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Articles 31 - 37 of 37
Full-Text Articles in Engineering
Development Of Strategies For Enhanced In Situ Bioremediation Of High Concentrations Of Halogenated Methanes, Huifeng Shan
Development Of Strategies For Enhanced In Situ Bioremediation Of High Concentrations Of Halogenated Methanes, Huifeng Shan
All Dissertations
ABSTRACT
Bioremediation of high concentrations of halomethanes e.g., carbon tetrachloride (CT), trichlorofluoromethane (CFC-11) and chloroform (CF) has seldom been addressed before and remains highly challenging. A microcosm study was conducted to investigate bioremediation strategies for groundwater contaminated with CT (6 to 10 mg/L), CFC-11 (1 to 26 mg/L), CF (3-500 mg/L), and 1,1-dichloroethene (1,1-DCE; up to 9 mg/L) at a former industrial site in California. Biostimulation with corn syrup and catalytic amounts of vitamin B12 was demonstrated as a feasible remedial strategy and bioaugmentation with B12 represents the most promising bioremediation method of the ones studied. Halomethane transformation …
An Examination Of Confined Aquifer Gradient Behavior Under Pumping Conditions, Stefanie Fountain
An Examination Of Confined Aquifer Gradient Behavior Under Pumping Conditions, Stefanie Fountain
All Dissertations
Accurate and reliable estimates of groundwater flow and contaminant transport models are dependent on an understanding of the aquifer properties used to create the models. The borehole flowmeter has been used with increasing frequency at a variety of sites to produce high resolution vertical hydraulic conductivity (K(z)) distributions [Boggs et al. 1990; Rehfeldt et al. 1989b; Molz et al. 1989, Boman et al. 1997; Dinwiddie et al. 1999]. In theory, the validity of measurements obtained using borehole flowmeters is contingent on the hydraulic head gradients near the well at each discrete depth resulting from the pumping-induced flow having reached quasi-steady-state. …
Experimental And Modeling Studies For Optimizing Flocculant-Aided Sediment Retention Ponds, Byung Joon Lee
Experimental And Modeling Studies For Optimizing Flocculant-Aided Sediment Retention Ponds, Byung Joon Lee
All Dissertations
Attempts to control sediment-containing runoff and associated water quality problems have involved the establishment of many small to medium sediment retention ponds and the injection of nonionic and anionic polyacrylamide (PAM) flocculants to enhance colloid removal. However, to date use has been driven more by practicing engineers and trial-and-error approaches than by logical and consistent design approaches. Therefore, the purpose of this research was to optimize colloidal clay removal in PAM-aided sediment retention ponds by applying experimental and theoretical methodologies.
Initially, simple measurement techniques for the molecular weight (MW) and charge density (CD) of various PAMs were tested and their …
Anaerobic Biodegradation Of Ethylene Dibromide And 1,2-Dichloroethane In The Presence Of Fuel Hydrocarbons, James Henderson
Anaerobic Biodegradation Of Ethylene Dibromide And 1,2-Dichloroethane In The Presence Of Fuel Hydrocarbons, James Henderson
All Dissertations
Field evidence from underground storage tank (UST) sites where leaded gasoline leaked indicates the lead scavengers 1,2-dibromoethane (ethylene dibromide, or EDB) and 1,2-dichloroethane (1,2-DCA) may be present in groundwater at levels that pose unacceptable risk. These compounds are seldom tested for at UST sites. Although dehalogenation of EDB and 1,2-DCA is known to occur, the effect of fuel hydrocarbons on their biodegradability under anaerobic conditions is poorly understood. Microcosms (2 L glass bottles) were prepared with soil and groundwater from a UST site in Clemson, South Carolina, using samples collected from the source (containing residual fuel) and less contaminated downgradient …
Laboratory Evaluation Of Chlorinated Ethene Transformation Processes In Fractured Sandstone, Ramona Darlington
Laboratory Evaluation Of Chlorinated Ethene Transformation Processes In Fractured Sandstone, Ramona Darlington
All Dissertations
A fractured sandstone aquifer at an industrial site in southern California is contaminated with trichloroethene (TCE) to depths in excess of 244 m. Field monitoring data suggest that TCE is undergoing reduction to cis-DCE and that additional attenuation is occurring. However, vinyl chloride (VC) and ethene have not been detected in significant amounts, so that if transformation is occurring, a process other than reductive dechlorination must be responsible. The overall objective of this study was to evaluate the occurrence of biotic and abiotic transformation processes at this site for TCE, cis-DCE and VC. Anaerobic microcosms were constructed with site groundwater …
Modeling Long-Term Plutonium Transport In The Savannah River Site Vadose Zone, Deniz Demirkanli
Modeling Long-Term Plutonium Transport In The Savannah River Site Vadose Zone, Deniz Demirkanli
All Dissertations
Improved understanding of flow and radionuclide transport in vadose zone sediments is fundamental to future planning involving radioactive materials. Long-term experiments were conducted at the Savannah River Site (SRS), where a series of lysimeters containing sources of different Pu oxidation states were placed in the shallow subsurface and exposed to the environment for 2 to 11 years. After the experiments, Pu activity concentrations were measured along vertical cores. The distributions were anomalous in nature, with irregular downward migration and unexpected upward migration. Previous studies suggested that surface-mediated, oxidation/reduction (redox) reactions may be responsible for the anomalies. This hypothesis is tested …
Controlling Steam Flood Migration With Air Injection Wells, Rex Hodges
Controlling Steam Flood Migration With Air Injection Wells, Rex Hodges
All Dissertations
Steam flooding is an aggressive remediation technology for removing volatile organic chemical (VOC) sources that slowly dissolve into passing groundwater. Plume concentrations can be reduced, accelerating cleanup, and decreasing plume management costs. Steam injected in wells surrounding the source spreads outward and develops into a front that drives contamination to a system of groundwater pumping wells in the saturated zone and soil vapor extraction wells in the vadose zone. The process can be modeled with the non-isothermal multi-phase flow simulator T2VOC to include operation designs and factors at individual sites.
A pilot field-scale test at the Savannah River Site (SRS) …