Open Access. Powered by Scholars. Published by Universities.®
- Discipline
Articles 1 - 3 of 3
Full-Text Articles in Quantum Physics
Contributions Of Tunneling In 8Π-6Π Electrocyclic Cascade Reactions Of Bicyclo[4.2.0]Octa-2,4-Diene Moieties, Ishika Jain, Claire Castro, William L. Karney
Contributions Of Tunneling In 8Π-6Π Electrocyclic Cascade Reactions Of Bicyclo[4.2.0]Octa-2,4-Diene Moieties, Ishika Jain, Claire Castro, William L. Karney
Featured Student Work
Six-electron electrocyclic reactions usually require relatively high temperatures; however recent research has shown that such reactions can occur at significantly lower temperatures in biosynthetic and biomimetic pathways. Pathways resulting in bicyclo[4.2.0]octa-2,4-diene moieties arise from thermally allowed 8π-6π electrocyclization cascade reactions of 1,3,5,7-octatetraenes, as in the biosynthesis of endiandric acids, elysiapyrones, and numerous other natural products. We report multidimensional tunneling calculations to explore the possible contribution of heavy-atom tunneling (e.g. by carbon) to biosynthetic pathways and biomimetic syntheses, and thus to provide a more complete picture of biochemical kinetics. M06-2X/cc-pVDZ calculations on the 8π-6π cascade cyclizations of methylated octatetraene model systems …
The Mceliece Cryptosystem As A Solution To The Post-Quantum Cryptographic Problem, Isaac Hanna
The Mceliece Cryptosystem As A Solution To The Post-Quantum Cryptographic Problem, Isaac Hanna
Senior Honors Theses
The ability to communicate securely across the internet is owing to the security of the RSA cryptosystem, among others. This cryptosystem relies on the difficulty of integer factorization to provide secure communication. Peter Shor’s quantum integer factorization algorithm threatens to upend this. A special case of the hidden subgroup problem, the algorithm provides an exponential speedup in the integer factorization problem, destroying RSA’s security. Robert McEliece’s cryptosystem has been proposed as an alternative. Based upon binary Goppa codes instead of integer factorization, his cryptosystem uses code scrambling and error introduction to hinder decrypting a message without the private key. This …
Liouvillian Dynamics Of The Open Schwinger Model: String Breaking And Kinetic Dissipation In A Thermal Medium, Kyle Lee, James Mulligan, Felix Ringer, Xiaojun Yao
Liouvillian Dynamics Of The Open Schwinger Model: String Breaking And Kinetic Dissipation In A Thermal Medium, Kyle Lee, James Mulligan, Felix Ringer, Xiaojun Yao
Physics Faculty Publications
Understanding the dynamics of bound state formation is one of the fundamental questions in confining quantum field theories such as Quantum Chromodynamics (QCD). One hadronization mechanism that has garnered significant attention is the breaking of a string initially connecting a fermion and an antifermion. Deepening our understanding of real-time string-breaking dynamics with simpler, lower dimensional models like the Schwinger model can improve our understanding of the hadronization process in QCD and other confining systems found in condensed matter and statistical systems. In this paper, we consider the string-breaking dynamics within the Schwinger model and investigate its modification inside a thermal …