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- Actinide (2)
- Adsorption (1)
- Amines (1)
- CO2 storage (1)
- Carbon Nanotube (1)
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- Carbon sequestration (1)
- Chloramines (1)
- Disinfection By-Products (1)
- Drinking Water Treatment (1)
- Hematite (1)
- LSER (1)
- N-Nitrosodimethylamine (1)
- Plutonium (1)
- Pre-Oxidation (1)
- Predictive Modeling (1)
- QSAR (1)
- Secondary trapping (1)
- Sorption (1)
- Synthetic Organic Contaminants (1)
- TOUGH2-ECO2N (1)
- Thermodynamics (1)
Articles 1 - 5 of 5
Full-Text Articles in Engineering
Toward Understanding The Thermodynamics And Mechanisms Of Actinide Sorption Reactions, Shanna Estes
Toward Understanding The Thermodynamics And Mechanisms Of Actinide Sorption Reactions, Shanna Estes
All Dissertations
The environmental fate of actinides is greatly influenced by interfacial reactions, including sorption onto solid surfaces. Because changes in the primary hydration sphere of the actinide are expected to greatly influence the thermodynamics (i.e., reaction enthalpy and entropy) of these reactions, examining actinide sorption thermodynamics may provide insight into actinide sorption mechanisms. Additionally, examining actinide sorption thermodynamics may enhance the ability to model or predict these reactions in environmental or engineered systems where variable or elevated temperatures are expected. However, few researchers have studied actinide sorption thermodynamics. Therefore, this research examined the thermodynamics of Eu(III) (a trivalent actinide analog), Th(IV), …
The Effects Of Secondary Trapping Mechanisms On Geologic Storage Of Carbon Dioxide, Catherine Ruprecht
The Effects Of Secondary Trapping Mechanisms On Geologic Storage Of Carbon Dioxide, Catherine Ruprecht
All Dissertations
The goal of this Dissertation is to further the understanding of secondary trapping mechanisms in geologic CO2 storage systems to improve storage design and security. This Dissertation takes the form of three chapters. The objective of the first chapter was to analyze the storage performance of supercritical and brine saturated CO2 injection strategies to determine their advantages and disadvantages on distribution and immobilization of CO2 and pressure buildup. Results showed dissolved CO2 injection was favorable in terms of storage security in all cases as it resulted in smaller areal extents on the caprock and did not …
Experimental Evidence For Colloid-Facilitated Transport Of Plutonium, Hilary Emerson
Experimental Evidence For Colloid-Facilitated Transport Of Plutonium, Hilary Emerson
All Dissertations
Colloid-facilitated transport of the actinides has been observed previously in the field on the kilometer scale. The objective of this work is to investigate the mechanisms of colloid-facilitated transport with controlled settings and conditions. The experimental work in this dissertation investigates transport of a ternary complex with iron oxide colloids, organic ligands and actinides in the presence of quartz or a natural sandy soil as well as simplified systems building up to the ternary complexes. The first three papers investigate the following: (1) unsaturated transport of iron oxide colloids in a natural sandy soil lysimeter with and without natural organic …
The Effects Of Amine Structure, Chloramine Species And Oxidation Strategies On The Formation Of N-Nitrosodimethylamine, Meric Selbes
The Effects Of Amine Structure, Chloramine Species And Oxidation Strategies On The Formation Of N-Nitrosodimethylamine, Meric Selbes
All Dissertations
To comply with the increasingly stringent disinfection by-product (DBP) regulations in the United States, many water treatment plants have been switching from chlorination to chloramination in the last decade. Although chloramination reduces the formation of regulated DBPs such as trihalomethanes and haloacetic acids, it causes the formation of nitrosamines. Nitrosamines are a class of compounds that are probable human carcinogens, mutagens and teratogens at concentrations as low as 0.2 ng/L. In particular, N-nitrosodimethylamine (NDMA) is the most frequently detected nitrosamine in distribution systems in the United States. Although, nitrosamines are currently not regulated by the USEPA, they have been recently …
Predictive Model Development For Adsorption Of Organic Contaminants By Carbon Nanotubes, Onur Apul
Predictive Model Development For Adsorption Of Organic Contaminants By Carbon Nanotubes, Onur Apul
All Dissertations
The main objective of the study was to investigate mechanisms and statistical modeling of synthetic organic contaminant (SOC) adsorption by carbon nanotubes (CNTs). First, predictive models were developed for adsorption of low molecular weight aromatic compounds by multi-walled carbon nanotubes (MWCNTs) using experimental data for 59 compounds. Quantitative structure-activity relationship (QSAR) and linear solvation energy relationship (LSER) approaches were employed and developed models were externally validated using an independent dataset obtained from the literature. Up to date, no QSAR model has been reported for predicting adsorption of organics by CNTs. No LSER model is available which comprehensively investigates the adsorption …