiated Heater For Hot And Cold Fire Collisions, Adrian Trejo

Open Access Theses & Dissertations

Material testing is a crucial step during the design process as particular materials serve as safety and life saving conditions. In this study, a MoSi2 is chosen as the target specimen to undergo impact under high temperatures. An impact apparatus is designed and constructed for the purpose of propelling alumina particles at high velocities. A nozzle using compressed nitrogen gas is used to fire the particle at the desired velocities. Due to the possibility of thermal shock occurring at higher temperatures, a separate nozzle utilizing vitiation heating is designed to fire the particle at equally higher temperatures to prove the …

Stereolithography Of Poly(Ethylene Glycol) Hydrogels With Application In Tissue Engineering As Peripheral Nerve Regeneration Scaffolds, Karina Arcaute

Open Access Theses & Dissertations

In recent years, rapid prototyping (RP) technologies initially developed to create prototypes prior to production for the automotive, aerospace, and other industries, have found applications in tissue engineering (TE). Several different RP technologies are being used to fabricate biocompatible 3D structures with controlled micro- and macro-scale characteristics. The focus of this research was to explore the capabilities of the RP technology, stereolithography (SL), for creating complex, 3D scaffolds with applications in TE using a photocrosslinkable biopolymer, poly(ethylene glycol) (PEG). The primary objective was to create an implantable multi-lumen nerve guidance conduit (NGC) for the regeneration of peripheral nerves.

Studies of …

A Study Of The Interaction Of Thioindigo Dye, With Several Inorganic Host Materials, Alejandra Ramirez

Open Access Theses & Dissertations

Maya Blue has been the focus of numerous studies and is believed to be a mixture of palygorskite clay and indigo dye.^1,2 Several derivatives of this pigment have been developed with intriguing properties. For instance, the dye thioindigo reacts with the palygorskite clay to exhibit a broad range of colors from red to blue under UV-Vis excitation. Based on FT-Raman and computer simulation, previous work performed in our group could relate indigo and thioindigo interaction to the aluminum sites in the framework. super>3,4

The work performed with other inorganic host materials such as, layer structures and zeolites have …