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Catalysis and Reaction Engineering Commons™
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- Formaldehyde (5)
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- Acetylene alcohols (4)
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- Phenylacetylene (3)
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Articles 31 - 38 of 38
Full-Text Articles in Catalysis and Reaction Engineering
The Study Of The Component Composition Of The Reaction Mixture Containing Formaldehyde Reaction Products, Hurramov Lochinbek, Alimukhamedova Nozima, Adilov Ravshan, Alimukhamedov Muzafar
The Study Of The Component Composition Of The Reaction Mixture Containing Formaldehyde Reaction Products, Hurramov Lochinbek, Alimukhamedova Nozima, Adilov Ravshan, Alimukhamedov Muzafar
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of this work is to study the effect of the conditions of the reaction of monoethanolamine (Meol) with formaldehyde (FD) on the composition of the reaction mixture. Interaction of monoethanolamine with formaldehyde leads to the formation of N,N’,N”-tris(β-oxyethyl) hexahydro-S-triazine or N,N-bisoxazolidine. The type of final product was determined by the conditions of the reaction and the molar ratio of aminoalcohol:formaldehyde. The chromatogram of the vacuum-distilled final product obtained at the molar ratio of monoethanolamine:formaldehyde=1:1 shows on an individual compound with a retention time of 4.173 s. With increase in the molar ratio of monoethanolamine:formaldehyde=1: 2, the final product …
Influence Of Conditions For Alcoholysis Of Secondary Polyethylene Terephthalate On The Output Of Bis (Hydroxyethyl) Terephthalate, Abduvokhidov Iqboljon, Jurayev Asror, Alimukhamedov Muzafar, Magrupov Farkhad
Influence Of Conditions For Alcoholysis Of Secondary Polyethylene Terephthalate On The Output Of Bis (Hydroxyethyl) Terephthalate, Abduvokhidov Iqboljon, Jurayev Asror, Alimukhamedov Muzafar, Magrupov Farkhad
CHEMISTRY AND CHEMICAL ENGINEERING
The paper presents the results of a study of the process of alcoholysis of secondary polyethylene terephthalate ethylene glycol (EG). The main attention is paid to determining the optimal conditions for the formation of bis-hydroxy ethylene terephthalate, since this product is an intermediate in the production of polyethylene terephthalate. At the same time, the effects of the duration of alcoholysis, the type and amount of catalyst on the yield of bis-hydroxy ethylene terephthalate (ratio of PET: EG = 1 mol elementary link 4 mol) were studied. Changing the duration of alcoholysis from 8 to 10 hours, the type and amount …
Research On The Process Of Obtaining Industrial Important From Wheat Straw, Kedelbayev Bakhytzhan, Rakhmanberdiev Gaffar, Lahanova Kulzada, Kalymbetov Gani
Research On The Process Of Obtaining Industrial Important From Wheat Straw, Kedelbayev Bakhytzhan, Rakhmanberdiev Gaffar, Lahanova Kulzada, Kalymbetov Gani
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of this work was to develop a process of chemical hydrolytic hydrogenation of cellulose wheat straw, with the aim of increasing the yield of valuable products necessary for the biotechnology, pharmaceutical and chemical indus-tries. To obtain cellulose wheat straw carried out the process of auto hydrolysis. Studies have been conducted to study the process of chemical hydrolytic hydrolysis and hydrogenation of cellulose from rice processing waste, and optimal process parameters have been developed. As a result, we have implemented a combined (hybrid) hydrolysis-hydrogenation process for producing sorbitol. Developed catalysts for this process, investigated their activity. The influence of …
Synthesis And Study Of The Products Of The Interaction Of Diethanolamine And Aldehyde., Magrupov Farkhad Asadullayevich, Alimukhamedov Muzaffar Ganiyevich, Adilov Irkinovich, Khudoyberdiev Akhmadali
Synthesis And Study Of The Products Of The Interaction Of Diethanolamine And Aldehyde., Magrupov Farkhad Asadullayevich, Alimukhamedov Muzaffar Ganiyevich, Adilov Irkinovich, Khudoyberdiev Akhmadali
CHEMISTRY AND CHEMICAL ENGINEERING
The influence of the nature of aldehydes of the structure of the products of their interaction with diethanolamine was studied. It was found that the interaction of one mole of diethanolamine with one mole of aldehyde produces 2-substituted 1,3- oxosolidines. Moreover, hydroxylase-containing compounds are formed at molar ratios of diethanolamine: aldehyde = 2: 1 mol / mol. By carrying out the reaction of the interaction of diethanolamine with an aldehyde at their molar ratios of 2: 1 mol / mol, hydroxylase-containing compounds containing two tertiary nitrogen and four hydroxyl groups in their structure were synthesized. The exothermic effect of the …
Synthesis Of Pyridine Bases And Application As Corrosion Inhibitors, Sarsenbaev Nurlan Tenelbayevich, Kadirov Xasan Irgashevich
Synthesis Of Pyridine Bases And Application As Corrosion Inhibitors, Sarsenbaev Nurlan Tenelbayevich, Kadirov Xasan Irgashevich
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of this work was to obtain corrosion inhibitors. It has been established that heterocyclic compounds, including pyridine and its derivatives, are more frequently used as the active component in the combination of modern inhibitors of carrosion The catalytic reaction of obtaining pyridine and its derivatives by passing a mixture of acetaldehyde and formalin with ammonia was studied. By modifying the mixture of the obtained pyridine bases with urotropine, acrylic emulsion, thiourea, copper salts, etc., compositions are obtained that can serve as inhibitors of hydrochloric acid treatment.
Influence Of Conditions For Alcoholysis Of Secondary Polyethylene Terephthalate On The Output Of Bis (Hydroxyethyl) Terephthalate, Abduvokhidov Iqboljon, Jurayev Asror, Alimukhamedov Muzafar, Magrupov Farkhad
Influence Of Conditions For Alcoholysis Of Secondary Polyethylene Terephthalate On The Output Of Bis (Hydroxyethyl) Terephthalate, Abduvokhidov Iqboljon, Jurayev Asror, Alimukhamedov Muzafar, Magrupov Farkhad
CHEMISTRY AND CHEMICAL ENGINEERING
The paper presents the results of a study of the process of alcoholysis of secondary polyethylene terephthalate ethylene glycol (EG). The main attention is paid to determining the optimal conditions for the formation of bis-hydroxy ethylene terephthalate, since this product is an intermediate in the production of polyethylene terephthalate. At the same time, the effects of the duration of alcoholysis, the type and amount of catalyst on the yield of bis-hydroxy ethylene terephthalate (ratio of PET: EG = 1 mol elementary link 4 mol) were studied. Changing the duration of alcoholysis from 8 to 10 hours, the type and amount …
Alkinylation Reactions Of Benzaldehyde By Ethynylbenzene In The Presence Of Some Catalysts, Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvakhab, Dobrynkin Nikolay
Alkinylation Reactions Of Benzaldehyde By Ethynylbenzene In The Presence Of Some Catalysts, Abdurakhmanova Saida, Ziyadullaev Odiljon, Ikramov Abduvakhab, Dobrynkin Nikolay
CHEMISTRY AND CHEMICAL ENGINEERING
The synthesis of acetylene alcohol 1,3-diphenyl propin-2-ol-1, which has several reaction centers in the molecule, is studied. This product was obtained for the first time from a representative of aromatic hydrocarbons of benzaldehyde with phenylacetylene based on an alkynylation reaction in the presence of stereoselective catalysts - ZnEt2/Ti(OiPr)4/PhMe and Sn(OTf)2/NEt3/MeCN. The influence of the activity, stability, and selectivity of the selected catalysts on the yield of products, as well as, the rate of the main reactions, along with side reactions was analyzed. The optimal conditions for the alkynylation reaction and the selectivity of the process are determined. The main and …
Influence Of Nanostructural Catalyst In The Synthesis Of Allyl Phenyl Ether And Of Its Isomerization Products, Musaev Khusniddin, Azimova Gulmira, Tajimukhammedov Khabibulla, Yuldasheva Мukhabbat
Influence Of Nanostructural Catalyst In The Synthesis Of Allyl Phenyl Ether And Of Its Isomerization Products, Musaev Khusniddin, Azimova Gulmira, Tajimukhammedov Khabibulla, Yuldasheva Мukhabbat
CHEMISTRY AND CHEMICAL ENGINEERING
Attention to 2-allylphenol (2-AF) and its synthesis is due by the fact that this compound is the starting material for the production of a number of biologically active natural compounds, such as synthetic fungicide. A number of recent publications have shown the high activity of zeolite, rhodium, iridium, and ruthenium catalysts in allylation reactions. The lack of these catalysts is their high cost. Therefore, the use of new effective and inexpensive catalysts in the reactions of synthesis and isomerization of allyl phenyl ether is important problem. The aim of this work is the selective synthesis of o-allylphenols in the isomerization …