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Full-Text Articles in Membrane Science

Phase-Field Modeling Of The Polymer Membrane Formation Process For Micro- And Ultra-Filtration, Michael Rosario Cervellere Jul 2021

Phase-Field Modeling Of The Polymer Membrane Formation Process For Micro- And Ultra-Filtration, Michael Rosario Cervellere

Graduate Theses and Dissertations

Porous polymer membrane filters are widely used in separation and filtration process. Micro- and ultra-filtration membranes are commonly used in biopharmaceutical applications such as filtering viruses and separating proteins from a carrier solution. The formation of these membrane filters via phase inversion is a complex and interconnected process where varying casting conditions can have a wide variety of effects on the final membrane morphol- ogy. Tailoring membrane filters for specific performance characteristics is a tedious and time consuming process. The time and length scales of membrane formation make it extremely difficult to experimentally observe membrane formation. Modeling the membrane formation …


Investigation Of Membrane Based Processes For Biomedical Applications, Efecan Pakkaner Jul 2021

Investigation Of Membrane Based Processes For Biomedical Applications, Efecan Pakkaner

Graduate Theses and Dissertations

As substantial developments were achieved in nanotechnology and polymer engineering, especially in the last few decades, the use of membranes and membrane-based procedures was found to be expanding into more and more research and development areas; including biological engineering, life sciences and biomedical engineering. Not only have they been the main focus of meaningful research, but they have also been the main pieces of the solutions to very thorny problems encountered within a wide range of applications from microfluidics to water treatment, thanks to their versatility, cost-effectiveness and biocompatibility, when compared to conventional separation techniques. To celebrate and embrace these …


Capturing Ultrasmall Emt Zeolite From Template-Free Systems, Eng-Poh Ng Dr. Jan 2012

Capturing Ultrasmall Emt Zeolite From Template-Free Systems, Eng-Poh Ng Dr.

Eng-Poh Ng

No abstract provided.


Discrete Mnalpo-5 Nanocrystals Synthesized By An Ionothermal Approach, Eng-Poh Ng, Satpal Singh Sekhon, Svetlana Mintova Jan 2009

Discrete Mnalpo-5 Nanocrystals Synthesized By An Ionothermal Approach, Eng-Poh Ng, Satpal Singh Sekhon, Svetlana Mintova

Eng-Poh Ng

Discrete MnAlPO-5 nanocrystals with monomodal particle size distribution (diameter of 80 nm) were synthesized using an ionothermal technique; the pore filling effect of the ionic liquid molecules during the synthesis of microporous nanocrystals is verified.


Selective Capture Of Water Using Microporous Adsorbents To Increase The Lifetime Of Lubricants, Eng-Poh Ng, Luc Delmotte, Svetlana Mintova Jan 2009

Selective Capture Of Water Using Microporous Adsorbents To Increase The Lifetime Of Lubricants, Eng-Poh Ng, Luc Delmotte, Svetlana Mintova

Eng-Poh Ng

Eco-recycling towards an increase of the lifetime of lubricating mineral oil by selective capturing of water with nanosized microporous aluminophosphate and aluminosilicate materials is reported. Quantitative water measurements of oxidized lubricating oil before and after treatment with microporous materials were carried out by FT-IR spectroscopy combined with Karl Fischer titration method. The high selectivity of the nanosized aluminophosphate to water without adsorbing other additives in comparison to nanosized aluminosilicates that are adsorbing altogether polar oxidation products, ionic additives and water are revealed. A removal of nearly 98 % of moisture from the lubricating oil at ambient condition is achieved, which …


Nanoporous Materials With Enhanced Hydrophilicity And High Water Capacity, Eng-Poh Ng, Svetlana Mintova Sep 2008

Nanoporous Materials With Enhanced Hydrophilicity And High Water Capacity, Eng-Poh Ng, Svetlana Mintova

Eng-Poh Ng

The main types of nanoporous adsorbents for water are identified and described with emphasis on the mechanism of adsorption, modification, improvement of the water sorption capacity, possible regeneration, and stabilization. Among the three main groups of water sorbents, i.e. inorganic materials (zeolites, clays, silica), carbon based materials and organic polymers, the first one is described in details. The significance of their porosity, chemical and structural features relative to the water adsorptive properties of each inorganic type materials is reviewed. Important features for silicates, zeolites, aluminophosphates, mesoporous materials and clays are described, which define the interactions between the water and the …


Alpo-18 Seed Layers And Films By Secondary Growth, Lubomira Tosheva, Eng-Poh Ng, Svetlana Mintova, Manfred Holzl, Till H. Metzger, Aidan M. Doyle Jan 2008

Alpo-18 Seed Layers And Films By Secondary Growth, Lubomira Tosheva, Eng-Poh Ng, Svetlana Mintova, Manfred Holzl, Till H. Metzger, Aidan M. Doyle

Eng-Poh Ng

AlPO-18 layers were prepared on Si wafers via spin-coating or the Langmuir−Blodgett (LB) method using nanosized crystals. Multilayers were deposited by spin-coating, whereas the seeds assembled by the LB technique were monolayers. The seeded layers were not stable upon secondary growth under microwave radiation, and no films were formed on the supports. Dense AlPO-18 films could be obtained by secondary growth after stabilization of the seed layers by adding prehydrolyzed tetraethylorthosilicate (TEOS) to the colloidal AlPO-18 suspension prior to support seeding. The stabilized seed layers and the grown AlPO-18 films were stable. The structure and the morphology of the films …


Environmentally Benign Synthesis Of Nanosized Aluminophosphate Enhanced By Microwave Heating, Eng-Poh Ng, Luc Delmotte, Svetlana Mintova Dec 2007

Environmentally Benign Synthesis Of Nanosized Aluminophosphate Enhanced By Microwave Heating, Eng-Poh Ng, Luc Delmotte, Svetlana Mintova

Eng-Poh Ng

The problem addressed with our paper is on the efficient utilization of reacting materials for enhanced syntheses of nanosized aluminophosphate molecular sieve by microwave heating, and decreasing or almost eliminating the related waste. The synthesis procedure deals with the environmental issues concerning the future manufacture re-use and disposal of non-reacted chemicals associated with the production of nanosized aluminophosphate. Nanosized AlPO-18 has been prepared by a multicycle synthesis approach via re-using non-reacted compounds from precursor suspensions with minimal requirement of chemical compensation after recovering of crystalline nanoparticles from each step. This approach is implied as environmentally benign and results in almost …


What More In Nanosized Molecular Sieves, Eng-Poh Ng, Gerardo Majano, Louwanda Lakiss, Svetlana Mintova Jan 2007

What More In Nanosized Molecular Sieves, Eng-Poh Ng, Gerardo Majano, Louwanda Lakiss, Svetlana Mintova

Eng-Poh Ng

No abstract provided.


Sulphated Almcm-41: Mesoporous Solid Brønsted Acid Catalyst For Dibenzoylation Of Biphenyl, Eng-Poh Ng, Hadi Nur, Mohd Nazlan Mohd Muhid, Halimaton Hamdan Jan 2006

Sulphated Almcm-41: Mesoporous Solid Brønsted Acid Catalyst For Dibenzoylation Of Biphenyl, Eng-Poh Ng, Hadi Nur, Mohd Nazlan Mohd Muhid, Halimaton Hamdan

Eng-Poh Ng

Sulphated mesoporous solid Brønsted acid catalyst (SO4-AlMCM-41) was prepared by impregnation of sulphuric acid on the surface of H-AlMCM-41. Characterization of SO4-AlMCM-41 by pyridine adsorption studies and 27Al MAS NMR showed that the presence of Brønsted acidity was correlated with octahedrally coordinated aluminium and solvent environment. Catalytic study demonstrated that the SO4-AlMCM-41 catalyst has a higher activity in the dibenzoylation of biphenyl with benzoyl chloride than sulphuric acid, H-AlMCM-41 and sulphated amorphous silica.