Engineering Commons^™

Individual Copper Nanowire Decorated By Gold Nanoparticles For Surface Enhanced Raman Scattering, Roshan Guttikonda

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this Thesis, I discuss the theory, implementation and applications of Surface enhanced Raman scattering (SERS). Surface enhanced Raman scattering has been used to detect 4 mercaptopyridine molecules. On a Silicon wafer, Gold nanoparticles are deposited onto Copper nanowires. Hotspots occur at the small gap (less than 10nm) between the nanowire and nanoparticle. The interaction of the electromagnetic field of the incident laser and the surface plasmon resonances of the metal nanoparticles at the hot spots enhances the Raman scattering signal of the adsorbed pyridine molecule (10 -3 M ). The dependence of SERS signal on the polarization angle of …

Soil Moisture And Water Stage Estimation Using Precipitation Radar, Sumit Puri

UNLV Theses, Dissertations, Professional Papers, and Capstones

In south-western United States, soil moisture data is important for drought studies in the region which is experiencing a drought for many years, whereas in South Florida, water stage data is required by hydrologists to monitor the hydrological flow in wetlands. Soil moisture data and water stage data are not sufficiently available due to sparse monitoring stations. Installation of dense measuring stations over an extended area is costly and labor intensive. Therefore, there is a need to develop an alternative method of measuring soil moisture and water stage. Microwave remote sensing has proven to be a useful tool in the …

Spectroscopic Investigation Of Palladium-Copper Bimetallic Systems For Pem Fuel Cell Catalysts, Timo Hofmann

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the main barriers to commercialization of polymer electrolyte membrane fuel cells systems is cost, which is largely due to the need of platinum (Pt)-containing catalysts. In this thesis we investigate bimetallic systems consisting of a base metal (copper) and a noble metal (palladium) that, as an alloy on the nanoscale, mimic the electronic properties that make Pt desirable as a catalyst.

We present a detailed investigation of the electronic structure of carbon-supported Pd/Cu nanoparticle catalysts, model bilayer thin film systems, alloys, and various metal reference samples. We have investigated the valence band structure of the catalysts using a …

Mitigation Of Impact Vibrations Using Impedance Mismatch In Cylindrical Structures, Sachiko Sueki

UNLV Theses, Dissertations, Professional Papers, and Capstones

The focus of this work is to study the phenomenon of material impedance mismatch to determine its effect on the mitigation of high frequency accelerations in projectile and long bar structures within linear ranges of materials. In this study, the acceleration responses of structures with various materials and material combinations were studied experimentally, numerically and by the Finite Element Analysis (FEA). Air-gun tests conducted by the US Army Research Laboratory were modeled using FEA to simulate the acceleration pulse and shock waves experienced by artillery components during a launch. After the prototype of projectile was selected, further studies were conducted …

Parametric Study Of Stimulus-Response Behavior Incorporating Vehicle Heterogeneity In Car-Following Models, Saidi Siuhi

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this study was to develop a family of car-following models that address the shortcomings of car-following models developed by General Motors (GM) in the 1950s. The developed models consist of separate models for acceleration, deceleration, and steady-state responses for congested freeway traffic conditions. The study calibrated the models using individual vehicle trajectory data collected on a segment of Interstate 101 in Los Angeles, California. Furthermore, the study validated the models using individual vehicle trajectory data collected on a segment of Interstate 80 in Emeryville, California. The study used nonlinear regression with robust standard errors to estimate the …

Evaluation Of Rapid Electric Battery Charging Techniques, Ronald Baroody

UNLV Theses, Dissertations, Professional Papers, and Capstones

Battery powered electric vehicles are gaining popularity worldwide. This is trend is driven by several factors including the need to reduce air and noise pollution, and dependence on fossil fuels. The main drawback of today's electric vehicle is its limited range, and the long time duration that is required to charge the electric batteries. This thesis addresses the latter problem.

In recent years, significant progress (through research and development) has been made to accelerate the charging time of the electric vehicle batteries through pulse charging rather than supplying continuous current and/or voltage. Some patented fast charging techniques demonstrated reduced charging …

Analysis Of A Caliche Stiffened Pile Foundation, Richard C. Stone Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

Cemented carbonate deposits (known locally as "caliche") in Las Vegas have been used to support shallow and deep foundations with relatively high bearing pressures compared to soil. Most high rise structures in Las Vegas are founded on either a large mat or a long pile foundation. Recently, a new foundation type consisting of a short pile system bonded to shallow cemented layers was utilized for a large high rise building in Las Vegas and settlements during construction were recorded. The bonding of caliche layers together with short piles forms a caliche stiffened pile (CSP) foundation. The CSP foundation is unique …

Metal Induced Crystallization Of Silicon Thin Films, Sandeep Kumar Raju Sangaraju

UNLV Theses, Dissertations, Professional Papers, and Capstones

Low temperature crystallization of thin film silicon is important for many industrial applications including flat panel displays and silicon thin film solar cells. Unfortunately this remains a major challenge since crystallization temperature of silicon is above 1,000 degrees Celsius, thus limiting to substrates that can tolerate high temperatures. The inability to deposit crystalline thin films on glass substrates is the reason why flat panel display industry uses amorphous silicon for LCD active matrix displays. Thus the ability to deposit crystallized thin film silicon at low temperatures will have significant impact on thin film silicon applications. It has been observed that …

Effect Of Mechanical Vibrations On Light Emitting Diode Luminaires, Jayalakshmi Paladugu

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this work, a LED and two types of Compact fluorescent lamps were investigated for the intensity variation due to mechanical vibrations in the range of 0 to 30 HZ. In general, subjecting the lamps to 24-hour vibration affects the total intensity percentage variations of peak intensities after vibrations is in the range of -25 to +15% compared to those of no vibrations for the light emitting diode luminaires. For the case of compact fluorescent lamps (Nuvue) the variations are in range from +10 to +35%, whereas for the Compact fluorescent lamps (Ecosmart) the intensity peaks range from -10 to …

Islanded Operation Of A Distribution Feeder With Distributed Generation, Chandu Venu

UNLV Theses, Dissertations, Professional Papers, and Capstones

A distribution system that is equipped with distributed generators, such as roof-mounted photovoltaic systems, can operate as a microgrid (i.e., separated from the grid) under some specific conditions. A key feature of a microgrid is its ability to separate and isolate itself from the utility seamlessly with little or no disruption to the loads within the microgrid. Then, when the utility grid returns to normal, the microgrid automatically resynchronizes and reconnects itself to the grid, in an equally seamless manner. This thesis addresses the conditions necessary for proper microgrid operation: these include local generation-load mismatch, local energy storage, load switching, …

Studying The Impacts Of Primary Incidents On Freeways To Identify Secondary Incidents, Rohit Reddy Saddi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Freeway incidents are associated with different impacts such as traffic congestion, delays, fuel consumption, secondary incidents etc. Secondary incidents are caused due to primary incidents and require the same personnel who are already engaged. This thesis studies various impacts caused by primary incident in space and time occurring on the freeways and these results are applied to identify secondary incidents. Three types of impacts are identified and proposed in this study. Dynamic nature of queue length in the direction of accident is studied. Dynamic nature of congestion in the opposite direction of the freeway till the accident is cleared is …

On-Board Three-Dimensional Object Tracking: Software And Hardware Solutions, Ajay Kumar Mandava

UNLV Theses, Dissertations, Professional Papers, and Capstones

We describe a real time system for recognition and tracking 3D objects such as UAVs, airplanes, fighters with the optical sensor. Given a 2D image, the system has to perform background subtraction, recognize relative rotation, scale and translation of the object to sustain a prescribed topology of the fleet. In the thesis a comparative study of different algorithms and performance evaluation is carried out based on time and accuracy constraints. For background subtraction task we evaluate frame differencing, approximate median filter, mixture of Gaussians and propose classification based on neural network methods. For object detection we analyze the performance of …

Empirically Derived Formulas To Predict Indoor Maximum, Average, And Minimum Temperatures In Roofpond Buildings Using Minimum Climatic Information, Ibrahim Kivarkis Kako

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis introduces an empirically developed formula to predict the comfort conditions and thermal performance of a Skytherm(TM) Southwest Roofpond placed over a light-weight un-insulated structure built at the School of Architecture at the University of Nevada, Las Vegas.

The predictive formula introduced in this study may be used in different parts of the world (particularly developing nations where insulation and air-conditioning are rarely used) to predict the performance of a Skytherm(TM) Southwest Roofpond using minimal climate data.

The data collected in the experimental setup at the Natural Energies Advanced Technologies Laboratory included outside and inside temperatures of various surfaces …

Two-Tank Indirect Thermal Storage Designs For Solar Parabolic Trough Power Plants, Joseph E. Kopp

UNLV Theses, Dissertations, Professional Papers, and Capstones

The performance of a solar thermal parabolic trough plant with thermal storage is dependent upon the arrangement of the heat exchangers that ultimately transfer energy from the sun into steam. The steam is utilized in a traditional Rankine cycle power plant. The most commercially accepted thermal storage design is an indirect two-tank molten salt storage system where molten salt interacts with the solar field heat transfer fluid (HTF) through a heat exchanger. The molten salt remains in a closed loop with the HTF and the HTF is the heat source for steam generation. An alternate indirect two tank molten salt …

Quantity-Based Cost Forecasting System For Street Construction Projects, Nipesh Pradhananga

UNLV Theses, Dissertations, Professional Papers, and Capstones

Construction projects typically are not withdrawn after going into the competitive bidding process. The decision of contracting authorities regarding which projects will proceed to the bidding stage depends, in part, upon the early estimates of probable cost. Efforts are made to make this estimate as realistic as possible. Irrespective of the estimate of probable cost, the actual project cost is established by the amount of the winning bid.

This study analyzed historical bid data of street construction projects undertaken by the Public Works Department, Clark County, Nevada, from 1991 through 2006. The focus of this study was on utilizing statistical …

Study Of Secondary Electron Emission From Niobium At Cryogenic Temperatures, Anoop George

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this project is to study the properties of secondary electron emission from niobium samples, cleaned at the Los Alamos National Laboratory, at cryogenic temperatures to enhance existing multipacting codes with data on the samples. The predominant cause of power loss in radio-frequency superconducting accelerators cavities is multipacting. This project studies the secondary electron distribution from niobium metal due to incident primary electrons. The experiments on the niobium sample are performed in an environment close to that present in a superconducting accelerator cavity.

The experiment is performed in a vacuum chamber capable of achieving ultra high vacuum levels …

Cfd Analysis Of 3-D Thermalhydraulics Flow Effects On Wall Concentration Gradient Profiles For Lbe Loop Fittings, Narain Armbya

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of the thesis is to study the effects of thermalhydraulics flows on the wall concentration gradient profiles in LBE loop fittings. To that end detailed models of the fittings have been constructed to study these effects. These fittings include sudden expansion, sudden contraction, t-joint and elbow. The typical flow rates chosen for these simulations are typical of design criteria chosen for the loop with Reynolds numbers expected around 200,000 and the usual axial temperature profiles which are being characterized in the DELTA loop at LANL. STAR-CD is the simulation package used to make these predictions, which include detailed …

Stress Corrosion Cracking And Hydrogen Embrittlement Of Martensitic Alloy Ep-823, Mohammad K. Hossain

UNLV Theses, Dissertations, Professional Papers, and Capstones

This investigation is focused on the evaluation of stress corrosion cracking (SCC), localized corrosion, and hydrogen embrittlement (HE) susceptibility of martensitic Alloy EP-823 in neutral and acidic solutions at ambient and elevated temperatures. While no failures were observed in smooth specimens in the neutral solution, failures were noticed in the 90°C acidic solution at constant-load (CL) leading to a threshold stress (O'_th) of 102 ksi. The presence of a notch reduced the O'_th value to 91 ksi in a similar environment. The ductility (%El and %RA), time-to-failure (TTF), and true failure stress (O'_r) were gradually …

Environment Assisted Cracking Of Target Structural Materials Under Different Loading Conditions, Venkataramakrishnan Selvaraj

UNLV Theses, Dissertations, Professional Papers, and Capstones

Martensitic Alloy HT-9 has been tested for its evaluation of stress corrosion cracking resistance in neutral and acidic solutions at ambient and elevated temperatures incorporating smooth and notched cylindrical specimens under constant load and slow strain rate (SSR) conditions. C-ring and U-bend specimens have also been tested for stress corrosion cracking evaluation in the acidic solution. The role of hydrogen on the cracking tendency has been evaluated by cathodic applied potential.

The results of constant load testing enabled the determination of the threshold stress for stress corrosion cracking in susceptible environments. The magnitudes of ductility parameters were reduced with increasing …

Stress Corrosion Cracking Resistance Of Martensitic Stainless Steels For Transmutation Applications, Phani P. Gudipati

UNLV Theses, Dissertations, Professional Papers, and Capstones

The susceptibility of Alloy EP-823 to stress corrosion cracking has been evaluated using smooth and notched cylindrical specimens in neutral and acidic solutions at ambient and elevated temperatures using constant load and slow strain rate testing (SSR) techniques. C-ring and U-bend specimens have also been tested in the acidic solution. The effect of hydrogen on the cracking susceptibility has been evaluated under controlled cathodic potential. While no failures were observed with smooth specimens at constant load, the notched specimens showed failure. The SSR test results indicate that the true failure stress (o'_f), time to failure and ductility parameters …

Embrittlement And Localized Corrosion In Alloy Ht-9, Sudheer Sama

UNLV Theses, Dissertations, Professional Papers, and Capstones

This investigation is focused on the evaluation of stress corrosion cracking (SCC), hydrogen embrittlement (HE) and localized corrosion susceptibility of Alloy HT -9 in neutral and acidic solutions at 30, 60 and 90°C. Constant-load and slow-strain-rate (SSR) testing techniques were used to evaluate the SCC and HE behavior of this alloy by using smooth and notched tensile specimens. Hydrogen effect on the cracking behavior was evaluated by applying cathodic (negative) potential to the test specimens. Localized corrosion susceptibility was evaluated by cyclic potentiodynamic polarization technique. The results of constant load SCC testing showed a threshold stress at 80% of the …

Environment-Induced Degradations In A Target Structural Material For Transmutation Applications, Ramprashad Prabhakaran

UNLV Theses, Dissertations, Professional Papers, and Capstones

This investigation is focused on the evaluation of stress corrosion cracking (SCC) and localized corrosion behavior of Type 422 stainless steel in aqueous environments at ambient and elevated temperature. The results of constant load SCC testing using smooth specimens showed no failure in the neutral solution but a threshold stress of 97 ksi was observed in the 90°C acidic environment. SCC testing by the slow-strain-rate test method indicate that the time-to-failure, true failure stress and ductility parameters were gradually reduced with increasing temperature, showing more pronounced effect in the acidic solution. The application of a controlled cathodic potential showed further …

Design And Simulation Of An Induction Skull Melting System, Taide Tan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Incorporating volatile actinides, mainly americium into a metallic fuel pin (MFP) has been a serious problem due to americium’s high vapor pressure. An Induction Skull Melting (ISM) system was identified by Argonne National Laboratory (ANL) as a potential furnace design to cast MFPs. Through the development of the ISM system, the nuclear waste feedstock can be melted and injected into the mold for fabricating MFPs in the advanced nuclear fuel cycles. The main phenomena in this system include: induction melting process, casting process and mass transfer process of americium. Issues related to ISM system design for casting MFPs are discussed …

Modeling, Optimization, And Flow Visualization Of Chemical Etching Process In Niobium Cavities, Sathish K. Subramanian

UNLV Theses, Dissertations, Professional Papers, and Capstones

Niobium cavities are important component of the linear accelerators. Researchers have concluded that buffered chemical polishing on the inner surface of the cavity improves its performance. However the mechanism of chemical polishing is not well understood. A finite element computational fluid dynamics (CFD) model was developed to simulate the fluid flow characteristics of chemical etching process inside the cavity. The CFD model is then used to optimize the baffle design. The analysis confirmed the observation of other researchers that the iris section of the cavity received more etching than the equator regions. The baffle, which directs flow towards the walls …

Chemical Kinetics And Thermal Hydraulics Of Lead Bismuth Flow Loops, Kanthi Kiran Dasika

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of the thesis is to study the effect of chemical kinetics and thermal hydraulics of Lead Bismuth Eutectic (LBE) flow in the Materials Test Loop (MTL). The Materials Test Loop, also known as the Delta Loop, was built in Los Alamos National Laboratories (LANL) to obtain the experimental data for corrosion estimation and analysis. It is a well-known fact that corrosion plays an important role in the design of nuclear thermal hydraulic systems. Since the MTL is a multi-section closed system that differs in diameter from one part to another, an intensive study on the overall and regional …

Development Of A Systems Engineering Model For Chemical Separation Process, Lijian Sun

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis is concerned with the efforts to develop a general-purpose systems engineering model software TRPSEMPro1 that can be used to improve productivity in the design process. Different features of TRPSEMPro will be presented in this thesis. First, Systems Engineering technology is presented, followed by the exposition of different numerical optimization technologies and DOE (Design of Experiments) study technologies. Second, the detailed software process, Object-Oriented Analysis and Design (OOA&D) for the TRPSEMPro is presented. All the design data models are expressed by using Unified Modeling Language (UML).

AMUSESimulator is another software package which has been designed and implemented in order …

Study Of Geometric Effects On Local Corrosion Rates For Lbe Loop, Chao Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

Corrosion is an extremely important issue in nuclear cooling system applications. Many scientific and engineering efforts have been contributed to the research of finding an ideal material, which has resistance to corrosive Lead Bismuth Eutectic (LBE). A Delta Loop was designed and constructed in Los Alamos National Lab (LANL) to obtain the experimental data. This loop is a multi-section closed system that differs in diameter from one part to another. As a result, an intensive study on the geometry effect is hence necessary and valuable. In this thesis, this problem was simulated by commercial software STAR-CD. Results provide a good …

Investigation Of The Corrosion Of Steel By Lead-Bismuth Eutectic (Lbe) Using Scanning Electron Microscopy And X-Ray Photoelectron Spectroscopy, Daniel Koury

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lead Bismuth Eutectic (LBE) has been proposed for use in programs for accelerator transmutation of waste. LBE is the leading candidate material as a spallation target and an option for the sub-critical blanket coolant. The corrosion of 316 and 316L stainless steels by LBE has been studied using UNLV's facilities for Scanning Electron Microscopy (SEM) and X-ray Photoelectron Spectroscopy (XPS). We have compared exposed and unexposed samples and studied the differences. Some amount of surface contamination is present on the samples and has been removed by ionbeam etching. The unexposed samples reveal typical stainless steel characteristics: a chromium oxide passivation …

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides, Xiaolong Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fundamental issues related to the selection of a metallic fuel casting furnace design are presented and discussed including heating mechanisms, casting issues, crucible design, and issues related to the mass transport of americium. The process of evaluating all of these different criteria is undertaken to select a concept that would have the greatest chance of success for casting americium in a metallic fuel rod. Based on this evaluation process, a concept for the casting of metallic fuel pins containing high vapor pressure materials is selected and discussed. The important physics of this concept include mass transport of americium from the …

Modeling And Simulation Of The Chemical Etching Process In Niobium Cavities, Qin Xue

UNLV Theses, Dissertations, Professional Papers, and Capstones

Niobium Cavities are important parts of the integrated NC/SC high-power linear accelerator (linac) that can accelerate over 100 mA of protons to several GeV. Surface finish of the niobium cavity plays an important role of achieving the best performance of niobium cavity. The chemical etching techniques have been widely used.

Chemical etching of the inner surface of the cavity is achieved by circulating acid through it. The acid interacts with the surface and eliminates imperfections. During the etching process, a pipe with baffles is inserted within the cavity to direct the flow along the surfaces.

A 2-D, axisymmetric, steady state, …