Engineering Commons^™

Evaluating Direct Filtration As An Alternative To Conventional Carbon-Based Advanced Treatment For Indirect Potable Reuse, Savannah M. Flemmer

Civil & Environmental Engineering Theses & Dissertations

Hampton Roads Sanitation District (HRSD) is recharging purified wastewater into the Potomac Aquifer via the Sustainable Water Initiative for Tomorrow (SWIFT) project. Conventional SWIFT treatment applies coagulation, flocculation, sedimentation, ozonation, biofiltration, granular activated carbon (GAC) adsorption, and ultraviolet disinfection to secondary effluent to produce water that meets drinking water standards for managed aquifer recharge. HRSD is considering implementing direct filtration as an alternative to conventional treatment for two additional SWIFT facilities. Direct filtration presents an opportunity for significant cost savings by eliminating sedimentation, shortening flocculation detention time, and reducing coagulant usage. Without upstream removal of solids and organics, however, biofilters …

Biocrude Production From Lignin In Hydrothermal Medium: Effect Of Rapid Heating And Short Residence Time, Kyoko Hirayama

Civil & Environmental Engineering Theses & Dissertations

This study aims to address knowledge gaps in the production of valuable products from waste streams generated during lignocellulosic biofuel production. The primary objective is to develop a process that converts lignin, a byproduct of bioethanol refineries, into a sustainable biolubricant.

The first chapter examines recent advancements in synthesizing biolubricants and investigates their scalability. It explores innovative materials, catalysts, chemical modification approaches, and additives that have emerged in the field. A particular hurdle is the oxidative stability of biolubricants derived from plant oils, which are prone to autooxidation due to their C=C bonds. To overcome this, the study aims to …

Integrated Processing Of Municipal Solid Waste For Maximizing Waste Reduction, Carbon Recovery And Fuel Production, Kameron J. King

Civil & Environmental Engineering Theses & Dissertations

Nationally and internationally, waste generation is increasing and along with it negative environmental impacts. Many people think waste ends at disposal; however, environmental impacts have already begun. Unfortunately, 50% of waste ends up in a landfill which is the third largest source of human related methane emissions and a leading cause of global climate change. This study investigated a novel waste management strategy in hopes of mitigating negative environmental effects caused by conventional waste management practices. The novelty of the study lies in the development of an integrated method of hydrothermal carbonization and an anaerobic digestion (HTC + AD) process …

Assessment Of The Hydrograv® Adapt Variable Height Secondary Clarifier Inlet At Hrsd Nansemond Treatment Plant, Matthew Poe

Civil & Environmental Engineering Theses & Dissertations

The Hampton Roads Sanitation District (HRSD) recently completed the first North American and center driven installation of the Hydrograv® Adapt Variable Height Secondary Clarifier Inlet (Adapt) at HRSD’s Nansemond Treatment Plant. This is a variable height inlet structure designed to decrease clarifier effluent turbidity and maintain low turbidity during high flow events. Low turbidity is achieved by feeding the secondary clarifier influent within the solids blanket during dry weather conditions and lifting the inlet structure during wet weather conditions to avoid disrupting the blanket. The Adapt clarifier was monitored alongside an identical fixed inlet clarifier to assess performance. Both clarifiers …

Stability Of Low Crested And Submerged Breakwaters: A Reanalysis And Model Development, Christopher P. Burgess

Civil & Environmental Engineering Theses & Dissertations

Low-crested and submerged structures (LCS) play an integral part in the stabilization of shorelines for recreational purposes, yet there are a plethora of empirical models and gaps in the understanding of their stability and damage progression. The objectives were: i) to evaluate the present formulae, ii) explore variable importance, iii) formulate a stability model, iv) extend the current datasets and v) explore a new model for LCS. The literature points to an increasing understanding of the initiation of damage of LCS and recent exploration of the shear stress-induced erosion (van Rijn, 2019). Assessment of two existing models (Kramer, 2006 and …

The Impacts Of Surface Gravity Waves On Buoyant Plume Dilution, Bruce William Husselbee

Civil & Environmental Engineering Theses & Dissertations

A common practice in coastal areas is to collect, treat and discharge fluids including treated wastewater, stormwater or power plant effluent to areas of lesser impact. The discharge of these fluids, conveyed through pipelines into coastal areas, continues to be an important human health and environmental concern. The fluid discharged from these pipelines is often buoyant which allows for dilution and dispersion into these ambient waters.

Initial dilution, defined as the maximum concentration of a discharged fluid at the maximum rise in height within a buoyant plume, is critical in the consideration of the environmental impacts of a discharge into …

Application Of A Biodegradable And Recyclable Chelating Agent For Ash Removal From Algae, Temitope George Daramola

Civil & Environmental Engineering Theses & Dissertations

Ash is inherent in algae biomass and it causes operational difficulties, equipment failure, and disposal issues during biomass conversion to biofuels and bioproducts. The objectives of this study are to (i) investigate the use of the biodegradable chelating agent for reducing ash content of algae and (ii) evaluate the potential of regeneration and recycle of the chelating agent for multiple uses. Conventionally, ethylenediamine-tetraacetic acid (EDTA) has been studied extensively to remove ash from biomass. However, EDTA is non-biodegradable and causes environmental issues at the disposal.

Nitrilotriacetic acid (NTA) is a biodegradable chelating agent and was used in this study for …

Challenges Of Designing And Operating A Pilot Scale Short Residence Time Continuous Hydrothermal Flash Hydrolysis Reactor For High Slurry Load Biomass Processing, Mason James Martin

Civil & Environmental Engineering Theses & Dissertations

Increasing demand for renewable energy, fuels, and bioproducts has resulted in a push for increasingly efficient and economically favorable biomass pretreatment methods. Flash Hydrolysis, (FH) a promising biomass pretreatment method, has been extensively studied at a laboratory scale. FH employs a continuous subcritical hydrothermal process capable of fractionating microalgae for lipid and protein recovery. FH is unique in that the residence time is very short (~ 10 s). Maintaining this residence time was key in designing a scaled pilot flash hydrolyzing unit (FHU). We have developed a one of its kind pilot FHU capable of increasing the processing output of …

Catalytic Transfer Hydrogenation Reactions Of Lipids, Alexander Asiedu

Civil & Environmental Engineering Theses & Dissertations

Catalytic transfer hydrogenation (CTH) of lipids was investigated using 2-propanol as hydrogen donor for producing liquid hydrocarbons, e.g. jet fuels. The main sources of lipids selected in this study were waste cooking oil (WCO) and oil-laden algae-derived biofuel intermediate (BI). Two different catalysts were employed in this study, namely activated carbon and trimetallic-doped zeolite.

The CTH reaction was between WCO and 2-propanol in a continuous flow reactor over a packed-bed activated carbon at near atmospheric pressure. Results revealed a high level of alkenes and aromatics compounds, which are not stable and are not environmentally unfriendly. To reduce these compounds in …

Sidestream Ras Fermentation For Stable Bio-P Combined With Short Cut Nitrogen Removal In An A/B Process, Lindsey Elise Ferguson

Civil & Environmental Engineering Theses & Dissertations

It is well known that soluble organic carbon (sCOD), especially in the form of volatile fatty acids (VFA), is critical to achieving reliable enhanced biological phosphorus removal (EBPR) in biological nutrient removal (BNR) processes. Consistent and reliable EBPR in systems treating wastewaters deficient in sCOD may be accomplished by the addition of VFA and sCOD – rich fermentate produced by the fermentation of primary sludge, return / waste activated sludge (RAS / WAS), or other suitable carbon sources. The solids retention time (SRT) of fermenters being used to supplement carbon in sidestream EBPR processes must be controlled such that complex …

Measuring And Modeling Bare Desert Wind Erosion From Steppe Grassland Of Northern China As Affected By Soil Moisture And Climate, Nicholas Morgan Potter

Civil & Environmental Engineering Theses & Dissertations

Soil erosion by wind has been found to be negatively related to soil water content, as evidenced by that for a given area, such a soil erosion can be much less in a wet than a dry year. However, few studies have examined the functional relationship between wind erosion and soil moisture, primarily due to lack of field measured data. The objectives of this study were to: 1) measure wind erosion in field using a portable wind tunnel devised and made by the author; 2) use the measured data to calibrate/validate a wind erosion model previously developed by the author; …

The Evaluation Of Enhancing Biological Phosphorus Removal And Improving Settleability Using Mainstream Hydrocyclones For External Selection, Amanda Carrie Ford

Civil & Environmental Engineering Theses & Dissertations

Hydrocyclones, which receive mixed liquor tangentially, separate lighter solids from more dense solids through their tapered shape. Increasing the velocity of liquid as it moves downward allows for the selection of a desired solids fraction. Limited research has been conducted utilizing 20 m³hr^-1 hydrocyclones, with the intent of improving settleability and biological phosphorus removal (Bio-P) for mainstream processes. Improved settleability would allow for increased capacity in the secondary clarifiers which prevents the loss of biomass and subsequent treatment disruption, especially during wet weather scenarios. In addition, treatment intensification can be accomplished by maintaining a higher mixed liquor …

Techno-Economic And Life Cycle Assessment Of Hydrothermal Processing Of Microalgae For Biofuels And Co-Product Generation, Andrew P. Bessette

Civil & Environmental Engineering Theses & Dissertations

Traditional processing methods of algae to biofuels require dewatering after harvesting of the algae before the lipids can be extracted. This is typically the most energy intensive and therefore the most expensive step. Old Dominion University (ODU) has successfully utilized a flash hydrolysis (a kind of hydrothermal) process where proteins are solubilized into the liquid phase of product and the remainder lipid-rich, low nitrogen product is separated into a solid phase. The solid phase (lipid-rich) is then an ideal candidate for biofuel feedstock and the liquid phase, or hydrolysate, can be used for coproducts such as a source of nutrients …

Predicting Effects Of Climate Change And Sea Level Rise On Hydrologic Processes In A Mid-Atlantic Coastal Watershed, Rui Li

Civil & Environmental Engineering Theses & Dissertations

This dissertation assessed impacts of Climate Change (CC) and Sea Level Rise (SLR) on coastal hydrologic processes using the Lynnhaven River watershed as a test bed. The watershed is part of Chesapeake Bay Watershed and hydraulically connected with mid-Atlantic Ocean. Six CC scenarios were considered in terms of eight Regional Climate Models’ predictions for three Intergovernmental Panel on Climate Change (IPCC) emission assumptions, namely, B1, A1B, and A2, for two future periods, namely 2046 to 2065 and 2081 to 2099. The ensemble means of downscaling results from four methods were used to represent the future climates. On the other hand, …

Modeling Effects Of Rainwater Harvesting Systems On Water Yield Increase And Non-Beneficial Evaporation Reduction To Sustain Agriculture In A Water-Scarce Region Of China, Tennille Wade

Civil & Environmental Engineering Theses & Dissertations

The northwestern region of China, which has an arid/semiarid climate, relies heavily on agriculture to provide food for the growing population. Climate change is affecting water availability in the region, causing long periods of drought and water scarcity followed by shorter periods of heavy rainfall and excess water availability. The ridge and furrow rainwater harvesting systems (RFRWHS) are a means of solving the problem of water scarcity; the systems can replenish soil moisture, reduce non-beneficial evaporation from bare soils, and increase surface water yield. In such a region, the hydrologic cycle is dominated by soil evaporation, leading to minimal surface …

Value Added Products From Lignin And Biomass Derivatives, Chen Li

Civil & Environmental Engineering Theses & Dissertations

Pyrolysis is one of the traditional lignin and biomass utilization methods. The liquid products bio-oil and solid products bio-char are the main value-added products from lignin pyrolysis. Due to the narrow application and low quality, using the pyrolysis method to produce bio-oil and bio-char cannot bring sufficient economic benefits. In this dissertation, two methods were investigated to improve the quality of lignin bio-products.

Instead of direct pyrolysis, chemical activation (pyrolysis) was introduced in this dissertation. Compared to bio-char, the lignin chemical activation product lignin-activated-carbon has better economic value. With the best activation conditions, the lignin-activated-carbon produced a surface area of …

Quantifying Pollutant Removal Rates Of Bioretention Basins As A Stormwater Best Management Practice, Evan Nathanial Waagen

Civil & Environmental Engineering Theses & Dissertations

Water pollution is an ongoing problem that can be attributed to human activities. As world population increases and countries become more developed, this problem intensifies. Fortunately, the causes and solutions of water pollution are documented and have been implemented with various levels of success. These solutions, or Best Management Practices (BMPs), vary in type and function and remove pollutants from runoff prior to it reaching rivers, lakes, and other bodies of water. This study investigates bioretention basins, a specific group of BMPs, and presents analysis and prediction of their performance, of which our knowledge is incomplete in the existing literature. …

Holistic Approach In Microalgae Conversion To Bioproducts And Biofuels Through Flash Hydrolysis, Ali Teymouri

Civil & Environmental Engineering Theses & Dissertations

In recent years, the demand for renewable energy, mainly biomass has increased. The U.S. Energy Information Administration reported that more than 13.3% of the total energy production in the first seven months of 2017 was produced from a biomass source. Among all biomass resources, microalgae has brought a lot of attention due to their numerous advantages such as higher growth rate and productivity compared with the conventional energy crops, higher energy conversion efficiency by photosynthesis, and less water requirement than terrestrial crops. However, its development is far behind industrial production. Several research efforts across the globe have been concerned with …

Simulated Dynamics Of Soil Water And Pore Vapor In A Semi-Arid Sandy Ecosystem, Shohreh Pedram

Civil & Environmental Engineering Theses & Dissertations

Understanding dynamics of soil water content (SWC) and pore air relative humidity (RHpa), as influenced by wetting-drying cycles, is crucial for sustaining fragile ecosystems of desert lands across the world and needed for improving the prediction accuracy of global climate change. However, to date, such an understanding is still incomplete. The objective of this dissertation was to examine such dynamics at a typical desert site within the Horqin Sandy Land, located in Mongolian Plateau of north China. The examination was done by using a HYDRUS-1D computer simulation model and the continuous sensor-based soil water data for two calendar years. HYDRUS-1D …

A Comparative Study Of The Effects Of External Selection On Settleability And Formation Of Aerobic Granular Sludge, Tyler A. Brickles

Civil & Environmental Engineering Theses & Dissertations

Aerobic granular sludge (AGS) has shown much promise in the advancement of the wastewater treatment industry. AGS has been studied intensely since the early 1990’s due to highly desirable characteristics of nutrient removal efficiency, low footprint, and abnormally faster settling rates than conventional activated sludge. With the exception of a few on-going research projects, all AGS systems have been studied and implemented through the use of sequencing batch reactors (SBR). Recently, a novel approach to developing AGS and improving settling characteristics of activated sludge within conventional activated sludge (CAS) processes has being attempted through the use of external selection.

Activated …

Investigation And Analysis Of The Fluctuating Brominated To Total Trihalomethane Ratio In The Virginia Beach Distribution System, Christopher Steven Mihalkovic

Civil & Environmental Engineering Theses & Dissertations

An increasing trend in the brominated-trihalomethane to total-trihalomethane concentration ratio from 2001 to 2016 in the Virginia Beach water distribution system was established and investigated. This study aimed at identifying factors contributing to fluctuations in trihalomethane speciation in finished water. Reservoir management practices, treatment processes, and source water conditions were examined to quantitatively and qualitatively discern the impact of their variations on finished water THM speciation. Data on water quality constituents and parameters from the Moore’s Bridges Treatment Facility and within the Virginia Beach distribution system were examined to interpret spatial and temporal relationships with trihalomethane concentrations using established research …

Quantifying Cyanide Inhibition Of Nitrification And Developing Cost-Effective Treatment Processes, Germano M. Salazar-Benites

Civil & Environmental Engineering Theses & Dissertations

All wastewater treatment plants that operate multiple hearth furnaces (MHF) and are required to nitrify must manage the inhibitory effects of free cyanide (HCN, CN-) in the scrubber return flows due to inhibitory impacts on nitrifying bacteria.

HRSD Boat Harbor Treatment Plant (BHTP) a 25 MGD facility consisting of primary and secondary treatment, employs an anoxic selector process for nitrification and partial denitrification and operates a MHF. There is a desire to improve TN removal performance at BHTP due to an annual mass-based bubble permit limit on a combined discharge from seven HRSD plants, and there are no discharge limitations …

Effects Of Surrounding Water Table On A Forested Wetland Habitat In East Coast Of Virginia, Lane Stokes

Civil & Environmental Engineering Theses & Dissertations

Exchanges into and out of a wetland, including surface water flow, groundwater flow, and constituents in the flows, usually determine the wetland physicochemical characteristics and biodiversity. To date, of these three exchanges, groundwater flow is the least studied, particularly in the United States of America. In this thesis, field observations were conducted at a forested non-tidal wetland, located on a flat hilltop. The position of the wetland is such that groundwater outflow is the only significant exchange that could be impacted by the surrounding land use. In addition, a spatially variable steady-state model was set up to extrapolate the observations …

Longitudinal Tidal Dispersion Coefficient Estimation And Total Suspended Solids Transport Characterization In The James River, Beatriz Eugenia Patino

Civil & Environmental Engineering Theses & Dissertations

The longitudinal dispersion coefficient is a parameter used to evaluate the effect of cross-sectional variations on substance mixing mechanisms in estuaries influenced by tide, wind and internal density variations. Considering a two dimensional approach, this study aims at evaluating a tidal area of the lower James River at approximately 19 miles upstream from the mouth at the Chesapeake Bay, in the City of Newport News, and applies an experimental procedure based on in-situ salinity concentrations to estimate the dispersion coefficient in the area where receives a discharge from the HRSD James River Wastewater Treatment Plant, and further characterizes Total Suspended …

Impacts Of Operating Parameters On Extracellular Polymeric Substances Production In A High Rate Activated Sludge System With Low Solids Retention Times, Matthew S. Elliot

Civil & Environmental Engineering Theses & Dissertations

The Adsorption/Bio-oxidation (A/B) process accomplishes carbon capture via bio-flocculation in the adsorption stage (A-stage) to maximize energy recovery while simultaneously providing an optimal carbon to nitrogen (C/N) ratio for denitrification in the Bio-oxidation stage (B-Stage). The present study evaluated the influence of the solids retention time (SRT), dissolved oxygen (DO) concentration, and production of extracellular polymeric substances (EPS) on bio-flocculation and subsequent carbon capture using a pilot-scale A-stage process. A mixed liquor suspended solids (MLSS)-based control strategy was implemented to manage carbon capture by maintaining a constant MLSS concentration of 3,000 mg/L in response to diurnal variations in organic loading. …

Comparing Nutrient Recovery Via Rapid (Flash Hydrolysis) And Conventional Hydrothermal Liquefaction Processes For Microalgae Cultivation, Caleb Richard Talbot

Civil & Environmental Engineering Theses & Dissertations

Algal biofuels have the potential to provide a scalable source of renewable fuels in the near future. The high nutrient use in algae cultivation and its recovery and recycling is one of the challenges that may limit the scalability and sustainability of algal biofuels. The present study evaluates the use of Hydrolysate obtained after Flash Hydrolysis (FH) of Scenedesmus at 280 C as a nutrient source for microalgae cultivation. FH Hydrolysate nutrient recycling was compared with low temperature batch Hydrothermal Liquefaction (HTL) nutrient recycling. Oocystis and Scenedesmus were cultivated using Hydrolysate as a partial phosphorous (P) and nitrogen (N) source. …

A Risk Assessment Of The Impacts Of Coastal Flooding And Sea Level Rise On The Existing And New Pump Stations 113, Norfolk, Va, David A. Pezza

Civil & Environmental Engineering Theses & Dissertations

The author assessed the risk to a wastewater pump station and a planned replacement located nearby due to coastal flooding and rising sea levels. The locations for the pump stations are in the Larchmont neighborhood by the Lafayette River tidal estuaries in Norfolk, Virginia. The Lafayette River is a tributary to the Elizabeth River, which flows to the Chesapeake Bay. The low-lying areas along the river are subject to coastal surges caused by tropical and extra-tropical storms that flood the bay.

The region is considered one of the urban areas most exposed to the accelerating rate of rising sea levels. …

Techno-Economic Analysis Of Protein Concentrate Produced By Flash Hydrolysis Of Microalgae, Alexander Nana Yaw Asiedu

Civil & Environmental Engineering Theses & Dissertations

Process simulation and techno-economic analysis of 95wt.% protein concentrate from microalgae has been performed using SuperPro Designer v. 9.0. This work, first of its kind, is focused on the economic analysis of protein concentrate that includes processes such as microalgae cultivation, harvesting, protein extraction and drying steps. A baseline capacity of 160 MT/day protein concentrate production on commercial basis has been analyzed. This throughput requires 336 MT/day dry algae (54 wt.% protein). The amount of carbon dioxide required to grow this quantum of algae is estimated to be 648 MT/day, which is produced from an in situ 21 MW power …

Hydrothermal Catalytic Liquefaction And Deoxygenation Of Biomass For Renewable Fuel Production, Sergiy Popov

Civil & Environmental Engineering Theses & Dissertations

In recent years, sub- and supercritical water technologies received an increasing attention because of the numerous advantages they offer for biomass converting into biofuels. Water at elevated temperatures and pressures provides an ideal medium for chemical transformations. It serves as a reactant, reaction medium, and catalyst that helps biomass compounds undergo hydrolysis, depolymerization, dehydration, decarboxylation, and condensation/repolymerization reactions. Biomass is the fourth largest source of energy in the world after coal, oil, and natural gas that has the potential to provide the large scale substitution of hydrocarbon-based liquid transportation fuels and minimize the environmental issues. Biomass typically contains 40-60% oxygen. …

Polychlorinated Biphenyl Source Identification In Fish Tissue Using A Multivariate Statistical Evaluation Of Congeners And Stable Isotope Ratio Mass Spectrometry, William Edward Corl Iii

Civil & Environmental Engineering Theses & Dissertations

Polychlorinated biphenyls (PCBs) were commercially produced mixtures primarily utilized as dielectric fluids in the electrical industry. However, due to their stability, they were widely used in many other applications. Although production of PCBs ceased in the 1970's, they continue to be a contaminant in the environment due to their widespread use, their recalcitrant behavior, and their proposed toxicological effects.

In 2008, a routine environmental investigation of an abandoned, concrete-lined pool at a Department of Defense (DoD) training facility in Williamsburg, Virginia led to the discovery of a PCB release from the facility into an adjacent reservoir. A forensic study was …