Other Physics Commons^™

Viscosities, Diffusion Coefficients, And Mixing Times Of Intrinsic Fluorescent Organic Molecules In Brown Limonene Secondary Organic Aerosol And Tests Of The Stokes–Einstein Equation, Dagny A. Ullmann, Mallory L. Hinks, Adrian M. Maclean, Christopher Butenhoff, James W. Grayson, Kelley Barsanti, Jose L. Jimenez, Sergey A. Nizkorodov, Saeid Kamal, Allan K. Bertram

Physics Faculty Publications and Presentations

Viscosities and diffusion rates of organics within secondary organic aerosol (SOA) remain uncertain. Using the bead-mobility technique, we measured viscosities as a function of water activity (a_w) of SOA generated by the ozonolysis of limonene followed by browning by exposure to NH₃ (referred to as brown limonene SOA or brown LSOA). These measurements together with viscosity measurements reported in the literature show that the viscosity of brown LSOA increases by 3–5 orders of magnitude as the aw decreases from 0.9 to approximately 0.05. In addition, we measured diffusion coefficients of intrinsic fluorescent organic molecules within brown …

Pseudocapacitors For Energy Storage, Anuradha Venkataraman

Dissertations and Theses

Fluctuation in the demand for electrical power and the intermittent nature of the supply of energy from renewable sources like solar and wind have made the need for energy storage a dire necessity. Current storage technologies like batteries and supercapacitors fall short either in terms of power output or in their ability to store sufficient energy. Pseudocapacitors combine features of both and offer an alternative to stabilize the power supply. They possess high rates of charge and discharge and are capable of storing much more energy in comparison to a supercapacitor. In the quest for solutions that are economical and …

Bicrystallography In Two Dimensions: A Graphical Procedure And Comparison Of Its Results To Experiments, Andrew M. Maas, Peter Moeck

Student Research Symposium

Three dimensional (3D) bicrystallography describes ideal structures of grain boundaries comprehensively at the atomic level as a function of the five macroscopic and two of the four microscopic parameters [1,2]. Free energy minimization of these structures leads to the real structure of these topologically distinct regions within crystals. These minimizations may either reduce the symmetries of ideal bicrystals or leave them intact. Since the symmetries of physical properties need to be compatible (by the Shubnikov-Curie and Curie-Minnigerode-Neumann principles [3]) with the symmetries of the atomic arrangements from which they arise, bicrystallography allows for predictions about which phenomena can occur in …

Confined Mesoscopic Fluid-Like Films Analyzed With Frequency Modulation And Acoustic Detection, Rodolfo Fernandez Rodriguez

Dissertations and Theses

Complete understanding of the physics underlying the changes in viscoelasticity, relaxation time, and phase transitions that mesoscopic fluid-like systems undergo at solid-liquid interfaces or under confinement remains one of the major challenges in condensed matter physics. Moreover, studies of confined mesoscopic fluid films are relevant to technological areas like adhesion, wetting processes and nanotribology.

This thesis addresses the interaction between two sliding solids interfaces separated by a nanometer sized gap, with emphasis on the role of the mesoscopic fluid film trapped between them. For this purpose we integrated two acoustic techniques, recently introduced by our group, into a sub-nanometer precision …

Crystallographic Image Processing With Unambiguous 2d Bravais Lattice Identification On The Basis Of A Geometric Akaike Information Criterion, Taylor Thomas Bilyeu

Dissertations and Theses

Crystallographic image processing (CIP) is a technique first used to aid in the structure determination of periodic organic complexes imaged with a high-resolution transmission electron microscope (TEM). The technique has subsequently been utilized for TEM images of inorganic crystals, scanning TEM images, and even scanning probe microscope (SPM) images of two-dimensional periodic arrays. We have written software specialized for use on such SPM images. A key step in the CIP process requires that an experimental image be classified as one of only 17 possible mathematical plane symmetry groups. The current methods used for making this symmetry determination are not entirely …

Characterization Of Mesoscopic Fluid Films For Applications In Spm Imaging And Fabrication Of Nanostructures On Responsive Materials, Xiaohua Wang

Dissertations and Theses

This dissertation focuses on characterization of the mesoscopic fluid film, testing its behavior in different application scenarios, including its role in near-field scanning probe microscopy imaging, contribution to the phononic mechanism in nanotribology phenomena, utilizing it as a natural environment in the study of carbohydrate-protein interactions, and harnessing it as bridge to transport ions in the fabrication of nanostructures on responsive polymer materials.

Due to their high resolution and versatile applications in a variety of fields, the family of scanning probe microscopy (SPM) has found widespread acceptance as an analytical and fabrication tool. However, the working mechanism of SPM that …

A 30-Year Record Of The Isotopic Composition Of Atmospheric Methane, Doaa Galal Mohammed Teama

Dissertations and Theses

Methane (CH₄) is one of the most important greenhouse gases after water vapor and carbon dioxide due to its high concentration and global warming potential 25 times than that of CO₂ (based on a 100 year time horizon). Its atmospheric concentration has more than doubled from the preindustrial era due to anthropogenic activities such as rice cultivation, biomass burning, and fossil fuel production. However, the rate of increase of atmospheric CH₄ (or the growth rate) slowed from 1980 until present. The main reason for this trend is a slowdown in the trend of CH₄ sources. …

A Locking-Free Hp Dpg Method For Linear Elasticity With Symmetric Stresses, Jamie Bramwell, Leszek Demkowicz, Jay Gopalakrishnan, Weifeng Qiu

Mathematics and Statistics Faculty Publications and Presentations

We present two new methods for linear elasticity that simultaneously yield stress and displacement approximations of optimal accuracy in both the mesh size h and polynomial degree p. This is achieved within the recently developed discontinuous Petrov- Galerkin (DPG) framework. In this framework, both the stress and the displacement ap- proximations are discontinuous across element interfaces. We study locking-free convergence properties and the interrelationships between the two DPG methods.

Quantum Physics And Welfare Policy?, Jack C. Straton

Physics Faculty Publications and Presentations

Welfare policy is examined through the paradoxical logic of Nagarjuna’s tetralema, providing a lens through which wave-particle duality in quantum mechanics is then viewed. Through this process students are challenged to radically expand their critical-thinking horizons beyond conventional dualistic bounds. They learn not only this key property of quantum reality, but have to come to grips with the nature of knowledge itself, and the degree to which they censor their own awarenesses.

Discharge Suppression System For A Double Focusing, Atmospheric Pressure Ionization Mass Spectrometer, Andrew H. Grange, Robert J. O'Brien, Douglas F. Barofsky

Chemistry Faculty Publications and Presentations

An electrical discharge suppression system for a medium throughput (∼2 l/s) pumping line has been devised that works up to potentials of ±15 kV. This device permits atmospheric pressure ionization sources to be interfaced to high-resolution, magnetic sector mass spectrometers with source potentials of 6-10 kV