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Full-Text Articles in Engineering

Sidestream Ras Fermentation For Stable Bio-P Combined With Short Cut Nitrogen Removal In An A/B Process, Lindsey Elise Ferguson Apr 2019

Sidestream Ras Fermentation For Stable Bio-P Combined With Short Cut Nitrogen Removal In An A/B Process, Lindsey Elise Ferguson

Civil & Environmental Engineering Theses & Dissertations

It is well known that soluble organic carbon (sCOD), especially in the form of volatile fatty acids (VFA), is critical to achieving reliable enhanced biological phosphorus removal (EBPR) in biological nutrient removal (BNR) processes. Consistent and reliable EBPR in systems treating wastewaters deficient in sCOD may be accomplished by the addition of VFA and sCOD – rich fermentate produced by the fermentation of primary sludge, return / waste activated sludge (RAS / WAS), or other suitable carbon sources. The solids retention time (SRT) of fermenters being used to supplement carbon in sidestream EBPR processes must be controlled such that complex …


Tsunamigenic Potential Of The Baiyun Slide Complex In The South China Sea, Linlin Li, Fengyan Shi, Gangfeng Ma, Qiang Qiu Jan 2019

Tsunamigenic Potential Of The Baiyun Slide Complex In The South China Sea, Linlin Li, Fengyan Shi, Gangfeng Ma, Qiang Qiu

Civil & Environmental Engineering Faculty Publications

The Baiyun slide complex contains geological evidence for some of the largest landslide ever discovered in the continental slopes of the South China Sea. High-resolution seismic data suggest that a variety of landslides with varied scales have occurred repeatedly in this area. The largest landslide reconstructed from bathymetric and seismic data has an estimated spatial coverage of ~5,500 km2 and a conservative volume of ~1,035 km3. Here, using geomorphological and geotechnical data, we construct a series of probable landslide scenarios and assess their tsunamigenic capacity. By treating the slides as deformable mudflows, we simulate the dynamics of …


Predicting Effects Of Climate Change And Sea Level Rise On Hydrologic Processes In A Mid-Atlantic Coastal Watershed, Rui Li Apr 2018

Predicting Effects Of Climate Change And Sea Level Rise On Hydrologic Processes In A Mid-Atlantic Coastal Watershed, Rui Li

Civil & Environmental Engineering Theses & Dissertations

This dissertation assessed impacts of Climate Change (CC) and Sea Level Rise (SLR) on coastal hydrologic processes using the Lynnhaven River watershed as a test bed. The watershed is part of Chesapeake Bay Watershed and hydraulically connected with mid-Atlantic Ocean. Six CC scenarios were considered in terms of eight Regional Climate Models’ predictions for three Intergovernmental Panel on Climate Change (IPCC) emission assumptions, namely, B1, A1B, and A2, for two future periods, namely 2046 to 2065 and 2081 to 2099. The ensemble means of downscaling results from four methods were used to represent the future climates. On the other hand, …


Modeling Effects Of Rainwater Harvesting Systems On Water Yield Increase And Non-Beneficial Evaporation Reduction To Sustain Agriculture In A Water-Scarce Region Of China, Tennille Wade Apr 2018

Modeling Effects Of Rainwater Harvesting Systems On Water Yield Increase And Non-Beneficial Evaporation Reduction To Sustain Agriculture In A Water-Scarce Region Of China, Tennille Wade

Civil & Environmental Engineering Theses & Dissertations

The northwestern region of China, which has an arid/semiarid climate, relies heavily on agriculture to provide food for the growing population. Climate change is affecting water availability in the region, causing long periods of drought and water scarcity followed by shorter periods of heavy rainfall and excess water availability. The ridge and furrow rainwater harvesting systems (RFRWHS) are a means of solving the problem of water scarcity; the systems can replenish soil moisture, reduce non-beneficial evaporation from bare soils, and increase surface water yield. In such a region, the hydrologic cycle is dominated by soil evaporation, leading to minimal surface …


Techno-Economic And Life Cycle Assessment Of Hydrothermal Processing Of Microalgae For Biofuels And Co-Product Generation, Andrew P. Bessette Apr 2018

Techno-Economic And Life Cycle Assessment Of Hydrothermal Processing Of Microalgae For Biofuels And Co-Product Generation, Andrew P. Bessette

Civil & Environmental Engineering Theses & Dissertations

Traditional processing methods of algae to biofuels require dewatering after harvesting of the algae before the lipids can be extracted. This is typically the most energy intensive and therefore the most expensive step. Old Dominion University (ODU) has successfully utilized a flash hydrolysis (a kind of hydrothermal) process where proteins are solubilized into the liquid phase of product and the remainder lipid-rich, low nitrogen product is separated into a solid phase. The solid phase (lipid-rich) is then an ideal candidate for biofuel feedstock and the liquid phase, or hydrolysate, can be used for coproducts such as a source of nutrients …


The Evaluation Of Enhancing Biological Phosphorus Removal And Improving Settleability Using Mainstream Hydrocyclones For External Selection, Amanda Carrie Ford Apr 2018

The Evaluation Of Enhancing Biological Phosphorus Removal And Improving Settleability Using Mainstream Hydrocyclones For External Selection, Amanda Carrie Ford

Civil & Environmental Engineering Theses & Dissertations

Hydrocyclones, which receive mixed liquor tangentially, separate lighter solids from more dense solids through their tapered shape. Increasing the velocity of liquid as it moves downward allows for the selection of a desired solids fraction. Limited research has been conducted utilizing 20 m3hr-1 hydrocyclones, with the intent of improving settleability and biological phosphorus removal (Bio-P) for mainstream processes. Improved settleability would allow for increased capacity in the secondary clarifiers which prevents the loss of biomass and subsequent treatment disruption, especially during wet weather scenarios. In addition, treatment intensification can be accomplished by maintaining a higher mixed liquor …


Simplified, Alternative Formulation Of Numerical Simulation Of Proton Exchange Membrane Fuel Cell, Russell L. Edwards Apr 2018

Simplified, Alternative Formulation Of Numerical Simulation Of Proton Exchange Membrane Fuel Cell, Russell L. Edwards

Mechanical & Aerospace Engineering Theses & Dissertations

Three-Dimensional proton exchange fuel cell (PEMFC) operation in steady-state is simulated with computational fluid dynamics / multiphysics software that is based upon the finite-element method. PEMFC operation involves the simultaneous simulation of multiple, interconnected physics involving fluid flows, heat transport, electrochemical reactions, and both protonic and electronic conduction. Modeling efforts have varied by how they treat the physics occurring within and adjacent to the membrane-electrode assembly (MEA). Several approaches treat the MEA as part of the computational domain, solving multiple, and coupled conservation equations via the CFD approach within the 3 regions of the MEA. The thickness dimensions of the …


Optimizing Nature-Based Features For Wave Dissipation And Land-Water Connectivity, Maura Boswell, Navid Tahvildari Jan 2018

Optimizing Nature-Based Features For Wave Dissipation And Land-Water Connectivity, Maura Boswell, Navid Tahvildari

Civil & Environmental Engineering Faculty Publications

Living shorelines integrate structural and natural features to stabilize the shoreline, through reduction of erosion from the wave climate, while keeping the connectivity between land and aquatic ecosystems. This study includes field study for two different types of living shoreline systems to quantify and compare their wave dissipation services and provide physics-based guidance for the design of living shoreline systems that are efficient in wave dissipation yet maximize land-water connectivity.


Collaborative Strategies For Sea Level Rise Adaptation In Hampton Roads, Virginia, Carol Considine, Emily Steinhilber Jan 2018

Collaborative Strategies For Sea Level Rise Adaptation In Hampton Roads, Virginia, Carol Considine, Emily Steinhilber

Engineering Technology Faculty Publications

[Introduction] The Hampton Roads region is located in southeastern Virginia where the Chesapeake Bay meets the Atlantic Ocean. The region includes seventeen municipal governments and has a large federal government presence with 26 federal agencies represented (See Figure 1). The region has a population that exceeds 1.7 million and is home to the deepest water harbor on the U.S. East Coast. Hampton Roads' economy is dependent on the local waterways and houses the world's largest naval facility, the sixth largest containerized cargo complex and supports a thriving shipbuilding and repair industry as well as a tourism industry. However, the region's …


Value Added Products From Lignin And Biomass Derivatives, Chen Li Jan 2018

Value Added Products From Lignin And Biomass Derivatives, Chen Li

Civil & Environmental Engineering Theses & Dissertations

Pyrolysis is one of the traditional lignin and biomass utilization methods. The liquid products bio-oil and solid products bio-char are the main value-added products from lignin pyrolysis. Due to the narrow application and low quality, using the pyrolysis method to produce bio-oil and bio-char cannot bring sufficient economic benefits. In this dissertation, two methods were investigated to improve the quality of lignin bio-products.

Instead of direct pyrolysis, chemical activation (pyrolysis) was introduced in this dissertation. Compared to bio-char, the lignin chemical activation product lignin-activated-carbon has better economic value. With the best activation conditions, the lignin-activated-carbon produced a surface area of …


Effects Of Vacuuming Pervious Concrete On Infiltration Rate, Demetrios E. Maurakis, Eugene G. Maurakis Oct 2017

Effects Of Vacuuming Pervious Concrete On Infiltration Rate, Demetrios E. Maurakis, Eugene G. Maurakis

Virginia Journal of Science

The objectives of this research were twofold: test the infiltration rate of pervious concrete before and after vacuum cleaning, and assess infiltration variability over time. Infiltration tests were performed on a 558.2 m2 area of pervious concrete, divided into sixteen 0.35 m2 test areas in a parking area at the Science Museum of Virginia in Richmond, Virginia on five dates from November 4-December 30, 2013. Average infiltration rates (avg.= 22.8 and 36.3 L/m2/min) immediately after vacuuming were lower than those (avg.=30.7 and 41.3 L/m2/min) before vacuuming. We hypothesize that the vacuuming lifted materials towards the surface …


Holistic Approach In Microalgae Conversion To Bioproducts And Biofuels Through Flash Hydrolysis, Ali Teymouri Oct 2017

Holistic Approach In Microalgae Conversion To Bioproducts And Biofuels Through Flash Hydrolysis, Ali Teymouri

Civil & Environmental Engineering Theses & Dissertations

In recent years, the demand for renewable energy, mainly biomass has increased. The U.S. Energy Information Administration reported that more than 13.3% of the total energy production in the first seven months of 2017 was produced from a biomass source. Among all biomass resources, microalgae has brought a lot of attention due to their numerous advantages such as higher growth rate and productivity compared with the conventional energy crops, higher energy conversion efficiency by photosynthesis, and less water requirement than terrestrial crops. However, its development is far behind industrial production. Several research efforts across the globe have been concerned with …


Quantifying Pollutant Removal Rates Of Bioretention Basins As A Stormwater Best Management Practice, Evan Nathanial Waagen Oct 2017

Quantifying Pollutant Removal Rates Of Bioretention Basins As A Stormwater Best Management Practice, Evan Nathanial Waagen

Civil & Environmental Engineering Theses & Dissertations

Water pollution is an ongoing problem that can be attributed to human activities. As world population increases and countries become more developed, this problem intensifies. Fortunately, the causes and solutions of water pollution are documented and have been implemented with various levels of success. These solutions, or Best Management Practices (BMPs), vary in type and function and remove pollutants from runoff prior to it reaching rivers, lakes, and other bodies of water. This study investigates bioretention basins, a specific group of BMPs, and presents analysis and prediction of their performance, of which our knowledge is incomplete in the existing literature. …


Inertization, Utilization, And Safe Disposal Of Incineration Residues, Anil Mehrotra Jul 2017

Inertization, Utilization, And Safe Disposal Of Incineration Residues, Anil Mehrotra

Civil & Environmental Engineering Projects for D. Eng. Degree

Combustion of coal or Municipal Solid Waste (MSW) caused air pollution and produces solid residues which contain high levels of toxic elements. The toxic characteristics of residues generated from combustion of MSW in waste-to-energy plants are strictly controlled by Federal and State Waste Management Regulations. According to Resource Conservation and Recovery Act (RCRA), residue generated from combustion of MSW is considered hazardous and must be tested according to EPA Toxic Characteristics Leaching Procedure (TCLP) Method 1311 and suitably treated for its safe disposal to landfills. Experiments with various treatment chemicals as primary independent variable had earlier been conducted by several …


Investigation And Analysis Of The Fluctuating Brominated To Total Trihalomethane Ratio In The Virginia Beach Distribution System, Christopher Steven Mihalkovic Jul 2017

Investigation And Analysis Of The Fluctuating Brominated To Total Trihalomethane Ratio In The Virginia Beach Distribution System, Christopher Steven Mihalkovic

Civil & Environmental Engineering Theses & Dissertations

An increasing trend in the brominated-trihalomethane to total-trihalomethane concentration ratio from 2001 to 2016 in the Virginia Beach water distribution system was established and investigated. This study aimed at identifying factors contributing to fluctuations in trihalomethane speciation in finished water. Reservoir management practices, treatment processes, and source water conditions were examined to quantitatively and qualitatively discern the impact of their variations on finished water THM speciation. Data on water quality constituents and parameters from the Moore’s Bridges Treatment Facility and within the Virginia Beach distribution system were examined to interpret spatial and temporal relationships with trihalomethane concentrations using established research …


Simulated Dynamics Of Soil Water And Pore Vapor In A Semi-Arid Sandy Ecosystem, Shohreh Pedram Jul 2017

Simulated Dynamics Of Soil Water And Pore Vapor In A Semi-Arid Sandy Ecosystem, Shohreh Pedram

Civil & Environmental Engineering Theses & Dissertations

Understanding dynamics of soil water content (SWC) and pore air relative humidity (RHpa), as influenced by wetting-drying cycles, is crucial for sustaining fragile ecosystems of desert lands across the world and needed for improving the prediction accuracy of global climate change. However, to date, such an understanding is still incomplete. The objective of this dissertation was to examine such dynamics at a typical desert site within the Horqin Sandy Land, located in Mongolian Plateau of north China. The examination was done by using a HYDRUS-1D computer simulation model and the continuous sensor-based soil water data for two calendar years. HYDRUS-1D …


A Comparative Study Of The Effects Of External Selection On Settleability And Formation Of Aerobic Granular Sludge, Tyler A. Brickles Jul 2017

A Comparative Study Of The Effects Of External Selection On Settleability And Formation Of Aerobic Granular Sludge, Tyler A. Brickles

Civil & Environmental Engineering Theses & Dissertations

Aerobic granular sludge (AGS) has shown much promise in the advancement of the wastewater treatment industry. AGS has been studied intensely since the early 1990’s due to highly desirable characteristics of nutrient removal efficiency, low footprint, and abnormally faster settling rates than conventional activated sludge. With the exception of a few on-going research projects, all AGS systems have been studied and implemented through the use of sequencing batch reactors (SBR). Recently, a novel approach to developing AGS and improving settling characteristics of activated sludge within conventional activated sludge (CAS) processes has being attempted through the use of external selection.

Activated …


Hydrologic Response Caused By Wetland Expansion At Huntley Meadows Park In Hybla Valley, Virginia, Stephen Fraser Stone Apr 2017

Hydrologic Response Caused By Wetland Expansion At Huntley Meadows Park In Hybla Valley, Virginia, Stephen Fraser Stone

OES Theses and Dissertations

The goal of this study was to understand the effects of wetland expansion across a watershed. The 2013 restoration and expansion of the wetlands at Huntley Meadows Park (Fairfax County, VA) performed by Wetland Studies and Solutions, Inc. provided the opportunity to study this process. The 630 ha park contains more than 364 ha of freshwater emergent and freshwater forested wetlands. The restoration and expansion project used a subsurface vinyl-piling dam that impedes groundwater flow leaving the wetland, thus expanding the existing pond and the surrounding wetland.

This study used a network of more than twenty monitoring instruments making observations …


Quantifying Cyanide Inhibition Of Nitrification And Developing Cost-Effective Treatment Processes, Germano M. Salazar-Benites Apr 2017

Quantifying Cyanide Inhibition Of Nitrification And Developing Cost-Effective Treatment Processes, Germano M. Salazar-Benites

Civil & Environmental Engineering Theses & Dissertations

All wastewater treatment plants that operate multiple hearth furnaces (MHF) and are required to nitrify must manage the inhibitory effects of free cyanide (HCN, CN-) in the scrubber return flows due to inhibitory impacts on nitrifying bacteria.

HRSD Boat Harbor Treatment Plant (BHTP) a 25 MGD facility consisting of primary and secondary treatment, employs an anoxic selector process for nitrification and partial denitrification and operates a MHF. There is a desire to improve TN removal performance at BHTP due to an annual mass-based bubble permit limit on a combined discharge from seven HRSD plants, and there are no discharge limitations …


Heavy Metal Distribution And Groundwater Quality Assessment For A Coastal Area On A Chinese Island, Sha Lou, Shuguang Liu, Chaomeng Dai, An Tao, Bo Tan, Gangfeng Ma, Roman Sergeeyvich Chalov, Sergey Romanovich Chalov Jan 2017

Heavy Metal Distribution And Groundwater Quality Assessment For A Coastal Area On A Chinese Island, Sha Lou, Shuguang Liu, Chaomeng Dai, An Tao, Bo Tan, Gangfeng Ma, Roman Sergeeyvich Chalov, Sergey Romanovich Chalov

Civil & Environmental Engineering Faculty Publications

Chongming Island is located in the lower Yangtze Estuary in China. Due to the Leachate from a refuse landfill and the hydrodynamics of the Yangtze Estuary, the groundwater environment is particularly complicated on Chongming Island. Field observations were carried out around the landfill disposal site. The groundwater table, temperature, pH, salinity, and dissolved oxygen were measured in the field by portable equipment, and 192 water samples were collected at eight groundwater sites and one surface water site. Through laboratory analysis we found the highest measured concentration of Cr to be 54.07 μg/L, and the measured concentration of Zn was in …


Modeling Algae Powered Neighborhood Through Gis And Bim Integration, Florina Dutt, Steven Jige Quan, Erik Woodworth, Daniel Castro-Lacouture, Ben J. Stuart, Perry Pei-Ju Yang Jan 2017

Modeling Algae Powered Neighborhood Through Gis And Bim Integration, Florina Dutt, Steven Jige Quan, Erik Woodworth, Daniel Castro-Lacouture, Ben J. Stuart, Perry Pei-Ju Yang

Civil & Environmental Engineering Faculty Publications

This paper aims to propose a modeling method for algae powered neighborhoods through GIS-BIM integration. In the first part of the paper, the applicability of different types of algae systems in an urban neighborhood are studied. The various systems of algae provide different strengths and weakness that affect their performance and suitability for given urban scenarios. Through extensive literature review, the variables that affect the performance of the micro-algae in the built environment are identified, with a focus on flat-panel photo bio-reactors and tubular photobioreactors. A previous GIS model for data management, performance analysis and design of the algae systems …


Upscaling Stem To Community-Level Transpiration For Two Sand-Fixing Plants: Salix Gordejevii And Caragana Microphylla, Limin Duan, Yang Li, Xue Yan, Tingxi Liu, Xixi Wang Jan 2017

Upscaling Stem To Community-Level Transpiration For Two Sand-Fixing Plants: Salix Gordejevii And Caragana Microphylla, Limin Duan, Yang Li, Xue Yan, Tingxi Liu, Xixi Wang

Civil & Environmental Engineering Faculty Publications

The information on transpiration is vital for sustaining fragile ecosystem in arid/semiarid environment, including the Horqin Sandy Land (HSL) located in northeast China. However, such information is scarce in existing literature. The objectives of this study were to: (1) measure sap flow of selected individual stems of two sand-fixing plants, namely Salix gordejevii and Caragana microphylla, in HSL; and (2) upscale the measured stem-level sap flow for estimating the community-level transpiration. The measurements were done from 1 May to 30 September 2015 (i.e., during the growing season). The upscaling function was developed to have one dependent variable, namely sap …


Effects Of Nonaerated Circulation Water Velocity On Nutrient Release From Aquaculture Pond Sediments, Xiangju Cheng, Dantong Zhu, Xixi Wang, Deguang Yu, Jun Xie Jan 2017

Effects Of Nonaerated Circulation Water Velocity On Nutrient Release From Aquaculture Pond Sediments, Xiangju Cheng, Dantong Zhu, Xixi Wang, Deguang Yu, Jun Xie

Civil & Environmental Engineering Faculty Publications

Sustaining good water quality in aquaculture ponds is vital. Without an aerator, the dissolved oxygen in ponds comes primarily from mass transfer at the water-ambient atmosphere interface. As sediment can seriously affect water quality, this study used indoor experiments to examine the nutrient (nitrogen and phosphorus) release mechanisms and fluxes from sediment in aquaculture ponds with moving water but no aeration. The results showed that the ammonia nitrogen (NH3-N) concentration in the overlying water was inversely proportional to flow velocity and that a higher flow velocity tended to result in a lower concentration in the overlying water, a …


Spatiotemporal Distribution Of Eutrophication In Lake Tai As Affected By Wind, Wenhui Zhang, Qiujin Xu, Xixi Wang, Xiaozhen Hu, Cheng Wang, Yan Pang, Yanbin Hu, Yang Zhao, Xiao Zhao Jan 2017

Spatiotemporal Distribution Of Eutrophication In Lake Tai As Affected By Wind, Wenhui Zhang, Qiujin Xu, Xixi Wang, Xiaozhen Hu, Cheng Wang, Yan Pang, Yanbin Hu, Yang Zhao, Xiao Zhao

Civil & Environmental Engineering Faculty Publications

One common hypothesis is that wind can affect concentrations of nutrients (i.e., nitrogen and phosphorus) and chlorophyll-a (Chl-a) in shallow lakes. However, the tests of this hypothesis have yet to be conclusive in existing literature. The objective of this study was to use long-term data to examine how wind direction and wind speed affect the spatiotemporal variations of total nitrogen (TN), total phosphorus (TP) and Chl-a in Lake Tai, a typical shallow lake located in east China. The results indicated that the concentrations of nutrients and Chl-a tended to decrease from the northwest to the southeast of Lake Tai, with …


Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar Jan 2017

Water–Soil–Vegetation Dynamic Interactions In Changing Climate, Xixi Wang, Xuefeng Chu, Tingxi Liu, Xiangju Cheng, Rich Whittecar

Civil & Environmental Engineering Faculty Publications

Previous studies of land degradation, topsoil erosion, and hydrologic alteration typically focus on these subjects individually, missing important interrelationships among these important aspects of the Earth's system. However, an understanding of water–soil–vegetation dynamic interactions is needed to develop practical and effective solutions to sustain the globe's eco-environment and grassland agriculture, which depends on grasses, legumes, and other fodder or soil-building crops. This special issue is intended to be a platform for a discussion of the relevant scientific findings based on experimental and/or modeling studies. Its 12 peer-reviewed articles present data, novel analysis/modeling approaches, and convincing results of water–soil–vegetation interactions under …


Longitudinal Tidal Dispersion Coefficient Estimation And Total Suspended Solids Transport Characterization In The James River, Beatriz Eugenia Patino Oct 2016

Longitudinal Tidal Dispersion Coefficient Estimation And Total Suspended Solids Transport Characterization In The James River, Beatriz Eugenia Patino

Civil & Environmental Engineering Theses & Dissertations

The longitudinal dispersion coefficient is a parameter used to evaluate the effect of cross-sectional variations on substance mixing mechanisms in estuaries influenced by tide, wind and internal density variations. Considering a two dimensional approach, this study aims at evaluating a tidal area of the lower James River at approximately 19 miles upstream from the mouth at the Chesapeake Bay, in the City of Newport News, and applies an experimental procedure based on in-situ salinity concentrations to estimate the dispersion coefficient in the area where receives a discharge from the HRSD James River Wastewater Treatment Plant, and further characterizes Total Suspended …


Effects Of Surrounding Water Table On A Forested Wetland Habitat In East Coast Of Virginia, Lane Stokes Oct 2016

Effects Of Surrounding Water Table On A Forested Wetland Habitat In East Coast Of Virginia, Lane Stokes

Civil & Environmental Engineering Theses & Dissertations

Exchanges into and out of a wetland, including surface water flow, groundwater flow, and constituents in the flows, usually determine the wetland physicochemical characteristics and biodiversity. To date, of these three exchanges, groundwater flow is the least studied, particularly in the United States of America. In this thesis, field observations were conducted at a forested non-tidal wetland, located on a flat hilltop. The position of the wetland is such that groundwater outflow is the only significant exchange that could be impacted by the surrounding land use. In addition, a spatially variable steady-state model was set up to extrapolate the observations …


Possible Sources And Impacts Of Biochar Water Extractable Organic Compounds On Aquatic Microorganisms, Cameron Russell Smith Jul 2016

Possible Sources And Impacts Of Biochar Water Extractable Organic Compounds On Aquatic Microorganisms, Cameron Russell Smith

Chemistry & Biochemistry Theses & Dissertations

Smokeless biomass pyrolysis with application of biochar as a soil amendment could be a significant approach for carbon sequestration to possibly control climate change for energy and environmental sustainability. If biochar were to be utilized as a soil amendment and a carbon sequestration agent at Gt C scales, the release of potentially toxic compounds into soils and associated hydrological systems, through soil rainwater runoff and leaching, might have negative consequences, in both agro-ecosystems and aquatic environmental systems. Therefore, the main focus of this dissertation was to study the sources and chemical composition of biochar water extractable (soluble) organic compounds and …


Impacts Of Operating Parameters On Extracellular Polymeric Substances Production In A High Rate Activated Sludge System With Low Solids Retention Times, Matthew S. Elliot Apr 2016

Impacts Of Operating Parameters On Extracellular Polymeric Substances Production In A High Rate Activated Sludge System With Low Solids Retention Times, Matthew S. Elliot

Civil & Environmental Engineering Theses & Dissertations

The Adsorption/Bio-oxidation (A/B) process accomplishes carbon capture via bio-flocculation in the adsorption stage (A-stage) to maximize energy recovery while simultaneously providing an optimal carbon to nitrogen (C/N) ratio for denitrification in the Bio-oxidation stage (B-Stage). The present study evaluated the influence of the solids retention time (SRT), dissolved oxygen (DO) concentration, and production of extracellular polymeric substances (EPS) on bio-flocculation and subsequent carbon capture using a pilot-scale A-stage process. A mixed liquor suspended solids (MLSS)-based control strategy was implemented to manage carbon capture by maintaining a constant MLSS concentration of 3,000 mg/L in response to diurnal variations in organic loading. …


Characterization Of Biochars Produced From Peanut Hulls And Pine Wood With Different Pyrolysis Conditions, James W. Lee, Bob Hawkins, Michelle K. Kidder, Barbara R. Evans, A. C. Buchanan, Danny Day Jan 2016

Characterization Of Biochars Produced From Peanut Hulls And Pine Wood With Different Pyrolysis Conditions, James W. Lee, Bob Hawkins, Michelle K. Kidder, Barbara R. Evans, A. C. Buchanan, Danny Day

Chemistry & Biochemistry Faculty Publications

Background

Application of modern biomass pyrolysis methods for production of biofuels and biochar is potentially a significant approach to enable global carbon capture and sequestration. To realize this potential, it is essential to develop methods that produce biochar with the characteristics needed for effective soil amendment.

Methods

Biochar materials were produced from peanut hulls and pine wood with different pyrolysis conditions, then characterized by cation exchange (CEC) capacity assays, nitrogen adsorption–desorption isotherm measurements, micro/nanostructural imaging, infrared spectra and elemental analyses.

Results

Under a standard assay condition of pH 8.5, the CEC values of the peanut hull-derived biochar materials, ranging from …