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Theses and Dissertations

Uranium dioxide

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Full-Text Articles in Engineering Physics

Electrical Characterization Of Crystalline Uo2, Tho2 And U0.71Th0.29O2, Christina L. Dugan Dec 2018

Electrical Characterization Of Crystalline Uo2, Tho2 And U0.71Th0.29O2, Christina L. Dugan

Theses and Dissertations

Uranium dioxide (UO2), thorium dioxide (ThO2), and UxTh1-xO2 alloys are characterized for suitability in uranium-based neutron detectors. ThO2 was studied for an envisioned UO2/ThO2 heterojunction. A U0.71Th0.29O2 alloy was studied because of its resistance to oxidation and potential use in surface passivation. The U0.71Th0.29O2 effective Debye temperature of 217± 24 K was measured using temperature-dependent x-ray photoemission spectroscopy (XPS). The specific heat capacity for the U0.71Th0.29O2 alloy was calculated from the Debye …


Band Gap Transition Studies Of U:Tho2 Using Cathodoluminescence, Joshua D. Reding Mar 2014

Band Gap Transition Studies Of U:Tho2 Using Cathodoluminescence, Joshua D. Reding

Theses and Dissertations

The Department of Defense has expressed interest in thorium dioxide (ThO2) and uranium dioxide (UO2) as possible candidates for use as special nuclear material in designing neutron detectors. Both materials have large neutron interaction cross sections. Uranium dioxide is particularly attractive due to its semiconducting properties and a relatively small band gap of 2 eV. Both materials fluoresce under ionizing radiation making them candidates for scintillating detectors. Three Ux:Th1-xO2 (x= 0.00, 0.01, 0.22) hydrothermally grown single crystals were examined using cathodoluminescence to interrogate the changing electronic properties of ThO2 as it became an alloy. Both depth-resolved and temperature- dependent cathodoluminescence …