Quantum Physics Commons^™

Noise Characterization And Mitigation In Intermediate-Scale Quantum Systems, Muhammad Qasim Khan

Dartmouth College Ph.D Dissertations

Current quantum processors, at the intermediate scale of tens to hundreds of qubits, remain error-limited. This thesis studies two related sources of error. The first is environmental noise, which may have temporal and spatial correlations and nonclassical components. The second is state-preparation and measurement (SPAM) error, which arises in the operations used to characterize this noise, a prerequisite for boosting operational fidelities. Neither can be characterized alone. Noise spectroscopy techniques use imperfect preparation and readout, while SPAM characterization is affected by qubit decoherence. Our methods vary measurement depth, drive duration, or sequence repetition so each source changes the measured signal …

Electronic Structure Discretization And Compression Using Diagonal Basis Sets, Casey Lee Dowdle

Dartmouth College Ph.D Dissertations

Numerically solving the electronic structure problem is a fundamentally difficult problem due to the exponential growth in the dimension of the Hilbert space as the system size increases. In order to solve problems at a chemically relevant accuracy, both the choice of basis set and numerical method are important factors that are intrinsically connected.

In this thesis, we study the discretization and resulting compression of electronic Hamiltonians using diagonal basis sets. A diagonal basis set approximately diagonalizes the matrix and tensor representations of the one- and two-body potentials. This can reduce storage, simplify matrix-vector products, and lower the complexity of …

Dynamics Of Localized Wave Packets In Quantum Mechanics, Ayla Zook, Keigo L. Fujita, Rufus Boyack Phd

Wetterhahn Science Symposium Posters

Quantum wave packets are localized, time-dependent solutions of the Schrödinger equation that mimic classical particle motion. In his 1926 paper, Schrödinger famously showed that displacing the ground state of the harmonic oscillator produces a wave packet whose probability density maintains its shape and saturates the Heisenberg uncertainty bound. Motivated by this result, we construct and analyze wave-packet solutions for the Airy potential, the simple harmonic oscillator (SHO), and the pseudoharmonic oscillator (PHO). Our general approach is to find expansion coefficients and take a superposition of the energy eigenstates of the time-independent Schrödinger equation. We examine spatially displaced eigenstates alongside alternative …

Basis Design For Electronic Structure And Beyond, Weishi Wang

Dartmouth College Ph.D Dissertations

At the intersection of quantum physics, quantum chemistry, and materials science, electronic structure is the study of electrons in solid-state and molecular systems. Electronic-structure computation relies on discretizing the many-electron Hamiltonian with a finite single-particle basis set. However, basis-set construction is conventionally treated as an ad hoc preprocessing step. This thesis develops an expressive and flexible framework for active, system-oriented basis-set design and numerical modeling strategies that treat basis functions as tunable representations to encode electronic ground-state information.

We first introduce a multi-layered, differentiable basis-construction framework that embeds a set of primitive parameters into mixed-contracted Gaussian-type orbitals. We then develop …

Quantum Mechanics As A Framework For Data Assimilation And Its Application To Atmospheric Parameterization, David Freeman

Dartmouth College Ph.D Dissertations

Quantum mechanics, as a mathematical system, can be understood as a generalization of classical probability theory. Quantum Mechanical Data Assimilation (QMDA) is a method in which classical dynamical systems are embedded into a quantum mechanical setting, with an associated data assimilation scheme leveraging the operator algebraic setting. In this dissertation, the algebraic structure underlying the operator theoretic formulation of QMDA is discussed. A procedure for closure of dynamical systems based on QMDA, known as Quantum Mechanical Closure (QMCl), is then constructed, and the procedures for constructing the quantum embeddings and implementing QMCl in practice are laid out and implemented for …

Entanglement-Assisted Metrology Under Spatiotemporally Correlated Quantum Noise, Francisco U. Riberi

Dartmouth College Ph.D Dissertations

Quantum sensors operating at the microscale are an emerging branch of quantum technologies where tangible experimental successes have already been reported. State-of-the-art atomic interferometers allow to measure and estimate a variety of physical parameters with unprecedented precision. In principle, exploiting the full power of quantum mechanics would lead to quantitatively better performance bounds over the best possible classical strategies under the same given set of resource constraints. However, the quantum systems' fragility to external disturbances has so far hindered most of these gains to be reached in practice, particularly in the limit of large probe number $N$. Parallel, {\em purely …

Explorations Of Amplified Feedback In Quantum Circuits, Maxwell B. Weiner

Dartmouth College Master’s Theses

The Josephson Traveling Wave Parametric Amplifier (TWPA) has emerged as a key technology for high-fidelity qubit readout in superconducting quantum computing. By leveraging the nonlinear inductance of an array of Josephson Junctions, the TWPA enables broadband, near-quantum-limited amplification with minimal added noise, significantly improving the signal-to-noise ratio in qubit measurements. Unlike traditional resonant parametric amplifiers, which suffer from bandwidth constraints, the traveling wave design of the TWPA allows for wideband operation, making it particularly suited for multiplexed readout of both simple qubits and large-scale quantum processors.

In this thesis, we explore how the TWPA can be integrated into a feedback …

Quantum Control And Simulation Using Hamiltonian Engineering In Solid-State Nmr, Linta Joseph

Dartmouth College Ph.D Dissertations

Lattices of dipolar coupled nuclear spins in natural crystals are large, interacting quantum systems -- ideal platforms to simulate non-equilibrium many-body dynamics. Using the magnetic resonance toolkit, which includes Dynamic Nuclear Polarization (DNP), Hamiltonian engineering, and multiple-quantum Nuclear Magnetic Resonance (NMR) experiments, we study aspects of coherent control, manipulation, and readout of the complex dynamics of the spin system in NMR quantum simulation.

First, applying Hamiltonian engineering sequences, we control the system evolution. Specifically, we use a combination of numerical simulations and NMR experiments on adamantane to evaluate and compare the performance of several known sequences that aim to suppress …

Design, Characterization, And Simulation Of A 2d Dual-Rail Quantum Processor, Diego Barrutia

Dartmouth College Master’s Theses

Bosonic systems, such as three-dimensional (3D) λ/4 coaxial cavities and two-dimensional (2D) λ/2 coplanar waveguide (CPW) resonators, are quantum harmonic oscillators that encode information in phase space, offering a hardware-efficient route toward quantum error correction and simulation in superconducting circuits. In this thesis, we present the design, characterization, and simulation of a dual-rail processor constructed with a 2D λ/2 coplanar waveguide resonators, demonstrating a percent error between experimental and analytical results within a range of 3.31% - 13.16%. The analytical results exhibit high precision but lower accuracy relative to experimental measurements. By integrating both closed-source and open-source software tools, we …

Thermal Phase Fluctuations In Narrow Superfluid Rings, Parth Sabharwal

Dartmouth College Ph.D Dissertations

Remarkable advances have been made in the past decade in the ability to control superfluids in circuit-like configurations. Especially notable are the improvements in the initialization, stabilization and measurement of the circulation of superfluids in geometries with periodic boundary conditions, such as rings. This has significant implications for applications as rotation sensors, magnetometers, and in the emerging field of atomtronics. As the push towards studying supercurrents in lower dimensions and higher aspect ratios continues, in order to realize idealized experimental conditions and explore unusual quantum phases, phase fluctuations become increasingly pronounced, with the potential to destroy long-range order. In this …

Probing Central Spin Decoherence Dynamics Of Electronic Point Defects In Diamond And Silicon, Ethan Que Williams

Dartmouth College Ph.D Dissertations

Electron spins of point defects in diamond and silicon can exhibit long coherence times, making them attractive platforms for the physical implementation of qubits for quantum sensing and quantum computing. To realize these technologies, it is essential to understand the mechanisms that limit their coherence. Decoherence of these systems is well described by the central spin model, wherein the central electron spin weakly interacts with numerous electron and nuclear spins in its environment. The dynamics of the resultant dephasing can be probed with pulse electron paramagnetic resonance (pEPR) experiments.

Using a 2.5 GHz pEPR spectrometer built in-house, we performed multi-pulse …

Effective Non-Hermiticity And Topology In Markovian Quadratic Bosonic Dynamics, Vincent Paul Flynn

Dartmouth College Ph.D Dissertations

Recently, there has been an explosion of interest in re-imagining many-body quantum phenomena beyond equilibrium. One such effort has extended the symmetry-protected topological (SPT) phase classification of non-interacting fermions to driven and dissipative settings, uncovering novel topological phenomena that are not known to exist in equilibrium which may have wide-ranging applications in quantum science. Similar physics in non-interacting bosonic systems has remained elusive. Even at equilibrium, an "effective non-Hermiticity" intrinsic to bosonic Hamiltonians poses theoretical challenges. While this non-Hermiticity has been acknowledged, its implications have not been explored in-depth. Beyond this dynamical peculiarity, major roadblocks have arisen in the search …

Fermion Encodings And Algorithms For Quantum Simulation, Riley W. Chien

Dartmouth College Ph.D Dissertations

The study of the properties of quantum mechanical systems of many particles occupies a central role in condensed matter physics, high-energy physics, and quantum chemistry. In recent decades, developments in quantum information theory have suggested that quantum computers could become an especially useful tool for studying such quantum systems.

In this thesis, we address the additional challenges for quantum simulations posed by particles which are fermionic in nature, namely those caused by the nonlocal fermionic statistics. In particular, we study the encodings of fermionic degrees of freedom into the qubits of a quantum computer. We focus on finding a scheme …

Machine Learning For Electronic And Atomistic Simulations, Jun Yang

Dartmouth College Ph.D Dissertations

The demand for accurate and efficient atomistic simulations and electronic structure calculations in materials science and quantum chemistry has motivated the development of novel computational methodologies. The rapid evolution of machine learning has brought new techniques for advancing the accuracy, efficiency, and predictive power of atomistic simulations and electronic structure calculations.

In this thesis, we explore the symmetry requirements and physics intuitions needed for developing machine-learning interatomic potentials, which are the most critical component in atomistic simulations. Specifically, we introduce a novel physics-inspired graph neural network interatomic potential that enables accurate and efficient atomistic simulations of complex materials. The machine …

Approaching Quantum-Limited Electrometry In The Single-Photon Regime, Sisira Kanhirathingal

Dartmouth College Ph.D Dissertations

Mesoscopic quantum systems currently serve as essential building blocks in many quantum information and metrology devices. This thesis investigates the potential of quantum-limited detection in a mesoscopic electrometer named the cavity-embedded Cooper pair transistor (cCPT). As one application, this charge detector can act as the basis for an optomechanical system in the single-photon strong coupling regime. The realization of this scheme would entail near quantum-limited, ultra-sensitive electrometry at the single-photon level, the feasibility of which is studied at length in this thesis.

On the one hand, we approach this question using a fundamental, first-principles study, where an operator scattering model …

The Cavity-Embedded Cooper Pair Transistor As A Charge Detector Operating In The Nonlinear Regime, Bhargava Thyagarajan

Dartmouth College Ph.D Dissertations

The cavity-embedded Cooper pair transistor (cCPT) has been shown to be a nearly quantum limited charge detector operating with only a single intracavity photon. Here, we use the inherent Kerr nonlinearity to demonstrate a dispersive charge sensing technique inspired by the Josephson bifurcation amplifier. Operating in the bistable regime close to a bifurcation edge, the cCPT is sensitive to charge shifts of 0.09e in a single-shot readout scheme with a detection time of 3 μs and a detection fidelity of 94%. The readout is implemented with only ∼ 25 intracavity photons in the high oscillation amplitude state, still several orders …

Mermin Inequalities For Perfect Correlations In Many-Qutrit Systems, Jay Lawrence

Dartmouth Scholarship

The existence of Greenberger-Horne-Zeilinger (GHZ) contradictions in many-qutrit systems was a long-standing theoretical question until its (affirmative) resolution in 2013. To enable experimental tests, we derive Mermin inequalities from concurrent observable sets identified in those proofs. These employ a weighted sum of observables, called M, in which every term has the chosen GHZ state as an eigenstate with eigenvalue unity. The quantum prediction for M is then just the number of concurrent observables, and this grows asymptotically as 2N/3 as the number of qutrits N→∞. The maximum classical value falls short for every N≥3, so that the quantum to classical …

Operator Locality In The Quantum Simulation Of Fermionic Models, Vojtěch Havlíček, Matthias Troyer, James D. Whitfield

Dartmouth Scholarship

Simulating fermionic lattice models with qubits requires mapping fermionic degrees of freedom to qubits. The simplest method for this task, the Jordan-Wigner transformation, yields strings of Pauli operators acting on an extensive number of qubits. This overhead can be a hindrance to implementation of qubit-based quantum simulators, especially in the analog context. Here we thus review and analyze alternative fermion-to-qubit mappings, including the two approaches by Bravyi and Kitaev and the Auxiliary Fermion transformation. The Bravyi-Kitaev transform is reformulated in terms of a classical data structure and generalized to achieve a further locality improvement for local fermionic models on a …

Local Spin Operators For Fermion Simulations, James D. Whitfield, Vojtěch Havlíček, Matthias Troyer

Dartmouth Scholarship

Digital quantum simulation of fermionic systems is important in the context of chemistry and physics. Simulating fermionic models on general purpose quantum computers requires imposing a fermionic algebra on qubits. The previously studied Jordan-Wigner and Bravyi-Kitaev transformations are two techniques for accomplishing this task. Here, we reexamine an auxiliary fermion construction which maps fermionic operators to local operators on qubits. The local simulation is performed by relaxing the requirement that the number of qubits should match the number of single-particle states. Instead, auxiliary sites are introduced to enable nonconsecutive fermionic couplings to be simulated with constant low-rank tensor products on …

Exact Solution Of Quadratic Fermionic Hamiltonians For Arbitrary Boundary Conditions, Abhijeet Alase, Emilio Cobanera, Gerardo Ortiz, Lorenza Viola

Dartmouth Scholarship

We present a procedure for exactly diagonalizing finite-range quadratic fermionic Hamiltonians with arbitrary boundary conditions in one of D dimensions, and periodic in the remaining D−1. The key is a Hamiltonian-dependent separation of the bulk from the boundary. By combining information from the two, we identify a matrix function that fully characterizes the solutions, and may be used to construct an efficiently computable indicator of bulk-boundary correspondence. As an illustration, we show how our approach correctly describes the zero-energy Majorana modes of a time-reversal-invariant s-wave two-band superconductor in a Josephson ring configuration, and predicts that a fractional 4π-periodic Josephson effect …

Dynamical Decoupling Sequences For Multi-Qubit Dephasing Suppression And Long-Time Quantum Memory, Gerardo A. Paz-Silva, Seung-Woo Lee, Todd J. Green, Lorenza Viola

Dartmouth Scholarship

We consider a class of multi-qubit dephasing models that combine classical noise sources and linear coupling to a bosonic environment, and are controlled by arbitrary sequences of dynamical decoupling pulses. Building on a general transfer filter-function framework for open-loop control, we provide an exact representation of the controlled dynamics for arbitrary stationary non-Gaussian classical and quantum noise statistics, with analytical expressions emerging when all dephasing sources are Gaussian. This exact characterization is used to establish two main results. First, we construct multi-qubit sequences that ensure maximum high-order error suppression in both the time and frequency domain and that can be …

Superadiabatic Control Of Quantum Operations, Jonathan Vandermause, Chandrasekhar Ramanathan

Dartmouth Scholarship

Adiabatic pulses are used extensively to enable robust control of quantum operations. We introduce an approach to adiabatic control that uses the superadiabatic quality factor as a performance metric to design robust, high-fidelity pulses. This approach permits the systematic design of quantum control schemes to maximize the adiabaticity of a unitary operation in a particular time interval given the available control resources. The interplay between adiabaticity, fidelity, and robustness of the resulting pulses is examined for the case of single-qubit inversion, and superadiabatic pulses are demonstrated to have improved robustness to control errors. A numerical search strategy is developed to …

Effective Microscopic Models For Sympathetic Cooling Of Atomic Gases, Roberto Onofrio, Bala Sundaram

Dartmouth Scholarship

Thermalization of a system in the presence of a heat bath has been the subject of many theoretical investigations especially in the framework of solid-state physics. In this setting, the presence of a large bandwidth for the frequency distribution of the harmonic oscillators schematizing the heat bath is crucial, as emphasized in the Caldeira-Leggett model. By contrast, ultracold gases in atomic traps oscillate at well-defined frequencies and therefore seem to lie outside the Caldeira-Leggett paradigm. We introduce interaction Hamiltonians which allow us to adapt the model to an atomic physics framework. The intrinsic nonlinearity of these models differentiates them from …

Switching Quantum Dynamics For Fast Stabilization, Pierre Scaramuzza, Francesco Ticozzi

Dartmouth Scholarship

Control strategies for dissipative preparation of target quantum states, both pure and mixed, and subspaces are obtained by switching between a set of available semigroup generators. We show that the class of problems of interest can be recast, from a control-theoretic perspective, into a switched-stabilization problem for linear dynamics. This is attained by a suitable affine transformation of the coherence-vector representation. In particular, we propose and compare stabilizing time-based and state-based switching rules for entangled state preparation, showing that the latter not only ensure faster convergence with respect to nonswitching methods, but can be designed so that they retain robustness …

General Transfer-Function Approach To Noise Filtering In Open-Loop Quantum Control, Gerardo A. Paz-Silva, Lorenza Viola

Dartmouth Scholarship

We present a general transfer-function approach to noise filtering in open-loop Hamiltonian engineering protocols for open quantum systems. We show how to identify a computationally tractable set of fundamental filter functions, out of which arbitrary transfer filter functions may be assembled up to arbitrary high order in principle. Besides avoiding the infinite recursive hierarchy of filter functions that arises in general control scenarios, this fundamental filter-functions set suffices to characterize the error suppression capabilities of the control protocol in both the time and frequency domain. We prove that the resulting notion of filtering order reveals conceptually distinct, albeit complementary, …

Robustness Of Composite Pulses To Time-Dependent Control Noise, Chingiz Kabytayev, Todd J. Green, Kaveh Khodjasteh, Michael J. Biercuk, Lorenza Viola, Kenneth R. Brown

Dartmouth Scholarship

We study the performance of composite pulses in the presence of time-varying control noise on a single qubit. These protocols, originally devised only to correct for static, systematic errors, are shown to be robust to time-dependent non-Markovian noise in the control field up to frequencies as high as ∼10% of the Rabi frequency. Our study combines a generalized filter-function approach with asymptotic dc-limit calculations to give a simple analytic framework for error analysis applied to a number of composite-pulse sequences relevant to nuclear magnetic resonance as well as quantum information experiments. Results include examination of recently introduced concatenated composite pulses …

Fundamental Bounds In Measurements For Estimating Quantum States, Hyang-Tag Lim, Young-Sik Ra, Kang-Hee Hong, Seung-Woo Lee, Yoon-Ho Kim

Dartmouth Scholarship

Quantum measurement unavoidably disturbs the state of a quantum system if any information about the system is extracted. Recently, the concept of reversing quantum measurement has been introduced and has attracted much attention. Numerous efforts have thus been devoted to understanding the fundamental relation of the amount of information obtained by measurement to either state disturbance or reversibility. Here, we experimentally prove the trade-off relations in quantum measurement with respect to both state disturbance and reversibility. By demonstrating the quantitative bound of the trade-off relations, we realize an optimal measurement for estimating quantum systems with minimum disturbance and maximum reversibility. …

Signatures Of The Valley Kondo Effect In Si/Sige Quantum Dots, Mingyun Yuan, R. Joynt, Zhen Yang, Chunyang Tang, D. E. Savage, M. G. Lagally, M. A. Eriksson, A. J. Rimberg

Dartmouth Scholarship

We report measurements consistent with the valley Kondo effect in Si/SiGe quantum dots, evidenced by peaks in the conductance versus source-drain voltage that show strong temperature dependence. The Kondo peaks show unusual behavior in a magnetic field that we interpret as arising from the valley degree of freedom. The interplay of valley and Zeeman splittings is suggested by the presence of side peaks, revealing a zero-field valley splitting between 0.28 to 0.34 meV. A zero-bias conductance peak for nonzero magnetic field, a phenomenon consistent with valley nonconservation in tunneling, is observed in two samples.

Quantum Resources For Purification And Cooling: Fundamental Limits And Opportunities, Francesco Ticozzi, Lorenza Viola

Dartmouth Scholarship

Preparing a quantum system in a pure state is ultimately limited by the nature of the system's evolution in the presence of its environment and by the initial state of the environment itself. We show that, when the system and environment are initially uncorrelated and arbitrary joint unitary dynamics is allowed, the system may be purified up to a certain (possibly arbitrarily small) threshold if and only if its environment, either natural or engineered, contains a “virtual subsystem” which has the same dimension and is in a state with the desired purity. Beside providing a unified understanding of quantum purification …

A Cavity-Cooper Pair Transistor Scheme For Investigating Quantum Optomechanics In The Ultra-Strong Coupling Regime, A. J. Rimberg, M. P. Blencowe, A. D. Armour, P. D. Nation

Dartmouth Scholarship

We propose a scheme involving a Cooper pair transistor (CPT) embedded in a superconducting microwave cavity, where the CPT serves as a charge tunable quantum inductor to facilitate ultra-strong coupling between photons in the cavity and a nano- to meso-scale mechanical resonator. The mechanical resonator is capacitively coupled to the CPT, such that mechanical displacements of the resonator cause a shift in the CPT inductance and hence the cavity's resonant frequency. The amplification provided by the CPT is sufficient for the zero point motion of the mechanical resonator alone to cause a significant change in the cavity resonance. Conversely, a …