Engineering Commons^™

Synthesis And Molecular Transport Studies In Zeolites And Nanoporous Membranes, Vivek Vattipalli

Doctoral Dissertations

The advent of nanoporous materials such as zeolites and nanoporous membranes has provided cost-effective solutions to some of the most pressing problems of the 20^th century such as the conversion of crude oil into fuels and valuable chemicals. Hierarchical zeolites and mesoporous inorganic membranes are showing great promise in addressing new problems such as the conversion of biomass into value-added chemicals and development of energy-efficient separation processes. The synthesis and fundamental aspects of molecular transport in these new materials with hierarchical porosities need to be better understood in order to rationally develop them for these desired applications. Pore narrowing …

Development Of Functional Biomaterials Using Protein Building Blocks, Li-Sheng Wang

Doctoral Dissertations

Proteins have intrinsic molecular properties that are highly useful for materials applications, especially for biomaterials. My research has focused on translating these molecular properties to materials surface behavior. In one approach, I developed a fluorous-based thermal treatment strategy to generate stable thin films from a variety of naturally abundant proteins. The different surface properties generated from the choice of protein were utilized to modulate cell-surface interactions, prevent bacterial adhesions, and control drug loading/release. I have used nanoimprint lithography to generate patterned protein films for cell alignment. Coupling with inkjet printing deposition, I have fabricated mixed protein films with spatial and …

Chemical Stability And Performance Influence Of Choice Substituents And Core Conjugation Of Organic Semiconductors, Jack Ly

Doctoral Dissertations

Realizing organic based active materials for electronic devices, such as thin film transistors and photovoltaics, has been long sought after. Advancement in the field driven by chemists, engineers, and physicists alike have bolstered organic based semiconductor performance levels to rival those of traditional inorganic amorphous silicon-based devices. Within the field of organic semiconductors (OSC), two categories of active materials may be generalized: (1) polymer and (2) small molecule semiconductors. Each class of OSC inherently have their own advantages and disadvantages. Polymer semiconductors (PSC) allow a wide range in tunability via choice monomers and side chain engineering to illicit desirable energy …

Building The Outer Membrane Protein G (Ompg) Nanopore Library: From The Discrimination Of Biotin-Binding Proteins In Serum To Resolving Human Carbonic Anhydrase From Human Red Blood Cells, Bib Yang

Doctoral Dissertations

The use of pore-forming proteins (PFPs) in nanopore sensing has been fruitful largely due to their nanoscale size and the ease with which protein nanopores can be manipulated and consistently reproduced at a large scale. Nanopore sensing relies heavily on a steady ionic current afforded by rigid nanopores, as the change in current is indicative of analyte detection, revealing characteristics of the analyte such as its relative size, concentration, and charge, as well as the nanopore:analyte interaction. Rigid PFPs have been used in applications such as DNA sequencing, kinetic studies, analyte discrimination, and protein conformation dynamics at the single-molecule level. …

Modeling Temporal Structures In Time-Varying Networks, Kun Tu

Doctoral Dissertations

A dynamic network is a network whose structure changes because of the emergence and disappearance of node or edges. It can be used to study complex systems where individuals in a system are represented as nodes and their relations/interactions are represented as edges. Studying dynamic network structures helps to better understand changes in relationships. Considerable work has been conducted on learning network structure. However, due to the complexity of dynamic networks, there is considerable room for improvement to obtain better analysis results. This thesis studies different aspects of characteristic and dynamics of a network, focusing on their application in link …

Direct Patterning Of Nature-Inspired Surfaces For Biointerfacial Applications, Feyza Dundar

Doctoral Dissertations

There are three major challenges for the design of patterned surfaces for biointerfacial applications: (i) durability of antibacterial/antifouling mechanisms, (ii) mechanical durability, and (iii) lifetime of the master mold for mass production of patterned surfaces. In this dissertation, we describe our contribution for the development of each of these challenges. The bioinspired surface, Sharklet AF^TM, has been shown to reduce bacterial attachment via a biocide-free structure-property relationship effectively. Unfortunately, the effectiveness of polymer-based sharkskin surfaces is challenged over the long term by both eventual bacteria accumulation and a lack of mechanical durability. To address these common modes of …

Direct Printing Of Conductive Inks For Organic Electronics And Wearable Microfluidics, Aditi Naik

Doctoral Dissertations

This dissertation examines the direct printing of conductive inks on polymeric substrates for applications in organic electronics, microfluidic valving systems, and wearable sweat sensors. The inexpensive production of solution-based electrodes with high electrical conductivity is necessary to enable the next-generation of printed, flexible, and organic electronics. Specifically, the optimization and printing of liquid-phase graphene ink and nanoparticle-based silver ink by soft nanoimprint lithography and inkjet-printing is discussed to achieve printed functional devices. Using scalable low-cost patterning systems, these flexible applications are compatible with roll-to-roll processing, enabling large-scale manufacturing. This research expands the knowledge of high-resolution printing optimization for the direct …

The Investigation Of Surface Barrier During Molecular Transport In Hierarchical Zeolites, Xiaoduo Qi

Doctoral Dissertations

Hierarchical zeolites with micropore lengths on the order of nanometers have been synthesized with the aim of reducing mass transfer limitation. However, due to large external surface to volume ratios, the mass transport in these materials can be hindered by a secondary rate limitation step imposed on the external surface of the zeolites. This has led to the general phenomenon referred to as “surface barriers”, which cause the enhancement in mass transport being far lower than expected. In order to fully unlock the potential of hierarchical zeolites, it is imperative to fundamentally understand the molecular transport in these new types …

Modeling And Optimizing Routing Decisions For Travelers And On-Demand Service Providers, Xinlian Yu

Doctoral Dissertations

This thesis investigates the dynamic routing decisions for individual travelers and on-demand service providers (e.g., regular taxis, Uber, Lyft, etc). For individual travelers, this thesis models and predicts route choice at two time-scales: the day-to-day and within-day. For day-to-day route choice, methodological development and empirical evidences are presented to understand the roles of learning, inertia and real-time travel information on route choices in a highly disrupted network based on data from a laboratory competitive route choice game. The learning of routing policies instead of simple paths is modeled when real-time travel information is available, where a routing policy is defined …

A Multiline Anchor Concept For Floating Offshore Wind Turbines, Casey Fontana

Doctoral Dissertations

Floating offshore wind turbines (FOWTs) hold great potential for the renewable energy industry, but capital costs remain high. In efforts to increase FOWT substructure efficiency and reduce costs, this thesis investigates a novel multiline anchor concept in which FOWTs share anchors instead of being moored separately. The goal of this thesis is to evaluate the force dynamics, design, and potential cost reduction of the system. Anchor forces are simulated using the NREL 5 MW reference turbine and OC4-DeepCwind semisubmersible platform, and multiline anchor force is computed as the vector sum of the contributing mooring line tensions. The use of a …

Sequence Design Via Semidefinite Programming Relaxation And Randomized Projection, Dian Mo

Doctoral Dissertations

Wideband is a booming technology in the field of wireless communications. The receivers in wideband communication systems are expected to cover a very wide spectrum and adaptively extract the parts of interest. The literature has focused on mixing the input spectrum to baseband using a pseudorandom sequence modulation and recovering the received signals from linearly independent measurements by parallel branches to mitigate the pressures from required extreme high sampling frequency. However, a pseudorandom sequence provides no rejection for the strong interferers received together with weak signals from distant sources. The interferers cause significant distortion due to the nonlinearity of the …

Applications Of Machine Learning Methods In Macroscopic Crash Analysis For Transportation Safety Management, Somaye Garmroudi Dovirani

Doctoral Dissertations

Transportation Safety Planning (TSP) is a statewide-scale tool and combines transportation planning processes with safety aims to increase safety and reduce transportation fatalities and injuries. Traffic safety, which continues to remain a critical issue worldwide, has led to a myriad of modeling techniques to improve analytical capabilities with respect to crash modeling and prediction. State and metropolitan transportation planning processes must be consistent with Strategic Highway Safety Plans. This research aims to identify models and methods to improve the ability to capture variables that have the most significant impact on traffic safety through crash prediction modeling. In order to achieve …

Energy Efficiency Of Computation In All-Spin Logic: Projections And Fundamental Limits, Zongya Chen

Masters Theses

Built with nanomagnets, a spintronic device called the all-spin logic (ASL) device carries information with only spin currents, resulting in a low power supply--10 mV. This voltage is 100 times smaller than the conventional CMOS devices (usually 0.8~1V). The potential for improved energy efficiency made possible by the low operating voltage of ASL makes it one of the most promising devices among its post-CMOS competitors.

The basic working principles of ASL device are introduced in this thesis and two complementary approaches to studying energy efficiency of computation are applied to a common set of ASL circuits: (1) a circuit simulation …

Thermodynamic And Economic Analysis Of Several Hybrid Multigeneration Cycles And Waste Heat Recovery Systems Driven By Concentrated Solar Tower, Kasra Mohammadi

Doctoral Dissertations

In recent decades, growth in the world population, economic and living standards have been responsible for substantial increases in global energy consumption. Moreover, exploitation of fossil fuels to supply energy demands has led to global climate change, which is expected to have far-reaching and long-lasting consequences on the planet. These factors have motivated the importance and necessity of developing more efficient ways for energy conservation and generation that avoid the production of greenhouse gases that contribute to climate change. One method to address these issues is to develop combined production such as multigeneration for simultaneous production of electricity, cooling, fresh …

Fundamental Limits Of Covert Communication In Packet Channels, Ramin Soltani

Doctoral Dissertations

This dissertation focuses on covert communication in channels where the communication takes place by the transmission of packets. Consider a channel where authorized transmitter Jack sends packets to authorized receiver Steve according to a Poisson process with rate $\lambda$ packets per second for a time period $T$. Jack's transmitted packet visit Alice, Willie, Bob and Steve, respectively. Suppose that covert transmitter Alice wishes to communicate information to covert receiver Bob without being detected by a watchful adversary Willie. We consider three sets of assumptions for this channel. For each set of assumptions, we present a technique for establishing covert communication …

Application Of Ground Penetrating Radar For Use In Thermal Conductivity Site Investigations, Aaron J. Rubin

Doctoral Dissertations

Measurement of soil thermal conductivity in-situ is important for many practical geotechnical and civil engineering applications. However, for a variety of reasons it can be difficult to measure in-situ. A novel method to estimate the thermal conductivity of sands based on electrical relative permittivity (dielectric constant) measurements and GPR data is presented. First, an analytical model to estimate thermal conductivity of soils was developed and validated using a database of thermal conductivity measurements. The new thermal conductivity model was then compared to existing models using a larger database of new and pervious thermal conductivity measurements conducted on a wide range …

Analysis Of Adhesive Anchorage Systems Under Extreme In-Service Temperature Conditions, Rachel Wang

Masters Theses

Adhesive anchorage systems have found widespread use in structural applications, including bridge widening, concrete repair and rehabilitation, and barrier retrofitting. Because these applications typically require adhesive anchorage systems to be installed outdoors, the effects of climate conditions and day-to-day temperature fluctuations on adhesive behavior and performance should be considered. The purpose of this thesis is to simulate pullout tests of adhesive anchorage systems for threaded rod and reinforcing bars and to emulate effects under various temperature conditions through the use of finite element analysis. Results from the finite element simulation are then compared to the physical tests conducted at UMass …

Ammonia Production From A Non-Grid Connected Floating Offshore Wind-Farm: A System-Level Techno-Economic Review, Vismay V. Parmar

Masters Theses

According to U.S. Department of Energy, offshore wind energy has the potential to generate 7,200 TWh of energy annually, which is nearly twice the current annual energy consumption in the United States. With technical advances in the offshore wind industry, particularly in the floating platforms, windfarms are pushing further into the ocean. This creates new engineering challenges for transmission of energy from offshore site to onshore. One possible solution is to convert the energy produced into chemical energy of ammonia, which was investigated by Dr. Eric Morgan. In his doctoral dissertation, he assessed the technical requirements and economics of a …

Performance Of Concrete Tunnel Systems Subject To Fault Displacement, Michael Morano

Masters Theses

A Finite Element Analysis (FEA) investigation of concrete tunnel systems traversing seismic faults is carried out to determine how to effectively mitigate the stresses induced in the liner when subject to fault displacement. A parametric study of various fault parameters, both in the damage zone and competent rock, is carried out to determine the site conditions which induce the most stress on the tunnel liner system. Results indicate that friction angle, cohesion, and elastic modulus of fault zones have varying effects on the stresses induced on the liner. The width of damage zone and expected displacements are also investigated and …

Insar Simulations For Swot And Dual Frequency Processing For Topographic Measurements, Gerard Masalias Huguet

Masters Theses

In Earth remote sensing precise characterization of the backscatter coefficient is important to extract valuable information about the observed target. A system that eliminates platform motion during near-nadir airborne observations is presented in this thesis, showing an improvement on the accuracy of measurements for a Ka- band scatterometer previously developed at Microwave Remote Sensing Laboratory (MIRSL). These very same results are used to simulate the reflectivity of such targets as seen from a spaceborne radar and estimate height errors based on mission-specific geometry. Finally, data collected from a dual-frequency airborne interferometer com- prised by the Ka-band system and an S-band …

High Fidelity Modeling Of Cold-Formed Steel Single Lap Shear Screw Fastened Connections, Rita Kalo

Masters Theses

Cold-formed steel connections are commonly fastened using self-tapping self-drilling screws. The behavior of these connections can differ based on the screw manufacturer or the cold-formed steel product used, both of which have a large selection available for use in industry. Because of their popularity and the many possible variations of these connections, researchers have frequently tested screw connections to characterize their behavior. However, repeatedly conducting this type of experiment is time consuming and expensive. Therefore, the purpose of this work was to create finite element models that can successfully predict the behavior of single lap shear screw connections, a common …

The Evacuation Problem In Multi-Story Buildings, Quang Hong Cung

Masters Theses

The pressure from high population density leads to the creation of high-rise structures within urban areas. Consequently, the design of facilities which confront the challenges of emergency evacuation from high-rise buildings become a complex concern. This paper proposes an embedded program which combines a deterministic (GMAFLAD) and stochastic model (M/G/C/C State Dependent Queueing model) into one program, GMAF_MGCC, to solve an evacuation problem. An evacuation problem belongs to Quadratic Assignment Problem (QAP) class which will be formulated as a Quadratic Set Packing model (QSP) including the random flow out of the building and the random pairwise traffic flow among activities. …