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Corrosion

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Full-Text Articles in Civil Engineering

The Influence Of Bio-Inhibitor On The Corrosion Resistance Of Reinforced Concrete Beams Containing Mswi-Ba As A Partial Sand Replacement, Jamal Khatib, Israa Amer, Ghanem Hassan, Adel Elkordi Jun 2023

The Influence Of Bio-Inhibitor On The Corrosion Resistance Of Reinforced Concrete Beams Containing Mswi-Ba As A Partial Sand Replacement, Jamal Khatib, Israa Amer, Ghanem Hassan, Adel Elkordi

BAU Journal - Science and Technology

In this paper, the corrosion behavior of reinforced concrete beams containing municipal solid waste incineration bottom ash (MSWI-BA) as a partial sand replacement and Ceratonia siliqua extract as a green corrosion inhibitor was investigated. Four mixes were prepared: (0 and 20% replacement of sand by MSWI-BA with and without Ceratonia siliqua extract). Tests conducted were UPV, compressive strength, split tensile strength, and elastic modulus. RC beams were prepared for determining the flexural performance. Eight beams were casted. Four beams were exposed to accelerated corrosion test and four beams were kept at room temperature. It was found that the compressive strength, …


Revised Load Rating Procedures For Deteriorated Prestressed Concrete Beams, Alex Stripsky, Sergio F. Brena, Jessica Boakye, Scott A. Civjan, Simos Gerasimidis Jan 2023

Revised Load Rating Procedures For Deteriorated Prestressed Concrete Beams, Alex Stripsky, Sergio F. Brena, Jessica Boakye, Scott A. Civjan, Simos Gerasimidis

Structural Engineering and Mechanics Research Reports

The first prestressed concrete bridge in the United States was built in the early 1950s. Since then, several typical sections have been developed for use in bridge construction including I-beams, deck slabs, box beams, double tees, etc. In bridges under aggressive environments, corrosion deterioration of prestressing strands and stirrups has occurred creating challenges associated with determining the strength of deteriorated existing bridge sections. The MassDOT LRFD Bridge Manual includes provisions to estimate strength of corrosion deteriorated prestressed concrete box beams allowing engineers to calculate the load rating of these types of bridges. The provisions are based on the observed condition …


Impedance Analysis Of Anodized Aluminum And Structural Bridge Tendons, Justin Silnutzer Jun 2022

Impedance Analysis Of Anodized Aluminum And Structural Bridge Tendons, Justin Silnutzer

USF Tampa Graduate Theses and Dissertations

This is a two-part thesis with the overall investigation technique being electrochemical impedance spectroscopy (EIS). In the first part, EIS is used to estimate the layer thickness of anodized aluminum oxide. This required the development of an appropriate electrical circuit model; that with parameters that correspond to physical properties of the oxide. In this work, it was found that for thicker oxides of which the outer porous layer is greater than 12 microns, impedance may be used to estimate the outer layer thickness. However, further research is required to understand the role of outer porous layer structure on the impedance …


A Novel Probabilistic Framework Of Rc Corroded Structures Under Dynamic Loading, Rawan Mouin Mashmoushy Eng., Wael Slika, Adel Elkordi Jun 2021

A Novel Probabilistic Framework Of Rc Corroded Structures Under Dynamic Loading, Rawan Mouin Mashmoushy Eng., Wael Slika, Adel Elkordi

BAU Journal - Science and Technology

Steel corrosion in reinforced concrete structures can lead to severe deterioration damage under static and seismic loads. In practice, it is essential to mitigate failure risk by quantifying the extent of damage and simulating the structural response of damaged structures. However, numerical modeling of the dynamic behavior of corroded structure is challenging due to high nonlinearity of the problem and its multidisciplinary nature. In addition, corrosion damage exhibits various sources of uncertainty that impede accurate deterministic modeling of the dynamic response of RC structures. Therefore, this study presents a simplified framework, to simulate the non-linear response of corroded structures under …


Probabilistic Prediction Model For Rc Bond Failure Mode, Ahmad Soraghi, Qindan Huang Apr 2021

Probabilistic Prediction Model For Rc Bond Failure Mode, Ahmad Soraghi, Qindan Huang

Civil and Environmental Engineering Faculty Research and Publications

Adequate rebar-concrete bonding is crucial to ensure the reliable performance of reinforced concrete (RC) structures. Many factors such as the concrete properties, concrete cover depth, transverse reinforcement, and the presence of corrosion will affect the bond behavior, and consequently, the structural performance. While many prior studies have focused on the influence of the aforementioned factors on the bond strength, the impact of these factors on the bond failure mode has not been thoroughly investigated. A probabilistic bond failure mode prediction model that considers various influencing factors including loading type and corrosion is developed in this study. This study uses the …


Rapid Cross-Section Imaging With Magnetic And Impedance Sensors For Grout Anomaly Detection In External Post-Tensioned Tendons, Hani Freij Apr 2020

Rapid Cross-Section Imaging With Magnetic And Impedance Sensors For Grout Anomaly Detection In External Post-Tensioned Tendons, Hani Freij

USF Tampa Graduate Theses and Dissertations

Post-tensioned (PT) bridges have had severe corrosion issues with tendons that fail suddenly without prior notice. The corrosion of external post-tensioned tendons has been associated with grout deficiencies/anomalies from inadequate grouting. Deficiencies include voids, regions of chalky low strength grout, and regions where excessive water content or even free water is present. In those zones mechanical bonding of strand to the grout is degraded and, of more concern, the strand steel risks corrosion failure reducing the expected lifespan of the structure. As tendons are critical structural components, it is important to detect those deficiencies during inspection preferably by a cross …


Relating Surface Resistivity To Corrosion Of Rebar Embedded In Portland Cement Concrete, Luisa Alejandra Morales Jan 2020

Relating Surface Resistivity To Corrosion Of Rebar Embedded In Portland Cement Concrete, Luisa Alejandra Morales

Open Access Theses & Dissertations

Reinforced concrete is widely used as a construction material known for its durability and proficiency of withstanding large forces in severe environments. Despite that the majority of these structures result in long-term performance, there is still a large number of failures of reinforced concrete structures as a result in corrosion of the reinforcement and concrete degradation. It is critical to assess the state of the corroded structure to decide on whether maintaining or replacing the structure is needed. The objective of this study is to characterize a relationship between the steel reinforcement corrosion and the concrete's resistivity. It is widely …


Strengthening Of Corroded Steel Structures Using Cfrp – An Experimental Review, Ghada El-Mahdy Ph.D., P.Eng, Abdallah H. Yassin, Abdel El Rahman Khaled Dec 2019

Strengthening Of Corroded Steel Structures Using Cfrp – An Experimental Review, Ghada El-Mahdy Ph.D., P.Eng, Abdallah H. Yassin, Abdel El Rahman Khaled

Civil Engineering

Fibre reinforced polymers (FRP) have been widely used to strengthen reinforced concrete structures, however, nowadays their use to strengthen steel structures is under investigation. In particular, the need to strengthen corroded steel structures found in aggressive environments, such as marine environments, which have undergone a reduction in cross-sectional area and hence a reduction in their load-carrying capacity is in need of studying. The main problems that arise when using carbon fibre reinforced polymer (CFRP) sheets to strengthen steel structures is the weakness in the interfacial bond between the CFRP and the steel surface, the thinness of CFRP sheet, and the …


Application Of Bayesian Networks To Integrity Management Of Energy Pipelines, Wei Xiang Dec 2019

Application Of Bayesian Networks To Integrity Management Of Energy Pipelines, Wei Xiang

Electronic Thesis and Dissertation Repository

Metal-loss corrosion and third-party damage (TPD) are the leading threats to the integrity of buried oil and natural gas pipelines. This thesis employs Bayesian networks (BNs) and non-parametric Bayesian networks (NPBNs) to deal with four issues with regard to the reliability-based management program of corrosion and TPD. The first study integrates the quantification of measurement errors of the ILI tools, corrosion growth modeling and reliability analysis in a single dynamic Bayesian network (DBN) model, and employs the parameter learning technique to learn the parameters of the DBN model from the ILI-reported and filed-measured corrosion depths. The second study develops the …


Integrated Sensor Network For Monitoring Steel Corrosion In Concrete Structures, José Enrique Ramón-Zamora, José Manuel Gandia-Romero, Román Bataller, Ana Martínez-Ibernón, Isabel Gasch, Juan Soto Nov 2019

Integrated Sensor Network For Monitoring Steel Corrosion In Concrete Structures, José Enrique Ramón-Zamora, José Manuel Gandia-Romero, Román Bataller, Ana Martínez-Ibernón, Isabel Gasch, Juan Soto

International Conference on Durability of Concrete Structures

The developed Integrated Sensor Network (ISN) allows a non-destructive monitoring of the rebar condition at different parts of the structure. The corrosion sensor allows the accurate determination of the corrosion rate (µm/year). Moreover, additional sensors are integrated in order to detect relevant changes in the concrete electrochemical condition.

The ISN has been published as an international invention patent (reference number WO 2016/177929 A1). The system is based on an economic, simple, reliable and durable technology, which makes its implementation viable on new and repaired reinforced concrete structures (RCS). Therefore, it is also possible monitoring non-accessible parts such as deep foundations …


Micro-Mechanical Analysis Of Corrosion Products Formed During Long-Term Carbonation Induced Corrosion Of Steel, Marijana Serdar, Dubravka Bjegovic, Valérie L’Hostis, Stéphane Poyet, Damien Féron Nov 2019

Micro-Mechanical Analysis Of Corrosion Products Formed During Long-Term Carbonation Induced Corrosion Of Steel, Marijana Serdar, Dubravka Bjegovic, Valérie L’Hostis, Stéphane Poyet, Damien Féron

International Conference on Durability of Concrete Structures

During corrosion distinct types of corrosion products form, composed of different ratios of ferrous ions and oxide, hydroxides. Corrosion products have different physical and mechanical properties, mainly density, resistivity, volume and modulus of elasticity compared to iron. Knowing properties of corrosion products is indispensable for service life modelling of structures and can give valuable insight into the long-term corrosion propagation process. In this study micro-indentation method was used to evaluate mechanical properties of different layers formed during long-term carbonation induced corrosion of steel in concrete. Investigation was performed on three sets of reinforced concrete samples, that underwent corrosion during 50, …


Comparison Data Between Hybrid And Galvanic Anode Installation In The Arousa Island Bridge, José Antonio Becerra Mosquera, Diego Carro López, José Enrique Pardo Landrove, José Manuel Millán Pérez Nov 2019

Comparison Data Between Hybrid And Galvanic Anode Installation In The Arousa Island Bridge, José Antonio Becerra Mosquera, Diego Carro López, José Enrique Pardo Landrove, José Manuel Millán Pérez

International Conference on Durability of Concrete Structures

The Arousa Island Bridge, with its 1980 m is the only road access to the Arousa Island. Built in 1985, this single-cell box girder divided in 40 spans runs entirely on the sea. The deck is between 2 to 12 m above sea level, so after 25 years in a marine environment, the structure showed reinforcement corrosion, especially in piles and deck bottom. Attending to the corrosion damages, caused simply from a chloride attack, the local government decided to intervene with an ambitious repair project. This decision has been taken only after an exhaustive cost analysis to determine the feasibility …


Effect Of Time-Dependent Chloride Profile And Temperature Variation On Chloride Diffusion In Concrete, Feras Alsheet, A. Ghani Razaqpur Nov 2019

Effect Of Time-Dependent Chloride Profile And Temperature Variation On Chloride Diffusion In Concrete, Feras Alsheet, A. Ghani Razaqpur

International Conference on Durability of Concrete Structures

Reinforcement corrosion due to chlorides diffusion is one of the main problems in reinforced concrete structures exposed to certain environments. The diffusion rate is function of chloride surface concentration, concrete temperature, humidity, composition and microstructure. The intruded chlorides are partially chemically bound by the concrete and it is the unbound or free chloride which upon exceeding a defined threshold initiates corrosion. The time to corrosion initiation depends on the above variables; therefore, it is important to model their spatial and temporal variations in a manner that will yield a realistic estimate of the actual initiation period. In this study, the …


Durability Design Of Segmental Linings For Intended Service Life Of Tunnels, Mehdi Bakhshi, Verya Nasri Nov 2019

Durability Design Of Segmental Linings For Intended Service Life Of Tunnels, Mehdi Bakhshi, Verya Nasri

International Conference on Durability of Concrete Structures

In one-pass lining systems, the durability of tunnel structure is directly related to durability of concrete segments acting as both the initial support and the tunnel final lining. In this paper, most-frequent degradation mechanisms of concrete linings are discussed including chloride- and carbonation- induced corrosions, sulfate, acid and freeze-and-thaw attacks, and alkali-aggregate reactions. Mitigation method for each specific degradation mechanism is explained. A durability factor specific to railway and subway tunnel known as stray current corrosion is presented. Mitigation methods for this specific corrosion together with coupling effects with other conventional damage mechanisms are explained. Prescriptive approaches for durability design …


Sustainable Concrete With Seawater And Corrosion Resistant Reinforcement: Results Of Monitoring Of Corrosion Behaviour, Elena Redaelli, Maddalena Carsana, Federica Lollini, Matteo Gastaldi, Forood Torabian Isfahani Nov 2019

Sustainable Concrete With Seawater And Corrosion Resistant Reinforcement: Results Of Monitoring Of Corrosion Behaviour, Elena Redaelli, Maddalena Carsana, Federica Lollini, Matteo Gastaldi, Forood Torabian Isfahani

International Conference on Durability of Concrete Structures

The use of seawater for mixing concrete for reinforced concrete structures is prohibited, since it can promote steel corrosion. However, the use of seawater would contribute to decrease the environmental impact of concrete, in particular in those regions of the world where potable water is a precious resource. The project SEACON-INFRAVATION between University of Miami and Politecnico di Milano, with various industrial partners, aims at investigating the use of seawater for the construction of sustainable and durable reinforced concrete structures and infrastructures. Within the project, that included a vast campaign of laboratory tests, also two demo projects – one in …


Corrosion Durability Of A Nano-Particle Enriched Zinc-Rich Coating System For Highway Steel Bridges, Saiada Fuadi Fancy Nov 2019

Corrosion Durability Of A Nano-Particle Enriched Zinc-Rich Coating System For Highway Steel Bridges, Saiada Fuadi Fancy

FIU Electronic Theses and Dissertations

Corrosion is a major concern for the long-term durability and structural integrity of steel components of highway bridges when unprotected. The application of protective coatings has been widely used for corrosion mitigation of atmospherically exposed structural steel. At present, the zinc-rich primer (ZRP) based three-coat system is widely used in the United States. The metallic zinc pigment ideally would provide corrosion resistance by sacrificial as well as barrier protection. The life of these coating systems is at best only half of the bridge design life. Furthermore, premature degradation may occur if there are flaws in the system due to improper …


The Influence Of Incorporation Of Mn On The Pitting Corrosion Performance Of Crfeconi High Entropy Alloy At Different Temperatures, H. Torbati-Sarraf, Mitra Shabani, Paul D. Jablonski, Garrett J. Pataky, A. Poursaee Aug 2019

The Influence Of Incorporation Of Mn On The Pitting Corrosion Performance Of Crfeconi High Entropy Alloy At Different Temperatures, H. Torbati-Sarraf, Mitra Shabani, Paul D. Jablonski, Garrett J. Pataky, A. Poursaee

Publications

The electrochemical behavior and susceptibility to pitting corrosion of CrFeCoNi and CrMnFeCoNi high entropy alloys were studied in a 0.1 M NaCl solution at temperatures ranging from 25 to 75 °C. Electrochemical measurements revealed that CrMnFeCoNi is more susceptible to oxide film breakdown and localized corrosion compared to CrFeCoNi. Post corrosion microscopic observations showed severe pitting corrosion for CrMnFeCoNi in higher temperatures compared to CrFeCoNi. Based on in-depth XPS profile measurements on the remaining oxide films, this behavior was attributed to the depletion of Cr in the oxide film and detrimental presence of Mn in the matrix solid solution of …


Retrofitting Of Bridge Elements Subjected To Predominantly Axial Load Using Uhpc Shell, Mahsa Farzad Apr 2019

Retrofitting Of Bridge Elements Subjected To Predominantly Axial Load Using Uhpc Shell, Mahsa Farzad

FIU Electronic Theses and Dissertations

In the United States, ~30% of the ~600,000 highway bridges are categorized as structurally deficient or functionally obsolete. These bridges should be replaced or upgraded to sustain the transportation needs of the growing public and private sectors of the U.S. economy. It is not uncommon for structures to have advanced levels of corrosion-induced damage where major repair and maintenance works are required. However, the transportation infrastructure may undergo disruption during rehabilitation causing interruption to critical economic public, civil and commercial activities. This mandates the development of new techniques and materials for accelerated rehabilitation and resilience. To address this issue, a …


Sustainability-Based Long-Term Management Of Bridges Under Multi-Hazard Exposure, Mohamed Soliman Dec 2018

Sustainability-Based Long-Term Management Of Bridges Under Multi-Hazard Exposure, Mohamed Soliman

Data

Corresponding data set for Tran-SET Project No. 17STOKS01. Abstract of the final report is stated below for reference:

"Bridges are under deterioration due to various mechanical and environmental stressors. Hydraulic-related hazards (e.g., flood and scour), aggressive environmental conditions, and seismic events (e.g., earthquake) are recognized as the most significant threats to the safety of bridges. In traditional risk assessment methods for structures susceptible to damage due to floods and other natural hazards (e.g., corrosion and seismic events), future hazard predictions are conducted using historic return periods and climate records. However, recent increase in flood intensity in central-southern states indicate that …


Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla Dec 2018

Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla

Data

Corresponding data set for Tran-SET Project No. 17CLSU08. Abstract of the final report is stated below for reference:

"Reinforced Concrete (RC) structures are vital to the US’s civil infrastructure for their strength and versatility. Unfortunately, RC elements deteriorate rapidly when exposed to corrosive environments. One possible solution is to extend the life of RC elements and systems using microencapsulated corrosion inhibitors to reduce the rebar corrosion rate. The capsules house an anodic corrosion inhibitor agent including calcium nitrate (CN) and triethanolamine (TEA). The integration of such microencapsulated materials will enhance the durability and extend the useful life by controlling the …


Sustainability-Based Long-Term Management Of Bridges Under Multi-Hazard Exposure, Mohamed Soliman Nov 2018

Sustainability-Based Long-Term Management Of Bridges Under Multi-Hazard Exposure, Mohamed Soliman

Publications

Bridges are under deterioration due to various mechanical and environmental stressors. Hydraulic-related hazards (e.g., flood and scour), aggressive environmental conditions, and seismic events (e.g., earthquake) are recognized as the most significant threats to the safety of bridges. In traditional risk assessment methods for structures susceptible to damage due to floods and other natural hazards (e.g., corrosion and seismic events), future hazard predictions are conducted using historic return periods and climate records. However, recent increase in flood intensity in central-southern states indicate that future hazard occurrence rate may not necessarily follow past trends. Accordingly, current design, assessment, and management methodologies should …


Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla Nov 2018

Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla

Publications

Reinforced Concrete (RC) structures are vital to the US’s civil infrastructure for their strength and versatility. Unfortunately, RC elements deteriorate rapidly when exposed to corrosive environments. One possible solution is to extend the life of RC elements and systems using microencapsulated corrosion inhibitors to reduce the rebar corrosion rate. The capsules house an anodic corrosion inhibitor agent including calcium nitrate (CN) and triethanolamine (TEA). The integration of such microencapsulated materials will enhance the durability and extend the useful life by controlling the corrosion precursors and the corrosion process during damage evolution. Therefore, this work aims to develop and characterize the …


Spatial Delineation Of Corrosion Zones For Metal Culverts Based On Coastal Louisiana Soil Characteristics, Sanjay Tewari, Francis Manning Jan 2018

Spatial Delineation Of Corrosion Zones For Metal Culverts Based On Coastal Louisiana Soil Characteristics, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Corrosion of metal pipes used as culverts is a problem that affect many agencies directly involved in designing and maintaining these culverts. The corrosive environment of soil types found in a region could vary in a significant way (mildly corrosive to extremely corrosive) based on soil characteristics. Environmental conditions such as high water table, acidity and presence of various salts could make a soil corrosive to metal pipes. In this article, authors have applied a methodology of processing readily available soil data such as spatial distribution of soil types and soil characteristics (e.g. pH and conductivity) in delineating spatial corrosion …


Detection Of Buried Non-Metallic (Plastic And Frp Composite) Pipes Using Gpr And Irt, Jonas Kavi Jan 2018

Detection Of Buried Non-Metallic (Plastic And Frp Composite) Pipes Using Gpr And Irt, Jonas Kavi

Graduate Theses, Dissertations, and Problem Reports

This research investigated alternative strategies for making buried non-metallic pipes (CFRP, GFRP, and PVC) easily locatable using Ground Penetrating Radar (GPR). Pipe diameters up to 12" and buried with up to 4 ft. of soil cover were investigated. The findings of this study will help address the detection problem of non-metallic pipelines and speed the adoption of composite pipes by the petroleum and natural gas industry. The research also investigated the possibility of locating buried pipes transporting hot fluids using Infrared Thermography (IRT).

Results from the study have shown that, using carbon fabric and aluminum tape overlay on non‑metallic pipes …


Assessing Corrosivity Of Galvanized Soil Reinforcements From Electrochemical Tests, Diana Alejandra Cabrera Jan 2018

Assessing Corrosivity Of Galvanized Soil Reinforcements From Electrochemical Tests, Diana Alejandra Cabrera

Open Access Theses & Dissertations

The accurate estimation of the service lives of mechanically stabilized earth (MSE) walls requires a proper evaluation of the corrosion potential through electrochemical test methods. Robust field tests are required to assess the corrosivity of galvanized metal used in MSE walls. To simulate an environment similar to an MSE wall, cylindrical soil specimens about 12 in. (300 mm) in diameter and 10 in. (250 mm) in height were constructed. For every specimen, two instruments were used. The first instrument measured the polarization resistance corrosion tests carried out on galvanized strips and meshes, as well as epoxy-coated rebars. The second instrument …


Evaluation Of Orthophosphate Based Corrosion Inhibitors In Treated Water For El Paso Region, Francisco Solis Jr Jan 2018

Evaluation Of Orthophosphate Based Corrosion Inhibitors In Treated Water For El Paso Region, Francisco Solis Jr

Open Access Theses & Dissertations

Corrosion is an electrochemical phenomenon that involves the deterioration of a metal by the reaction of itself with its surrounding environment. One of the greatest issues for water utilities around the country is to keep the water quality safe. Corrosion can affect the quality of the water that we use on a daily basis by adding a bad taste, increasing the concentration of heavy metals, and allowing outside contaminants to enter the distribution system. The use of phosphate based corrosion inhibitors was tested in two different metals: iron and copper. The phosphate in the inhibitors react with the calcium in …


Corrosion Map For Metal Pipes In Coastal Louisiana, Sanjay Tewari Jun 2017

Corrosion Map For Metal Pipes In Coastal Louisiana, Sanjay Tewari

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table, and saltwater intrusion).

This project was focused on applying available soil data, such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity), towards creating a Geographic Information System (GIS) based map to identify corrosion zones in coastal Louisiana. The effect of the soil characteristics (pH and conductivity) was incorporated in to the published corrosion models for calculating …


Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel Apr 2017

Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel

Makara Journal of Technology

Development of fuel cladding and structural materials in Pb-Bi environment, especially at high temperature, is a critical issue for the deployment of LFR (Lead alloy-cooled Fast Reactor) and ADS (Accelerator Driven Transmutation System). This is because of the corrosive characteristic of Pb-Bi to metals as constituent materials of fuel cladding and structural of the reactors. Corrosion test of a high-chromium austenitic stainless steel i.e. SS316Ti in molten Pb-Bi at 550 ºC has been carried out for about 300 hours continuously. The characterization using SEM-EDS (Scanning Electron Microscopy - Energy Dispersive X-ray Spectroscopy) showed that an iron oxide as the outer …


Mechanism Of Cathodic Prevention Of Carbon Steel In Concrete, Krittin Rattakham Mar 2017

Mechanism Of Cathodic Prevention Of Carbon Steel In Concrete, Krittin Rattakham

USF Tampa Graduate Theses and Dissertations

In this work, I aim to clarify the mechanism that allows steel to attain higher chloride threshold as it is cathodically polarized. Specifically, I seek to provide empirical information on whether an intrinsic (predominantly interfacial effects of polarization) or an extrinsic (predominantly concentration changes due to polarization) mechanism may be dominant in the beneficial effect of polarization. I carried out this experiment with 12 identical concrete specimens, each with a cast-in steel plate, constantly exposed them to high-chloride environment. The specimens were divided into 4 triplicates and polarized at 4 different level from OCP, -200, -300 to -400 mVSCE …


Corrosion Degradation Mechanism Of Cbpc Coating System For Highway Bridge Steel Components, Md Ahsan Sabbir Mar 2017

Corrosion Degradation Mechanism Of Cbpc Coating System For Highway Bridge Steel Components, Md Ahsan Sabbir

FIU Electronic Theses and Dissertations

Coatings are widely used to mitigate corrosion of structural steel in aggressive humid environments. However, the service life is often diminished in aggressive environments. Repair of coatings can be costly due to materials, labor and environmental controls. So, in search for novel coatings, Chemically Bonded Phosphate Ceramic (CBPC) coating was investigated for marine bridge application. The research on CBPC coating considered various exposure environments such as inland, beach, salt-fog, wet and alternate wet and dry exposure to identify the degradation mechanism. To assess the corrosion damage, the coating was evaluated by visual inspection, thickness, adhesion, microscopy and X-ray diffraction.

The …