Engineering Commons^™

Layer-By-Layer Assembled Membranes With Immobilized Porins, Sebastián Hernández, Cassandra Porter, Xinyi Zhang, Yinan Wei, Dibakar Bhattacharyya

Chemical and Materials Engineering Faculty Publications

New and advanced opportunities are arising for the synthesis and functionalization of membranes with selective separation, reactivity, and stimuli-responsive behavior. One such advancement is the integration of bio-based channels in membrane technologies. By a layer-by-layer (LbL) assembly of polyelectrolytes, outer membrane protein F trimers (OmpF) or “porins” from Escherichia coli with central pores ∼2 nm in diameter at their opening and ∼0.7 × 1.1 nm at their constricted region are immobilized within the pores of poly(vinylidene fluoride) microfiltration membranes, in contrast to traditional ruptured lipid bilayer or vesicle processes. These OmpF-membranes demonstrate selective rejection of non-charged organics over ionic solutes, …

Cellulose Nanofiber-Reinforced Impact Modified Polypropylene: Assessing Material Properties From Fused Layer Modeling And Injection Molding Processing, Jordan Elliott Sanders

Electronic Theses and Dissertations

The purpose of this research was to investigate the use of cellulose nanofibers (CNF) compounded into an impact modified polypropylene (IMPP) matrix. A IMPP was used because it shrinks less than a PP homopolymer during FLM processing. An assessment of material properties from fused layer modeling (FLM), an additive manufacturing (AM) method, and injection molding (IM) was conducted. Results showed that material property measurements in neat PP were statistically similar between IM and FLM for density, strain at yield and flexural stiffness. Additionally, PP plus the coupling agent maleic anhydride (MA) showed statistically similar results in comparison of IM and …

Heterogeneous Anisotropy Index And Scaling In Multiphase Random Polycrystals, Muhammad Ridwan Murshed

Theses and Dissertations

Under consideration is the finite-size scaling of elastic properties in single and two-phase random polycrystals with individual grains belonging to any crystal class (from cubic to triclinic). These polycrystals are generated by Voronoi tessellations with varying grain sizes and volume fractions. By employing variational principles in elasticity, we introduce the notion of a 'Heterogeneous Anisotropy Index' and investigate its role in the scaling of elastic properties at finite mesoscales. The index turns out to be a function of 43 variables, 21 independent components for each phase and the volume fraction of either phase. Furthermore, the relationship between Heterogeneous Anisotropy Index …

Synthesis And Characterization Of Thermoresponsive Hydrogels Based On N-Isopropylacrylamide Crosslinked With 4,4′-Dihydroxybiphenyl Diacrylate, Shuo Tang, Martha Floy, Rohit Bhandari, Manjula Sunkara, Andrew J. Morris, Thomas D. Dziubla, J. Zach Hilt

Chemical and Materials Engineering Faculty Publications

A novel crosslinker [4,4′-dihydroxybiphenyl diacrylate (44BDA)] was developed, and a series of temperature-responsive hydrogels were synthesized through free radical polymerization of N-isopropylacrylamide (NIPAAm) with 44BDA. The temperature-responsive behavior of the resulting gels was characterized by swelling studies, and the lower critical solution temperature (LCST) of the hydrogels was characterized through differential scanning calorimetry. Increased content of 44BDA led to a decreased swelling ratio and shifted the LCST to lower temperatures. These novel hydrogels also displayed resiliency through multiple swelling–deswelling cycles, and their temperature responsiveness was reversible. The successful synthesis of NIPAAm-based hydrogels crosslinked with 44BDA has led to a …

Experimental Study On Automatic Control For Collision Avoidance Of Ships, Daeng Paroka, Muhammad Fahmi Kamil, Andi Haris Muhammad

Makara Journal of Technology

Automatic control system is widely applied to control the ship direction or heading angle in accordance with the decided trajectory. Several methods for improving performance of control system have been developed such as Proportional-Integral-Derivative (PID) control and fuzzy logic based control. Within the last decade, application of automatic control system is not only for ship navigation but also for avoiding collision risk of ships in seaways. This paper discusses the application of automatic control system for avoiding ship collision by free running experiment. Fuzzy logic based control was developed using Mamdani Centroid method to estimate the necessary rudder angle in …

Innovation Of Hydrocarbon Investigation Using Audio-Magnetotelluric In Cepu Field, Indonesia, Iqbal Fauzi Aditama, Widodo Widodo

Makara Journal of Technology

An audio-magnetotelluric (AMT) survey has been performed at Cepu oil field located in Indonesia. The objective of this research is to detect resistivity structures of this important hydrocarbon rock. This research can be classified as an innovation in application of the AMT method for hydrocarbon exploration. The lack of seismic resolution has been provided by the AMT method, especially in the location of sub-basalt and sub-salt plays. In additional, the cost of AMT survey is quite low compared to seismic. The forward modelling is included in this research to understand the measurement data response from a mathematical model. In the …

Adsorption Of Cu(Ii) Ions In Aqueous Solution Onto Limonia Acidissima Shellbased Activated Carbon: Kinetic And Isotherm Studies, Abrar Muslim, Syahiddin Dahlan Said, Gita Suci Hariati, Siti Fajar Karina, Fauzi Muhammad Djuned, Rizka Mulyawan

Makara Journal of Technology

Adsorption of Cu(II) ions from aqueous solution using activated carbon prepared from Limonia acidissima fruit shell (LAFS-AC) was conducted in batch mode experiments at pH 5 (±0.15), 100 rpm and 1 atm. The effects of contact time, initial Cu(II) ions concentration, KOH concentration, and adsorption temperature on Cu(II) ions adsorption capacity were investigated. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy analyses were performed to investigate the active site and surface morphology of the LAFS-AC, respectively. The Cu(II) ions adsorption was fitted very well (R2 = 0.94 on average) to the pseudo second-order adsorption kinetic with the adsorption capacity and …

Experimental Study Of The Chimney Height Variation Against Double Pots Biomass Stove Performance, Faisal Faisal, Adi Setiawan, Wusnah Wusnah, Khairil Khairil, Luthfi Luthfi, Mona Fajriana

Makara Journal of Technology

This research aims to get optimal chimneys height of double pots biomass stove. Optimal chimneys height needs to provide best performance of the stove. Experimental study was done by varied the chimney heights. Water boiling test as the standard method was used to obtained stove performance for each chimney height variation. The results showed that best performance stove was the one with 1.65 cm chimney height, with thermal efficiency at 37.66%.

Indonesia’S Municipal Solid Waste 3r And Waste To Energy Programs, Farizal Farizal, Radityo Aji, Amar Rachman, Nasruddin Nasruddin, Teuku Meurah Indra Mahlia

Makara Journal of Technology

Like most cities in the world, population in Indonesia continues to grow every year. Problems that can arise from this are the increasing amount of municipal solid waste (MSW) production and the growing demand for electricity. To deal with the problems, Indonesian government runs 3R (Reduce, Reuse and Recycle) and WTE (Waste to Energy) Programs simultaneously. 3R program aims to reduce the number of waste, while WTE program aims to generate electricity as an alternative energy source. This study aims to find out the optimal proportion of MSW treated through the 3R and WTE programs. For the purpose, a goal …

Energy Potentials Of Briquette Produced From Tannery Solid Waste, Olatunde Ajani Oyelaran, Faralu Muhammed Sani, Olawale Monsur Sanusi, Olusegun Balogun, Adeyinka Okeowo Fagbemigun

Makara Journal of Technology

The vast quantity of waste generated from industries is one of the serious outcomes of unplanned development, resulting into quantum of hazardous organic and inorganic waste generating daily. Proper waste management is a challenging issue that must be addressed adequately. This is, therefore, carried out with a view of assessing the energy and combustion quality of tannery solid waste with a view of converting them into briquettes for cooking, heating and small home industries and reducing the menace caused by tannery waste disposal. The results of the experiments showed that the combustion rate ranged between 0.171 and 0.217 g/min, the …

Study On Semiconductor Properties Of Acetylide-Thiourea Fabricated Onto Interdigitated Electrodes (Ides) Platform Towards Application In Gas Sensing Technology, Adibah Izzati Daud, Wan M. Khairul, M. I. N. Isa, Khairul Anuar Abdul Wahid

Makara Journal of Technology

In the past few decades, the unique properties of acetylide and thiourea moieties individually have attracted great attention from researchers in various fields to be developed in numerous applications in advanced materials technology, especially as an active layer in gas sensing devices. The molecular systems of acetylide and thiourea provide a wide range of electronic properties as they possess rigid π-systems in their designated structures. In this study, a derivative of acetylide-thiourea featuring N-(4[4-aminophenyl] ethynyl benzonitrile)-N’-(4-ethyl benzoyl) thiourea (TCN) has been synthesised with the general formula of ArC(O)NHC(S)NHC≡C)Ar adopted the system of D-π-A for the significant development of conductive materials. …

Assessment On Heck-Immine Derivatives As Organic Semiconductor Materials, Rafizah Rahamathullah, Lim Keemi, Wan M. Khairul

Makara Journal of Technology

This paper reports the synthetic, characterization and theoretical evaluation of new class of hybrid Heck-immine system involving mixed moieties of vinylene (C=C) and azomethines (CH=N) which has been successfully integrated into an addition of organic semiconducting materials. The assessment of 4-[(hexyloxyphenyl)methylene]amino)-4’-chloro-stilbene (HEXCS) based on Donor (D)-π-Acceptor (A) was evaluated as active semiconductor material candidates via several spectroscopic and analytical techniques. In turn, the investigation of its potential as dopant system in conductive film was successfully deposited on indium tin oxide (ITO) coated substrate via spin coating method. The relationship between electronic and optical properties, chemical modelling at molecular interactions and …

Novel Fission Track Detection For Identification And Characterization Of Special Nuclear Materials, Jonathan Allen Gill

Doctoral Dissertations

Fission track detection and analysis is used primarily in nuclear safeguards to identify special nuclear material. Identification of isotopic ratios is a crucial step in understanding the intended use of nuclear material and the nature of the materials production cycle. Unfortunately, this methodology uses etchable track detectors that require significant expertise and intensive labor to process.

This study developed a novel method using lithium fluoride (LiF) as a fluorescing nuclear track detector to conduct fission track analysis for isotopic prediction of uranium enrichment. Individual latent tracks produced by fission products were observed in LiF for the first time. These tracks …

Development Of High-Performing Polydimethylsiloxane-Based Membranes For Carbon Dioxide Separation, Tao Hong

Doctoral Dissertations

Membrane separation is highlighted as one of the most promising approaches to mitigate the excessive CO₂ [carbon dioxide] emission, due to its significant reduction of energy cost compared with many conventional separation techniques. Unfortunately, the separation performance of current membranes does not meet the practical CO₂/N₂ [nitrogen] separation requirements. And due to the huge volume of industrial flue gas, membranes with exceptionally high permeability are needed for practical reasons.

Currently, the separation mechanism of most polymeric membranes is based on size-sieving. However, this method is not sufficient for CO₂/N₂ separations due to the …

Low Energy Recoil Simulations In Mgo, Linbo3, And Litao3 Using Ab Initio Molecular Dynamics, Benjamin Aaron Petersen

Doctoral Dissertations

Ab initio molecular dynamics (AIMD) was utilized to test a series of materials, MgO, LiNbO₃ , and LiTaO₃ , to determine defect structures produced due to low energy recoil events . The kinetic energy required to displace an atom from its lattice site, the threshold displacement energy, was calculated for an array of directions in each material, based on symmetry and complexity of the structure. MgO having a simple rock salt structure provided a model material for demonstrating computational techniques used later on LiTaO₃ and LiNbO₃ . The minimum values for displacing an atom were at …

Mechanical Behavior Of Pipeline Steels And An Al0.1cocrfeni High-Entropy Alloy, Bilin Chen

Doctoral Dissertations

This dissertation is composed of two parts. The first part focuses on the mechanical behavior study on pipelines steels. More specifically, the effect of hydrogen on the deformation behavior of the crack tip of an X52 pipeline steel specimen, and the overload effects on the fatigue crack growth of an x70 pipeline weld metal are discussed. For the second part of the dissertation, fatigue behavior of an Al0.1CoCrFeNi high-entropy alloy (HEA) is studied, and the influence of heat treatment is discussed.

The objectives of the first part of this proposed work are to (1) detect the influence of hydrogen on …

Transport Of Water And Ions Through Single-Walled Armchair Carbon Nanotubes: A Molecular Dynamics Study, Michelle Patricia Aranha

Doctoral Dissertations

The narrow hydrophobic interior of a carbon nanotube (CNT) poses a barrier to the transport of water and ions, and yet, unexpectedly, numerous experimental and simulation studies have confirmed fast water transport rates comparable to those seen in biological aquaporin channels. These outstanding features of high water permeability and high solute rejection of even dissolved ions that would typically require a lot of energy for separation in commercial processes makes carbon nanotubes an exciting candidate for desalination membranes. Extending ion exclusion beyond simple mechanical sieving by the inclusion of electrostatics via added functionality to the nanotube bears promise to not …

A High Quality And Quantity Hybrid Perovskite Quantum Dots (Cspbx3, X= Cl, Br And I) Powders Synthesis Via Ionic Displacement, Yuhang Yin, Weiling Luan, Chengxi Zhang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Recently, all-inorganic perovskites CsPbX₃ (X= Cl, Br and I) quantum dots (QDs) have drawn great attentions because of their PL spectra tunable over the whole visible spectral region (400-700 nm) and adjustable bandgap, which revealed a promising potential on the field of photoelectronic devices, such as solar cells, LEDs and sensors. In this paper, CsPbX₃ QDs and hybrid QDs, CsPbClxBr3-x and CsPbBrxI3-x were synthesized via one-step and two-step methods comparably. The optical bandgaps of CsPbCl₃, CsPbBr₃, and CsPbI₃, were calculated as 3.08, 2.36, and 1.73eV, respectively, based on the Tauc's equation and …

Usa Boccia Ball Ramp For Athletes With Quadriplegia, Alissa A. Koukourikos, Matthew Lee, Nathan Bernards

Mechanical Engineering

In this report, the design process in creating an assistive device for Boccia Classification 3 (BC3) players is outlined. The initial research steps, including research into the rules of the game, capabilities of the players, and existing products is documented to show where ideas for the product stemmed from. This transitions into requirements that the sponsor requested, and preliminary designs and ideas for the product. Finally, this report explains the details of the final design, which has been analyzed for safety, ease of use, and ability to function under different conditions. The processes of manufacturing and testing will also be …

Real-Time, Selective Detection Of Heavy Metal Ions In Water Using 2d Nanomaterials-Based Field-Effect Transistors, Guihua Zhou

Theses and Dissertations

Excessive intake of heavy metals damages the central nervous system and causes brain and blood disorders in mammals. Heavy metal contamination is commonly associated with exposure to mercury, lead, arsenic, and cadmium (arsenic is a metalloid, but classified as a heavy metal). Traditional methods to detect heavy metal ions include graphite furnace atomic absorption spectroscopy (GFAAS), inductively-coupled plasma optical emission spectroscopy (ICP-OES), and inductively-coupled plasma mass spectroscopy (ICP-MS). Recently, many new methods have been proposed to detect heavy metal ions, including atomic absorption spectrometry, fluorescent sensors, colorimetric sensors, electrochemical sensors, X-ray absorption fine structure spectroscopy, ultrasensitive dynamic light scatting assays, …

Controlled Electrochemical Reduction Of Gold And Palladium Metal Precursors In Polyaniline, Nicole Goodwin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Polyaniline (PANI) has been extensively studied due to its unique electrochemical properties. The conjugated polymer is conductive with high chemical stability below 100°C, mechanical strength, and large surface area. The applications of PANI have included chemical sensing, corrosion inhibition coatings, light emitting diode and as a substrate for metal composite catalysts. Both chemical and electrochemical methods have been developed and utilized in the synthesis of PANI/metal composites. The simultaneous reduction of aniline and metal precursor produces a composite of PANI encapsulated metal, reducing the active surface area available for catalysis. Alternatively, chemical reduction of the metal precursor into preformed PANI …

Extended Lamer Synthesis Of Cobalt Doped Ferrite, Benjamin D. Fellows, Sarah Sandler, Jacob Livingston, Kristin Fuller, Lotanna Nwandu, Sarah Timmis, Kayla A. Lantz, Morgan Stefik, O. Thompson Mefford

Publications

Nonstoichiometric cobalt ferrite nanoparticles have drawn interest in magnetically mediated energy delivery due to their high magnetocrystalline anisotropy and their high peak loss frequency. The use of an extended LaMer synthesis allows for size control of the doped particles up to a threshold core diameter of 18 nm. Above this diameter, particles become unstable and drop out of suspension, allowing for further nucleation events to occur. This leads to a cyclic nucleation, growth, and destabilization regime seen during the course of the reaction. Using the size control of the extended LaMer synthesis technique, we examine the specific absorption rate (SAR) …

Material Properties Design Using Simulations And Experiments For Powder Injection Molding Of Lead Zirconate Titanate (Pzt)., Bhushan Pramod Bandiwadekar

Electronic Theses and Dissertations

Powder injection molding (PIM) process simulations can be performed to minimize the number of injection molding experiments by estimating material properties necessary for PIM simulations. In current work, lead zirconate titanate (PZT) powder-polymer binder feedstock was compounded for 45 vol. % and 52 vol. % solids loading. PIM experiments on designed micro-pillar array geometry were performed using 52 vol. % PZT. Using PIM experiments results as basis, PIM simulations were performed on designed micro-pillar array geometries to understand the effectiveness of PIM simulations with the use of estimated feedstock properties in predicting molding behavior that have micro-features. Additionally, PIM simulations …

Nanograin Size Effects On The Strength Of Biphase Nanolayered Composites, Sixie Huang, Irene J. Beyerlein, Caizhi Zhou

Materials Science and Engineering Faculty Research & Creative Works

In this work, we employ atomic-scale simulations to uncover the interface-driven deformation mechanisms in biphase nanolayered composites. Two internal boundaries persist in these materials, the interlayer crystalline boundaries and intralayer biphase interfaces, and both have nanoscale dimensions. These internal surfaces are known to control the activation and motion of dislocations, and despite the fact that most of these materials bear both types of interfaces. From our calculations, we find that the first defect event, signifying yield, is controlled by the intralayer spacing (grain size, d), and not the intralayer biphase spacing (layer thickness, h). The interplay of two internal sizes …

Modeling Of Dislocation Channel Formation And Evolution In Irradiated Metals, Peter James Doyle

Masters Theses

Defect-free dislocation channel formation has been reported to promote plastic instability during tensile testing via localized plastic flow, leading to a distinct loss of ductility and strain hardening in many low-temperature irradiated materials. In order to study the underlying mechanisms governing dislocation channel width and formation, the channel formation process is modeled via a simple stochastic dislocation-jog process dependent upon grain size, defect cluster density, and defect size. Dislocations traverse a field of defect clusters and jog stochastically upon defect interaction, forming channels of low defect-density. Based upon prior molecular dynamics (MD) simulations and in-situ experimental transmission electron microscopy (TEM) …

Surface Alloying Of Plain-Carbon Steels During The Casting Manufacturing Process, Michael Beining

Theses and Dissertations

At times, the surface properties of an engineered component must be improved or enhanced when compared to the bulk of the component. Thus, various methods of surface alloying, one of the most important surface engineering processes, have been studied and developed for the decades. This study is concerned with the modification of the surface of WCB plain-carbon steel to improve corrosion and wear resistance of components used in the fresh water industry. The objective is to create a corrosion and wear resistant surface on an engineered component by enriching the surfaces with nickel or nickel and chromium, while the bulk …

Effects Of Electrolyte Formulation On Graphite Anode For Wide Temperature Application, Jeremy Chang

Theses and Dissertations

In this study, we demonstrate that the low temperature power capability of a Li-ion battery can be substantially improved not by adding exotic additives into the electrolyte, but by rational design of the composition of the most commonly used solvents. Through the detailed analysis with electrochemical impedance spectroscopy, the formation of a homogenous solid electrolyte interphase (SEI) layer on the carbon anode surface is critical to ensure the performance of a Li-ion battery in a wide temperature range. Subsequent post mortem analysis after cycling of the negative electrode by XPS revealed that all the electrolyte compositions form similar compounds in …

Antibacterial Activity Of Zno Nanoparticles On Silica Thin Film For Wastewater Treatment, S Chanrawangyot, S Rattanachan, A Watcharenwong, T Fangsuwannarak

Journal of Metals, Materials and Minerals

Zinc Oxide nanoparticles on silica matrix thin films were prepared by the Sol-gel method and dip coating on ceramic tiles. In this study, EC (Ethyl cellulose) and TP (alpha-terpineol) used as a binder and a solvent in Sol-gel method, respectively, were studied on the characteristics of thin films. The thin films were dried and calcined at the temperature of 500, 600˚C soaking 30 minutes with the heating rate of 1˚C/minutes. The result of Glancing X-Ray Diffraction showed that thin films were ZnO phase on the amorphous phase of silica matrix. Scanning electron microscope showed the ZnO nanoparticles dispersed on thin …

Development Of Wo3 Nanostructure By Acid Treatment And Annealing, T Sanasi, S Pinitsoontorn, M Horprathum, P Eiamchai, C Chananonnawathorn, W Hincheeranun

Journal of Metals, Materials and Minerals

Tungsten oxide (WO3) nanostructure is an interesting material for many applications such as batteries, gas sensors, photocatalysts, display utilizing, and smart windows. In this work, we fabricated the WO3 nanoplates by sputtering, acid treatment and annealing. Firstly, a tungsten film was deposited on a silicon or glass substrate by sputtering. The film was then immersed in nitric acid (HNO3) at 80 °C. The effect of the exposure time, and annealing temperature was investigated. After the acid treatment, the tungsten oxide hydrate or tungstile (WO3•H2O) with nanoplate structure was developed. The optical transmittance in the visible range was significantly improved compared …

Utilization Of Aluminium Dross As A Main Raw Material For Synthesis Of Geopolymer, P Puksisuwan, P Laoratanakul, B Cherdhirunkorn

Journal of Metals, Materials and Minerals

Aluminium dross contains both small particles and large agglomerates, where the recyclable part is the large agglomerates with high aluminium metal content. The residual Al dross is unrecyclable small particles with very low aluminium metal content. In this research, the residual Al dross from the aluminium recycle industry and the bagasse ash from a biomass power plant were used as main raw materials for geopolymer fabrication with alkaline solutions (Na2SiO3 and NaOH) using in the typical geopolymerization process. After mixing with alkaline solutions, the mixtures were uniaxially pressed into a cylinder die. The samples were cured for 3, 7, 14 …