Engineering Science and Materials Commons^™

Localized Corrosion Behavior Of Sensitized 304 Stainless Steel By Scanning Reference Electrode Technique, Chen-Qing Ye, Rong-Gang Hu, Rui-Qing Hou, Xiao-Ping Wang, Rong-Gui Du, Chang-Jian Lin

Journal of Electrochemistry

Based on a home-built setup of scanning reference electrode technique, and combined with conventional electrochemical measurements, the localized corrosion behavior of sensitized 304 stainless steel (304ss) had been investigated in this work. The results showed that, the non-sensitized 304ss or 304ss sensitized at 550 oC was susceptible to pitting; while 304ss sensitized at 650 oC or 750 oC suffered severe intergranular corrosion in 10% FeCl3 solution.

Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery, Qing Zhao, Yu-Xiang Hu, Kai Zhang, Li-Jiang Wang, Zhan-Liang Tao, Jun Chen

Journal of Electrochemistry

A series of ordered mesoporous carbon (CMK-3)/sulfur composite (C_xS_y) with different sulfur contents were synthesized via a melt-diffusion method. XRD, Raman, BET, SEM, and TEM techniques were used to characterize the structure and morphology of the as-prepared composite. The electrochemical performance of CMK-3/sulfur composite as the electrode of Na/S battery was tested at room temperature. Cyclic voltammograms show that one obvious reduction peak was located at about 1.61V, which is corresponding to the formation of Na₂S_x (x=2~5), while two oxidation peaks were displayed at about 1.82V and 1.95V, which are belonging to the …

Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4, Huai-Fang Shang, Wei-Feng Huang, Wang-Sheng Hu, Ding-Guo Xia, Zi-Yu Wu

Journal of Electrochemistry

Despite there are many successful reports about the preparation of electrode materials with surface coating for lithium ion batteries, the study in surface self-coating of cathode materials using segregation of doping elements and their electrochemical properties is still very rare. The LiFePO₄ particles with rich-Al on the surface were synthesized by one step solvothermal route. TEM results demonstrated that the surface of the obtained LiFePO₄ particles was well-covered by the amorphous coating. The soft X-ray absorption spectroscopy (XAS) and Auger electron spectroscopy (AES) component analyses revealed that the amorphous coating was composed of LiFe_1-xAl_xPO …

Controllable Synthesis Of Dispersed Spherical Fe3O4 Nanoparticles As Lithium-Inserted Materials, Hong-Li Zou, Wei-Shan Li

Journal of Electrochemistry

Dispersed spherical Fe₃O₄ nanoparticles were synthesized by a hydrothermal method. The influences of odecyl trimethyl ammonium bromide (DTAB) concentration on the morphology and particle size of the as-prepared Fe₃O₄ were studied. Electrochemical performance of the as-prepared sample as anode materials of lithium ion battery was investigated. It is found that the as-prepared sample exhibits superior rate performance and cycle performance. The nano-sized materials provide structural stability and favor the transfer of lithium ions.

Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-Feng Qian, Xue-Ping Gao, Han-Xi Yang

Journal of Electrochemistry

Oncoming large scale electric energy storage (EES) requires battery systems not only to have sufficient storage capacity but also to be cost-effective and environmentally friendly. Li-ion batteries for widespread EES applications may be limited due to the constraint of global lithium resource. From the considerations of available resources and environmental impact, Na-ion batteries have potential advantages as next generation secondary batteries and an alternative to Li-ion batteries. However, in the present state of the art, the Na-storage cathodes reported so far are still deficient both in energy density and power capability, while the carbon and alloy anodes for Na-ion batteries …

Application Of Synchrotron Radiation Based Electrochemical In-Situ Techniques To Study Of Electrode Materials For Lithium-Ion Batteries, Zheng-Liang Gong, Wei Zhang, Dong-Ping Lv, Xiao-Gang Hao, Wen Wen, Zheng Jiang, Yong Yang

Journal of Electrochemistry

Due to its merits of high brightness and high intensity, high level of polarization and wide tunability in energy, etc., synchrotron radiation technique provides an unique platform for analysis of the relationship among composition–structure–performance of materials for lithium ion batteries, especially for in-situ, real time dynamic investigation of the electrochemical reaction mechanism, aging process and failure mechanism during charge-discharge cycling. In this paper, we review the latest developments in application of synchrotron based electrochemical in-situ experimental methods to studies of lithium ion batteries. The paper mainly focuses on the application of electrochemical in-siu XRD and XAFS techniques to the investigations …

Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li

Journal of Electrochemistry

The amorphous ZnSnO₃@C composite was synthesized via a simple glucose hydrothermal and subsequent carbonization approach. The structure, morphology and electrochemical property of the composite were characterized by XRD, TEM and electrochemical measurements. Compared to bare ZnSnO₃, the ZnSnO₃/C composite exhibited markedly enhanced lithium storage property and cycle performance, delivering a reversible capacity of 659 mAh·g^-1 after 100 cycles at a current density of 100 mA·g^-1.

An Investigation On The Solid Electrolyte Interphase Of Silicon Anode For Li-Ion Batteries Through Force Curve Method, Jie-Yun Zheng, Hao Zheng, Rui Wang, Hong Li, Li-Quan Chen

Journal of Electrochemistry

Non-aqueous electrolyte has been widely used in commercial Li-ion batteries. Optimized choices are proceeding among the various types of salts and solvents in an effort to achieve higher performance of electrolyte. However, the electrolyte will be reduced in low potential and the reductive product will be deposited on the surface of anode to form a passivating layer, solid electrolyte interphase (SEI). Herein an atomic force microscopy (AFM) based method was introduced to study the structure and mechanical property of SEI on silicon thin film anode during the first cycle. Silicon has been known as the most potential candidate anode for …

Aqueous Solution-Evaporation Route Synthesis And Phase Structural Research Of The Li-Rich Cathode Li1.23Ni0.09Co0.12Mn0.56O2 By In-Situ Xrd, Chong-Heng Shen, Shou-Yu Shen, Zhou Lin, Xiao-Mei Zheng, Hang Su, Ling Huang, Jun-Tao Li, Shi-Gang Sun

Journal of Electrochemistry

The Li-rich Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ material was synthesized via aqueous solution-evaporation route. The structure and morphology of the material were characterized by means of XRD and SEM. The results indicated that the single particle of the product was polygonal with the size of 330 nm and the structure was layered solid solution with a certain amount of Li₂MnO₃. Electrochemical tests showed that the first discharge capacity of the Li-rich layered material was 250.8 mAh·g^-1 at 0.1C，the capacity retention was 86.5% after 40 cycles. Through in-situ XRD study a …

Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method, Jiao-Li Sun, Zhi-Jiao Chen, Yi-Xiao Li, Hu Cheng

Journal of Electrochemistry

Li2FeSiO4/C cathode material was synthesized using Li₂SiO₃ and FeC₂O₄ as raw materials by solid state method. The structure and morphology of the material were characterized by XRD and SEM. The electrochemical properties of the material were studied by constant-current cyclic testing. The results show that Li₂FeSiO₄/C has a good electrochemical performance. The first discharge capacity of Li₂FeSiO₄/C cathode material at 30oC reached 167 mAhg^-1 when cycled at 10 mAg^-1 between 1.5 and 4.8 V.

Preparation And Electrochemical Properties Of Flake-Like Liv3O8 By Soft Template Assisted Sol-Gel Method As Anode Material For Aqueous Li-Ion Battery, Shuai Tan, Dan Sun, Hai-Yan Wang, Tian-Li Hou, Zhong-Xing Xiao, You-Gen Tang

Journal of Electrochemistry

Anode material has become the key issue for restricting the development of aqueous lithium ion battery (ALIB). Flake-like LiV3O8 materials were synthesized by sol-gel method using sodium dodecyl benzene sulfonate (SDBS) as a template. The XRD and SEM results showed that as-prepared flake-like LiV₃O₈ was of high purity with monoclinic system and P21/m space group. LiMn₂O₄//Li₂SO₄//LiV₃O₈ ALIB was assembled and tested. As observed, the flake-like LiV3O8 here exhibited good high-rate performance and cycling stability. A high discharge capacity of 154 mAh.g^-1 (based on the mass …

Synthesis And Electrochemical Performance Of Nano Licopo4 By Polyol Method, Fei Wang, Yang Jun

Journal of Electrochemistry

High potential LiCoPO₄ cathode material was synthesized by polyol method. Carbon layer of ca. 3 nm thick was coated on the LiCoPO4 surfaces by chemical vapor deposition from methylbenzene. Crystalline structure, morphology and electrochemical performance of the sample were studied by XRD, SEM, TEM, CV and galvanostatic charge/discharge curve. The synthesized material via polyol method showed a pure phase of LiCoPO₄. The LiCoPO₄/C electrode delivered a high discharge capacity of 132 mAh·g^-1 and maintained 78% of the initial capacity after 50 cycles at 0.1C rate. The two-step extraction/insertion behavior of Li⁺ in LiCoPO4/C …

Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia

Journal of Electrochemistry

We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO4 from different sized FePO4 precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO₄/C are, respectively, 162 mAh·g^-1, 142 mAh·g^-1 and 92 mAh·g^-1 at 0.1C rate. The nano-sized LiFePO₄-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g^-1 even at 30C, while the macroscopic LiFePO₄-c/C (1 μm) exhibits a much poorer discharge …

Corrosion Behavior Of Zinc Covered With Thin Electrolyte Layers Under External Electric Field, Xu-Jie Yuan, Jun-Xi Zhang, Shi-Ming Zhang, Tian Tan, Qi-Meng Chen

Journal of Electrochemistry

The corrosion behavior of zinc covered with thin electrolyte layers (TELs) under an application of external electric field was investigated by performing corrosion potential and cathodic polarization current measurements. The results showed that the Ecorr and ic values first increased and then decreased with the increase of electrolyte layer thickness. Pure zinc exhibited the maximum corrosion potential as the TELs increased to 400 μm under the controls of cathodic process and corrosion products. The application of external electric field resulted in either a negative shift in corrosion potential of zinc or an increase of cathodic current. The effect of external …

Corrosion Behavior Of A High Strength Low Alloy Steel Under Hydrostatic Pressure In Deep Ocean, Hai-Jing Sun, Li Liu, Ying Li

Journal of Electrochemistry

The corrosion behavior of a high strength low alloy steel (HSLA steel) in 3.5% NaCl solution under hydrostatic pressure (HP) in deep ocean has been investigated by performing weight loss measurement, obtaining potentiodynamic polarization curve and emplying electrochemical impedance spectroscopy (EIS) using the set up for simulation of deep sea environment in laboratory. The results were compared with that at atmospheric pressure and the influence of HP was emphatically discussed. The results revealed identical corrosion mechanism for HSLA steel at 3.5 × 106 Pa and 1 × 105 Pa. Howevere, the development of such a corrosion process was remarkably accelerated …

Corrosion Resistance Of Low Pressure Cold Sprayed Al Coating On Q235 Steel In Seawater, Xiang-Bo Li, Li-Kun Xu, Shan-Guang Qiu, Jia Wang, Guo-Sheng Huang, Cai-Chang Dong

Journal of Electrochemistry

Taking aluminium (Al) powder mixed with 10% (by volume) of Al2O3 powder as raw materials, the Al coating was prepared on the Q235 carbon steel substrate using a portable low pressure cold spraying equipment. Through the measurements of the corrosion potential and potentiodynamic polarization, the electrochemical corrosion behavior of the low pressure cold sprayed Al coating in seawater was studied in comparison with those of the Al coatings deposited with high pressure cold spray and thermal spray processes. At the same time, the surface and cross-section morphologies of these coatings were observed with scanning electron microscope. The results showed that …

Preparation Of Benzoquinone From Phenol By Electrooxidation, Dong-Fang Niu, Cheng-Kai Yu, Xin-Sheng Zhang

Journal of Electrochemistry

The benzoquinone was prepared from phenol by electrooxidation in an H-type cell with cation exchange membrane, in which lead plates were used both as an anode and a cathode, while H₂SO₄ was used as a supporting electrolyte. The effects of current density, concentration of sulphuric acid, concentrations of benzoquinone in electrolyte and extractant on the yields and efficiencies of electrolysis were investigated. Under the optimized conditions of current density being 4 A·dm^-2, concentration of sulphuric acid 1 mol·L^-1, passed charge 3.2 A·h, the yield and current efficiency of benzoquinone could reach 68% and …

Experimental Design Methodology Applied To The Oxidation Of Quinolines In Aqueous Medium By Electro-Fenton Process, Souissi Souhaila Trabelsi, Nihal Oturan, Nizar Bellakhal, Mehmet A. Oturan

Journal of Electrochemistry

The degradation behavior of 8-hydroxyquinoleine sulfate (8-HQS), a model molecule of quinolines, was studied in an aqueous medium by electro-Fenton process using a carbon felt cathode and a platinum anode. The great oxidation ability of this process is due to a large production of hydroxyl radical (OH) by electrochemically induced Fenton’s reagent (H2O2, Fe2+). Hydroxyl radicals are very powerful oxidizing agents which react on organics up to complete mineralization. A factorial experimental design was used for determining the operating parameters on the degradation of 8-HQS in an aqueous medium. The results showed that the current intensity and the initial concentration …

Synthesis Of Pani/Nihcf Nanocomposite Particles And Eqcm Measurement Of Ion Exchange Properties In Solutions Containing Cd2+, Yu-Jiao Yang, Xiao-Gang Hao, Xu-Li Ma, Zhong-De Wang, Zhong-Lin Zhang, Nian-Chen Han

Journal of Electrochemistry

The PANI/NiHCF nanocomposite particles were synthesized on the CNTs-modified Pt substrate by one-step co-polymerization using cyclic voltammetry. Electrochemical quartz crystal microbalance (EQCM) technique was adopted to investigate the polymerization process of the nanocomposite particles and the mechanism of ion exchange in aqueous solution containing Cd²⁺． The morphology and structure of the as-prepared composite particles were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), and Fourier transform infrared spectroscopy (FT-IR). Combined with cyclic voltammetry (CV) and energy dispersive spectroscopy (EDS), the electrochemical behavior and the mechanism of ion exchange were also investigated in electrolytes of Cd^{2+ …}

Basic Principles And Applications Of Secm In Metal Corrosion, Fa-He Cao, Yan Xia, Wen-Juan Liu, Lin-Rong Chang, Jian-Qing Zhang

Journal of Electrochemistry

Scanning electrochemical microscopy (SECM) is chemical microscopy with higher spatial resolution. After 24 years of development, SECM has been widely applied in mapping and kinetics study of heterogeneous electron transfer in localized processes at solid-liquid or liquid-liquid interfaces. The fundamentals and recent advances of SECM in corrosion applications are described, including SECM mapping and kinetics on localized corrosion of metal or coating. Research work of SECM in corrosion by our group is also introduced. Future applications of SECM in corrosion are highlighted.

A Comparative Study In Pretreatments Of Acid Chemical Wastewater By Electrochemical Oxidation And Ozonation, Han-Shui Liu, Su Yu, Shao-Ping Tong, Chun-An Ma

Journal of Electrochemistry

Under the condition of keeping certain acidity, the pretreatment efficiency of an acid chemical wastewater (pH 0.85) by electrochemical oxidation was compared with that by ozonation. The results showed that the electrochemical oxidation pretreatment could obtain a better result than the ozonation at pH 0.85. After the addition of 2 g·L^-1 NaCl and with the electrochemical oxidation pretreatment at 30 mA·cm^-2, the removal rate of chemical oxygen demand (CODCr) reached 43.4%, and the value of biochemical oxygen demand/chemical oxygen demand (BOD₅/COD_Cr) also increased from 0.034 to 0.14 in 20 minutes, indicating significantly improvement …

Applications Of Spectroscopic Ellipsometry In Corrosion Investigation, Ling-Jie Li, Yu-Ling He, Jing-Lei Lei, Sheng Tao Zhang

Journal of Electrochemistry

As a highly-sensitive and non-destructive in situ technique, spectroscopic ellipsometry has been widely applied in corrosion investigation to acquire the dynamic information of the “electrode-medium” interface during corrosion. This paper lays out some representative demonstrations in several established optical models used to interpret data obtained with spectroscopic ellipsometry in corrosion investigation. In addition, the latest trends in development of this technique are analyzed.

Preparation Of Mesoporous Silica Supported Ruthenium Oxides And The Application And Kinetic Study In The Catalysis Of Water Oxidation, Yang Zhang

Open Access Dissertations

Photo-induced water splitting of water into H2 and O2 has been a major focus in the development of clean and renewable energy. The development of viable and efficient catalysts that facilitates O2 production remains the major challenge in the study of the corresponding half-reaction of water oxidation. There are plenty of metal oxides reported active in the catalysis of water oxidation. However, several important performance bench marks of those materials, such as the non-stoichiometric production of O2, slow reaction rate and/or low quantum efficiency, remain to be improved.

Ruthenium oxide (RuO2) has long been known as one of the most …

Advanced Treatment Of Dyeing Wastewater For Reuse By Electrochemical Oxidation, Fei-Xiang Chen, Chu-Yin Yang, Ming-Ming Zhou, Jia-De Wang

Journal of Electrochemistry

In response to the characteristics of dye wastewater, the electrochemical oxidation of effluents from the biochemical process of dyeing wastewater was studied in the electrochemical reactor using PbO₂/Ti electrode as the anode and stainless steel plate as the cathode. The results revealed that the electrochemical oxidation could simultaneously remove the Chemical Oxygen Demand (COD), ammonia and chromaticity. At the residence time of 60 min and current density of 10 mA·cm^-2, the COD, ammonia, chromaticity, concentration of chloride ion and pH values could meet the water standards for “the reuse of urban recycling water-water quality standard for …

Electrochemically Switched Ion Exchange Properties Of Pani-Snp Composite Films In Wastewater Containing Ni2+ And Cd2+, Yan-Ting Feng, Jun-Qiang Xiao, Xiao-Gang Hao, Xu-Li Ma, Zhong-De Wang, Nian-Chen Han

Journal of Electrochemistry

Electroactive PANI-SnP composite films were prepared by drop-coating method on Pt electrodes and investigated as electrochemically switched ion exchange (ESIX) materials for the separation of Cd²⁺ from aqueous solutions. The composition and morphology of the composite film were characterized by Fourier transform infrared spectrometer (FTIR) and scanning electron microscope (SEM). In solutions containing 0.1 mol·L^-1 Ni(NO₃)₂ and Cd(NO₃)₂, cyclic voltammetry (CV) and electrochemical quartz crystal microbalance (EQCM) were used to investigate the electrochemical behavior and ion-exchange mechanism of PANI-SnP composite film. The elementary composition of PANI-SnP composite films in both oxidation …

Research Progress Of Intermediate Layers In Ti-Based Oxide Anodes, Xiu-Li Song, Hui-Min Yang, Zhen-Hai Liang

Journal of Electrochemistry

Titanium (Ti)-based oxide anodes are excellent anode materials which have been applied widely in electrochemical fields all over the world. Adding intermediate layers in Ti-based oxide anodes can improve the conductivity, lengthen the lifetime and strengthen the stability between Ti base and metal oxides active layers of electrodes. This article reviews the research progress of intermediate layers in Ti-based oxide anodes. At the same time, current problems existed in the field of Ti-based oxide anodes are pointed out and future development trend in oxide electrode with intermediate layers is prospected.

Using Hydrolyzed Sludge Liquor As The Substrate Of Microbial Fuel Cell, Liang Peng, Guo Chao, Huang Xia

Journal of Electrochemistry

Hydrolyzed sludge liquor was used as the substrate of microbial fuel cell. When the thermal treatment time increased from 2 h to 96 h, pH varied little between 7.4 and 8.0. When the treatment time increased, the conductivity, COD and alkaline condition increased to 2.53 mS·cm^-1, 2520 mg·L^-1 and 800 mg·L^-1, respectively. Meanwhile, the power density increased to 25 W·m^-3. The COD removal increased firstly, then decreased, and finally reached the maximum of 47% at the hydrolyzed time of 6 h. The maximal coulombic efficiency was 71% when the treatment time was 4 …

Electrosynthesis Of Glycerol Carbonate From Co2 And Glycerol, Huan Wang, Mei-Xia Zhu, La-Xia Wu, Xiao-Ming Xu, Xue-Ru Zhao, Jia-Xing Lu

Journal of Electrochemistry

Glycerol carbonate was obtained from glycerol and carbon dioxide under room temperature and normal pressure by electrochemical method. The effects of synthesis conditions, such as cathode, charge, current density and temperature, on the reaction of glycerol and carbon dioxide have been investigated. The yields of 73% were produced by electrosynthesis of carbonate under the optimized condition, which is much higher than that by common catalysis method. The electrochemical behavior of the reaction system has been studied by cyclic voltammetry, through which the reaction process has been proposed.

Effects Of Fluoroethylene Carbonate Additive On Low Temperature Performance Of Li-Ion Batteries, Feng-Ju Bian, Zhong-Ru Zhang, Yong Yang

Journal of Electrochemistry

The effects of fluoroethylene carbonate (FEC) on the low temperature performance of lithium ion phosphate full battery are evaluated by different techniques. By addition of 5 wt% FEC into a commercial electrolyte, effective solid electrolyte interface (SEI) film can be formed on the graphite electrodes, the discharge capacity retention at -40 ^oC was increased from 31.7% to 43.7%, and the discharge voltage plateau of the cell is raised. This is attributed to a reduced charge transfer resistance and a lowered polarization on the graphite electrode by electrochemical impedance spectroscopy (EIS) and reference electrode test.

Electrochemical Behavior And Content Determination Of Paeonol At Poly Sudan Ⅲ Modified Electrode, Yan-Jie Zheng, Ai-Lin Liu, Yun Lei, Xin-Hua Lin

Journal of Electrochemistry

The poly SudanⅢ modified electrode was characterized by electrochemical impedance spectroscopy（EIS）and cyclic voltammetry (CV), while the electrochemical behavior of paeonol was studied by cyclic voltammetry (CV). The result shows that the poly Sudan Ⅲ modified electrode exhibits excellent electrocatalytic effect on the oxidation of paeonol. The peak currents of differential pulse voltammetry are linear to the paeonol concentrations over the range of 3.0*10^-7 ~ 2.2*10^-5 mol·L^-1. The detection limit has been estimated to be 5.0*10^-8 mol·L^-1. This method can be used for determination of paeonol content in real sample with satisfactory results.